Thanks to visit codestin.com
Credit goes to link.springer.com

Skip to main content
Springer Nature Link
Log in

Solvation/desolvation during the redox transformation of poly(3-methylthiophene)

  • Original Paper
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

Solvation/desolvation effects were studied during the redox transformation of poly(3-methylthiophene) by electrochemical quartz crystal microbalance technique. The effect was demonstrated by studying the phenomenon in different solvents, and comparing the results after a solution change. From the data obtained with the same film transferred between nitrobenzene and acetonitrile in both directions, the solvation effect was directly evidenced, and the virtual molar mass of the moving species in and from the same film was determined to illustrate semi-quantitatively the effect of the solvation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
£29.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (United Kingdom)

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

Explore related subjects

Discover the latest articles and news from researchers in related subjects, suggested using machine learning.

References

  1. Brédas JL, Themans B, Fripiat JG, André JM, Chance RR (1984) Phys Rev B 29:6761

    Article  Google Scholar 

  2. Skotheim TA (ed) (1986) Handbook of Conducting Polymers vol 1,2. Marcel Dekker, New York

    Google Scholar 

  3. Chen J, Heeger AJ, Wudl F (1986) Solid State Commun 58:251

    Google Scholar 

  4. Tourillon G, Garnier F (1984) J Electroanal Chem 161:407

    Google Scholar 

  5. Hayashi S, Kaneto S, Yoshino K, Matsushita R, Matsuyama T (1986) J Phys Soc Jpn 55:1971

    Google Scholar 

  6. Sato M, Tanaka S, Kaeriyama K (1986) Synth Met 14:279

    Google Scholar 

  7. Zotti G, Schiavon G (1989) Synth Met 31:347

    Google Scholar 

  8. Inzelt G, Horányi G (1986) J Electroanal Chem 200:405

    Google Scholar 

  9. Inzelt G, Horányi G, Chambers JQ, Day EW (1987) J Electroanal Chem 218:297

    CAS  Google Scholar 

  10. Inzelt G, Horányi G, Chambers JQ (1987) Electrochim Acta 32:757

    CAS  Google Scholar 

  11. Horányi G, Inzelt G (1988) Electrochim Acta 33:947

    Google Scholar 

  12. Hill MG, Penneau J-F, Zinger B, Mann KR, Miller LL (1992) Chem Mater 4:1106

    Google Scholar 

  13. Hong Y, Yu Y, Miller LL (1995) Synth Met 74:133

    Google Scholar 

  14. Tol AJW (1995) Synth Met 74:95

    Google Scholar 

  15. Furukawa Y (1996) J Phys Chem 100:15644

    Google Scholar 

  16. Vorotyntsev MA, Vieil E, Heinze J (1998) J Electroanal Chem 450:121

    Google Scholar 

  17. Barbero C, Miras MC, Haas O, Kötz R (1991) J Electrochem Soc 138:669

    Google Scholar 

  18. Matenzio T, Vieil E (1991) Synth Met 44:349

    Google Scholar 

  19. Skompska M, Szkurlat A, Kowal A, Szklarczyk M (2003) Langmuir 19:2318

    Google Scholar 

  20. Hillman AR, Swann MJ, Bruckenstein S (1990) J Electroanal Chem 291:147

    Google Scholar 

  21. Inzelt G (1990) J Electroanal Chem 287:171

    CAS  Google Scholar 

  22. Hillman AR, Bruckenstein S (1993) J Chem Soc Faraday Trans 89:339

    Google Scholar 

  23. Bruckenstein S, Brezinska K, Hillman AR (2000) PCCP 2:1221

    Google Scholar 

  24. Kriván E, Visy C, Kankare J (2004) Electrochim Acta 50:1247

    Google Scholar 

  25. Kriván E, Visy C, Kankare J (2003) J Phys Chem B 107:1302

    Google Scholar 

  26. Visy C, Kankare J (2000) Electrochim Acta 45:45

    Google Scholar 

  27. Skompska M, Jackson A, Hillman AR (2000) PCCP 2:4748

    Google Scholar 

  28. Abrantes LM, Correira JP (1999) Electrochim Acta 44:1901

    Google Scholar 

  29. C Visy, J Kankare, E Kriván (2000) Electrochim Acta 45:3851

    Google Scholar 

  30. Tamm T, Johanson U, Marandi M, Tamm J (2004) 55th ISE meeting, book of abstracts, II p 989

Download references

Acknowledgements

This work was supported by the Hungarian National Research Fund (OTKA no.T 42539).

Author information

Authors and Affiliations

  1. Institute of Physical Chemistry, University of Szeged, Hungary

    Csaba Visy, Csaba Janáky & Emese Kriván

Authors
  1. Csaba Visy
    View author publications

    Search author on:PubMed Google Scholar

  2. Csaba Janáky
    View author publications

    Search author on:PubMed Google Scholar

  3. Emese Kriván
    View author publications

    Search author on:PubMed Google Scholar

Corresponding author

Correspondence to Csaba Visy.

Additional information

This paper is dedicated to Professor G. Horányi on the occasion of his 70th birthday and in recognition of his outstanding contribution of electrochemistry

Csaba Visy, Emese Kriván are ISE members

Rights and permissions

Reprints and permissions

About this article

Cite this article

Visy, C., Janáky, C. & Kriván, E. Solvation/desolvation during the redox transformation of poly(3-methylthiophene). J Solid State Electrochem 9, 330–336 (2005). https://doi.org/10.1007/s10008-005-0661-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-005-0661-y

Keywords