Printing
Printing
The textile printing is the art of design by mechanical and chemical application.
It entails the localized of dye of pigment the design being created by different
colour or motives.
OR
By the term “ Textile printing” we mean the localized application of dyes or
pigments and chemicals by any method which can produce particular effect of
colour on the fabric according to the design.
Steps/stages of printing:
Grey textiles / Raw materials
↓
Preparation of textile mtls
( singening, desizing , bleaching scouring)
Preparation of printing paste
Printing (with a certain style and method)
Drying of the printed fabric (in the drier)
Steaming of the printed fabric
(to transfer dye into fibre, 100-1020 C, 15 min in a steamer)
After treatment (Soaping of washing)
1. Direct style: The dyes are printed directly at the required places of the
multicolored design on the fabric, leaving the other portions white. Thus a
multi-colored print on a white ground can be produced.
Green Green
White Green
Red Red
Color resist:
Coloring mtl is added to the print past with resist salt
The printed area contain the color added to print paste and the remaining areas will
contain the color of dye sol.
2). Padding: Then napthalation occurs i.e. napthol is added to the fabric.
The printing of B napthol is an example of azoic style of printing.
(6) Raised style: It is the same process of white discharge style of printing.
(7) Metal style: In this style of printing some spangle type metals are printed on the fabric
as it will be brighter.
(9) Creep style: In this style, printing is performed after alkali treatment or heat setting.
Difference bet Discharge style of printing & Resist:
Discharge Style Resist style of printing
1. It is always sharp in outline, bright 1. It is less sharp in out line and less
in appearance bright
2. Discharging agent used 2. Resist salt used
3. Strong chemical reaction is 3. No chemical reaction due to pre
required dyeing
4. At first the fabric is dyed and then 4. At first reisting salt printed, and
discharging printing then fabric is dyed.
5. Two or more coloured can be dyed 5. Only two class can be dyed
at a time
6. Discharging agent destroy pre 6. Resisting salt resist to be fixed of
fixed dye of fabric colour on the fabric
7. The cost of discharging agent is 7. Cheap
high
8. More wastages of dye 8. Less wastage of dye
2
Thickener
Definition: Thickener is a thick mass which imparts stickiness and plasticity to the
print paste so that it may be applied on the fabric surface without bleeding or
spreading and be capable of maintaining the design out lines.
Thickener Preparation:
1. Starch and Starch derivatives:
Starch is a homopolymer of glucose. It consists of 20-30% linear Amylose and
80-70% branched Amylopoctire. Normally 10% Starch paste is prepared.
CH2OH CH2OH
H OH H OH
H H
OH H OH H
OH O O
H OH H OH
CH 2
C H 2O H
H O H H O H
H H
OH H OH H
OH O O
H OH H OH
A p a rt o f a m y lo p e c tin (B ra n c h e d c h a in )
Recipe:
Starch – 100 parts
Water – 900 parts
Total – 1000 parts
Time – 15 min.
Temp. – Maximum 600 c
Procedure: At first starch is immersed to the cold water according to Recipe. Then temp.
is increased gradually to boiling. Starch starts to swollen up to 70 0 c. In this way after
boiling 15 min. a required viscosity of starch thickener is prepared.
3. Starch Tragacanth:
Recipe: Wheat starch- 400 parts.
Gum tragacanth-600 “
Temp -1000 c
H O O H H O O
H H O O H
O
CH2OH
NaOH
CH2ONa CH2ONa
H O O H H O O
H H O O H
O
CH2ONa
ClCH2COONa
CH2OCH2COONa CH2OCH2COONa
H O O H H O O
H H O O H
O
CH2OCH2COONa
Advantage:
Viscosity very high.
Good thickener.
Compatible with acid or alkali solution.
1. Newtonian flow: In this case, the viscocity is not dependent upon the time or shear
rate. It is, however dependents upon solution concentration and temperature
solutions of high polymers are very rarely Newtonian. In applied shearing stress,
The proportionality-viscosity- remains constant with the shear rate.
2. Dilatent flow: This is rarely encountered except in dispersions having about 50%
solids. It involves and increase in viscocity with increasing shear rate. Starch
exhibits dilatent flow.
3. Thixotropic flow: This involves a decrease in viscocity as a function of time.
Thixotropic systems re-establish their structure upon standing
undisturbed.Thixotropic flow never exists alone; it is a super imposition of the
viscocity-time relationship upon either Newtonian, dilatent or pendoplastic flow.
The most common is the thixotropic-pseudo plastic flow combination. Solutions of
CMC, hydroxyethylcellulose etc. can be thixotropic or pseudoplastic.
Printing Ingredients:
1. Dyestuffs or Pigments.
2. Wetting agents.
3. Thickener.
4. Solvent, dispersing agents.
5. Dofoaming agents.
6. Oxidising and Reducing agents.
7. Catalyst and Oxygen Carrier.
8. Acids and alkalis.
9. Carrier and Swelling agents.
10. Miscellaneous agents.
Function:
1. Dyes/Pigments:
Attraction of dye stuff to the fibre due to presence of auxochrome.
To achieve colour effect on the fabric
To produce required shade.
e.g. Vat, Azoic, Reactive, direct etc.
2. Wetting agents:
To wet the fabric as well as dyestuff.
To reduce surface tension of water allowing the dyestuff for easy penetration into
fibre.
To obtain smooth paste.
To dissolve the dyestuff in the paste
e.g.: Olive oil, T.R oil, caster oil .
Lissapol N. Animal oil, Glycerine.
4. Thickener:
To give required viscosity to the printing paste.
To prevent premature reactions betn the chemicals contained in the print paste.
To hold the ingredients of the print paste on the fabric
Ex: Na-alginate, fine gum, british gum, CMC.
5. Defoaming agents:
To prevent the foam generation during printing.
e.g. Silicone, defoamers, sulphated oil, perminol KB, Emulsified pine oil.
6. Oxidising and reducing agent:
Oxidising agent:
To develop the final colour during steaming or in the subsequent after treatment.
Assists to dye fixation.
e.g.: Sodium chlorate, Potasium chlorate, Sodium nitrate, Resist Salf Ammonium
chloride, Ludigol, Na or K dichromate
Reducing agent:
Used for reduction of different dyes.
Used for mainly in discharge printing.
To destroy colour from the ground of fabric.
To make the insoluble dyes to soluble
e.g. Sodium hydrosulphite, Stanus chloride etc. Rongolite-C
Crrier:
Used for fixing disperse dyes on polyester or polyster wool blends at temp below
105oC.
Cl
OH Cl
OH Cl
5. Transfer printing
(i) Flat bed press transfer printing m/c
(ii) Continuous transfer printing m/c
(iii) Vacuum transfer printing m/c
1. Block Printing: Block printing is the oldest method of printing which still
exists but use is limited to the decoration of scraves and handker chiefs.
Block size: Generally 3” X 4”—4”-12”
Maximum—36” X 36”
Required equipment:
I). long table (generally made of wood).
II). sieves.
III). Resilence pad of woolen felt cloth/foam.
IV). Gummy cloth.
V). Back grey.
Table size: Length—as required.
Width—1.5-2 m
Height—depend on labour height.
Block preparation: Generally block is made from pear wood which is cut so that
the design is raised in relief. The size of the block depends on the design
characteristics. Normally block is used only for single colour. The printing does
not become uniform with large size block.
Printing procedure:
The fabric for printing is stretched on a flat table covered with resilience
substance and then back grey and gummy cloth.
The printing paste is kept in a colour pad which is a blanket. The colour
pad or sieves is kept in a colour tlray.
The block is pressed into the sieve and smeared with colour paste. Then it
is raised and pressed upon the fabric so that coloured pattern to transfer to
it.
Advantage:
The method is simple to operate and does not require elaborate and
expensibe equipmet.
Design in any no of colours and on any scale can be reproduced.
Fast rate block print posses richness, fullness and purity of colour.
There is no limiting factor in repeat unit.
Disadvantage:
Slow method, low out put and hece costly.
Not possible to obtain sharp out lines of design.
Difficult to join up each impression or repeat perfectly.
This method involves manual work and hence quite laborious.
Stencil Printing:
-Stencil made from (I) Steel (II) paper (III) plastic (IV) Laminated.
Paper: Transparent paper imaging a design and then chemically treatment to make
water proof.
Advantage:
Stencil is much easier handle than the block and the cost of production is
low.
Possible to produce various shade effect.
Direct application of print paste and any kind of colour can be used in
stencil.
IV). Profitable for small scale production.
Disadantage:
Complete circular/rings can’t be obtained and designers freedom is limited.
Complex design is not suitable.
Not suitable for large scale production.
It involves manual work and hence laborious.
Roller printing:
Rollor printing or M/C printing is the most economical and fastest way of
printing. The output of this M/C can not be surpassed by any other method of
printing. Designs with up to 16 colours present no problem in Roller printing.
Construction:
This M/C consists of a central pressure bowl(1) suitably wrapped with layers
of cloth called lapping (2) around which an endless woollen blanket (3) ,a
back grey (4) and the cloth (5) to be printed circulate in contact with each
other.
An engraved printing roller of shell (6) mounted on a steel shaft or mandrel
(7) revolves in contact with the pressure bowl above and a furnisher roller
(8) below which partly dips in the printing paste kept in the colour box (9).
A sharp edged steel blade called colour doctor (10) rests on the engraved
roller on one side and a brass blade lint doctor(11) rests on the other by
suitable weights and levers.
Working procedure:
The fabric to be printed is placed on the impression cylinder. The pressure
cylinder comes to the contact of engraved roller by rotating forwards.
The engraved roller is first supplied with the printing paste by the
furnishing roller. This paste is deposited in the engravings as well as applied
on the smooth surface.
Advantages:
Suitable for large scale production.
High speed M/C and hence more production.
Can be used for fine printing.
Can be made/prepared high quality design due to not joint mark.
Possible to print in complex weaven design.
Disadvantages:
Changing time high. So not suitable in small scale production.
Engraving the printing roller is an expensive operation.
May be light printing shade.
Crush effect produce.
Screen Printing:
1. Hand Screen printing.
2. Flat bed screen printing.
Semi-automatic
Full automatic
3. Rotary screen printing
Fundamental characteristics of Screen Printing:
(1) In screen printing process, hydrodynamic pressure is built up in the
print paste between. the squeeze and the screen surface through which the paste
is passed. Important elements here are the force (pressure) exerted by the
squeezes, the holes through which the paste must pass and the receptivites of the
cloth for the colour.
(2) The hydrodynamic pressure appears to be inversely proportional to the
1
radius of the pores ( HP )where the power of r not exceed 2) Here pore radius
rn
greatly affects the winorenl of paste flowing through screens. H.P viscosity of
the paste.
(3) The % of open area of the screen also plays a role. More open
screens allows more paste to pass.
(4) The fabric to be printed forms a three dimensional structural with the
screen where the absorbency of the fibers and penetration capacity between pores
also affect the take up of the paste.
(5) The usual hexagonal opening which are larger at the outside of the
screen that’s at the inside the capillary and surface tension forces etc result in a
printing with actually more colour deposited in the areas between hole than
opposite holes.
Pore Printing paste
F a b ric
B a c k g re y
T a b le
Procedure:
The fabric to be printed is feed to the printing table by feed system and
is welded by glue with endless conveyor belt.
The conveyor draws forward below screen in equal difference and printing
paste mechanically supplied is welded on fabric according to design by
squeeze through screen.
Automatic squeeze system of individual screen is controlled by
mechanically or electro magnatic power with individual motor.
By using different colours in different screens, printing effect of different
colour can be made.
By washing device weld glue on belt can be cleared.
Advantages:
Highest production.
As many as 24 colours in a pattern can be produced, 8-10 colour can be
printed easily.
No joint mark.
Suitable for woven and knitted fabric.
Stripe design can be done in warp.
Disadvantages:
Printing cost is high due to high price of screen.
Not suitable for short runs.
Different screens are needed for varying colours.
Not possible of fine line design.
Difference between. Rotary Screen and Roller Printing:
Rotary Screen Printing Roller Printing
1. Printing is done by specially 1. Printing is done by specially
made perforated cylindrical or engraved cupper roller.
spherical screen
2. Paste is pumped to the screen and 2. Paste is transferred to the engraved
distributed lengthwise by pumps. roller by colour furnishing roller.
3. Upto 24 colours can be printed but 8- 3.Even 16 engraved roller can be used for
10 are printed easily. different colours of
pattern only 4-6 may
4. Can be printed woven and knitted fabric. 4. Can be printed woven and tricot fabric.
12. Colour applied is more adaptable. 12. Colour applied is less in general.
Transfer Printing: Transfer printing is such the printing which can be printed on
fabric by transfering design of printing paper using only methods.
P r in tin g in k
T ra n sfe r
P r in tin g p a p e r
T ra n sfe r
T e x tile m tls .
Basic Principle:
Transfer printing technology is done by two steps-
At first step, the definite design is printed on transfer paper by sublimable
dyestuff paste. This transfer paper is printed by flexographic lithographic.
In 2nd step- this transfer paper is kept contact into the fabric to be printed.
As a result design of printing paste is transferred to the fabric from
transfer paper under the condition of time, temp and pressure.
In this method cut piece fabric is printed in flat bed M/C and long fabric is
printed by continuous transfer printing M/C.
Working principle:
In this M/C, since preprinted paper and fabric contact to each other passes
through, design is transfered to fabric which is done in a biggest heated
cylinder.
Here, cylinder is heated at 2200C in interlly and design is transfered due to
the pressure of cylinder and pre-printed paper.
A tension device is used for pressure of printing paper to fabric.
Required time for printing is 15-30 s.
Backing paper is used for uniform pressure fabric and transfer paper.
The speed of M/C is 1300 m/hr.
The speed of machine varies between 6-15 m/min depending on the diameter fo the
heated cylinder.
3. Vacuum Transfer printing:
Disadvantages:
Only volatile dye can be used.
The technique mainly aims at synthetic fibres baised on synthetic polymer.
There is extra step of 1st working on paper.
Once the transfer printing paper has been used it cannot be used.
Costly.
Printing of fabric
Printing of cellulosic fabrics
At first the cloth dyed with an easily reducible direct dye and padded with 10
gm/l mild oxidizing agent followed by drying, is printed with the above paste,
dried and steamed for 5 min. The cloth is then rinsed with water, the leuco vat
dye is oxidised to the parent vat dye by treatment with potassium dichromate and
Acetic acid, sodium perborate and acetic acid. Finally the cloth is washed and
dried.
ii) Anthraquinone
O
Range of colour: Range of shades like blues, yellows, greens, reds, violets, orange,
grey, black, scarlet. Range is very high and possible to any colour shade.
Thickener:
One stage method Two stage method
-British gum -Methyl cellulose
-Gum Arabic -Locust bean gum
-Starch Tragacanth etc.
-Starch
etc.
Methods of Printing:
1. Potash Rongalite method:
a. Without pre -reduction
b. With pre-reduction.
2. Potash Caustic Method:
a. Without pre-reduction
b. With pre-reducing.
Potash Rongalite Method:
a) Without pre-reduction:
Recipe:
100-200 parts Vat dye (Paste form)
50-75 parts Glycerine
30 parts solution salt B
500 parts Starch Tragacanth paste
80-120 parts potassium carbonate (K2CO3)
60-100 parts Rongalite-C
210-250 parts water
----------------------------------
1000 parts
b) With pre-reduction:
Recipe:
100-200 gm vat dye (Paste form)
50-75 parts Glycerine
30 parts solution salt B
500 parts starch tragacanth paste
80-120 parts potassium carbonate
40 parts sodium hydro sulphite
160 parts Rongolite C
----------------------------------
1000 parts
After printing, dried and steaming as soon as possible steamed (air free) for 5-10
min at 1000-1020C.
Oxidation: Leuco-vat convert into insoluble vat dye. Incomplete oxidation produces
uneven prints of inferior fastness proporties. Oxidation may be carried out by any
of the folowing process-
I). Air oxidation:
-Cheapest and simplest to handle.
-Slow process
-complete oxidation may not be takes place of sufficient times is not given.
II). Chemical oxidation:
(a) Perborate:
2-4 parts sodium perborate
5 parts acetic acid
991 parts water
---------------------------
1000 parts
This treatment is given at 600-700C water.
(b) Potassium dichromate method
2 parts potassium dichromate
5 parts acetic acid (30%)
993 parts water
------------------------
1000 parts
This traeatment is given at 500 C and is widely used to effect the oxidation to the leuco
vat dye.
c ) Amonium/Pottasium per sulphate:
2-3 gm Amonium Persulphate
1000 parts of Water
At 700C
d) Per oxide method:
4 gm Hydrogen peroxide in 1L Water
Temp 600-700C
After oxidation the cloth is rinsed, soaped at boil (detergent + soda ash), washed
and dried.
Printing of Silk
Printing with Acid dye on silk:
Style of printing: Direct style of printing.
Method of printing: Block printing
Sample: A bleached, scoured fabric.
Thickener:
Gum Arabic
Gum Tragacanth
British gum
Recipe:
40-50 parts Acid dye
40 parts Solvents
50 parts Glycerine
200 parts Hot water
20 parts Ammonium oxalate
20 parts Glacial acetic acid
20 parts Water
600 parts Crystal gum(thickener)
1000 parts
Procedure:
I. Thickener preparation: 80 gm Crystal gum is mixed with water and heated until
required viscosity at 5-10 min. The mixture is stirred continuously while heating.
II.Acid dye +Solvent +Glycerine +Hot water --- Paste
III. Ammonium oxalate + Small water --- Paste
IV.Glacial acetic acid +water------Paste
V. Paste II + Paste III + Paste IV +Thickener --- Printing paste
The cloth may be printed with the above paste, dried and steamed for 1 hr at
1000-1020C in a cottage steamer. Washed in cold water and then dried.
Printing of Wool
Printing wool with Acid dye: With wool, apart from normal preparation
processes lsuch as scouring, bleaching, chlorination is always required to assist
wetting and dye absorption.
Style of printing: Direct style of printing.
Method of printing: Block printing
Sample: A bleached, scoured fabric.
Thickener used:
i) Gum Senegal/Arabic
ii) Gum Tragacanth
iii) British gum
Printing recipe:
30-40 gm Acid dye
50 parts Solvents
40 parts Glycerine
600 parts British gum
210 parts water
70 parts Acetic acid
1000 parts
Procedure:
I. Thickener preparation: 80 gm British gum is mixed with water and heated until
required viscosity at 5-10 min. The mixture is stirred continuously while heating.
II.Acid dye +Solvent +Glycerine + water --- Paste
III. Acetic acid + Small water --- Paste
IV.Paste II + Paste III +Thickener --- Printing paste
The cloth may be printed with the above paste, dried at moderate temperature and
Steamed for 1 hr at 1000C washed and dried.
White discharge on wool/Silk: The fabric is dyed with selected acid dyes and
then printed with recipes as under.
40 parts Thiodiglycol (Penetration agent)
100 parts hot water
500 parts Gum Tragacanth (Thickener)
100-150 parts Rongalite-C (Reducing agent)
75 parts TiO2 (Brightening agent)
175-185 parts Water
----------------
1000 parts
After printing and drying the cloth are steamed for 15 to 20 mins at 100 to
1020C and then Rinsing, Soap washing and drying.
Colour discharge on Wool/Silk:
Recipe:
20-40 parts discharge resistant acid dye
40 parts Thiodiglycol (Peretration agent)
200 parts Hot water
500 parts Gum Tragacanth
100-150 parts Rongaite-C
100-120 parts Water
---------------------------
1000parts
After printing and drying, the fabric are steamed at atmospheric pressure for 15-20
min followed by rinsed and soaping treatment at 500C. Finally washed and dried.
Printing of Acrylic fibre by Basic dye:
The printing is carried out in two stage-
1. Preparatory (Singeing, desizing and scouring, bleaching, drying and
stentering).
2. Printing (Printing, steaming, washing, soaping).
Recipe:
10-40 parts Cationic dye
20 parts Acetic acid (50%)
20-30 parts Thiodiethylene glycol
20to 30 parts Tartaric acid (50%)
4 to 8 parts Sodium choloride
X gm parts water
Y gm parts stock thickening
20-40 parts Phenol
--------------
1000 parts
The acrylic fiber may be printed with the above paste on dried in a hot flue
drier. The printed and dried fabrics may be steamed in a star ager at 103 0C for
40 min. A temp of 1050C is the maximum allowable steaming temp.
The steamed fabric may be after-treated (after a cold and hot rinse) with a bath
containing 1-2 g/L anon ionic detergent at 600C for 25 to 30 min.