IITJEE 2011 Paper 2 Solutions
IITJEE 2011 Paper 2 Solutions
PART-1- CHEMISTRY
SECTION-1 (TOTAL MARKS: 24)
(SINGLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has four choices (a), (b), (c) and (d) out of
which ONLY ONE is correct.
1.
1.
(b)
2.
(c) an ether
(d) an ester
product is an acetal
(a) A ketohexose
(c) An D furanose
(b) An aldohexose
d) An D Pyranose
2.
(b)
3.
Oxidation states of the metal in the minerals haematite and magnetite, respectively, are
(a) I,III in haematite and III in magnetite
(b) II,III in haematite and II in magnetite
(c) II in haematite and II, III in magnetite
(d) III in haematite and II, III in magnetite
3.
(d)
4.
and Zn H 2 O 6 NO3
(c)
(c) L,M,O,P
1
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(d) L,M,N,O
5.
5.
(a)
6.
Eo
1.67V
Fe 2 10 3 M, P O 2
0.1 atm and pH = 3, the cell potential at 25o C is
(a) 1.47 V
(b) 1.77 V
(c) 1.87 V
(d) 1.57 V
At
6.
(d)
1.67
.06
2
7.
log Fe
2
2
O2 H
.06
log
4
H2O
1.55V
1.86K kg mol1 is
(b) 5.7 u 10 2
1.86 u 0.1u 20 u 4 / 329
(c) 5.7 u 10 3
(d) 1.2 u 10 2
2.3 u10 2
7.
(a)
8.
Amongst the compound given, the one that would form a brilliant colored dye on treatment with
NaNO2 in dil. HCl followed by addition to an alkaline solution of E naphthol is
8.
(c)
2
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9.
(abc)
693
t1/ 2
2.4
?
?
10.
2.3
100
log
8 u t1/ 2
At
log
100
At
100 / 250
0.4
99.6%
The correct functional group X and the reagent / reaction conditions Y in the following scheme are
(a) X COOCH 3 , Y H 2 / Ni / heat
(b) X CONH 2 , Y H 2 / Ni / heat
(c) X
CONH 2 , Y
Br2 / NaOH
(d) X
CN, Y
10.
11.
The equilibrium
2Cu I Cu o Cu II
In aqueous medium at 25o C shifts towards the left in the presence of
(a) NO3
(b) Cl
(c) SCN
H 2 / Ni / heat
(d) CN
Cl ,SCN and CN form insoluble compound of CuCl, CuSCN and CuCN which
drags the equilibrium reaction in backward direction.
11.
(bcd)
12.
12.
(ad)
3
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Among the following, the number of compounds that can react with PCl5 to give POCl3 is
O 2 .CO 2 ,SO 2 , H 2 O, H 2SO 4 , P4 O10
13.
(4)
14.
14.
(7)
Cl
Cl
Ag Cu
2
1.6 u1010 10 6 | 10 6
? Cl 10 3
? Ag 1.6 u107
?x
15.
15.
(8)
16.
The total number of contributing structures showing hyperconjugation (involving C-H bonds) for
the following carbocation is
16.
(6)
4
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17.
The maximum number of isomers (including stereoisomers) that are possible on monochlorination
of the following compound, is
17.
(8)
The volume (in mL) of 0.1M AgNO3 required for complete precipitation of chloride ions present
in 30mL of 0.01 M solution of Cr H 2 O 5 Cl Cl2 as silver chloride is close to
18.
(6)
30 u 0.01u 2 0.1u V
? V 6 ml
5
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CO 2 s o CO 2 g
(p)
Phase transition
(b)
CaCO3 s o CaO s CO 2 g
(q)
Allotropic change
(c)
2Hx o H 2 g
(r)
'H is
(s)
'S is positive
(t)
'S is negetive
(d)
a o (p, r,s)
19.
20.
b o (r,s)
positive
c o (t) d o (q, r)
Match the reactions in Column I with appropriate types of steps/ reactive intermediate involved in
these reactions as given in Column II.
Column- I
Column- II
(a)
(p)
Nucleopphilic substitution
(b)
(q)
Electrophilic substitution
(c)
(r)
Dehydration
(d)
(s)
Nucleophilic addition
Carbanion
(t)
20.
a o (r,s, t)
b o (s, p)
c o (s, r)
d q, r
6
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PHYSICS PAPER-II
PART II-PHYSICS
SECTION I (TOTAL MARKS: 24)
(SINGLE CORRECT CHOICE TYPE)
This Section contains 8 multiple choice questions. Each question ha four choice (a),(b),(c) and (d) out of
which ONLY ONE is correct.
21.
The density of a solid ball is to be determined in an experiment. The diameter of the ball is
measured with a screw gauge, whose pitch is 0.5mm and there are 50divisions on the circular
sacle. The reading on the main scale is 2.5mm and that on the circular scale is 20 divisions. If the
measured mass of the ball has relative error of 2%, the relative percentage error in the density is
(a) 0.9%
(b) 2.4%
(c) 3.1%
(d) 4.2%
21.
(c)
LC = (0.5/50)=102mm
Reading = 2.5 + 20 u 102 = 2.7 mm
m
U
'U / U 'm / m 3. 'd / d
3
4 d
S
3 2
2 3 u 10 2 / 2.7 u 100
22.
3.1%
A wooden block performs SHM on a frictionless surface with frequency, Q 0 . The block carries a
JG
charge +Q on its surface. If now a uniform electric filed E is switched-on as shown, the SHM of
the block will be:
(a)
7
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23.
A light ray travelling in glass medium is incident on glass-air interface at an angle of incidence T .
The reflected (R) and transmitted (T) intensities, both as function of T , are plotted. The correct
sketch is
23.
(c)
for 0 T TC
T!R
& T t TC
Also T o 0
T 0, R 100%
T 100%, R ! 0%
24.
A satellite is moving with a constant speed V in a circular orbit about the earth. An object of
mass m is ejected from the satellite such that it just escapes from the gravitational pull of the
earth. At the time of its ejection, the kinetic energy of the object is
(a) (1 / 2)mV 2
(b) mV 2
(c) 3 / 2 mV 2
(d) 2mV 2
24.
(b)
mV 2 / r
GmM e / r 2 r
GM e / V 2
2
2
1 / 2 Mu
mV
K.E
8
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25.
25.
A long insulated copped wire is closely wound as a spiral of N turns. The spiral has inner radius
a and out radius b. The spiral lies in the X-Y plane and a steady current l flows through the
wire. The Z-component of the magnetic filed at the centre of the spiral is:
(a)
P 0 Nl
b
ln
2 ba
a
(b)
P 0 Nl
ba
ln
2 ba
ba
(c)
P 0 Nl b
ln
2b
a
(d)
P0 Nl b a
ln
2b
ba
(a)
26.
26.
Bsin Zt I brings the mass to a complete rest. The values of B and I are
(a)
2 A, 3S / 4
(b) A, 4S / 3
(c)
3 A, 5S / 6
(d) A, S / 3
(b)
x1 x 2
A sin Zt A sin Zt 2S / 3
A 1 / 2 sin Zt 3 / 2 cos Zt
Now x1 x 2 x 3 0
A sin Zt S / 3
A sin Zt S / 3 Bsin Zt I
B A
& I 4 S/3
9
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27.
Which of the filed patterns given below is valid for electric field as well as for magnetic field?
27.
(c)
28.
A ball of mass 0.2kg rests on a vertical post of height 5m. A bullet of mass 0.01kg, travelling with
a velocity Vms 1 in a horizontal direction, hits the centre of the ball. After the collision, the ball
and bullet travel independently. The ball hits the ground at a distance of 20 m and the bullet ay a
distance of 100m from the foot of the post. The initial velocity V of the bullet is :
(a) 250ms 1
(b) 250 2 ms 1
(c) 400ms 1
10
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(d) 500ms 1
28.
(d)
2h / g
? Vbullet
Vball
1sec
100 /1
20 / 1
100ms 1
20ms 1
500ms 1
11
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29.
(cd)
For point charge, flux for a sphere if point charge is placed at the centre
1
u 4 Sr 2
[According to question]
4SH0 r 2.5
z q / H0
So Gauss law is not valid.
Electric field due to a dipole is not radially symmetric.
So Gauss law application does not give field distribution.
For electric field to be zero, directions of electric field must be opposite and equal in
magnitude. This occurs only if sign of both the charges is same.
W
UB UA
WAext.agent
elc.field
VB VA
oB
q 1
q 1
30.
A thin ring of mass 2kg and radius 0.5m is rolling without slipping on a horizontal plane with
velocity 1ms 1 . A small ball of mass 0.1kg moving with velocity 20ms 1 in the opposite direction,
hits the ring at a height of 0.75m and goes vertically up with velocity 10ms 1 . Immediately after
the collision.
12
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30.
(ac)
2VCoM ring
A series R-C circuit is connected to AC voltage source. Consider two cases; (a) when C is without
a dielectric medium and b when C is filled with dielectric of constant 4. The current IR of the
following is/are true ?
(a) I A R ! IB R
(b) I A R I B R
(c) V A C ! V BC
(d) V A C V BC
31.
(bc)
1
R2
ZC
R2
So ZB ZA
1
kZc
So, IB R ! IA R
Two solid spheres A and B of equal volumes but of different densities d A and d B are connected by
a string. They are fully immersed in a fluid of density dF. They get arranged into an equilibrium
state as shown in the figure with a tension in the string. The arrangement is possible only if
(a) d A d F
32.
(abd)
(b) d B ! d F
(c) d A ! d F
(d) d A d B
Vg d B d F
dB dA
13
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2d F
A train is moving along a straight line with a constant acceleration a. A body standing in the
train throws a ball forward with a speed of 10ms 1 , at an angle of 60o to the horizontal. The boy
has to move forward by 1.15m inside the train to catch the ball back at the initial height. The
acceleration of the train, in ms 2 is
33.
(5)
Let u be the speed of the train at the time when by throws the ball.
Time of flight t f 2 u10 sin 60o / g
3 sec
Strain ut f 1 / 2 at f2
Sball
ut f 10cos 60o t f
Sball Strain
3u 5 3 3u 3 / 2 a 1.15
1.15
a
5 ms 2
34.
Two batteries of different emfs and different internal resistances are connected as shown. The
voltage across AB in volts is
34.
(5)
V 6 & i2
Also i1 i 2
? V = 5V
V 3 / 2
..(ii)
14
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35.
Water (with refractive index = (4/3)) in a tank is 18 cm deep. Oil of refractive index (7/4) lies on
water making a convex surface of radius of curvature R = 6cm as shown. Consider oil to act as
thin lens. An object S is place 24 cm above water surface. The location of its image is at x cm
above the bottom of the tank. Then x is
35.
(2)
P1 1 / R
1/ 24 7 / 4 / v1 7 / 4 1 / 6 v1
Refraction at water surface: u 2 21cm
? 1/ 21 4 / 3 / 7 / 4 1 / v 2
0
v 2 16 cm (from water surface) ? x 18 16
21cm
2cm
36.
A silver sphere of radius 1 cm and work function 4.7 eV is suspended from an insulating thread in
free space. It is under continuous illumination of 200 nm wavelength light. As photoelectrons
are emitted, the sphere gets charged and acquires a potential. The maximum number of
photoelectrons emitted from the sphere is A u 10z (where 1 < A< 10). The value of Z is
36.
(7)
KE
max
E incident W
15 / 14.4 u 107
37.
37.
(4)
Z2
R 2 u X C2
R2 / 4
RC
R 2 1.25
2
R 2 1 / ZC
1 / 500C 2 RC
1 / 250 s 4 ms
4 / 500 2
15
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38.
A block of mass 0.18 kg is attached to a spring of force constant 2 Nm-1. The coefficient of
friction between the block and the floor is 0.1. Initially the block is at rest and the spring is un
stretched. An impulse is given to the block as shown in the figure. The block slides a distance of
0.06 m and comes to rest for the first time. The initial velocity of the block in ms-1 is V = N/10.
Then N is
38.
(4)
1 / 2 mV 2
1 / 2 Kx 2 fx
1/ 2 u 18 u102 V 2
V2
1 / 2 u 2 u 6 u 102
144 / 900 N / 10
12 / 30 N
16
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One mole of a monatomic ideal gas is taken through a cycle ABCDA as shown in the P V
diagram. Column II gives the characteristics involved in the cycle. Match them with each of the
processes given in Column I.
(a)
(b)
(c)
(d)
39.
Column I
Process A o B
Process B o C
Process C o D
Process D o A
Column II
Internal energy decreases
Internal energy increases
Heat is lost.
Heated is gained
Work is done on the gas.
(p)
(q)
(r)
(s)
(t)
(a) o (p, r, t); (b) o (p, r); (c) o (q, s); (d) o (r, t)
A o B: o IBC T p as well as V( p )
internal energy ( p ) as well as work is done on the gas.
also, ' Q = nCP. ' T: (-ve) (p, r, t ) is correct.
B o C : o ICC 'W 0, 'T : ve internal energy decreases.
also, 'Q
nCV 'T : ve
(p,r) is correct.
C o D : o IBE, V n
work done by the gas. also T ( n ) internal energy increases.
also, 'Q nCP 'T : ve q,s is correct.
D o A : o TA
We have, 'Q
TD 'T
'W 'U;
'U=0 V p
'Q
ve 0
ve
r, t is correct
17
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40.
40.
Column I shows four system, each of the same length L, for producing standing waves. The
lowest possible natural frequency of a system is called its fundamental frequency, whose
wavelength is denoted as O1 . Match each system with statements given in Column II describing
the nature and wavelength of the standing waves.
(A)
Column I
Pipe closed at one end
(p)
Column II
Longitudinal waves
(B)
(q)
Transverse waves
(C)
(r)
Of
(D)
(s)
Of
2L
(t)
Of
4L
L Of
4L p, t is correct
L Of
2L p,s is correct
L Of
2L q,s is correct
L Of
18
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L q, r
MATHEMATICS PAPER II
PART III MATHEMATICS
SECTION I (TOTAL MARKS: 24)
(SINGLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has four choices (a), (b), (c) and (d) out of
which ONLY ONE is correct.
41.
Let f(x) = x2 and g(x) = sin x for all x R. Then the set of all x satisfying ( f o g o g o g ) (x) = (g
o g o f) (x), where (f o g) (x) = f (g (x)) , is
(a) r nS , n 0,1, 2,.......
(b) r nS , n 1, 2,........
(c) S 2 2nS , n ......, 2, 1, 0,1, 2........
41.
(a)
(f o g o g o f ) (x) = ( g o g o f) (x)
sin sin x 2
0 or 1
r nS , n 0,1, 2......
42.
Let (x, y) be any point on the parabola y 2 4x . Let P be the point that divides the line segment
from (0, 0) to (x, y) in the ratio 1 : 3. Then the locus of P is
(a) x 2 y
(b) y 2 2x
(c) y 2 x
(d) x 2 2y
42.
(c)
y=2 x
43.
2k k 2
x 2 y2
1 . If the normal at the point P intersects the x
a 2 b2
axis at (9, 0), then the eccentricity of the hyperbola is
(a)
43.
(b)
(b)
52
(c)
32
6 6 b2 a 2
1 b2 a 2
3/ 2 e
9 b2 a2
1/ 2
3/ 2
19
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(d)
44.
45.
45.
Let Z z 1
1 a
Z 1
Z2 Z
(a)
3 ? b
(d)
i 3
be a cube root of unity and S be the set of all non singular matrices of the form
b
c , where each of a, b and c is either Z or Z2 . Then the number of distinct matrices in
1
the set S is
(a) 2
45.
(c) i 5
(b) 6
Z
Z2
1 c z0
Z 1
(c) 4
(d) 8
1 a c Z acZ2 z 0 ? a c z 1 ac z 1
Clearly a = Z or Z2 or c = Z or Z2
but c z Z2 as it makes the determinant zero.
also a z Z2
? a Z, b Z2 or Z, c Z
? No of such matrices = 2
46.
The circle passing through the point (-1, 0) and touching the y axis at (0, 2) also passes through
the point
(a) (-3/2, 0)
(b) (-5/2,2)
(c) (-3/2, 5/2)
(d) (-4, 0)
46.
(d)
'
47.
47.
Let C be (h, 2)
Equation of circle:
circle passes through (-1, 0) , h = -5/2
Equation of circle will be (x + (5/2))2 + (y 2) 2 = 25/4
Only (-4, 0) satisfies
If Lim 1 x ln 1 b 2
x o0
(a) r S 4
(d)
1 b2
1x
(c) rS / 6
2bsin 2 T b2 2bsin 2 T 1 0
2sin 2 T r 4sin 4 T 4
= sin 2 T r cos 2 T 1 sin 2 T
2
For b to be real, cos T 0 T r S 2
b
20
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(d) rS / 2
48.
Let f: 1, 2 o 0, f be a continuous function such that f(x) = f( 1 x) for all x 1, 2 . Let
2
R1
xf
x dx , and R2 be the area of the region bounded by y = f(x), x = -1, x = 2, and the x
1
axis. Then
(a) R 1 2R 2
(b) R 1
3R 2
(c) 2R 1
R 2 R 1 2R 1
R2
R2
48.
(c)
R1
1 x f 1 x dx
1
21
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(d) 3R 1
R2
49.
50.
50.
(c, d)
f' x
b2 1
1 bx
bx
, where b is a constant such that 0 < b < 1. Then
1 bx
1
(b) f z f 1 on (0,1) and f(b) =
f' 0
1
f' 0
0 x 0,1 as b 0,1
Also, f(x) is continuous for all x 0,1 as domain of definition is R 1 / b where 1/b
> 1. Hence, f(x) is strictly decreasing, so invertible.
bx
yb
bx
f x
y
x
f 1 x
f x
1 bx
yb 1
1 bx
1
and f ' 0 b 2 1
b 1
Since , f ' x exist for all x 0,1 f 1 is differentiable for all x 0,1
f' b
51.
Let E and F be two independent events. The probability that exactly one of them occurs is 11/25
and the probability of none of them occurring is 2/25. If P(T) denotes the probability of occurrence
of the event T, then
(a) P E, 4 / 5 , P F 3 / 5
(b) P E 1 / 5, P F 2 / 5
(c) P E
51.
(a, d)
2 / 5, P F
1/ 5
(d) P E
P E F + P E F = 11/25, P E F
Let P(E) = x, P(F) = y ? P E P F
Also P E P F P E P F
3 / 5, P F
4/5
2 / 25
2 / 25 1 x 1 y
2 / 25
11 / 25 x 1 y 1 x y 11 / 25
22
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52.
S
S
x , x d
2
2
x 1, 0 < x d 1
Inx, x > 1
52.
S
S
x , x d
2
2
x 1, 0 < x d 1
Inx, x > 1
Continuity at x = S / 2
L.H.L = R.H.L = f S / 2
1, x d - 2
? f ' x sin x, - x d 0
2
1, 0 < x d 1
1/ x, x > 1
23
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53.
iS
a bZ cZ
53.
(3)
x y z
a b c
x y z
is
xx c yy c zz c
= (a + b+ c)
a c bc cc a bZ cZ2
2
= 3 a b c
54.
54.
(0)
a c b c Z2 cc Z a bZ2 cZ a c bc Z cc Z2
x y z
a b c
g x g' x , y 0
df x
and g(x) is a
dx
given non constant differentiable function on R with g(0) = g(2) = 0. Then the value of y(2) is
y' x y x g ' x
g x g' x
x g ' x eg x dx y x e g x
0 and g 0
g x 1 e
g x
eg x g x 1 c
0 c=1
y 2
g 2 1 eg 2
M 1 2 , M 1 1 and M 1 1
0 3
0 1
1 12
Then the sum of the diagonal entries of M is
24
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55.
(9)
x1
x4
x
7
x2
x5
x8
x3
x6
x 9
0 1
M 1 2 x 2 1, x 5 2, x 8 3
0 3
1 1
M 1 1 x1 x 2 1, x 4 x 5 1, x 7 x 8
0 1
x1 0, x 4 3, x 7 2
1
0
M 1 M 0 x1 x 2 x 3
1
12
x 3 1, x 6 5, x 9 7
?M
56.
0 1 1
3 2 5
2 3 7
0; x 4 x 5 x 6
1
0, x 7 x 8 x 9
12
The straight line 2x 3y = 1 divides the circular region x 2 y2 d 6 into two parts. If
3 5 3 1 1 1 1
2, , , , , , , *
4 2 4 4 4 8 4
Then the number of point (s) in S lying inside the smaller part is
S
1
1 5 3
2x 3y = 1 meets co ordinate axes at , 0 & 0, , lies outside the circle
2
3 2 4
hence ruled out.
3
For, x 2, y
: 2x 3y 1 ! 0
4
1
1
,y
For, x
: 2x 3y 1 ! 0
4
4
1
1
For, x
,y
: 2x 3y 1 < 0
8
4
3 1 1
2, & , are the only two points
4 4 4
56.
(2)
57.
G
G
b = -i + j and cG i 2j 3k be three given vectors. If Gr is a vector such that
Let a i k,
G G G G
G G
G G
r u b c u b and r a 0 , then the value of r b 0 is
25
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G G G
G G G
r c u b 0 r c Ob 1 O j 2 O j 3k
G
GG
If r xi yj zk , then r.a 0 x z 0 x z
Also, x 1 O, y = 2 + O, z = 3 -3 = 1-O O = 4
G
G G
? r 3j 6j 3k
? r b 3 6 9
57.
(9)
58.
58.
(2)
Let us assume that all four roots are real and distinct
Hence, f(x) = 0 must have 3 distinct real roots and
f " x 0 must have 2 distinct real roots, but that is not true as
f cc x
12 x 2 2x 2 with D < 0
26
Quest Tutorials
H-108, New Asiatic Building, Connaught place, New Delhi 110001
59.
Match the statements given in Column I with the values given in Column II
(A)
Column I
G
G
b j 3k and
If a j 3k,
G
c 2 3k from a triangle, then the
(p)
Column II
S
6
If
f x 3x dx
a 2 b2 , then
(q)
2S
3
S
the value of f is
6
(C)
S2 6
The value of
sec Sx dx is
ln 3 7
(r)
S
3
(D)
(r)
(t)
S
2
59.
A o q , B o p , C o s , D o t
G
G
For (A): Since, side lengths are 2, 2, 2 3 , hence angle between a and b is
4 4 12
cos T
1/ 2 T 2S / 3
2 2 2
b
1 2
For (B) : f x dx
b a2 f x x f S / 6 S / 6
2
a
For (C) :
S
ln sec Sx tan Sx
ln 3
For (D) : z
eiT ,
1
1 z
sin T
1
? arg
1 z 1 cos T
S
1
ln 3 ln
ln 3
3
1 cos T i sin T
5/6
7 /6
1 cos T sin 2 T
f T , which is maximum when T
S 2
27
Quest Tutorials
H-108, New Asiatic Building, Connaught place, New Delhi 110001
60.
Match the statements given in Column I with the intervals/ union of intervals given in Column II
(A)
(B)
(C)
Column I
The set
2iz
: z is complex number, z 1, z z r1
Re
2
1 z
1 3
1
tan T
1
If f T
tan T
1
tan T , then the set
1
(D)
60.
tan T
2ie iT
Re
2iT
1 e
B o t Since, 1 d
Column II
f, 1 1, f
(q)
f, 0 0, f
(r)
2, f
(s)
f, 1 1, f
(t)
f, 0 2, f
f T : 0 d T is
2
3/ 2
3x 10 , x t 0 , then f(x) is
If f x x
increasing in
2iz
A o s Let k = Re
2
1 z
(p)
2i cos T i sin T
Re
2
2sin T 2i sin T cos T
1
sin
T
f, 1 1, f
8 3x 2
1 32x 2
d1
8.3x
d1
9 32 x
Put y 3x
1 d
1 d
8y
d1
9 y2
? 1 d
y 9 y 1
8y
t0
2
9y
y3 y3
y 9
y3
t0
y 3 and y t 9
x f,1 [2, f)
and
y 9 y 1
y 1
8y
d1
t0
t0
9 y2
y3 y3
y3
y d 1 and y ! 3
28
Quest Tutorials
H-108, New Asiatic Building, Connaught place, New Delhi 110001
x (f, 0] 2, f
? The common solution is x (f, 0] 2, f .
C o r
1
Since, f T
tan T
tan T
1
tan T
1
tan T
1
2sec 2 T ? f T [2, f )
D o r Let f(x) = x 3/ 2 3x 10
f' x
3 / 2 x1/2 3x 10 x 3/ 2 u 3
For increasing,
? f' x t0
3 x 3x / 2 5 x t 0
3 x 5x 10 t 0 x t 2
29
Quest Tutorials
H-108, New Asiatic Building, Connaught place, New Delhi 110001