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Mo (CN) 8

The document contains data from experiments measuring the reduction potentials (E) of ox and red species in gas and solvent phases across a range of temperatures from 278K to 338K. A linear trend is observed between E and temperature with a slope of 0.0002 and R^2 value of 1, indicating E becomes less negative with increasing temperature.

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0% found this document useful (0 votes)
42 views17 pages

Mo (CN) 8

The document contains data from experiments measuring the reduction potentials (E) of ox and red species in gas and solvent phases across a range of temperatures from 278K to 338K. A linear trend is observed between E and temperature with a slope of 0.0002 and R^2 value of 1, indicating E becomes less negative with increasing temperature.

Uploaded by

Bis Chem
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Gas Solv

Ox -810.82694331 -811.91251312
Red -810.52623944 -812.01363697
Gas Solv
Ox -810.82798842 -811.9135643
Red -810.52735341 -812.01472416
Gas Solv
Ox -810.82904233 -811.91462423
Red -810.52847631 -812.01582019
Gas Solv
Ox -810.83010495 -811.91569281
Red -810.52960801 -812.01692495
Gas Solv
Ox -810.83117616 -811.91676995
Red -810.53074841 -812.01803834
Gas Solv
Ox -810.83225589 -811.91785555
Red -810.53189741 -812.01916026
Gas Solv
Ox -810.83334403 -811.91894951
Red -810.53305491 -812.0202906
Gas Solv
Ox -810.83444049 -811.92005175
Red -810.5342208 -812.02142927
Gas Solv
Ox -810.83554518 -811.92116217
Red -810.53539499 -812.02257618
Gas Solv
Ox -810.83665801 -811.92228068
Red -810.53657738 -812.02373123
Gas Solv
Ox -810.83777889 -811.9234072
Red -810.53776787 -812.02489433
Gas Solv
Ox -810.83890774 -811.92454163
Red -810.53896638 -812.02606538
Gas Solv
Ox -810.84004447 -811.9256839
Red -810.5401728 -812.0272443
Tempearture Ox Red
Gas Solv Gas
278 -810.82694331 -811.91251312 -810.52623944
283 -810.82798842 -811.9135643 -810.52735341
288 -810.82904233 -811.91462423 -810.52847631
293 -810.83010495 -811.91569281 -810.52960801
298 -810.83117616 -811.91676995 -810.53074841
303 -810.83225589 -811.91785555 -810.53189741
308 -810.83334403 -811.91894951 -810.53305491
313 -810.83444049 -811.92005175 -810.5342208
318 -810.83554518 -811.92116217 -810.53539499
323 -810.83665801 -811.92228068 -810.53657738
328 -810.83777889 -811.9234072 -810.53776787
333 -810.83890774 -811.92454163 -810.53896638
338 -810.84004447 -811.9256839 -810.5401728
Red ∆Ggas ∆∆Gsolv E
Solv
-812.01363697 -188.6925805366 252.1480997832 -1.6782428774
-812.01472416 -188.64937068 252.1274863096 -1.6772629822
-812.01582019 -188.6060792481 252.106847736 -1.676280638
-812.01692495 -188.5627313408 252.0862028872 -1.6752961168
-812.01803834 -188.5193144083 252.0655329384 -1.6743096908
-812.01916026 -188.4758472754 252.0448567146 -1.67332136
-812.0202906 -188.4323236674 252.0241616656 -1.6723313964
-812.02142927 -188.3887561341 252.0034540667 -1.6713400723
-812.02257618 -188.3451446756 251.9827401926 -1.6703471155
-812.02373123 -188.3014955668 251.9620200435 -1.6693527981
-812.02489433 -188.257815083 251.9412936194 -1.6683573922
-812.02606538 -188.214103224 251.9205609203 -1.6673608978
-812.0272443 -188.1703725399 251.8998282212 -1.6663635871
Tempearture E

278 -1.678
E vs T
283 -1.677 -1.658
288 -1.676 250 260 270 280 290 300 310

293 -1.675 -1.66

298 -1.674 -1.662


303 -1.673
-1.664
308 -1.672
313 -1.671 -1.666
f(x) = 0.0002x - 1.7336
318 -1.67 R² = 1
-1.668
323 -1.669
328 -1.668 -1.67
333 -1.667
-1.672
338 -1.666
-1.674

-1.676

-1.678

-1.68
E vs T
280 290 300 310 320 330 340 350

f(x) = 0.0002x - 1.7336


R² = 1

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