Soaps & Detergents: Chemistry

To understand what is needed to achieve effective cleaning, it is helpful to have a basic knowledge of soap and

detergent chemistry.

Water, the liquid commonly used for cleaning, has a property called surface tension. In the body of

the water, each molecule is surrounded and attracted by other water molecules. However, at the
surface, those molecules are surrounded by other water molecules only on the water side. A tension

is created as the water molecules at the surface are pulled into the body of the water. This tension

causes water to bead up on surfaces (glass, fabric), which slows wetting of the surface and inhibits

the cleaning process. You can see surface tension at work by placing a drop of water onto a counter top. The drop

will hold its shape and will not spread.

In the cleaning process, surface tension must be reduced so water can spread and wet surfaces.

Chemicals that are able to do this effectively are called surface active agents, or surfactants. They

are said to make water "wetter."

Surfactants perform other important functions in cleaning, such as loosening, emulsifying

(dispersing in water) and holding soil in suspension until it can be rinsed away. Surfactants can also provide

alkalinity, which is useful in removing acidic soils.

Surfactants are classified by their ionic (electrical charge) properties in water:

anionic (negative charge), nonionic (no charge), cationic (positive charge) and

amphoteric (either positive or negative charge).

Soap is an anionic surfactant. Other anionic as well as nonionic surfactants are the main ingredients in today's

detergents. Now let's look closer at the chemistry of surfactants.

Soaps

Soaps are water-soluble sodium or potassium salts of fatty acids. Soaps are made from fats and oils, or their fatty

acids, by treating them chemically with a strong alkali.

First let's examine the composition of fats, oils and alkalis; then we'll review the soapmaking process.

Fats and Oils

The fats and oils used in soapmaking come from animal or plant sources. Each fat or oil is made up of a distinctive

mixture of several different triglycerides.

In a triglyceride molecule, three fatty acid molecules are attached to one molecule of glycerine. There are many types

of triglycerides; each type consists of its own particular combination of fatty acids.

Fatty acids are the components of fats and oils that are used in making soap. They are weak acids composed of two

parts:

A carboxylic acid group consisting of one hydrogen (H) atom, two oxygen (O) atoms, and one carbon (C) atom, plus a

hydrocarbon chain attached to the carboxylic acid group. Generally, it is made up of a long straight chain of carbon

(C) atoms each carrying two hydrogen (H) atoms.

Alkali

An alkali is a soluble salt of an alkali metal like sodium or potassium. Originally, the alkalis used in soapmaking were

obtained from the ashes of plants, but they are now made commercially. Today, the term alkali describes a substance

that chemically is a base (the opposite of an acid) and that reacts with and neutralizes an acid.

The common alkalis used in soapmaking are sodium hydroxide (NaOH), also called caustic soda; and potassium

hydroxide (KOH), also called caustic potash.

How Soaps are Made

Saponification of fats and oils is the most widely used soapmaking process. This method involves heating fats and

oils and reacting them with a liquid alkali to produce soap and water (neat soap) plus glycerine.

The other major soapmaking process is the neutralization of fatty acids with an alkali. Fats and oils are hydrolyzed

(split) with a high-pressure steam to yield crude fatty acids and glycerine. The fatty acids are then purified by
distillation and neutralized with an alkali to produce soap and water (neat soap).

When the alkali is sodium hydroxide, a sodium soap is formed. Sodium soaps are "hard" soaps. When the alkali is

potassium hydroxide, a potassium soap is formed. Potassium soaps are softer and are found in some liquid hand

soaps and shaving creams.

The carboxylate end of the soap molecule is attracted to water. It is called the

hydrophilic (water-loving) end. The hydrocarbon chain is attracted to oil and

grease and repelled by water. It is known as the hydrophobic (water-hating)

end.

How Water Hardness Affects Cleaning Action

Although soap is a good cleaning agent, its effectiveness is reduced when used in hard

water. Hardness in water is caused by the presence of mineral salts - mostly those of

calcium (Ca) and magnesium (Mg), but sometimes also iron (Fe) and manganese (Mn). The

mineral salts react with soap to form an insoluble precipitate known as soap film or scum.

Soap film does not rinse away easily. It tends to remain behind and produces visible

deposits on clothing and makes fabrics feel stiff. It also attaches to the insides of bathtubs,
sinks and washing machines.
Some soap is used up by reacting with hard water minerals to form the film. This reduces the amount of soap

available for cleaning. Even when clothes are washed in soft water, some hardness minerals are introduced by the

soil on clothes. Soap molecules are not very versatile and cannot be adapted to today's variety of fibers, washing

temperatures and water conditions.

Soaps & Detergents: Chemistry (Surfactants)

Surfactants in Detergents

A detergent is an effective cleaning product because it contains one or more surfactants. Because of their chemical

makeup, the surfactants used in detergents can be engineered to perform well under a variety of conditions. Such

surfactants are less sensitive than soap to the hardness minerals in water and most will not form a film.

Detergent surfactants were developed in response to a shortage of animal and vegetable fats and oils during World

War I and World War II. In addition, a substance that was resistant to hard water was needed to make cleaning more

effective. At that time, petroleum was found to be a plentiful source for the manufacture of these surfactants. Today,

detergent surfactants are made from a variety of petrochemicals (derived from petroleum) and/or oleochemicals

(derived from fats and oils).

Petrochemicals and Oleochemicals

Like the fatty acids used in soapmaking, both petroleum and fats and oils contain hydrocarbon

chains that are repelled by water but attracted to oil and grease in soils. These hydrocarbon chain

sources are used to make the water-hating end of the surfactant molecule.

Other Chemicals
Chemicals, such as sulfur trioxide, sulfuric acid and ethylene oxide, are used to produce the water-

loving end of the surfactant molecule.

Alkalis
As in soapmaking, an alkali is used to make detergent surfactants. Sodium and potassium hydroxide are the most

common alkalis.
How Detergent Surfactants Are Made
Anionic Surfactants
The chemical reacts with hydrocarbons derived from petroleum or fats and

oils to produce new acids similar to fatty acids.

A second reaction adds an alkali to the new acids to produce one type of

anionic surfactant molecule.

Nonionic Surfactants
Nonionic surfactant molecules are produced by first converting the hydrocarbon to an alcohol and then reacting the

fatty alcohol with ethylene oxide.

These nonionic surfactants can be reacted further with sulfur-containing acids to form another type of anionic

surfactant.

How Soaps and Detergents Work

These types of energy interact and should be in proper balance. Let's look at how they work together.

Let's assume we have oily, greasy soil on clothing. Water alone will not remove this soil. One important reason is that

oil and grease present in soil repel the water molecules.

Now let's add soap or detergent. The surfactant's water-hating end is repelled by water but attracted to the oil in the

soil. At the same time, the water-loving end is attracted to the water molecules.

These opposing forces loosen the soil and suspend it in the water. Warm or hot water helps dissolve grease and oil in

soil. Washing machine agitation or hand rubbing helps pull the soil free.
 Soaps & Detergents: Human Safety

As consumer needs and lifestyles change, and as new manufacturing processes become available, the soap and

detergent industry responds with new products. A commitment to safety is a top priority from the time a company

begins working on a new product and continues as long as the product is in the marketplace. Companies evaluate

the safety of existing cleaning products by talking with consumers, reviewing scientific developments and monitoring

product use data that may affect the safety assessment process.

To determine the safety of a cleaning product ingredient, industry scientists evaluate the toxicity of the ingredient.

Toxicity is generally defined as any harmful effect of a chemical on a living organism, i.e., a human, an animal, a plant

or a microorganism. Since all chemicals, including water (H2O), are toxic under certain conditions of exposure,

scientists must consider a number of factors affecting exposure. These include the duration and frequency of

exposure to the ingredient; the concentration of the ingredient at the time of exposure; and the route and manner in

which the exposure occurs, e.g., eye, skin or ingestion. This information is essential whether assessing the effect on

humans, animals, plants or microorganisms.

Because human safety and environmental evaluations consider different types of exposures, they are evaluated by

different procedures. The principal steps in the assessment process are, however, the same. They involve:

 assembling existing data on toxicity and exposure;

 determining where new information is needed and, if necessary, carrying out appropriate studies; and

 determining whether predicted exposure levels are below levels that cause significant toxic effects.
This safety evaluation process enables scientists to predict the potential risk, if any, associated with the use of the

ingredient or product, and determine if it is safe for consumers and the environment.

Medical science has long confirmed the important relationship between cleanliness and health.

The regular use of cleaning products is fundamental to the health of our society and the well-

being of its people.

Because cleaning products are part of our everyday lives, it is essential that they not present a

significant risk to health. In considering the human safety of an individual ingredient or product, toxicologists

(scientists who assess the safety of a chemical) are concerned with the effects from two types of exposures: intended

and unintended. Intended exposures occur with use of a cleaning product according to the manufacturer's directions.

Unintended exposures can result from misuse, through improper storage or by accidental contact, such as when a

liquid detergent is splashed in the eye.

Hazards from these types of exposures are evaluated from

information obtained through acute (short-term) and chronic (long-

term) tests and through a review of existing data. Expected exposure

routes are considered as part of this evaluation.

Human safety evaluations begin with the specific ingredients and then move on to the whole product. The effects for

all ingredients are considered as the product is formulated.

Toxicologists compare the expected exposure to the expected effect during both

product manufacture and use. How will workers be exposed in the plant? What is the

intended use of the product? Is it to be diluted? Undiluted? Used daily in the home?

Weekly in the workplace? Toxicologists also consider the expected effect of an

unintended exposure. What is the potential hazard, for example, if a child drinks a

product directly from the bottle?

If this human safety evaluation indicates an unacceptable risk, it may be possible to make the risk smaller by

changing the manufacturing process; reformulating to reduce or eliminate an ingredient contributing to the toxic

effect; or using labeling or a child-resistant closure. If the risk cannot be reduced, the

product will not be marketed.

Even though manufacturers formulate cleaning products to ensure that they are safe
or have very low risk, human health effects can still result from unintended exposure.
To warn consumers about a specific hazard, household cleaning products carry cautionary labeling whenever

necessary. For consumers, this is one of the most important features of the label.

Federal regulations govern how precautionary statements related to human safety are used on household cleaning

product labels. The regulations require that statements follow a standard format. There is first a "signal word,"
followed by a short description of the potential hazard. The following chart shows the signal words - CAUTION or

WARNING and DANGER - and what they mean:

POISON, which rarely appears on household cleaning products, is the strongest indication of hazard and means that

accidental exposure could cause severe medical effects. The term may be found on household lye and on some car

care products, such as antifreeze.

Along with the safety evaluation process and cautionary labeling, an extensive consumer education program on the

proper use, storage and disposal of cleaning products supports the human safety efforts of the soap and detergent

industry. In addition, the industry works closely with poison control centers to assure that, should an accidental

exposure occur, treatment information is available to health care providers. Together, these activities enable

consumers to use cleaning products with confidence in both their safety and performance.
Soaps & Detergents: Environmental Safety

Most household cleaning products are formulated to be used with water and "go down the drain"

into wastewater treatment systems (municipal sewage treatment plants or septic tank systems). To

assure that products are safe for the environment, manufacturers evaluate the impacts of product

ingredients in wastewater treatment systems, streams, rivers, lakes and estuaries. Scientific

principles that are widely recognized by the technical and regulatory communities are

used to assess the risk to the environment of these impacts.

Environmental risk assessment considers the exposure concentrations and effects of

individual ingredients. Two sets of information are used in these assessments. One set

enables industry scientists to predict the concentration of the ingredient from all

sources, including cleaning products, at various locations in the environment (the

predicted exposure concentration). The other set is used to find the highest

concentration of the ingredient at which no harm will occur to animals, plants or

microorganisms living in the environment (the no-effect concentration). Comparing the predicted exposure

concentration and the no-effect concentration enables scientists to determine whether the use of an ingredient is safe

for the environment. The planned use of a cleaning product ingredient is acceptable if the predicted exposure

concentration is lower than the concentration that would harm animals, plants or microorganisms.

This information applies to ingredients processed through household septic tank systems as

well as municipal treatment plants. Two basic steps occur in the treatment of wastewater in

both systems. The first step, called primary treatment, consists of

the removal of solid material, such as grit or grease, from the

wastewater by physical means, i.e., settling and flotation in tanks.

The second step, called secondary treatment, removes the dissolved material by
biological means, i.e., consumption by microorganisms. It is in the secondary treatment
stage where the most important process in reducing the exposure concentration of detergent ingredients occurs. This
is called biodegradation. Biodegradation describes how organic (carbon-containing) detergent ingredients, like

surfactants, enzymes and fragrances, are broken down into carbon dioxide, water and

minerals by the action of microorganisms such as bacteria. At this stage, biodegradation

reduces the amount of detergent ingredients discharged into the environment to levels

that do not present a risk to fish or other aquatic life. Any small amounts of chemicals

which are not biodegraded or removed during sewage treatment are diluted in surface

waters, soil and the ocean. They continue to biodegrade or be removed from water by attaching to solids, a process
known as adsorption.

Some inorganic (not carbon-containing) detergent ingredients, such as phosphates,

zeolites and some dyes, also attach to solids, and are further treated during processing

of the biosolids (sludge) produced in primary and secondary treatment. Biosolids are

often used as fertilizers and soil conditioners.

Because of modern treatment methods, only an insignificant amount of the ingredients used to clean clothes, dishes,

home and workplace surfaces actually reaches the environment. And that amount is at such levels as to not cause

any adverse effects.

Improving Environmental Quality

The soap and detergent industry is committed to understanding the impact of its products and packages on the

environment. With this understanding comes the ability to reduce their impact and improve their environmental

quality.

Manufacturers of cleaning products have been leaders in reducing packaging waste and encouraging sound waste

disposal practices. Advances in technology have resulted in products that are more concentrated, products that

combine two functions in one, products with refill packages and packages that use recycled materials. Concentrated

products need less energy to manufacture and transport, and require less packaging. Multifunctional products

eliminate the need for separate packages. Refill packages allow consumers to reuse primary packages many times,

decreasing the amount of packaging used and the volume of trash generated. Plastic and paperboard that would

otherwise be thrown away become usable materials through recycling.

Through education and community programs, the soap and detergent industry helps

consumers learn how to reduce waste and how best to dispose of it. Consumers are
reminded that the environmentally wise way of handling any household cleaning product is

to buy only the amount that can be used; to use it all up or give it away; and, if it must be
disposed, to dispose of it properly. As a rule of thumb, products designed for use with water should be disposed of by

pouring down the drain; solid products such as scouring pads should be put into the trash.

A promising method under development for improving the environmental quality

of a product is life cycle assessment (LCA). LCA describes a "cradle-to-grave"

look at all the environmental impacts of a product and its package, from

acquiring raw materials through manufacture and distribution to consumer use

and disposal. One advantage of LCA is that it can determine whether reducing

an environmental impact in one area, such as manufacturing, shifts the impact

to another, such as disposal. LCA also helps to identify where environmental

improvement efforts should be focused.

Sound scientific information provides the foundation for the soap and detergent industry's commitment to safety. The

industry maintains this commitment without compromising product performance, convenience or cost-effectiveness.

Soaps & Detergents: Products & Ingredients

Soaps and detergents are essential to personal and public health. Through their ability to loosen and remove soil

from a surface, they contribute to good personal hygiene; reduce the presence of germs that cause infectious
diseases; extend the useful life of clothes, tableware, linens, surfaces and furnishings; and make our homes and

workplaces more pleasant.

Soaps and detergents found in the home can be grouped into four general categories: personal cleansing, laundry,

dishwashing and household cleaning. Within each category are different product types formulated with ingredients

selected to perform a broad cleaning function as well as to deliver properties specific to that product. Knowing the

different products and their ingredients helps you select the right product for the cleaning job.

Products

Personal Cleansing Products include bar soaps, gels, liquid soaps and heavy duty

hand cleaners. These products get their cleaning action from soap, other surfactants or
a combination of the two. The choice of cleaning agent helps determine the product's lathering characteristics, feel on

the skin and rinsability.

Bar soaps or gels are formulated for cleaning the hands, face and body. Depending on the other ingredients, they

may also moisturize the skin and/or kill or inhibit bacteria that can cause odor or disease. Specialty bars include

transparent/translucent soaps, luxury soaps and medicated soaps.

Liquid soaps are formulated for cleaning the hands or body, and feature skin conditioners. Some contain antimicrobial

agents that kill or inhibit bacteria that can cause odor or disease.

Heavy duty hand cleaners are available as bars, liquids, powders and pastes. Formulated for removing stubborn,

greasy dirt, they may include an abrasive.

Laundry Detergents and Laundry Aids are available as liquids, powders, gels, sticks,

sprays, pumps, sheets and bars. They are formulated to meet a variety of soil and stain

removal, bleaching, fabric softening and conditioning, and disinfectant needs under varying

water, temperature and use condiditons.

Laundry detergents are either general purpose or light duty. General purpose detergents are

suitable for all washable fabrics. Liquids work best on oily soils and for pretreating soils and

stains. Powders are especialy effective in lifting out clay and ground-in dirt. Light duty detergents are used for hand or

machine washing lightly soiled items and delicate fabrics.

Laundry aids contribute to the effectiveness of laundry detergents and provide special functions.

Bleaches (chlorine and oxygen) whiten and brighten fabrics and help remove stubborn stains. They convert soils into

colorless, soluble particles that can be removed by detergents and carried away in the wash water. Liquid chlorine

bleach (usually in a sodium hypochlorite solution) can also disinfect and deodorize fabrics. Oxygen (color-safe)

bleach is more gentle and works safely on almost all washable fabrics.

Bluings contain a blue dye or pigment taken up by fabrics in the wash or rinse. Bluing absorbs the yellow part of the

light spectrum, counteracting the natural yellowing of many fabrics.

Boosters enhance the soil and stain removal, brightening, buffering and water softening performance of detergents.

They are used in the wash in addition to the detergent.

Enzyme presoaks are used for soaking items before washing to remove difficult stains and soils. When added to the

wash water, they increase cleaning power.

Fabric softeners, added to the final rinse or dryer, make fabrics softer and fluffier; decrease static cling, wrinkling and

drying time; impart a pleasing fragrance and make ironing easier.

Prewash soil and stain removers are used to pretreat heavily soiled and stained garments, especially those made

from synthetic fibers.

Starches, fabric finishes and sizings, used in the final rinse or after drying, give body to fabrics, make them more soil-

resistant and make ironing easier.

Water softeners, added to the wash or rinse, inactivate hard water minerals. Since detergents are more effective in

soft water, these products increase cleaning power.

Dishwashing Products include detergents for hand and machine dishwashing as

well as some specialty products. They are available as liquids, gels, powders and

solids.

Hand dishwashing detergents remove food soils, hold soil in suspension and

provide long-lasting suds that indicate how much cleaning power is left in the wash

water.

Automatic dishwasher detergents, in addition to removing food soils and holding them in suspension, tie up hardness

minerals, emulsify grease and oil, suppress foam caused by protein soil and help water sheet off dish surfaces. They
produce little or no suds that would interfere with the washing action of the machine.

Rinse agents are used in addition to the automatic dishwasher detergent to lower surface tension, thus improving

draining of the water from dishes and utensils. Better draining minimizes spotting and filming and enhances drying.

Film removers remove build-up of hard water film and cloudiness from dishes and the interior of the dishwasher. They

are used instead of an automatic dishwasher detergent in a separate cycle or together with the detergent.

Lime and rust removers remove deposits of lime and/or rust from the interior of the dishwasher. They are used when

no dishes or other dishwasher products are present.

Household Cleaners are available as liquids, gels, powders, solids, sheets and pads for use

on painted, plastic, metal, porcelain, glass and other surfaces, and on washable floor

coverings. Because no single product can provide optimum performance on all surfaces and

soils, a broad range of products has been formulated to clean efficiently and easily. While all-

purpose cleaners are intended for more general use, others work best under highly

specialized conditions.

All-purpose cleaners penetrate and loosen soil, soften water and prevent soil from redepositing on the cleaned

surface. Some also disinfect.

Abrasive cleansers remove heavy accumulations of soil often found in small areas. The abrasive action is provided

by small mineral or metal particles, fine steel wool, copper or nylon particles. Some also disinfect.

Specialty cleaners are designed for the soil conditions found on specific surfaces, such as glass, tile, metal, ovens,

carpets and upholstery, toilet bowls and in drains.

Glass cleaners loosen and dissolve oily soils found on glass, and dry quickly without streaking.

Glass and multi-surface cleaners remove soils from a variety of smooth surfaces. They shine surfaces without

streaking.

Tub, tile and sink cleaners remove normal soils found on bathroom surfaces as well as hard water deposits, soap

scum, rust stains, and/or mildew and mold. Some also treat surfaces to retard soiling; some also disinfect.

Metal cleaners remove soils and polish metalware. Tarnish, the oxidation of metal, is the principal soil found on
metalware. Some products also protect cleaned metalware against rapid retarnishing.

Oven cleaners remove burned-on grease and other food soils from oven walls. These cleaners are thick so the

product will cling to vertical oven surfaces.

Rug shampoos and upholstery cleaners dissolve oily and greasy soils and hold them in suspension for removal.

Some also treat surfaces to repel soil.

Toilet bowl cleaners prevent or remove stains caused by hard water and rust deposits, and maintain a clean and

pleasant-smelling bowl. Some products also disinfect.

Drain openers unclog kitchen and bathroom drains. They work by producing heat to melt fats, breaking them down

into simpler substances that can be rinsed away, or by oxidizing hair and other materials. Some use bacteria to

prevent grease build-up which leads to drain clogging.

Soaps & Detergents: Surfactants & Builders

Surfactants and builders are the major components of cleaning products. Other ingredients are added to provide a

variety of functions, such as increasing cleaning performance for specific soils/surfaces, ensuring product stability

and supplying a unique identity to a product. Let's examine how surfactants and builders work and then review other

commonly used ingredients.

Surfactants

Surfactants, also called surface active agents, are organic chemicals that change the properties

of water (see Chemistry.) By lowering the surface tension of water, surfactants enable the

cleaning solution to wet a surface (e.g., clothes, dishes, countertops) more quickly, so soil can

be readily loosened and removed (usually with the aid of mechanical action). Surfactants also

emulsify oily soils and keep them dispersed and suspended so they do not settle back on the

surface. To accomplish their intended jobs effectively, many cleaning products include two or more surfactants.

Surfactants are generally classified by their ionic (electrical charge) properties in water.

Anionic surfactants are used in laundry and hand dishwashing detergents; household cleaners; and

personal cleansing products. They ionize (are converted to electrically charged particles) in solution,

carry a negative charge, have excellent cleaning properties and generally are high sudsing. Linear

alkylbenzene sulfonate, alcohol ethoxysulfates, alkyl sulfates and soap are the most common

anionic surfactants.
 Nonionic surfactants are low sudsing and are typically used in laundry and automatic

dishwasher detergents and rinse aids. Because they do not ionize in solution and thus have no

electrical charge, they are resistant to water hardness and clean well on most soils. The most

widely used are alcohol ethoxylates.

Cationic surfactants are used in fabric softeners and in fabric-softening laundry detergents. Other

cationics are the disinfecting/sanitizing ingredient in some household cleaners. They ionize in

solution and have a positive charge. Quaternary ammonium compounds are the principal cationics.

Amphoteric surfactants are used in personal cleansing and household cleaning products for their

mildness, sudsing and stability. They have the ability to be anionic (negatively charged), cationic

(positively charged) or nonionic (no charge) in solution, depending on the pH (acidity or alkalinity) of the

water. Imidazolines and betaines are the major amphoterics.

Builders

Builders enhance or maintain the cleaning efficiency of the surfactant.

The primary function of builders is to reduce water hardness. This is

done either by sequestration or chelation (holding hardness minerals in

solution), by precipitation (forming an insoluble substance), or by ion

exchange (trading electrically charged particles). Complex phosphates and sodium citrate are common sequestering

builders. Sodium carbonate and sodium silicate are precipitating builders. Sodium aluminosilicate (zeolite) is an ion

exchange builder.

Builders can also supply and maintain alkalinity, which assists cleaning, especially of acid soils; help keep removed

soil from redepositing during washing; and emulsify oily and greasy soils.
Soaps & Detergents: Ingredient Key

The following key indicates the product category in which an ingredient may be used. The key

letters appear below each ingredient.

Personal Cleansing Laundry Dishwashing Household Cleaners

Ingredient Primary Functions Typical Examples

Comments

Abrasives Supply smoothing, scrubbing Calcite

and/or polishing action Feldspar

Quartz

Sand

Acids Neutralize or adjust alkalinity of Acetic acid

other ingredients Citric acid

Some specialty cleaners need Hydrochloric acid
extra acidity to remove mineral Phosphoric acid
build-up Sulfuric acid

Alkalis  Neutralize or adjust acidity of other Ammonium &nbsphydroxide

ingredients
Ethanolamines
 Make surfactants and builders
Sodium carbonate
more efficient
Sodium hydroxide
 Increase alkalinity
Sodium silicate
Alkalinity is useful in removing

acidic, fatty and oily soils.

Therefore, detergents are more

effective when they are alkaline.

Antimicrobial agents Kill or inhibit growth of Pine oil

microorganisms that cause Quaternary ammonium

diseases and/or odor compounds

Sodium hypochlorite
 Triclocarban

Triclosan

Antiredeposition agents Prevent soil from resettling after Carboxymethyl cellulose

removal during washing Polycarbonates

Polyethylene glycol

Sodium silicate

Bleaches Help whiten, brighten and remove stains

Chlorine bleach Also disinfects Sodium hypochlorite

Oxygen bleach In some products, may be Sodium perborate

combined with bleach activator for Sodium percarbonate

better performance in lower water

temperatures.

Colorants  Provide special identity to product Pigments or dyes

 Provide bluing action

Corrosion inhibitors Protect metal machine parts and Sodium silicate

finishes, china patterns and metal

utensils

Back to Top

Enzymes  Proteins classified by the type of Amylase (starch soils)

soil they break down to simpler
Lipase (fatty and oily soils)
forms for removal by detergent
Protease (protein soils)
 Cellulase reduces pilling and
greying of fabrics containing cotton Cellulase
and helps remove particulate soils.

Fabric softening agents Impart softness and control static Quaternary ammonium

electricity in fabrics compounds

Fluorescent whitening Attach to fabrics to create a Colorless fluorescing

agents whitening or brightening effect compounds
 when exposed to daylight
Also called optical brighteners.

Fragrances  Mask base odor of ingredients and Fragrance blends

package

 Cover odors of soil

 Provide special identity to product

 Provide pleasant odor to clothes

and rooms

Hydrotropes  Prevent liquid products from Cumene sulfonates

separating into layers
Ethyl alcohol
 Ensure product homogeneity
Toluene sulfonates

Xylene sulfonates

Opacifiers  Reduce transparency or make Polymers

product opaque
Titanium dioxide
 Provide a special effect

Preservatives Protect against natural effects of Butylated hydroxytoluene

product aging, e.g., decay, Ethylene diamine

discoloration, oxidation and tetraacetic acid

bacterial attack Glutaraldehyde

Processing aids  Provide important physical Clays

characteristics, e.g., proper pour
Polymers
or flow, viscosity, solubility,
stability and uniform density Sodium silicate

 Assist in manufacturing Sodium sulfate

Solvents

Solvents  Prevent separation or deterioration Ethanol

of ingredients in liquid products
Isopropanol
 Dissolve organic soils
Propylene glycol
 Clean without leaving residue
Solvents used in cleaning products
are water soluble

Suds control agents Ensure optimum sudsing (foaming) level needed for a cleaning job

Suds stabilizers Maintain high sudsing where suds Alkanolamides

level is an important indicator of Alkylamine oxides
 cleaning power

Suds suppressors Control sudsing where suds would Alkyl phosphates

interfere with cleaning action Silicones

Soap

Soaps & Detergents: Manufacturing

Soap and detergent manufacturing consists of a broad range of processing and packaging operations. The size and

complexity of these operations vary from small plants employing a few people to those with several hundred workers.

Products range from large-volume types like laundry detergents that are used on a regular basis to lower-volume

specialties for less frequent cleaning needs.

Cleaning products come in three principal forms: bars, powders and liquids. Some liquid products are so viscous that

they are gels. The first step in manufacturing all three forms is the selection of raw materials. Raw materials are

chosen according to many criteria, including their human and environmental safety, cost, compatibility with other

ingredients, and the form and performance characteristics of the finished product. While actual production processes

may vary from manufacturer to manufacturer, there are steps which are common to all products of a similar form.

Let's start by looking at bar soap manufacturing and then we'll review the processes used to make powder and liquid

detergents.

Traditional bar soaps are made from fats and oils or their

fatty acids which are reacted with inorganic water-soluble

bases. The main sources of fats are beef and mutton tallow, while palm, coconut

and palm kernel oils are the principal oils used in soapmaking. The raw materials

may be pretreated to remove impurities and to achieve the color, odor and

performance features desired in the finished bar. The chemical processes for making soap, i.e., saponification of fats

and oils and neutralization of fatty acids, are described in the Chemistry section.
Soap was made by the batch kettle boiling method until shortly after World War II, when continuous processes were

developed. Continuous processes are preferred today because of their flexibility, speed and economics.

Both continuous and batch processes produce soap in liquid form, called neat soap, and a valuable by-product,

glycerine (1). The glycerine is recovered by chemical treatment, followed by evaporation and refining. Refined

glycerine is an important industrial material used in foods, cosmetics, drugs and many other products.

The next processing step after saponification or neutralization is drying. Vacuum spray drying is used to convert the

neat soap into dry soap pellets (2). The moisture content of the pellets will vary depending on the desired properties

of the soap bar.

In the final processing step, the dry soap pellets pass through a bar soap finishing line. The first unit in the line is a

mixer, called an amalgamator, in which the soap pellets are blended together with fragrance, colorants and all other

ingredients (3). The mixture is then homogenized and refined through rolling mills and refining plodders to achieve

thorough blending and a uniform texture (4). Finally, the mixture is continuously extruded from the plodder, cut into

bar-size units and stamped into its final shape in a soap press (5).

Some of today's bar soaps are called "combo bars," because they get their cleansing action from a combination of
soap and synthetic surfactants. Others, called "syndet bars," feature surfactants as the main cleansing ingredients.
The processing methods for manufacturing the synthetic base materials for these bars are very different from those

used in traditional soapmaking. However, with some minor modifications, the finishing line equipment is the same.

Powder detergents are produced by spray drying, agglomeration, dry mixing or

combinations of these methods.

In the spray drying process, dry and liquid ingredients are first combined into a slurry, or thick suspension, in a tank

called a crutcher (1). The slurry is heated and then pumped to the top of a tower where it is sprayed through nozzles

under high pressure to produce small droplets. The droplets fall through a current of hot air, forming hollow granules

as they dry (2). The dried granules are collected from the bottom of the spray tower where they are screened to

achieve a relatively uniform size (3).

After the granules have been cooled, heat sensitive ingredients that are not compatible with the spray drying

temperatures (such as bleach, enzymes and fragrance) are added (4). Traditional spray drying produces relatively

low density powders.

New technology has enabled the soap and detergent industry to reduce the air inside the granules during spray

drying to achieve higher densities. The higher density powders can be packed in much smaller packages than were

needed previously.

Agglomeration, which leads to higher density powders, consists of blending dry raw materials with liquid ingredients.

Helped by the presence of a liquid binder, rolling or shear mixing causes the ingredients to collide and adhere to each

other, forming larger particles.

Dry mixing or dry blending is used to blend dry raw materials. Small quantities of liquids may also be added.
 Both batch and continuous blending

processes are used to manufacture liquid and gel cleaning products.

Stabilizers may be added during manufacturing to ensure the uniformity and

stability of the finished product.

In a typical continuous process, dry and liquid ingredients are added and

blended to a uniform mixture using in-line or static mixers.

Recently, more concentrated liquid products have been introduced. One method of producing these products uses

new high-energy mixing processes in combination with stabilizing agents.

The final step in the manufacture of soaps and detergents is

packaging. Bar soaps are either wrapped or cartoned in single packs or multipacks.

Detergents, including household cleaners, are packaged in cartons, bottles,

pouches, bags or cans. The selection of packaging materials and containers

involves considerations of product compatibility and stability, cost, package safety,

solid waste impact, shelf appeal and ease of use.