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Module 8 Thermochemistry

1) The document discusses the experimental determination of heat of reactions using a calorimeter. A sample undergoes a chemical reaction either absorbing or releasing heat which causes a change in temperature that is measured. 2) Formulas are provided to calculate the heat of reaction based on the mass of the sample, specific heat capacity of the calorimeter contents, and the temperature change. 3) Standard heats of formation are listed for several common compounds that can be used to calculate heats of reaction from balanced chemical equations.

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Nard Emsoc
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69 views33 pages

Module 8 Thermochemistry

1) The document discusses the experimental determination of heat of reactions using a calorimeter. A sample undergoes a chemical reaction either absorbing or releasing heat which causes a change in temperature that is measured. 2) Formulas are provided to calculate the heat of reaction based on the mass of the sample, specific heat capacity of the calorimeter contents, and the temperature change. 3) Standard heats of formation are listed for several common compounds that can be used to calculate heats of reaction from balanced chemical equations.

Uploaded by

Nard Emsoc
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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A.
B.
C.
D.
E.
F.
G.




J
CCu= ?
g x °C

q
C
m x ΔT
=
q
CCu = m x ΔT

CCu 849 J = 0.387 J


95.4 g x 23.0°C g x °C
=

COMPOUND ΔH⁰f(kJ/mole)
H2O(g) -241.83
H2O(l) -285.84
CO2(g) -393.5
CO(g) -110.5
CH4(g) -74.87
C2H2(g) 227
C2H4(g) 52.47
C2H6(g) -84.667
C6H12O6(s) -1273.3
C12H22O11(s) -2221.7
C2H5OH(g) -235.1
C2H5OH(l) -277.63
HCI(g) -92.31
NH3(g) -45.9
NO(g) 90.29
NO2(G) 33.2
SO2(g) -296.8
SO3(g) -396
CaCO3(s) -1206.9

𝚺 𝚺


⧍
⧍ ⧍ ⧍ ⧍ ⧍

⧍
 






1.00𝑔
( )
𝑚𝐿

1𝑘𝐽
( )
1000𝐽
1
⧍
2

ᶾ 
 ⧍

 ⧍

 

129𝑘𝐽
2𝑚𝑜𝑙𝑁𝑎𝐻𝐶𝑂3(𝑠)

129𝑘𝐽
2𝑚𝑜𝑙𝑁𝑎𝐻𝐶𝑂3(𝑠)

 ⧍
Objectives:
At the end of this lesson you
should be able to:
1. Explain the principle involved
in the experiment method for
the determination of heats of
reaction, and
2. Determine the heat of a
reaction experimentally.
⁻



a. 

b. 













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