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Chemistry Exam Practice Questions

This document contains 42 multiple choice questions related to acid-base chemistry and acid-base equilibria. The questions cover topics such as identifying conjugate acid-base pairs, calculating pH from concentrations of H+ or OH-, determining Ka or Kb values from given information, and solving for various quantities in acid-base equilibrium problems involving both monoprotic and polyprotic acids.

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Emily Swan
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180 views5 pages

Chemistry Exam Practice Questions

This document contains 42 multiple choice questions related to acid-base chemistry and acid-base equilibria. The questions cover topics such as identifying conjugate acid-base pairs, calculating pH from concentrations of H+ or OH-, determining Ka or Kb values from given information, and solving for various quantities in acid-base equilibrium problems involving both monoprotic and polyprotic acids.

Uploaded by

Emily Swan
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOC, PDF, TXT or read online on Scribd
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1) What is the conjugate acid of NH3?

A) NH3+ B) NH4OH C) NH2+ D) NH3 E) NH4+


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2) The conjugate base of HSO4- is
A) HSO4+ B) H3SO4+ C) OH- D) H2SO4 E) SO42-

3) The conjugate acid of HSO4- is


A) SO42- B) H+ C) HSO4+ D) HSO3+ E) H2SO4

4) What is the conjugate base of OH-?


A) O- B) H2O C) H3O+ D) O2- E) O2

5) What is the pH of an aqueous solution at 25.0 C in which [H+] is 0.00250 M?


A) -2.60 B) -3.40 C) 2.60 D) 3.40 E) 2.25

6) What is the pH of an aqueous solution at 25.0 C in which [OH-] is 0.00250 M?


A) +2.60 B) -2.60 C) +11.4 D) -11.4 E) -2.25

7) What is the pH of an aqueous solution at 25.0 C that contains 3.98 10-9 M hydronium ion?
A) 5.60 B) 7.00 C) 8.40 D) 9.00 E) 3.98

8) What is the pH of an aqueous solution at 25.0 C that contains 3.98 10-9 M hydroxide ion?
A) 5.60 B) 9.00 C) 7.00 D) 3.98 E) 8.40

9) What is the concentration (in M) of hydronium ions in a solution at 25.0 C with pH = 4.282?
A) 4.28
B) 5.22 10-5
C) 1.92 10-10
D) 9.71
E) 1.66 104

10) What is the concentration (in M) of hydroxide ions in a solution at 25.0 C with pH = 4.282?
A) 9.72
B) 1.66 104
C) 5.22 10-5
D) 1.91 10-10
E) 4.28

11) Calculate the pOH of a solution at 25.0 C that contains 1.94 10-10 M hydronium ions.
A) 1.94 B) 7.00 C) 9.71 D) 4.29 E) 14.0

12) Calculate the concentration (in M) of hydronium ions in a solution at 25.0 C with a pOH of 4.223.
A) 5.99 10-19
B) 5.98 10-5
C) 1.00 10-7
D) 1.67 10-10
E) 1.67 104
13) What is the pH of a 0.0150 M aqueous solution of barium hydroxide?
A) 10.4 B) 1.52 C) 12.2 D) 12.5 E) 1.82

14) What is the pOH of a 0.0150 M solution of barium hydroxide?


A) 12.2 B) 10.4 C) 1.82 D) 12.5 E) 1.52

15) An aqueous solution contains 0.100 M NaOH at 25.0 C. The pH of the solution is __________.
A) 1.00 B) -1.00 C) 7.00 D) 13.0 E) 0.100

16) HZ is a weak acid. An aqueous solution of HZ is prepared by dissolving 0.020 mol of HZ in


sufficient water to yield 1.0 L of solution. The pH of the solution was 4.93 at 25.0 C. The Ka of HZ
is __________.
A) 9.9 10-2
B) 1.2 10-5
C) 2.8 10-12
D) 6.9 10-9
E) 1.4 10-10

17) The pH of a 0.55 M aqueous solution of hypobromous acid, HBrO, at 25.0 C is 4.48. What is the
value of Ka for HBrO?
A) 1.1 10-9 B) 3.3 10-5 C) 2.0 10-9 D) 3.0 104 E) 6.0 10-5

2
18) A 0.15 M aqueous solution of the weak acid HA at 25.0 C has a pH of 5.35. The value of Ka for HA
is __________.
A) 3.0 10-5
B) 3.3 104
C) 7.1 10-9
D) 1.4 10-10
E) 1.8 10-5

19) The Ka of hypochlorous acid (HClO) is 3.00 10-8 at 25.0 C. Calculate the pH of a 0.0385 M
hypochlorous acid solution.
A) 8.94 B) 4.47 C) 7.52 D) 1.41 E) -1.41

20) The Ka of hypochlorous acid (HClO) is 3.00 10-8. What is the pH at 25.0 C of an aqueous
solution that is 0.0200 M in HClO?
A) +2.45 B) -2.45 C) -9.22 D) +9.22 E) +4.61

21) The Ka of hydrofluoric acid (HF) at 25.0 C is 6.8 10-4. What is the pH of a 0.35 M aqueous
solution of HF?
A) 12 B) 3.6 C) 1.8 D) 0.46 E) 3.2

22) The Ka of hydrazoic acid (HN3) is 1.9 10-5 at 25.0 C. What is the pH of a 0.35 M aqueous
solution of HN3?
A) 2.4 B) 11 C) 5.2 D) -2.4 E) 2.6

23) The acid-dissociation constants of sulfurous acid (H2SO3) are Ka1 = 1.7 10-2 and
Ka2 = 6.4 10-8 at 25.0 C. Calculate the pH of a 0.163 M aqueous solution of sulfurous acid.
A) 1.8 B) 1.3 C) 1.4 D) 4.5 E) 7.2

24) The acid-dissociation constants of phosphoric acid (H3PO4) are Ka1 = 7.5 10-3, Ka2 = 6.2 10-8,
and Ka3 = 4.2 10-13 at 25.0 C. What is the pH of a 2.5 M aqueous solution of phosphoric acid?
A) 0.87 B) 0.13 C) 1.8 D) 2.5 E) 0.40

25) The acid-dissociation constants of phosphoric acid (H3PO4) are Ka1 = 7.5 10-3, Ka2 = 6.2 10-8,
and Ka3 = 4.2 10-13 at 25.0 C. What is the molar concentration of phosphate ion in a 2.5 M
aqueous solution of phosphoric acid?
A) 0.13
B) 2.5 10-5
C) 8.2 10-9
D) 9.1 10-5
E) 2.0 10-19

26) The acid-dissociation constant for chlorous acid, HClO2, at 25.0 C is 1.0 10-2. Calculate the
concentration of H+ if the initial concentration of acid is 0.10 M.
A) 1.0 10-3 B) 1.0 10-2 C) 3.7 10-2 D) 2.7 10-2 E) 3.2 10-2

27) The pH of a 0.10 M solution of a weak base is 9.82. What is the Kb for this base?
A) 2.1 10-4 B) 4.3 10-8 C) 6.6 10-4 D) 2.0 10-5 E) 8.8 10-8

28) Calculate the pH of a 0.500 M aqueous solution of NH3. The Kb of NH3 is 1.77 10-5.
A) 11.5 B) 2.52 C) 5.05 D) 3.01 E) 8.95

29) Determine the pH of a 0.35 M aqueous solution of CH3NH2 (methylamine). The Kb of


methylamine is 4.4 10-4.
A) 10 B) 13 C) 1.9 D) 3.8 E) 12

30) An aqueous solution contains 0.050 M of methylamine. The concentration of hydroxide ion in this
solution is ________M. Kb for methylamine is 4.4 10-4.
A) 4.7 10-3
B) 2.2 10-5
C) 4.5 10-3
D) 0.050
E) -4.9 10-3

31) The acid-dissociation constant, Ka, for gallic acid is 4.57 10-3. What is the base-dissociation
constant, Kb, for the gallate ion?
A) 7.81 10-6
B) 4.57 10-3
C) 2.19 102
D) 2.19 10-12
E) 5.43 10-5

32) The base-dissociation constant, Kb, for pyridine, C5H5N, is 1.4 10-9. The acid-dissociation
constant, Ka, for the pyridinium ion, C5H5NH+, is __________.
A) 7.1 10-4
B) 1.0 10-7
C) 7.1 10-6
D) 1.4 10-23
E) 1.4 10-5

33) The Ka for HCN is 4.9 10-10. What is the value of Kb for CN-?
A) 4.9 10-24
B) 2.0 10-5
C) 2.0 109
D) 4.0 10-6
E) 4.9 104

34) Ka for HF is 7.0 10-4. Kb for the fluoride ion is __________.


A) 7.0 10-4
B) 1.4 10-11
C) 1.4 103
D) 2.0 10-8
E) 7.0 10-18

35) Calculate the pOH of a 0.0827 M aqueous sodium cyanide solution at 25.0 C. Kb for CN- is
4.9 10-10.
A) 5.2 B) 8.8 C) 10 D) 9.3 E) 1.1

36) Determine the pH of a 0.15 M aqueous solution of KF. For hydrofluoric acid, Ka = 7.0 10-4.
A) 5.8 B) 2.3 C) 6.6 D) 12 E) 8.2

37) Calculate the pH of 0.726 M anilinium hydrochloride (C6H5NH3Cl) solution in water, given that
Kb for aniline is 3.83 10-4.
A) 1.77 B) 12.2 C) 8.64 D) 12.4 E) 5.36

38) Kb for NH3 is 1.8 10-5. What is the pH of a 0.35 M aqueous solution of NH4Cl at 25.0 C?
A) 9.1 B) 11 C) 4.3 D) 4.9 E) 9.7

39) The Ka for formic acid (HCO2H) is 1.8 10-4. What is the pH of a 0.35 M aqueous solution of
sodium formate (NaHCO2)?
A) 5.4 B) 11 C) 3.3 D) 8.6 E) 4.2

40) Ka for HCN is 4.9 10-10. What is the pH of a 0.068 M aqueous solution of sodium cyanide?
A) 2.9 B) 0.74 C) 7.0 D) 13 E) 11

41) Ka for HX is 7.5 10-12. What is the pH of a 0.15 M aqueous solution of NaX?
A) 7.9 B) 6.0 C) 1.9 D) 12 E) 8.0

42) The pH of a 0.15 M aqueous solution of NaZ (the sodium salt of HZ) is 10.7. What is the Ka for HZ?
A) 1.6 10-6
B) 1.3 10-12
C) 6.0 10-9
D) 3.3 10-8
E) 8.9 10-4

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