Flow Chart of Yarn Dyeing Preparatory Process: Batching
Flow Chart of Yarn Dyeing Preparatory Process: Batching
Preparatory process
Soft winding
↓
Batching
↓
Batch loaded
↓
Demineralization (50˚C, 20 min; PH=4.5)
↓
Scouring & bleaching (100˚C×40 min.)
↓
Drain
↓
Rinse
↓
Drain
↓
Neutralization with acid (50°C ×20 min)
↓
Hot Wash with peroxide killer (60˚C,20 min.)
↓
Drain
↓
Dyeing
↓
Leveling agent & Salt (60° × 20 min; PH=6)
↓
Color dosing (60°C×20 min.)
↓
Run time = 10 min. (60°C)
↓
Color migration (80°C × 20 min.)
↓
Cooling (60°C)
↓
Level Check
↓
Soda dosing (60°C×30 min.)
↓
Dyeing run (Dark-60°C×60 min;Medium-60°C×40 min;Light-60°C×
30 min)
↓
Dyeing sample check
↓
(If Ok)
↓
Drain
↓
After-treatment
↓
Rinse (with cold Water)
↓
Neutralization after dyeing (50°C×20 min.)
↓
Drain
↓
Soaping (Hot wash)
↓
Drain
↓
Rinse
↓
Add finishing chemical(60°C×20 min)
↓
Drain
↓
Unload
Vat dyes:
Vat dyes can't be directly applied and required vatting because it is insoluble in water. But vat dyes fastness properties is good
among the all dyes. The word "vat" means vessels. The dye takes their generic name from vatting. The vat dyes are naturally
obtained coloring materials from the ancient time and kept into wooden vat and make soluble in vat by the process of fermentation-
so it is called vat dyes.
The required water for dyeing is taken in the dye bath and it is maintain at proper temperature (50º- 60 ºC) the reducing and dyeing
temperatures vary from dyestuffs to dyestuff. The vatted dye solution may than be added to the dye bath containing the required
amount of caustic soda sodium hydro sulphate, kept at recommended temperature.
The well scoured wet yarn is entered in the dye bath and turned several times, so that the affinity of the color may be uniform. The
yarn is then kept completely immersed under the dye liquor and the dyeing is continued for one hour. The yarn is turned from time to
time… Care should be taken to keep the bath at required temperature and also to keep the yarn thoroughly immersed under the
liquor.
Fig: Vat dyeing (Image courtesy: www.britannica.com)
The exhaustion agents or retarding agents are added to the dye bath depending upon the dyestuffs taken, during the entire dyeing
period. Excess quantities of both sodium hydroxide (NaoH) and sodium hydro sulphate (Na2s2O4) should be present in the dye
bath in order to keep the dye in the soluble form. At the end of the dyeing the partly or completely exhausted dye bath must be kept
in a distinctly reduced condition; otherwise oxidation of the residual vatted dye takes place in the dye bath itself leading to the
appearance of turbidity. This is ensured by adding sufficient sodium hydro sulphate. The dyed goods may then be removed from the
dye bath and excess liquor which contains the unexhausted vat dye, sodium hydroxide, sodium hydro sulphate is removed as for as
possible from the goods.
The dyed goods are rinsed with cold water and then subjected to an oxidation treatment by exposure to atmospheric oxygen. This is
called “air oxidation” or “airing” but the oxidation may be accelerated by using stronger oxidizing agent such as sodium per borate or
hydrogen peroxide or sodium dichromate in the presence of acetic acid. This process is usually referred to as chemical oxidation.
During the oxidation step the sodium salt of leuco vat dye absorbed by the fiber is oxidized and converted into insoluble dye in the
fiber. At the same time the vatted dye contained in the residual liquor in the goods being dyed also gets converted into the insoluble
form which is loosely deposited on the fibre surface. This loosely deposited dye on the surface of the fiber has to be removed for
achieving optimum fastness properties especially rubbing and washing fastness properties. This is achieved by soaping process.
The dyed material is treated in hot soap solution or a synthetic detergent solution for 15 – 30 minutes. After the soaping treatment
the dyed goods should be rinsed thoroughly and finally the dyed material is dried.
↓
Grey fabric inspection
↓
Batching
↓
Turning
↓
Sewing
↓
Fabric loading
↓
Pretreatment (Scouring & Bleaching)
↓
Enzyme (Antipilling)
↓
Dyeing
↓
Washing
↓
Fixing
↓
Softening/Finishing
↓
Unloading the dyed fabric
Cotton Dyeing Steps:
Enzyme:
Enzymes are protein catalysts produced by living cells that catalyze specific chemical or
biochemical reactions. The use of enzymes in textile processes has gained increased interest due
to the advantages of enzymes being non-toxic, biodegradable, and environmentally friendly.
Enzymes can be safely used in textile wet processing like desizing, scouring, bleaching, dyeing,
and finishing, while traditional chemicals can cause many problems including pollution of
effluents when disposed into the environment. Advances in enzyme technology use in the textile
industry have made it possible to explore the potential of single enzymes or enzyme mixtures for
specific applications. Hydrolases (e.g., amylases, cellulases, pectinases, proteases) and
oxidoreductases have been employed for fabric preparation and finishing.
Enzymes are large high-molecular weight protein structures with highly specific active sites
within the molecule that perform the catalytic reaction. Replacing enzymes with simpler
compounds that mimic the behavior of these biocatalysts could significantly increase the reaction
rate, facilitate the enzymatic process and decrease costs.
Introduction to Enzymes:
Enzymes are a Greek word ‘Enzymos’ meaning ‘in the cell’ or ‘from the cell’. They are the
protein substances made up of more than 250 amino acids. Based on specificity they are
grouped. The concept of treating fabrics with enzymes to improve their surface properties was
first developed in Japan in 1989. The treatment has assumed more important due present concern
of clean and eco-friendly environment under the following group:
They react with their substrates at a region within the protein molecule which is called active
site. The active site of the enzyme must have the necessary structure characteristics to recognize
the right substrate and the proper chemical environment to make the reaction happen.
The enzymes most commonly involved in textile applications are hydrolases and
oxidoreductases. They can be safely used in the textile industry in fabric preparation and
finishing processes.
The process continues until the enzyme is poisoned by a chemical bogie (Fig.2) or inactivated by
extremes of temperature, pH or by other negative conditions in the processing environment.
Pectinases: Which hydrolyse pectins consisting of linear polymers of galacturonic acid (bio-
scouring replacing caustic)
Lipases: Which hydrolyse fats and oils into alcohol and organic acids.
Proteases: Which catalyse splitting protein molecules, and in the extreme may break the protein
into the component amino acids.
Catalases or Peroxidases: Which catalyse the decomposition of peroxide, also known as
peroxide killer.
Enzymatic Desizing :
In the textile industry amylases are used to remove starch-based size for improved and uniform
wet processing. Amylase is a hydrolytic enzyme which catalyses the breakdown of dietary starch
to short chain sugars, dextrin and maltose. The advantage of these enzymes is that they are
specific for starch, removing it without damaging to the support fabric. An amylase enzyme can
be used for desizing processes at low-temperature (30-60ºC) and optimum pH is 5,5-6,5.
Enzymatic Bleaching:
The purpose of cotton bleaching is to decolourise natural pigments and to confer a pure white
appearance to the fibres. The most common industrial bleaching agent is hydrogen peroxide.
Bio-polishing:
Bio-polishing, a technique first adopted by the Danish Firm Novo Nordisk for the finishing
treatment of cellulosic fabrics with cellulase enzymes. The main objectives of the bio-polishing
is to upgrade the quality of the fabric by removing the protruded fibres from the surface and
modification of the surface structure of the fibre, thereby making it soft and smooth. In
conventional process protruded fibres are removed by singing process and smoothness imparted
by chemical treatment. The conventional methods are temporary, fibres return on the surface of
the fabric and chemicals are removed after few washing and fuzz is formed. The fuzz on the
surface spoils the fabric appearance and generates customer’s dissatisfaction whereas
biopolishing is permanent and it not only keeps the fabric in good condition after repeated
washing but also enhances feel, colour, drapeability etc consequently products become more
attractive to the customer and fetch better prices. The bio-polishing treatment offers the
following advantages:
This process has been replaced by proteinases treatment due to their high specificity and much
lower environmental impact. However, proteinase treatment leads to protein degradation,
resulting in deterioration of fiber strength and limited shrink resistance. A patent application
about the use of laccase from T. versicolor plus a mediator to increase the shrink resistance of
wool was published (Yoon 1998). Also, Lantto et al. (2004) found that wool fibers can be
activated with laccase if a suitable mediator is present. Therefore, the use of laccase for anti-
shrink treatment of wool seems very attractive.
Conclusions:
Enzymes can be used in order to develop environmentally friendly alternatives to chemical
processes in almost all steps of textile fibre processing. There are already some commercially
successful applications, such as amylases for desizing, cellulases and laccases for denim
finishing, and proteases incorporated in detergent formulations. Further research is required for
the implementation of commercial enzyme based processes for the biomodification of synthetic
and natural fibers. There is still considerable potential for new and improved enzyme
applications in future textile processing.
As with all chemicals and products, enzymes too have their own merits and limitations. They
show specific action without undesirable effects on other components and normally operate
under mild temperature and pressure conditions, but at the same time are sensitive to
temperature, pH, humidity and contaminants. They often shorten the process cycle reducing
time, water consumption and wastewater generation. The main hindrance in using enzymes is
their high cost. The textile industry was identified as a key sector where opportunities available
from adapting biotechnology are high but current awareness of biotechnology is low. In textile
processing the enzyme can be successfully used for preparatory process like desizing, scouring
and bleaching. These enzymatic processes are gives the similar results as that of conventional
methods. Though this enzymatic processes we can reduce the water consumption, power energy,
pollution, time, and increasing quality.
Enzymes are emerging in a big way in the field of textile wet processing. If their cost can be
managed, enzymes can be put to use in a much bigger way for textile processing applications.
Printing Processes:
There are five main methods of printing a fabric, these being the block, roller, screen, heat
transfer and ink-jet methods. The heat transfer method differs from the others in that it involves
the transfer of color from the design printed on paper through the vapour phase into the fibres of
the fabric. With the other methods the dye or pigment is applied to the fabric surface through a
print paste medium. The ink jet printing process however is a comparatively recent innovation
and is referred to as a 'non-impact' method, because the print paste is fired on to the textile from
a jet which is not actually in contact with the fabric.
Block Printing:
The blocks are usually made of wood and the design is hand carved, so that it stands out in relief
against the background surface. The print paste is applied to the design surface on the block and
the block then pressed against the fabric. The process is repeated with different designs and
colours until the pattern is complete.
Block printing is a slow, laborious process and is not suitable for high volume commercial use.
It is a method still practised in the oriental countries where markets exist for the types of printed
fabrics produced.
Roller Printing:
Roller printing has traditionally been preferred for long production runs because of the very
high speeds possible. It is also a versatile technique since up to a dozen different colours can be
printed simultaneously. The basic roller printing equipment, shown in below figure, consists of a
number of copper faced rollers in which the design is etched. There is a separate printing roller
for each colour being printed. Each of the rollers rotates over the fabric under pressure against an
iron pressure roller. A blanket and backing cloth rotate over the pressure roller under the fabric
and provide a flexible support for the fabric being printed. A colour doctor blade removes paste
or fibres adhering to the roller after contact with the fabric. After the impression stage the fabric
passes to the drying and steaming stages.
Roller Printing
Screen Printing :
This type of printing has increased enormously in its use in recent years because of its versatility
and the development of rotary screen printing machines which are capable of very high rates of
production. An additional significant advantage is that heavy depths of shade can be produced by
screen printing, a feature which has always been a limitation of roller printing because of the
restriction to the amount of print paste which can be held in the shallow depth of the engraving
on the print roller. Worldwide, some 61% of all printed textile fabric is produced by the rotary
screen method and 23% by flat screen printing.
There are two basic types of screen printing process, the flat screen printing and the rotary
screen printing methods.
Ink-Jet Printing :
There has been considerable interest in the technology surrounding non-impact printing, mainly
for the graphic market, but the potential benefits of reductions in the time scale from original
design to final production has led to much activity in developing this technology for textile and
carpet printing processes. The types of machines developed fall into two classes, drop-on-
demand (DOD) and continuous stream (CS).
Carpet Printing :
The printing of carpets only really achieved importance after the introduction of tufted carpets in
the late 1950s. Until then the market was dominated by the woven Wilton carpets and Axminster
designs were well established, but by the 1980s tufted carpet production accounted for some
80% (by area) of UK production. Much of this carpet production was printed because the range
of patterns possible to produce using tufting machines was limited and there was a desire to
produce a greater flexibility of design for these types of carpet.
Warp Printing:
The printing of a design on the sheet of warp yarns before weaving. The filling is either white or
a neutral color, and a grayed effect is produced in the areas of the design.
Resist Printing:
A printing method in which the design can be produced: (1) by applying a resist agent in the
desired design, then dyeing the fabric, in which case, the design remains white although the rest
of the fabric is dyed; or (2) by including a resist agent and a dye in the paste which is applied for
the design, in which case, the color of the design is not affected by subsequent dyeing of the
fabric background.
Photographic Printing:
A method of printing from photoengraved rollers. The resultant design looks like a photograph.
The designs may also be photographed on a silk screen which is used in screen printing.
Pigment Printing:
Printing by the use of pigments instead of dyes. The pigments do not penetrate the fiber but are
affixed to the surface of the fabric by means of synthetic resins which are cured after application
to make them insoluble. The pigments are insoluble, and application is in the form of water-in-
oil or oil-in-water emulsions of pigment pastes and resins. The colors produced are bright and
generally fat except to crocking.
Blotch Printing:
A process wherein the background color of a design is printed rather than dyed.
Burn-Out Printing:
A method of printing to obtain a raised design on a sheer ground. The design is applied with a
special chemical onto a fabric woven of pairs of threads of different fibers. One of the fibers is
then destroyed locally by chemical action. Burn-out printing is often used on velvet. The product
of this operation is known as a burnt-out print.
Direct Printing:
A process wherein the colors for the desired designs are applied directly to the white or dyed
cloth, as distinguished from discharge printing and resist printing.
Discharge Printing:
In “white” discharge printing, the fabric is piece dyed, then printed with a paste containing a
chemical that reduces the dye and hence removes the color where the white designs are desired.
In “colored” discharge printing, a color is added to the discharge paste in order to replace the
discharged color with another shade.
Duplex Printing:
A method of printing a pattern on the face and the back of a fabric with equal clarity.
Oxford cloth
Oxford cloth is a very popular shirting fabric, particularly for more casual or sporty
styles of dress shirts. It’s a bit thicker than what we’d consider “fine” dress shirt
fabrics, and has a hearty feel that is both durable and naturally resistant to
wrinkles. Oxford cloths can be found in a variety of qualities.
40/1×24/2: This is the classic heavier weight oxford cloth. These are
generally much thicker than the average shirt fabric. Make for really great casual
shirts. They are very durable and can be washed/dried with your socks and t-shirts
and worn a bit wrinkly. A good one will be quite soft to the touch and get better
with age.
80s two-ply: This is the classic pinpoint oxford cloth. It’s a nice quality
oxford cloth weave with a dense enough texture that works well for conservative
business settings. Thicker than broadcloth and relatively opaque, this is the classic
Brooks Brothers style shirt.
75/2×38/3: This construction comes from Thomas Mason and is what we
like to call a “premium oxford”. It has a similar thickness and heartiness to the
basic heavy oxford, but it is simultaneously a bit smoother and more refined. The
result is a shirt that looks great a bit rumpled casually, but can also be ironed up
sharp for a slick suited look.
50s single-ply: A crisp but lighter weight oxford. Can usually be found in
interesting patterns or colors. In appropriate patterns these can make for great
business shirts or relatively sharp casual shirts.
Overall, a nice casual oxford cloth shirt is a wardrobe essential for its durability
and versatility. Pair it with a button down collar for the low-maintenance OCBD.
Flow Chart of Woven Dyeing
Steaming
↓
Washing
↓
Dryeing
↓
Heat setting
↓
Finishing (Pre-shrinkage)
↓
Finished fabric
↓
Package
Flow Chart & Checking Points
Woven Solid Dyed Fabrics
1. Physicsl : Length, Width, Weight, Density, Composition, Tear Strength. As a result, grade A, B, C will be setted for
2. Appearance : Fabric defects including knots, holes etc. Dyeing or printing or return purpose
Remarks : Better to use same lot of greige fabric from same supplier for one order.
1. Physical : pH, Whiteness, Resin%, Capillarity effect / TEGEWA –Drop Test (Absorbency), TEGEWA-Violet-blue scale
(Degree of desize)
2. Appearance : Fabric Defects
3. Width (especially stretch fabric
* Stretch fabric need test shrinkage after each step of Scouring, bleaching & Mercerization.
Checking point (Finishing) : Compare width approved sample for handfeel, brush or other special treatment as per requirement.
Tear strength ( peach finish ) in case of finishing like Wrinkle free, tear strength, pH, smell
Checking point (Finished fabric): Final fabric inspection according to our fabric inspection guidline.
Checking point (Package) : Label including order no, width, composition, color, bale no.
Topping means Black color top (Sulfar) nd Blue color Bottom (Indigo)
And because it is made with knit and purl stitches it's a great stitch pattern for beginner
knitters to practice with.
222Save
All you do is alternate the knit and purl stitches which creates the bumps, just like waffles. I
love the textured feel of this too. Nice and squishy.
o It lies flat
o It's very stretchy
o Great for beginning knitters
o You'll have the pattern memorized after a couple of rounds
It's not really reversible but the wrong side doesn't look too bad. You'll have to decide for
yourself when you knit it.
Wouldn't it make a really nice tea towel set? Or even some nice table placemats. What a
great way to add a splash of color to your kitchen.
If you are going to be making any knit gifts like hats, socks, mittens, things like that and you
don't have the exact size, you can use this stitch pattern.
That way if you do knit something a little small it will stretch. You know what I mean? It's just
a nice thought to keep in mind when the time rolls around for making gifts.
This lovely stitch pattern would make terrific thermal knit under garments. What a great way
to keep your kids, toddlers and babies nice and warm when they're outside. Just don't forget
to make yourself some too.
Scarves, cowls and fingerless mittens are all great ideas as well so go ahead and get
started with this simple stitch pattern and let your imagination flow.
Multiple of 3 sts + 1
If you'd like to knit a sample cast on 13, 16, 19 or 22 stitches.
Row 3: Knit
Would you like to practice with a cool knitting pattern? I just happen to have one for you.
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I used the waffle stitch for my super scarf so you could practice.