SAFETY DATA SHEET

BUNX915

Section 1. Identification
Product name : DUPLI-COLOR® UNIVERSAL Touch Up Pen
Silver
Product code : BUNX915
Other means of : Not available.
identification
Product type : Liquid.
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.

Manufacturer : Dupli-Color Products Company

Cleveland, OH 44115

Emergency telephone : (216) 566-2917

number of the company
Product Information : (800) 247-3270
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 2
substance or mixture ACUTE TOXICITY (oral) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 2.4%
(oral), 51.9% (dermal), 20.9% (inhalation)
GHS label elements
Hazard pictograms :

Signal word : Danger

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Section 2. Hazards identification
Hazard statements : Highly flammable liquid and vapor.
Harmful if swallowed.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Suspected of causing cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to organs through prolonged or repeated exposure. (lungs)
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves, protective clothing and eye or face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment.
Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or
in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using
this product. Wash thoroughly after handling.
Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor if you feel unwell. IF SWALLOWED: Call a POISON CENTER or doctor if you
feel unwell. Rinse mouth. IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water. IF ON SKIN: Wash with plenty of water. If skin irritation
occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If
eye irritation persists: Get medical advice or attention.
Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep
cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
elements can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Other means of : Not available.
identification
CAS number/other identifiers

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Section 3. Composition/information on ingredients
Ingredient name % by weight CAS number
Methyl Ethyl Ketone ≥25 - ≤50 78-93-3
Toluene ≥10 - ≤25 108-88-3
Ethyl 3-Ethoxypropionate ≥10 - ≤25 763-69-9
Methyl Isobutyl Ketone ≤10 108-10-1
Ethanol ≤5 64-17-5
Cellulose Nitrate ≤3 9004-70-0
Mica ≤3 12001-26-2
2-Propanol ≤3 67-63-0
Titanium Dioxide ≤1 13463-67-7
Xylene, mixed isomers <1 1330-20-7
Med. Aliphatic Hydrocarbon Solvent ≤0.3 64742-88-7
Ethylbenzene ≤0.3 100-41-4
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. If necessary,
call a poison center or physician. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
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Section 4. First aid measures
Ingestion : Harmful if swallowed. Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
from the chemical In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.

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Section 5. Fire-fighting measures
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or

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Section 7. Handling and storage
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated
incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits (OSHA United States)
Ingredient name CAS # Exposure limits
Methyl Ethyl Ketone 78-93-3 ACGIH TLV (United States, 3/2020).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 200 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
Toluene 108-88-3 OSHA PEL Z2 (United States, 2/2013).
TWA: 200 ppm 8 hours.
CEIL: 300 ppm
AMP: 500 ppm 10 minutes.
NIOSH REL (United States, 10/2016).
TWA: 100 ppm 10 hours.
TWA: 375 mg/m³ 10 hours.
STEL: 150 ppm 15 minutes.
STEL: 560 mg/m³ 15 minutes.
ACGIH TLV (United States, 3/2020).
TWA: 20 ppm 8 hours.
Ethyl 3-Ethoxypropionate 763-69-9 None.
Methyl Isobutyl Ketone 108-10-1 ACGIH TLV (United States, 3/2020).
TWA: 20 ppm 8 hours.
STEL: 75 ppm 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 205 mg/m³ 10 hours.
STEL: 75 ppm 15 minutes.

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Section 8. Exposure controls/personal protection
STEL: 300 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 410 mg/m³ 8 hours.
Ethanol 64-17-5 ACGIH TLV (United States, 3/2020).
STEL: 1000 ppm 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 1000 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.
Cellulose Nitrate 9004-70-0 None.
Mica 12001-26-2 ACGIH TLV (United States, 3/2020).
TWA: 3 mg/m³ 8 hours. Form: Respirable
fraction
NIOSH REL (United States, 10/2016).
TWA: 3 mg/m³ 10 hours. Form: Respirable
fraction
OSHA PEL Z3 (United States, 6/2016).
TWA: 20 mppcf 8 hours.
2-Propanol 67-63-0 ACGIH TLV (United States, 3/2020).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2020).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 3/2020).
TWA: 100 ppm 8 hours.
TWA: 434 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 651 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
Med. Aliphatic Hydrocarbon Solvent 64742-88-7 OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 400 mg/m³ 8 hours.
Ethylbenzene 100-41-4 ACGIH TLV (United States, 3/2020).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 100 ppm 10 hours.
TWA: 435 mg/m³ 10 hours.
STEL: 125 ppm 15 minutes.
STEL: 545 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.

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Section 8. Exposure controls/personal protection
Occupational exposure limits (Canada)
Ingredient name CAS # Exposure limits
Methyl ethyl ketone 78-93-3 CA Alberta Provincial (Canada, 6/2018).
15 min OEL: 300 ppm 15 minutes.
8 hrs OEL: 200 ppm 8 hours.
8 hrs OEL: 590 mg/m³ 8 hours.
15 min OEL: 885 mg/m³ 15 minutes.
CA British Columbia Provincial (Canada,
1/2020).
TWA: 50 ppm 8 hours.
STEL: 100 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 200 ppm 8 hours.
STEL: 300 ppm 15 minutes.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 50 ppm 8 hours.
TWAEV: 150 mg/m³ 8 hours.
STEV: 100 ppm 15 minutes.
STEV: 300 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 300 ppm 15 minutes.
TWA: 200 ppm 8 hours.
Toluene 108-88-3 CA Alberta Provincial (Canada, 6/2018).
Absorbed through skin.
8 hrs OEL: 50 ppm 8 hours.
8 hrs OEL: 188 mg/m³ 8 hours.
CA British Columbia Provincial (Canada,
1/2020).
TWA: 20 ppm 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 20 ppm 8 hours.
CA Quebec Provincial (Canada, 7/2019).
Absorbed through skin.
TWAEV: 50 ppm 8 hours.
TWAEV: 188 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013). Absorbed through skin.
STEL: 60 ppm 15 minutes.
TWA: 50 ppm 8 hours.
Methyl isobutyl ketone 108-10-1 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 205 mg/m³ 8 hours.
8 hrs OEL: 50 ppm 8 hours.
15 min OEL: 75 ppm 15 minutes.
15 min OEL: 307 mg/m³ 15 minutes.
CA British Columbia Provincial (Canada,
1/2020).
TWA: 20 ppm 8 hours.
STEL: 75 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 20 ppm 8 hours.
STEL: 75 ppm 15 minutes.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 50 ppm 8 hours.
TWAEV: 205 mg/m³ 8 hours.
STEV: 75 ppm 15 minutes.
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Section 8. Exposure controls/personal protection
STEV: 307 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 75 ppm 15 minutes.
TWA: 50 ppm 8 hours.

Ethyl alcohol 64-17-5 CA Alberta Provincial (Canada, 6/2018).

8 hrs OEL: 1000 ppm 8 hours.
8 hrs OEL: 1880 mg/m³ 8 hours.
CA British Columbia Provincial (Canada,
1/2020).
STEL: 1000 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
STEL: 1000 ppm 15 minutes.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 1000 ppm 8 hours.
TWAEV: 1880 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 1250 ppm 15 minutes.
TWA: 1000 ppm 8 hours.
Isopropyl alcohol 67-63-0 CA Alberta Provincial (Canada, 6/2018).
15 min OEL: 984 mg/m³ 15 minutes.
8 hrs OEL: 200 ppm 8 hours.
15 min OEL: 400 ppm 15 minutes.
8 hrs OEL: 492 mg/m³ 8 hours.
CA British Columbia Provincial (Canada,
1/2020).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 400 ppm 8 hours.
TWAEV: 983 mg/m³ 8 hours.
STEV: 500 ppm 15 minutes.
STEV: 1230 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 400 ppm 15 minutes.
TWA: 200 ppm 8 hours.
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
1/2020).
TWA: 10 mg/m³ 8 hours. Form: Total dust
TWA: 3 mg/m³ 8 hours. Form: respirable
fraction
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 10 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.

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Section 8. Exposure controls/personal protection
Xylene 1330-20-7 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 100 ppm 8 hours.
15 min OEL: 651 mg/m³ 15 minutes.
15 min OEL: 150 ppm 15 minutes.
8 hrs OEL: 434 mg/m³ 8 hours.
CA British Columbia Provincial (Canada,
1/2020).
TWA: 100 ppm 8 hours.
STEL: 150 ppm 15 minutes.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 100 ppm 8 hours.
TWAEV: 434 mg/m³ 8 hours.
STEV: 150 ppm 15 minutes.
STEV: 651 mg/m³ 15 minutes.
CA Ontario Provincial (Canada, 6/2019).
STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.
Ethylbenzene 100-41-4 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 100 ppm 8 hours.
8 hrs OEL: 434 mg/m³ 8 hours.
15 min OEL: 543 mg/m³ 15 minutes.
15 min OEL: 125 ppm 15 minutes.
CA British Columbia Provincial (Canada,
1/2020).
TWA: 20 ppm 8 hours.
CA Ontario Provincial (Canada, 6/2019).
TWA: 20 ppm 8 hours.
CA Quebec Provincial (Canada, 7/2019).
TWAEV: 100 ppm 8 hours.
TWAEV: 434 mg/m³ 8 hours.
STEV: 125 ppm 15 minutes.
STEV: 543 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 125 ppm 15 minutes.
TWA: 100 ppm 8 hours.

Occupational exposure limits (Mexico)

CAS # Exposure limits
Methyl Ethyl Ketone 78-93-3 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 200 ppm 8 hours.
STEL: 300 ppm 15 minutes.
Toluene 108-88-3 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 20 ppm 8 hours.
Methyl Isobutyl Ketone 108-10-1 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 50 ppm 8 hours.
STEL: 75 ppm 15 minutes.
ethanol 64-17-5 NOM-010-STPS-2014 (Mexico, 4/2016).
STEL: 1000 ppm 15 minutes.
2-Propanol 67-63-0 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.

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Section 8. Exposure controls/personal protection
Ethylbenzene 100-41-4 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 20 ppm 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not applicable.
Melting point/freezing point : Not available.
Boiling point/boiling range : 77°C (170.6°F)

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Section 9. Physical and chemical properties
Flash point : Closed cup: 2°C (35.6°F) [Pensky-Martens Closed Cup]
Evaporation rate : 5.6 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 1%
(flammable) limits Upper: 19%
Vapor pressure : 12.1 kPa (90.6 mm Hg) [at 20°C]
Vapor density : 1.5 [Air = 1]
Relative density : 0.92
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Molecular weight : Not applicable.
Aerosol product
Heat of combustion : 23.605 kJ/g

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.

Incompatible materials : Reactive or incompatible with the following materials:

oxidizing materials

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg/kg -
LD50 Oral Rat 2737 mg/kg -
Toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours
LD50 Oral Rat 636 mg/kg -
Ethyl 3-Ethoxypropionate LD50 Oral Rat 3200 mg/kg -
Methyl Isobutyl Ketone LD50 Oral Rat 2080 mg/kg -
Ethanol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours
LD50 Oral Rat 7 g/kg -
Cellulose Nitrate LD50 Oral Rat >5 g/kg -
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Section 11. Toxicological information
2-Propanol LD50 Dermal Rabbit 12800 mg/kg -
LD50 Oral Rat 5000 mg/kg -
Xylene, mixed isomers LC50 Inhalation Gas. Rat 6700 ppm 4 hours
LD50 Oral Rat 4300 mg/kg -
Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Methyl Ethyl Ketone Skin - Mild irritant Rabbit - 24 hours 14 -
mg
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Toluene Eyes - Mild irritant Rabbit - 0.5 minutes -
100 mg
Eyes - Mild irritant Rabbit - 870 ug -
Eyes - Severe irritant Rabbit - 24 hours 2 -
mg
Skin - Mild irritant Pig - 24 hours 250 -
uL
Skin - Mild irritant Rabbit - 435 mg -
Skin - Moderate irritant Rabbit - 24 hours 20 -
mg
Skin - Moderate irritant Rabbit - 500 mg -
Ethyl 3-Ethoxypropionate Skin - Mild irritant Rabbit - 24 hours 500 -
mg
Methyl Isobutyl Ketone Eyes - Moderate irritant Rabbit - 24 hours 100 -
uL
Eyes - Severe irritant Rabbit - 40 mg -
Skin - Mild irritant Rabbit - 24 hours 500 -
mg
Ethanol Eyes - Mild irritant Rabbit - 24 hours 500 -
mg
Eyes - Moderate irritant Rabbit - 0.066666667 -
minutes 100
mg
Eyes - Moderate irritant Rabbit - 100 uL -
Eyes - Severe irritant Rabbit - 500 mg -
Skin - Mild irritant Rabbit - 400 mg -
Skin - Moderate irritant Rabbit - 24 hours 20 -
mg
2-Propanol Eyes - Moderate irritant Rabbit - 24 hours 100 -
mg
Eyes - Moderate irritant Rabbit - 10 mg -
Eyes - Severe irritant Rabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 -
ug I
Xylene, mixed isomers Eyes - Mild irritant Rabbit - 87 mg -
Eyes - Severe irritant Rabbit - 24 hours 5 -
mg
Skin - Mild irritant Rat - 8 hours 60 uL -
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Skin - Moderate irritant Rabbit - 100 % -
Ethylbenzene Eyes - Severe irritant Rabbit - 500 mg -
Skin - Mild irritant Rabbit - 24 hours 15 -
mg

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Section 11. Toxicological information
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.

Classification
Product/ingredient name OSHA IARC NTP
Toluene - 3 -
Methyl Isobutyl Ketone - 2B -
Ethanol - 1 -
2-Propanol - 3 -
Titanium Dioxide - 2B -
Xylene, mixed isomers - 3 -
Ethylbenzene - 2B -
Reproductive toxicity
Not available.

Teratogenicity
Not available.

Specific target organ toxicity (single exposure)

Name Category Route of Target organs
exposure
Methyl Ethyl Ketone Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Toluene Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Methyl Isobutyl Ketone Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Ethanol Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
2-Propanol Category 3 - Narcotic effects
Xylene, mixed isomers Category 3 - Respiratory tract
irritation
Med. Aliphatic Hydrocarbon Solvent Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Ethylbenzene Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)

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Section 11. Toxicological information
Name Category Route of Target organs
exposure
Methyl Ethyl Ketone Category 2 - -
Toluene Category 2 - -
Methyl Isobutyl Ketone Category 2 - -
Ethanol Category 2 - -
Mica Category 1 inhalation lungs
Xylene, mixed isomers Category 2 - -
Med. Aliphatic Hydrocarbon Solvent Category 1 - -
Ethylbenzene Category 2 - -
Aspiration hazard
Name Result
Toluene ASPIRATION HAZARD - Category 1
Xylene, mixed isomers ASPIRATION HAZARD - Category 1
Med. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1
Ethylbenzene ASPIRATION HAZARD - Category 1

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Harmful if swallowed. Can cause central nervous system (CNS) depression.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations

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Section 11. Toxicological information
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.

General : Causes damage to organs through prolonged or repeated exposure.

Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Oral 1859.2 mg/kg
Inhalation (vapors) 160.51 mg/l

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Methyl Ethyl Ketone Acute EC50 >500000 µg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 5091000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Larvae
Acute LC50 3220000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Toluene Acute EC50 12500 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 11600 µg/l Fresh water Crustaceans - Gammarus 48 hours
pseudolimnaeus - Adult
Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Acute LC50 5500 µg/l Fresh water Fish - Oncorhynchus kisutch - Fry 96 hours
Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days
Methyl Isobutyl Ketone Acute LC50 505000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas - 33 days
Embryo
Ethanol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 25500 µg/l Marine water Crustaceans - Artemia 48 hours

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Section 12. Ecological information
franciscana - Larvae
Acute LC50 42000 µg/l Fresh water Fish - Oncorhynchus mykiss 4 days
Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 100 ul/L Fresh water Daphnia - Daphnia magna - 21 days
Neonate
Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - 12 weeks
Larvae
Cellulose Nitrate Acute EC50 579000 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
2-Propanol Acute EC50 7550 mg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 4200 mg/l Fresh water Fish - Rasbora heteromorpha 96 hours
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours
Ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Acute EC50 6.53 mg/l Marine water Crustaceans - Artemia sp. - 48 hours
Nauplii
Acute EC50 2.93 mg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours

Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
Methyl Ethyl Ketone - - Readily
Toluene - - Readily
Methyl Isobutyl Ketone - - Readily
Ethanol - - Readily
2-Propanol - - Readily
Xylene, mixed isomers - - Readily
Ethylbenzene - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Toluene - 90 low
Xylene, mixed isomers - 8.1 to 25.9 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

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Section 13. Disposal considerations
Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.

Section 14. Transport information

DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1263 UN1263 UN1263 UN1263 UN1263

UN proper PAINT PAINT PAINT PAINT PAINT

shipping name
Transport 3 3 3 3 3
hazard class(es)

Packing group II II II II II
Environmental No. No. No. No. No.
hazards
Additional - Product classified - - Emergency
information as per the schedules F-E, S-
following sections E
of the
Transportation of
Dangerous Goods
Regulations:
2.18-2.19 (Class
3).
ERG No. ERG No. ERG No.
128 128 128

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Section 14. Transport information
Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.
Transport in bulk according : Not available.
to IMO instruments
Proper shipping name : Not available.

Section 15. Regulatory information

SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
International regulations
International lists : Australia inventory (AIIC): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (CSCL): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health * 3

Flammability 3

Physical hazards 0

The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
Procedure used to derive the classification

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Section 16. Other information
Classification Justification
FLAMMABLE LIQUIDS - Category 2 On basis of test data
ACUTE TOXICITY (oral) - Category 4 Calculation method
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
CARCINOGENICITY - Category 2 Calculation method
TOXIC TO REPRODUCTION - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Calculation method
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Calculation method
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Calculation method
History
Date of printing : 6/25/2021
Date of issue/Date of : 6/25/2021
revision
Date of previous issue : 4/13/2021
Version : 11.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.

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