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Hess's Law Reaction Calculations

This document contains 5 practice problems for calculating enthalpy change (ΔH) values for chemical reactions using Hess's Law and given thermochemical data. Each problem provides the thermochemical equations and enthalpy change values needed to calculate the ΔH for a given reaction. The answers to each problem are also provided.

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402 views1 page

Hess's Law Reaction Calculations

This document contains 5 practice problems for calculating enthalpy change (ΔH) values for chemical reactions using Hess's Law and given thermochemical data. Each problem provides the thermochemical equations and enthalpy change values needed to calculate the ΔH for a given reaction. The answers to each problem are also provided.

Uploaded by

Ori Sein
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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ENG 201: Hess’s Law Exercises

1. Calculate ΔH for the reaction: C2H4 (g) + H2 (g) --> C2H6 (g), from the following Data:
C2H4 (g) + 3 O2 (g) --> 2 CO2 (g) + 2 H2O (l) ΔH = -1411. kJ

C2H6 (g) + 3½ O2 (g) --> 2 CO2 (g) + 3 H2O (l) ΔH = -1560. kJ

H2 (g) + ½ O2 (g) --> H2O (l) ΔH = -285.8 kJ

Answer: -137 kJ

2. Calculate ΔH for the reaction 4 NH3 (g) + 5 O2 (g) à 4 NO (g) + 6 H2O (g), from the following Data:
N2 (g) + O2 (g) à 2 NO (g) ΔH = -180.5 kJ

N2 (g) + 3 H2 (g) à 2 NH3 (g) ΔH = -91.8 kJ

2 H2 (g) + O2 (g) à 2 H2O (g) ΔH = -483.6 kJ

Answer: -1628 kJ

3. Find
ΔH° for the reaction 2H2(g) + 2C(s) + O2(g) --> C2H5OH(l), using the following thermochemical data.
C2H5OH (l) + 2 O2 (g) --> 2 CO2 (g) + 2 H2O (l) ΔH = -875. kJ

C (s) + O2 (g) --> CO2 (g) ΔH = -394.51 kJ

H2 (g) + ½ O2 (g) --> H2O (l) ΔH = -285.8 kJ

Answer: -486 kJ

4. Calculate
ΔH for the reaction CH4 (g) + NH3 (g) à HCN (g) + 3 H2 (g), given:
N2 (g) + 3 H2 (g) à 2 NH3 (g) ΔH = -91.8 kJ

C (s) + 2 H2 (g) à CH4 (g) ΔH = -74.9 kJ

H2 (g) + 2 C (s) + N2 (g) à 2 HCN (g) ΔH = +270.3 kJ

Answer: +256 kJ

5. Calculate ΔH for the reaction 2 Al (s) + 3 Cl2 (g) --> 2 AlCl3 (s) from the Data.
2 Al (s) + 6 HCl (aq) --> 2 AlCl3 (aq) + 3 H2 (g) ΔH = -1049. kJ

HCl (g) --> HCl (aq) ΔH = -74.8 kJ

H2 (g) + Cl2 (g) --> 2 HCl (g) ΔH = -1845. kJ

AlCl3 (s) --> AlCl3 (aq) ΔH = -323. kJ

Answer: -6387 kJ

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