Abstract
Mineral particles could have influenced on the climate of Oviedo, a non-industrial city situated in the centre of an industrial zone of the North of Spain, increasing the temperature and the precipitations, in spite of the fact that “greenhouse gases” concentrations have diminished in this city in recent years. The directive (1999/30/EC) of the European Commission began to be applied in Oviedo in the year 2003. In agreement with this norm, our first aim was the identification of the inorganic particulate matter of the PM10 and PM2.5 fractions sampled in this city. X-ray diffraction and scanning electron microscopy coupled with X-ray dispersive energy spectrometry were used. The percentages of the different mineral phases of the PM were obtained by a Rietveld refinement of powder X-ray diffraction data. The compositions of the PM10 and PM2.5 fractions of this city are similar. Sulphates are the most abundant particles in the both fractions. Most sulphates, nitrates and sal-ammoniac would have formed by reaction between solid, liquid and/or gas particles and they could be associated with the power stations near to the city and traffic. Wüstite and haematites come from the iron and steel industries of Gijón and Avilés. The main natural sources of halite and carbonates and silicates are sea spray and soil resuspension by the wind, respectively.
Similar content being viewed by others
References
Anderson JR, Buseck PR, Patterson TL, Arimoto R (1996) Characterization of the Bermuda tropospheric aerosol by combined individual-particle and bulk-aerosol analysis. Atmos Environ 30:319–338
Andreae MO (1995) Climatic effects of changing atmospheric aerosol levels. In: Henderson-Sellers A (ed) Future climates of the World: a modelling perspective. World survey of climatology, vol 16. Elsevier, Amsterdam, pp 341–392
Andreae MO (1996) Raising dust in the greenhouse. Nature 380:389–390
Aramburu C, Bastida F (eds) (1995) Geología de Asturias. Ediciones Trea, Principado de Asturias
Breed CA, Arocena JM, Sutherland D (2002) Possible sources of PM10 in Prince George (Canada) as revelated by morphology and in situ chemical composition of particulate. Atmos Environ 36:1721–1731
Buseck PR, Pósfai M (1999) Airborne minerals and related aerosol particles: effects on climate and the environment. Proc Nat Acad Sci USA 96:3372–3379
Buseck PR, Jacob DJ, Pósfai M, Li J, Anderson JR (2000) Minerals in the air: an environmental perspective. Int Geol Rev 7:577–594
Connor M (1990) Les aerosoles antropogenes et l’alteration de la pierre. Proyect de Diplome Ecole Politechnyque de Laussane
Davis BL (1980) A study of the errors in X-ray quantitative analysis procedures for aerosols collected on filter media. Atmos Environ 15:291–296
Dentener FJ, Carmichael GR, Zhang Y, Lelieveld J, Crutzen PJ (1996) Role of mineral aerosol as a reactive surface in the global troposphere. J Geophys Res 101:22869–22889
Dockery DW, Pope A (1996) Epidemiology of acute health effects: summary of time-series studies. In: Wilson R, Spengler JD (eds) Particles in our air: concentration and health effects. Harvard University Press, Cambridge, pp 123–147
Donaldson K, MacNee W (1999) The mechanism of lung injury caused by PM10. Air pollution and health. In: Hester RE, Harrison RM (eds) Issue in environmental science and technology. Royal Society of Chemistry, Reedwood Books Ltd., Trowbridge
Duce RA (1995) Sources distributions and fluxes of mineral aerosols and their relationship to climate. In: Charlson RJ, Heintzenberg J (eds) Aerosol forcing of climate. Wiley, New York
Fenger J (1999) Urban air quality. Atmos Environ 33:4877–4900
González Frades L (1891) Resúmenes generales de las observaciones realizadas desde el año 1851 hasta 1890, inclusive, en la estación meteorológica de Oviedo. Establecimiento Tipográfico de Vicente Brid, Oviedo
Guthrie GD Jr, Mossman BT (1993) Merging the geological and biological sciences: an integrated approach to the study of mineral-induced pulmonary diseases. In: Guthrie GD Jr, Mossman BT (eds) Health effects of mineral dusts [Ribbe PH (ed.) Reviews in mineralogy, vol 28, Mineralogical Society of America]
Jones TP, Williamson BJ, Bérubé KA, Richards RJ (2000) Mycroscopy and chemistry of used TEOM filters Swansea 1998–1999. April (Paper presented at the fourth Annual Meeting of the Joint Research Programme on Outdoor and Indoor Air Pollution University of Leicester 12–13th, UK)
Jung CH, Kim YP (2006) Numerical estimation of the effects of condensation and coagulation on visibility using the moment method. J Aerosol Sci 37(2):143–161
Kunzli N, Kaiser R, Medina S, Studnicka M, Chanel O, Filliger P, Herry M, Horak F, Puybonnieux-Texier V, Quenel P, Schneider J, Seethaler R, Vergnaud JC, Sommer H (2000) Public-health impact of outdoor and traffic-related air pollution: a European assessment. Lancet 356(9232):795–801
Larsen S (2002) Air Quality in Europe State and trends 1990–99. European Environment Agency
Li X, Maring H, Savoir D, Voss K, Prospero JM (1996) Dominance of mineral dust in aerosol light-scattering in the North Atlantic trade winds. Nature 380:416–419
Mahowald N, Kohfeld K, Hansson M, Balkansky Y, Harrison SP, Prentice IC, Schulz M, Rodhe H (1999) Dust sources and deposition during the last glacial maximum and current climate: a comparison of model results with paleodata from ice cores and marine sediments. J Geophys Res 104:15895–15916
Mateo González P (1983) Series termométricas de la antigüa estación meteorológica de la Universidad de Oviedo. Instituto Nacional de Meteorología, Ministerio de Transportes, Turismo y Comunicaciones, Publicación A-73, Madrid
Mattsson JO, Nihlev T (1996) The transport of Saharan dust to Southern Europe: a scenario. J Arid Environ 32:111–119
Mészáros E (1999) Fundamentals of atmospheric aerosol chemistry. Akadémiai Kiado
Pope CA, Burnett RT, Thun MJ, Calle EE, Krewski D, Ito K, Thurston GD (2002) Lung cancer, cardio-pulmonary mortality, and long-term exposure to fine particulate air pollution. J Am Med Assoc 287(9):1132–1141
Querol X, Alastuey A, López-Soler A, Mantilla E, Plana F (1996) Mineral composition of atmospheric particulates around a large coal-fired power station. Atmos Environ 30:3557–3572
Rivera-Carpio CA, Corrigan CE, Novakov T, Penner JE, Rogers CF, Chow JC (1996) Derivation of contributions of sulphate and carbonaceous aerosols to cloud condensation nuclei from mass size distributions. J Geophys Res Atmos 101:19483–19493
Rodríguez I (2005) Mineralogía y evaluación ambiental de las partículas atmosféricas de Oviedo y Gijón. Doctoral thesis, University of Oviedo, Spain
Roldán Fernández A (1988) Notas para una Climatología de Oviedo. Instituto Nacional de Meteorología, Ministerio de Transportes, Turismo y Comunicaciones. Publicaciones K-48, Madríd, p 45
Ryall DB, Derwent RG, Manning AJ, Redington AL, Corden J, Millington W, Simmonds PG, O’Doherty SO, Carslaw N, Fuller GW (2002) The origin of high particulate concentrations over United Kingdom March 2000. Atmos Environ 36:1363–1378
Schwartz J, Dochery DW, Neas LM (1996) Is daily mortality associated specifically with fine particles? J Air Waste Manag Assoc 46:927–939
Sokolik IN, Toon OB (1996) Direct radiative forcing by anthropogenic airborne mineral aerosols. Nature 381:681–683
Tegen I, Lacis AA (1996) Modeling of particle size distribution and its influence on the radiative properties of mineral dust aerosol. J Geophys Res 101:19237–19244
Umbría A, Galá M, Muñoz MJ, Martín M (2004) Characterization of atmospheric particles: analysis of particles in the Campo de Gibraltar. Atmosfera, pp 191–206
Wiederkehr P, Yoon SJ (1998) Air quality indicators. In: Fenger J, Hertel O, Palmgren F (eds) Urban air pollution European aspects. Kluwer, Dordrecht
Zhang Y, Carmichael GR (1999) The role of mineral aerosol in troposheric chemistry in East Asia-A model study. J Appl Meteorol 38:353–366
Acknowledgments
We thank to Spanish Ministry of the Environment for the use of the unit mobile equipped with a high volume sampler and to Technical Department of the National Institute of Silicosis, Central Hospital of Oviedo, for the use of the Philips PW 3040/60 “X’pert” equipment.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rodríguez, I., Galí, S. & Marcos, C. Atmospheric inorganic aerosol of a non-industrial city in the centre of an industrial region of the North of Spain, and its possible influence on the climate on a regional scale. Environ Geol 56, 1551–1561 (2009). https://doi.org/10.1007/s00254-008-1253-9
Received:
Accepted:
Published:
Issue date:
DOI: https://doi.org/10.1007/s00254-008-1253-9