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Lembar Perhitungan HMJ 2

This document contains calculations for an experiment analyzing fatty acid content in palm oil through base-catalyzed hydrolysis. It determines: 1) Initial fatty acid concentration in the palm oil. 2) Fatty acid concentration and conversion over time for 3 reaction mixtures with varying molar ratios of oil to aqueous phase. 3) Rate constants for each reaction based on linear regression of the natural log of unconverted fatty acids versus time. The calculated rate constants are 0.111, 0.0864, and 0.0487 for mixtures 1, 2, and 3 respectively.

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Rendy Renaldy Firdaus
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39 views6 pages

Lembar Perhitungan HMJ 2

This document contains calculations for an experiment analyzing fatty acid content in palm oil through base-catalyzed hydrolysis. It determines: 1) Initial fatty acid concentration in the palm oil. 2) Fatty acid concentration and conversion over time for 3 reaction mixtures with varying molar ratios of oil to aqueous phase. 3) Rate constants for each reaction based on linear regression of the natural log of unconverted fatty acids versus time. The calculated rate constants are 0.111, 0.0864, and 0.0487 for mixtures 1, 2, and 3 respectively.

Uploaded by

Rendy Renaldy Firdaus
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Lembar Perhitungan Reagen

1. Perhitungan NaOH 0,125 N 300 ml

gr 1000
x eq
N= BM x V x 98%

gr 1000
x1
0,125 = 40 x 300 x 98%

Gr = 1,53 gram NaOH

2. Densitas Minyak Jarak


M 2M 1
= 25
46,330 gr 21,51 gr
= 25 = 0,9928 g/ml

3. Densitas Katalis (HCl)


M 2M 1
= 25
43,763 gr 15,269 gr
= 25 = 1,13976 g/ml

4. Volume HCl
N x V basis x BM
VHCl = x e x

0,125 N x 0,27 ml x 36,5 gr /mol


VHCl = 25 x 1 x 1,13976 gr /ml

VHCl = 4,3233 ml
5. Perhitungan variabel 1 (Mol mj : Mol aq = 1 : 8)
mj x V mj aq x V aq 1
( ) : ( ) =
BM BM 8
0,9928 gr /ml x V mj 1 x V aq 1
( ) : ( ) =
1067 18 8

( 9,3046 x 104 ) Vmj 1


0,055Vaq = 8

Vmj = 7,3888 Vaq

VBasis = Vmj + Vaq + Vemulsifier + VHCl


270 = Vmj + Vaq + 15 + 4,3233
Vmj + Vaq = 250,6767
7,3888 Vaq + Vaq = 250,6767
Vaq = 29,8016 ml
Vmj = 220 ml
6. Perhitungan variabel 2 (Mol mj : Mol aq = 1 : 9)
( 9,3046 x 104 ) Vmj 1
0,055Vaq = 9

Vmj = 6,5678 Vaq


Vmj + Vaq = 250,6767
(7,3888+1) Vaq = 250,6767
Vaq = 33,124 ml
Vmj = 217,55 ml
7. Perhitungan variabel 3 (Mol mj : Mol aq = 1 : 10)
( 9,3046 x 104 ) Vmj 1
0,055Vaq = 10

Vmj = 5,911 Vaq


Vmj + Vaq = 250,6767
(5,911+1) Vaq = 250,6767
Vaq = 36,27 ml
Vmj = 214,4067 ml
LEMBAR PERHITUNGAN

1. Analisis Kadar Asam Lemak dalam Minyak

( VxN ) NaOH x BM
x 100
% kadar asam lemak = ( x V ) MJ

( 9,3 ml x 0,125 N ) x 1067 g /mol


x 100
gr
=
(
0,9928
ml
x 10 ml )
= 12,5 %

% gliserida = 100% - %kadar asam lemak

= 100% - 12,5% = 87,5%

2. Perhitungan Asam Lemak Awal

( V x N ) NaOH 9,3 ml x 0,125 N


CAo Asam lemak = ( x V ) MJ = 0,9928 gr /ml x 10 ml
mol asam lemak
= 0,117 /gr mj
gliserida
Gliserida = %asam lemak x CAo

87,5
mol asam lemak
= 12,5 x 0,117 /gr mj
mol gliserida
= 0,819 /gr mj
3. Perhitungan setelah Hidrolisa
( V x N ) NaOH V ml x 0,125 N
CA Asam lemak = ( x V ) MJ = 0,9928 gr /ml x 10 ml
mol asam lemak
= 0,0125V /gr mj
CAs = CA CAo
= 0,0125V 0,117
4. Perhitungan Nilai Konstanta Reaksi
dC B
dt = k.CB
CB t
dC B

dt =k dt
C B0 0

CB
ln = k.t
CB0

C B 0 (1 X A )
ln = k.t
C Bo

ln ( 1X A )=k .t

y=mx

5. Menghitung Konversi (XA)


C A C As ( 0,0125 V 0,117 )
X A= =
MolGliserida 0,819 mol

6. Hasil Percobaan
a. Variabel 1 (Mol mj : Mol aq = 1 : 8)

t (Menit) V NaOH CA CAs XA 1 - XA


(ml) (Terhidrolisa) (Terbentuk)
0 24 0 0 0 0
5 25 0,3125 0,1955 0,079569 0,92043142
10 27 0,3375 0,2205 0,089744 0,91025641
15 29 0,3625 0,2455 0,099919 0,9000814

Variabel 1
0.12
f(x) = 0.01x
0.1 R = 0.92

0.08 LN(1-XA)
Linear (LN(1-XA))
0.06

0.04

0.02

0
0 2 4 6 8 10 12 14 16

b. Variabel 2 (Mol mj : Mol aq = 1 : 9)


t (Menit) V NaOH CA CAs XA 1 - XA
(ml) (Terhidrolisa) (Terbentuk)
0 19 0 0 0 0
5 20,2 0,2525 0,1355 0,055149 0,944851
10 21 0,2625 0,1455 0,059219 0,940781
15 25 0,3125 0,1955 0,079569 0,920431

Variabel 2
0.09
f(x) = 0.01x
0.08
R = 0.94
0.07
0.06 LN(1-XA)
0.05 Linear (LN(1-XA))
0.04
0.03
0.02
0.01
0
0 2 4 6 8 10 12 14 16

c. Variabel 3 (Mol mj : Mol aq = 1 : 10)

t (Menit) V NaOH CA CAs XA 1 - XA


(ml) (Terhidrolisa) (Terbentuk)
0 17,5 0,21875 0 0 1
5 18 0,225 0,108 0,043956 0,956044
10 18,4 0,23 0,113 0,045991 0,954009
15 18,5 0,23125 0,1142 0,046479 0,953521

Variabel 3
0.05
f(x) = 0x
R = 0.87
0.04

LN(1-XA)
0.03
Linear (LN(1-XA))
0.02

0.01

0
0 2 4 6 8 10 12 14 16
7. Perhitungan Kesetimbangan Reaksi
XA
K = XA1

a. Variabel 1
0,099919
K = 0,0,0999191 = 0,111

b. Variabel 2
0,079569
K = 0,0795691 = 0,0864
c. Variabel 3
0,046479
K = 0,0464791 = 0,0487

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