Thermodynamic System
Basic Thermodynamic Terminology
Dr. Md. Zahurul Haq
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A thermodynamic system is simply any object, quantity of matter,
or region of space that has been selected for thermodynamic
study. Everything that is not part of the system is referred to as
the surroundings.
Boundary or control surface (CS) separates the system from its
surroundings which
Professor
Department of Mechanical Engineering
Bangladesh University of Engineering & Technology (BUET)
Dhaka-1000, Bangladesh
[email protected]
http://teacher.buet.ac.bd/zahurul/
may be real or imaginary, at rest or in motion
may change its shape and size
neither contains matter nor occupies volume
has zero thickness and a property value at a point on the boundary
is shared by both the system and its surroundings.
ME 6101: Classical Thermodynamics
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A system defined to contain all of the air in a piston-cylinder device.
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A system defined to contain all of the air that is initially in a tank that
is being filled.
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Control Mass (CM) or Closed System
Control Volume (CV) or Open System
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When there is flow of mass through CS,
the system is called a Control Volume
(CV) or Open system.
In Control Mass (CM) or Closed system, the CS is closed to mass flow,
so that no mass can escape from or enter into the system. Heat & work
may cross the CS, but the system contains the same amount of matter
at all times.
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Adiabatic System
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Classification of Thermodynamic Systems
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An Adiabatic system is one in which the boundary is impermeable to
heat.
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An Isolated system is a special case of CM system that does not
interact in any way with its surroundings.
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Macroscopic & Microscopic Views of Thermodynamics
State & Property
Thermodynamic systems can be studied from two points of view:
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2
The condition of a system at any instant of time is called its state.
State at a given instant determines the properties of the system.
A property is a quantity whose numerical value depends on the
state but not on the history of the system. The origin of
properties include those
Microscopic approach or statistical thermodynamics
Macroscopic approach or classical thermodynamics
The microscopic approach recognizes that the system consists of
matter that is composed of countless, discrete molecules. Statistics
and probability theory are applied to deduce the macroscopic
behaviour or measurable quantities e.g. pressure, temperature etc.
1
2
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directly measurable
defined by laws of thermodynamics
defined by mathematical combinations of other properties.
In the macroscopic approach, the state of the system is described
by a relatively small set of characteristics that are called
properties e.g. mass, temperature, pressure and volume.
Two states are identical if, and only if, the properties of the two
states are identical.
Macroscopic approach works well when the system is sufficiently
large such that it contains many molecules. However, macroscopic
approach would not work well for a system that consists of a
rarefied gas (i.e., a vacuum with just a few molecules).
Intensive properties are independent of the size or extent of the
system. Extensive properties depend on the size or extent of the
system. An extensive property is additive in the sense that its
value for the whole system is the sum of the values for its parts.
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Process & Cycle
System boundary
E1, V1, T, P
Esystem = E1 + E2
Extensive Properties
Vsystem = V1 + V2 }
E2, V2, T, P
Tsystem = T1 = T2
} Intensive Properties
Psystem = P1 = P2
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c Dr. Md. Zahurul Haq
Property
Mass
Volume
KE
PE
Total Energy
Internal Energy
Enthalpy
Entropy
Extensive
m
~
V
1
mV 2
2
mgZ
E
U
H
S
A thermodynamic process is the succession of thermodynamic
states that a system passes through as it goes from an initial state
to a final state.
A system process is said to go through a thermodynamic cycle
when the final state and the initial state of the process are same.
Intensive
v
1 2
V
2
gZ
e
u
h
s
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Thermodynamic Equilibrium
A system in thermodynamic equilibrium satisfies the following
stringent requirements:
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Mechanical Equilibrium: no unbalance forces acting on any part of
the system or the system as a whole.
Thermal Equilibrium: no temperature differences between parts of
the system or between the system and the surrounding.
Chemical Equilibrium: no chemical reactions within the system and
no motion of any chemical species from one part to another part of
the system.
Any property has a fixed value in a give state in a given
equilibrium state, regardless of how the system arrives at the state.
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Categories of Thermodynamics Quantities
A system is said to be in Stable/Equilibrium State when no finite
change of state can occur unless there is an interaction between
the system and its environment which leaves a finite alteration in
the state of the environment.
State functions: all properties are state functions.
Process or Path functions: quantities whose values depend on the
path of the process.
During a quasi-static process, the system is at all times
infinitesimally near a state thermodynamic equilibrium; this
implies that the process should be carried out infinitely slowly to
allow the system to settle to a stable state at the end of each
infinitesimal step in the process.
Theoretical calculations must relate to Stable states, since it is
only for these we have thermodynamic data.
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dy = y2 y1 = y
dy = 0
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State function
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Z Z12 6= Z
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Path function
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Zeroth Law of Thermodynamics
Zeroth Law of Thermodynamics
Two systems with thermal equilibrium with a third are in thermal
equilibrium with each other.
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