Solution

CHECK YOUR GRASP SOLUTION EXERCISE-I

METHOD OF EXPRESSING CONCENTRATION 9. Which of the following statement is true :-
OF SOLUTION
(a) Molarity is the no. of moles of solute dissolved
1. 8 g NaOH is dissolved in one litre of solution, its per litre of solvent.
molarity is : (b) The molarity and normality of a solution of
(1) 0.8 M (2) 0.4 M sodium carbonate are same.

(3) 0.2 M (4) 0.1 M (c) molality (m) of a solution is defined as the
2. If 18 g of glucose is present in 1000 g of solvent, number of moles of solute dissolved is 1000 gm
the solution is said to be : of solution

(1) 1 molar (2) 0.1 molar (d) The ratio of mole fraction of solute and solvent
is in the ratio of there respective moles.
(3) 0.5 molar (4) 0.1 molal
3. The molarity of pure water is : (1) a & c (2) a & d

(1) 100 M (2) 55.6 M (3) b & c (4) Only d

(3) 50 M (4) 18M 10. The molarity of a solution of sodium chloride (mole
4. Mole fraction of C3H5(OH)3 (glycerine) in a solu- wt. = 58.5) in water containg 5.85 gm of sodium
tion of 36 g of water and 46 g of glycerine is : chloride in 500 ml of solution is :-

(1) 0.46 (2) 0.36 (1) 0.25 (2) 2.0

(3) 0.20 (4) 0.40 (3) 1.0 (4) 0.2
5. What is the normality of 1M H3PO4 solution ? 11. In a solution of 7.8 g benzene (C6H6) and 46.0g
(1) 0.5 N (2) 1.0 N toluene (C6H5CH3), the mole fraction of benzene
(3) 2.0 N (4) 3.0 N is:-
6. The molarity of 0.2 N Na2CO3 solution will be :
1 1
(1) 0.05 M (2) 0.2 M (1) (2)
6 5
(3) 0.1 M (4) 0.4 M
7. A molal solution is one that contains one mole 1 1
(3) (4)
of a solute in 2 3
(1) 1000 g of the solvent
12. The molarity of 98% by wt. H2SO4 (d = 1.8 g/
(2) one litre of the solution ml) is
(3) one litre of the solvent
(1) 6 M (2) 18 M
(4) 22.4 litres of the solution
(2) 10 M (4) 4 M
8. Which represents percent by strength :
RAOULT'S LAW AND IDEAL AND NON-IDEAL
Weight of solute
(1) × 100 SOLUTION
Weight of solution

13. If Raoult's law is obeyed, the vapour pressure of

Weight of solute the solvent in a solution is directly proportional
(2) × 100
Volume of solution to
(1) Mole fraction of the solvent
Volume of solute (2) Mole fraction of the solute
(3) × 100
Volume of solution (3) Mole fraction of the solvent and solute

(4) All of them (4) The volume of the solution

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14. Which one of the following is the incorrect form 19. Which condition is not satisfied by an ideal solu-
of Raoult's law tion
Ps N (1) ∆Hmixing = 0
(1) =
P0 n + N (2) ∆Vmixing = 0
(3) ∆Smixing = 0
P0 N
(2) 0 =1+ (4) Obeyance of Raoult's law
P − Ps n
20. The boiling point of C6H6, CH3OH, C6H5NH2 and
P − Ps
0
n C6H5NO2 are 800C, 650C, 1840C and 2120C
(3) =
Ps n+N respectively which will show highest vapour pres-
sure at room temperature :
Ps N
(4) P o − P = n (1) C6H6 (2) CH3OH
s
(3) C6H5NH2 (4) C6H5NO2
15. The vapour pressure of a solution having solid as
21. Azeotropic mixture are :
solute and liquid as solvent is :
(1) Mixture of two solids
(1) Directly proportional to mole fraction of the
(2) Those which boil at different temperatures
solvent
(3) Those which can be fractionally distilled
(2) Inversely proportional to mole fraction of the
(4) Constant boiling mixtures
solvent
22. An azeotropic mixture of two liquids boil at a lower
(3) Directly proportional to mole fraction of the
temperature than either of them when
solute
(1) It is saturated
(4) Inversely propartional to mole fraction of the
(2) It does not deviate from Raoult's law
solute
(3) It shows negative deviation from Raoult's law
16. If P0 and PS are the vapour pressure of solvent and
(4) It shows positive deviation from Raoult's law
its solution respectively. N1 and N2 are the mole
fraction of solvent and solute respectively then : 23. For a solution of two liquids A and B, it was proved
that P = XA (PA0 – PB0) + PB0. The solution is:–
P0
(1) PS = N (2) P0 – PS = P0N2 (1) Ideal (2) Non ideal
2
(3) Semiideal (4) None of the above
(3) PS = P0N2 (4)
24. Mole fraction of A vapours above solution in
( P0 − PS ) = N1
mixture of A and B (XA = 0.4) will be :-
PS ( N1 + N2 )
(PA° = 100mm, PB° = 200mm)
17. 1 mole of heptane (Pure V. P. = 92 mm of Hg)
(1) 0.4 (2) 0.8
was mixed with 4 moles of octane
(3) 0.25 (4) None
(Pure V. P. = 31mm of Hg). The vapour pressure
25. Which of the following does not show negative
of resulting ideal solution is :
deviation from Rault's law ?
(1) 46.2 mm of Hg
(1) Acetone – Chloroform
(2) 40.0 mm of Hg
(2) Toluene – Benzene
(3) 43.2 mm of Hg
(3) Nitric Acid – Water
(4) 38.4 mm of Hg
(4) Chloroform – Benzene
18. Among the following, that does not form an ideal 26. According to raoult's law the relative lowering of
solution is : vapour pressure for a solution is equal to
(1) C6H6 and C6H5CH3 (1) Moles of solute
(2) C2H5Cl and C6H5OH (2) Mole fraction of solvent
(3) C6H5Cl and C6H5Br (3) Moles of solvents
(4) C2H5Br and C2H5I (4) Mole fraction of solute

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 Solution
COLLIGATIVE PROPERTIES AND VANT HOFF 35. The ratio of the value of any colligative property
FACTOR for KCl solution to that for sugar solution is nearly
......................... :
27. Which solution will have least vapour pressure
(1) 1 (2) 0.5
(1) 0.1 M BaCl2
(3) 2 (4) 2.5
(2) 0.1 M urea
(3) 0.1 M Na2SO4 ELEVATION IN B.P. AND DEPRESSION IN F.P.

(4) 0.1 M Na3PO4 36. If the solution boils at a temperature T1 and the
28. Colligative properties of the solution depend upon solvent at a temperature T2 the elevation of boiling
(1) Nature of the solution point is given by
(2) Nature of the solvent (1) T1 + T2 (2) T1 – T2

(3) Number of solute particles (3) T2 – T1 (4) T1 ÷ T2

37. The molal elevation constant is the ratio of the
(4) Number of moles of solvent
elevation in B.P. to
29. Which is not a colligative property ?
(1) Molarity
(1) Osmotic pressure (2) Molality
(2) Lowering in vapour pressure (3) Mole fraction of solute
(4) Mole fraction of solvent
(3) Depression in freezing point
38. The temperature, at which the vapour pressure
(4) Refrective index
of a liquid becomes equal to the atmospheric
30. Van't Hoff factor is : pressure is known as
(1) Less than one in case of dissociation (1) Freezing point
(2) Boiling point
(2) More than one in case of association
(3) Absolute temperature
(3) Always less than one (4) None of these
(4) Less than one in case of association 39. When common salt is dissolved in water
(1) Melting point of the solution increases
31. The Vant Hoff factor (i) for a dilute solution of
(2) Boiling point of the solution increases
K3[Fe(CN)6] is (Asuming 100% ionsation) :
(3) Boiling point of the solution decreases
(1) 10 (2) 4
(4) Both Melting point and Boiling point is
(3) 5 (4) 0.25 decreases
32. The experimental molecular weight of an 40. The elevation in boiling point for one molal
electrolyte will always be less than its calculated solution of a solute in a solvent is called
value because the value of vant Hoff factor, 'i' is (1) Boiling point constant
(2) Molal elevation constant
(1) Less than 1 (2) Greater than 1
(3) Cryoscopic constant
(3) One (4) Zero
(4) None of these
33. The Vant Hoff factor (i) for a dilute aqueous
41. Solute when dissolved in water
solution of Glucose is :
(1) Increases the vapour pressure of water
(1) Zero (2) 1.0
(2) Decreases the boiling point of water
(3) 1.5 (4) 2.0
(3) Decreases the freezing point of water
34. The substance A when dissolved in solvent B (4) All of the above
shows the molecular mass corresponding to A3. 42. If Kƒ value of H2O is 1.86. The value of ∆Tƒ for
The Vant Hoff's factor will be - 0.1 m solution of non-volatile solute is
(1) 1 (2) 2 (1) 18.6 (2) 0.186
(3) 3 (4) 1/3 (3) 1.86 (4) 0.0186

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JEE ( Main) - Chemistry
43. What is the effect of the addition of sugar on the 50. Which can pass through semipermeable mem-
boiling and freezing points of water brane ?
(1) Both boiling point and freezing point increases
(1) Molecules of solvent
(2) Both boiling point and freezing point decreases
(3) Boiling point increases and freezing point (2) Molecules of solute
decreases
(3) Simple ion
(4) Boiling point decreases and freezing point
increases (4) Complex ion

44. Which of the following aqueous molal solution 51. In osmosis phenomenon :
have highest freezing point
(1) Solvent molecules move from higher
(1) Urea
concentration to lower concentration
(2) Barium chloride
(3) Potassium bromide (2) Solvent molecules move from lower

(4) Aluminium sulphate concentration to higher concentration

45. Which will show maximum depression in freezing (3) Solute molecules move from higher
point when concentration is 0.1M concentration to lower concentration
(1) NaCl (2) Urea
(4) Solute molecules move from lower
(3) Glucose (4) K2SO4
concentration to higher concentration
46. What should be the freezing point of aqueous
solution containing 17 gm of C2H5OH in 1000 52. At constant temperature the osmotic pressure of
gm of water (water Kƒ = 1.86 deg – kg mol–1) a solution is :
(1) – 0.69°C (2) – 0.34°C
(1) Directly proportional to the concentration
(3) 0.0°C (4) 0.34°C
(2) Inversely proportional to the concentration
OSMOTIC PRESSURE
(3) Directly proportional to the square of
concentration
47. Pure water can be obtain from sea water by
(1) Centrifugation (4) Directly proportional to the square root of
(2) Plasmolysis concentration
(3) Reverse osmosis 53. Which inorganic precipitate acts as
(4) Sedimentation semipermeable membrane ?
48. As a result of osmosis, the volume of the concen-
trated solution (1) Calcium sulphate

(1) Gradually decreases (2) Barium oxalate

(2) Gradually increases
(3) Nickel phosphate
(3) Suddenly increases
(4) None (4) Copper ferrocyanide
49. If a thin slice of sugar beet is placed in concen- 54. The osmotic pressure of solution increases if :
trated solution of NaCl then
(1) Temperature is decreased
(1) Sugar beet will lose water from its cells
(2) Sugar beet will absorb water from solution (2) Concentration is decreased
(3) Sugar beet will neither absorb nor lose water (3) Number of solute particle is increased
(4) Sugar beet will dissolve in solution
(4) Volume is increased

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 Solution
56. The best colligative property used for the deter-
55. The plant cell will shrink when placed in :
mination of molecular masses of polymers is :
(1) Water
(1) Relative lowering in vapour pressure
(2) A hypotonic solution (2) Osmotic pressure
(3) A hypertonic solution (3) Elevation in boiling point
(4) An isotonic solution (4) Depression in freezing point

CHECK YOUR GRASP ANSWER KEY EXERCISE-I

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans 3 4 2 3 4 3 1 2 4 4 1 2 1 3 1
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans 2 3 2 3 2 4 4 1 3 2 4 4 3 4 4
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans 2 2 2 4 3 2 2 2 2 2 3 2 3 1 4
Que. 46 47 48 49 50 51 52 53 54 55 56
Ans 1 3 2 1 1 2 1 4 3 3 2

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BRAIN TEASERS SOLUTION EXERCISE-II

1. For preparing 0.1 M solution of H2SO4 in one litre, 8. 100 ml of 0.3 N HCl solution is mixed with
we need H2SO4 : 200 ml of 0.6 N H2SO4 solution what is the
(1) 0.98 g (2) 4.9 g normality of the resultant solution.

(3) 49.0 g (4) 9.8 g (1) 0.9 (2) 0.6

(3) 0.4 (4) 0.5
2. 1000 g aqueous solution of CaCO3 contains 10
9. An Y molal solution of a compound in benzene
g of calcium carbonate concentration of the
has mole fraction of solute equal to 0.2. The value
solution is :
of Y is :-
(1) 10 ppm (2) 100 ppm
(1) 14 (2) 3.2
(3) 1000 ppm (4) 10,000 ppm
(3) 1.4 (4) 2
3. How much volume of 3.0 M H2SO4 is required
10. H2O2 solution used for hair bleaching is sold as
for the preparation of 1.0 litre of 1.0 M solution?
a solution of approximately 5.0 g H2O2 per 100
(1) 300 ml (2) 320 ml
mL of the solution. The molecular mass of H2O2
(3) 333.3 ml (4) 350.0 ml
is 34. The molarity of this solution is
N approximately:-
4. 25 ml NaOH solution will exactly neutralize
10 (1) 0.15 M (2) 1.5 M
(3) 3.0 M (4) 3.4 M
which of the following solution :-
11. What volume of 0.1 N HNO3 solution can be
N prepared from 6.3 g of HNO3 ?
(1) 25 ml KOH solution
10 (1) 1 litre (2) 2 litre
(2) 25 ml N H2SO4 solution (3) 0.5 litre (4) 5 litre
12. If 8.3 ml of a sample of H2SO4 (36 N) is diluted
N by 991.7 ml of water, the approximate normality
(3) 25 ml HCl solution
10 of the resulting soluttion is
(1) 0.4 (2) 0.2
N
(4) 2.5 ml HNO3 solution (3) 0.1 (4) 0.3
10
13. A mixture has 18 g water and 414 g ethanol. The
5. Equal weight of NaCl and KCl are dissolved mole fraction of water in mixture is (assume ideal
separately in equal volumes of solutions molarity behaviour of the mixture) :
of the two solutions will be – (1) 0.1 (2) 0.4 (3) 0.7 (4) 0.9
(1) Equal 14. The molarity of a solution made by mixing 50 ml
(2) That of NaCl will be less than that of KCl of conc. H2SO4 (36 N) with 50 ml. of water, is :
(3) That of NaCl will be more than that of KCl (1) 36 M (2) 18 M
Solution (3) 9 M (4) 6M
(4) That of NaCl will be half of that of KCl solution 15. 171 g of cane sugar (C12H22O11) is dissolved in
6. How much water should be added to 200 cc of 1 litre of water. The molarity of the solution is :
seminormal solution of NaOH to make it exactly (1) 2.0 M (2) 1.0 M
decinormal :- (3) 0.5 M (4) 0.25 M
(1) 1000 cc (2) 400 cc 16. How much grams of CH3OH should be dissolved
(3) 800 cc (4) 600 cc in water for preparing 150 ml. of 2.0 M CH3OH
7. Normality of 10% (W\V) H2SO4 solution is nearly solution
(1) 0.1 (2) 0.2 (1) 9.6 (2) 2.4

(3) 0.5 (4) 2 (3) 9.6 × 103 (4) 4.3 × 102

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 Solution
17. What is the molarity of H2SO4 solution which is 24. The vapour pressure of pure A is 10 torr and at
98% by weight and the density of solution at 350C the same temperature when 1 g of B is dissolved
is 1.84 gm/cm3 in 20 gm of A, then the vapour pressure of
(1) 4.18 M (2) 8.14 M solution is 9 torr. If the molecular mass of A is
(3) 18.4 M (4) 18 M 200 amu, then the molecular mass of B is :
18. How many grams of dibasic acid (mol wt. 200). (1) 100 amu (2) 90 amu
Should be present in 100 ml. of the aqueous (3) 75 amu (4) 120 amu
solution to give 0.1 normality ?
25. At 88 °C benzene has a vapour pressure of 900
(1) 10 g (2) 20 g
torr and toluene has a vapour pressure of 360 torr.
(3) 2 g (4) 1 g
19. Molarity of liquid HCl if density of solution is What is the mole fraction of benzene in the mixture
1.17 g/cc. : with toluene that will boil at 88 °C at 1 atm.
(1) 36.5 (2) 18.25 pressure, benzene - toluene form an ideal solution:
(3) 32.05 (4) 42.10 (1) 0.416 (2) 0.588
N (3) 0.688 (4) 0.740
20. 5 ml. of N HCl, 20 ml of H SO and 30 ml
2 2 4 26. The azeotropic mixture of water (B.P 1000C) and
HCl (B.P. 850C) boils at 108.50C. When this
N
of HNO3 are mixed together and volume made mixture is distilled, it is possible to obtain :
3
to one litre. The normality of the resulting solution (1) Pure HCl
is : (2) Pure water

N N (3) Pure water as well as HCl

(1) (2) (4) Neither HCl nor H2O in their pure states
5 10
27. The vapour pressure of pure benzene and toluene
N N
(3) (4) are 160 and 60 torr respectively. The mole
20 40
fraction of toluene in vapour phase in contact with
21. One mole of non volatile solute is dissolved in two
moles of water. The vapour pressure of the solution equimolar solution of benzene and toluene is :-
relative to that of water is (1)0.50 (2) 0.6
2 1 1 3 (3) 0.27 (4) 0.73
(1) (2) (3) (4)
3 3 2 2 28. The vapour pressure of a solvent decreases by 10mm.
22. The vapour pressure of a pure liquid 'A' is 70 torr of Hg when a non volatile solute was added to the
at 270C. It forms an ideal solution with another solvent. The mole fraction of the solute in the solution
liquid B. The mole fraction of B is 0.2 and total
is 0.2. What should be the mole fraction of the solvent
vapour pressure of the solution is 84 torr at 270C.
The vapour pressure of pure liquid B at 270C is if the decrease in vapour pressure is to be 20 mm.
(1) 14 (2) 56 of Hg
(3) 140 (4) 70 (1) 0.2 (2) 0.4
23. The vapour pressure of water at room temperature (3) 0.6 (4) 0.8
is 23.8 mm of Hg. The vapour pressure of an 29. Which of the following plots does not represent
aqueous solution of sucrose with mole fraction 0.1 the behaviour of an ideal binary liquid solution
is equal to :
(1) Plot of PA versus XA (mole fraction of A in liquid
(1) 23.9 mm Hg phase) is linear
(2) 24.2 mm Hg (2) Plot of PB versus XB is linear
(3) 21.42 mm Hg (3) Plot of ptotal versus XA (or XB) is linear
(4) 31.44 mm Hg (4) Plot of ptotal versus XA is non linear

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30. The vapour pressure of two pure liquids (A) and 36. The values of observed and calculated molecular
(B) are 100 and 80 torr respectively. The total weight of calcium nitrate are respectively 65.6 and
pressure of the solution obtained by mixing 2 mol 164. The degree of dissociation of calcium nitrate
of (A) and 3 mol of (B) would be will be :
(1) 20 torr (1) 25% (2) 50%
(3) 75% (4) 60%
(2) 36 torr
37. Which of the following salt has the same value of
(3) 88 torr Vant Hoff's factor as that of K3[Fe(CN)6]
(4) 180 torr (1) Al2(SO4)3 (2) NaCl
31. The vapour pressure of a pure liquid solvent (X) (3) Al(NO3)3 (4) Na2SO4
is decreased to 0.60 atm. from 0.80 atm on 38. The freezing point of 1 molal NaCl solution
addition of a non volatile substance (Y). The mole assuming NaCl to be 100% dissociated in water
fraction of (Y) in the solution is:- is : (Kf = 1.86 K Molality–1)
(1) –1.86 °C (2) –3.72 °C
(1) 0.20 (2) 0.25
(3) +1.86 °C (4) + 3.72 °C
(3) 0.5 (4) 0.75
39. The molal elevation constant of water is 0.51. The
32. A solution containing components A and B follows boiling point of 0.1 molal aqueous NaCl solution
Raoult's law :- is nearly :
(1) A – B attraction force is greater than A – A (1) 100.05 °C (2) 100.1 °C
and B – B
(3) 100.2° C (4) 101.0° C
(2) A – B attraction force is less than A – A and
40. The molal elevation constant of water = 0.52 K
B–B
molality–1. The boiling point of 1.0 molal aqueous
(3) A – B attraction force remains same as A – A KCl solution (assuming complete dissociation of
and B – B
KCl), should be :
(4) Volume of solution is different from sum of (1) 100.520C (2) 101.040C
volume of solute and solvent
(3) 99.480C (4) 98.960C
33. The vapour pressure of two liquids ‘P’ and ‘Q’ are
41. The correct relationship between the boiling points
80 and 60 torr, respectively. The total vapour
pressure of solution obtained by mixing 3 mole of of very dilute solutions of AlCl3(t1) and CaCl2(t2),

P and 2 mol of Q would be :- having the same molar concentration is :

(1) 68 torr (2) 140 torr (1) t1 = t2 (2) t1 > t2
(3) 72 torr (4) 20 torr (3) t2 > t1 (4) t2 > t1
34. The lowering of vapour pressure of 0.1M 42. Which of the following 0.1 M aqueous solutions
aqueous solutions of NaCl, CuSO4 and K2SO4 are: will have the lowest freezing point :
(1) All equal
(1) Potassium Sulphate
(2) In the ratio of 1 : 1 : 1.5
(2) Sodium Chloride
(3) In the ratio of 3 : 2 : 1
(4) In the ratio of 1.5 : 1 : 2.5 (3) Urea
35. The value of observed and calcutated molecular (4) Glucose
weight of silver nitrate are 92.64 and 170 43. Which has maximum freezing point :
respectively. The degree of dissociation of silver (1) 1 molar of NaCl solution
nitrate is : (2) 1 molar of KCl solution
(1) 60% (2) 83.5 % (3) 1 molar of CaCl2 solution
(3) 46.7% (4) 60.23% (4) 1 molar of urea solution

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 Solution
44. The freezing point of equimolal aqueous solution 52. Osmosis of A into solution B will not take place
will be highest for : if
(1) C6H5NH3Cl (2) Ca(NO3)2 (1) A is hypertonic
(3) La(NO3)3 (4) C6H12O6(Glucose) (2) A is hypotonic
45. Which one has the highest boiling point :- (3) A is isotonic
(1) 0.1N Na2SO4 (2) 0.1N MgSO4 (4) Either 1 or 3 may correct
(3) 0.1M Al2(SO4)3 (4) 0.1M BaSO4
53. Which of the following solutions would have the
46. Glucose is added to 1 litre water to such an extent
highest osmotic pressure -
∆Tf 1
that K becomes equal to , the weight of
f 1000 M M
glucose added is :- (1) NaCl (2) Urea
10 10
(1) 180 g (2) 18 g
(3) 1.8 g (4) 0.18 g M M
(3) BaCl2 (4) Glucose
47. What is the freezing point of a solution containing 10 10
8.1 gm. of HBr in 100gm. water assuming the
54. The compound whose 0.1 M solution has
acid to be 90% ionised (Kf for water=1.86 K
maximum osmotic pressure at 250C will be -
molality–1) :-
(1) CaCl2 (2) KCl
(1) 0.85°C (2) –3.53°C
(3) Glucose (4) Urea
(3) 0°C (4) –0.35°C
55. If 0.1 M solution of glucose and 0.1 M urea
48. A 0.2 molal aqueous solution of a weak acid (HX)
solution are placed on two sides of a
is 20% ionised. The freezing point of this solution
semipermeable membrane to equal heights, then
is (Given : Kf = 1.86°C/m for water)
it will be correct to say that :
(1) – 0.31°C (2) – 0.45°C
(1) There will be not movement across the
(3) – 0.53°C (4) – 0.90°C
membrane
49. The boiling point of an aqueous solution of a non
volatile solute is 100.15 °C. What is the freezing (2) Glucose will flow towards urea solution
point of an aqueous solution obtained by diluting (3) Urea will flow towards glucose solution
the above solution with an equal volume of water (4) Water will flow from urea solution towards
? The values of Kb and Kf for water are 0.5 and 1.8 glucose solution.
K molality–1 :
56. Osmotic pressure of a solution (density is 1g/ml)
(1) –0.54 °C (2) –0.512 °C
containg 3 g of glucose (molecualr weight = 180)
(3) –0.27 °C (4) –1.86 °C
in 60 g of water at 150C is
50. 1.00g of a non-electrolyte solute (molar mass
(1) 0.34 atm (2) 0.65 atm
250g mol–1) was dissolved in 51.2g of benzene.
(3) 6.25 atm (4) 5.57 atm
If the freezing point depression constant, Kf of
57. Osmotic pressure of a sugar solution at 240C is
benzene is 5.12 K kg mol–1, the freezing point
2.5 atmosphere. The concentration of the solution
of benzene will be lowered by :
in mole per litre is :
(1) 0.4 K (2) 0.3 K
(1) 10.25 (2) 1.025
(3) 0.5 K (4) 0.2 K
(3) 1025 (4) 0.1025
51. The relationship between the values of osmotic
58. A solution containing 4 g of a non volatile organic
pressure of solutions obtained by dissolving
solute per 100 ml was found to have an osmotic
6.00 gL–1 of CH3COOH (π1) and 7.45 gL–1 of
pressure equal to 500 cm Hg at 27 0C. The
KCl (π2) is
molecular weight of solute is :
(1) π1 > π2 (2) π1 < π2
(1) 14.97 (2) 149.7
(3) π1 = π2 (4) None of these (3) 1697 (4) 1.497

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JEE ( Main) - Chemistry
59. A solution containing 8.6 g urea in one litre was 66. The vapour pressure of ethanol and methanol are
found to be isotonic with 0.5% (wt./vol) solution 42.0 mm and 88.5 mm Hg respectively. An ideal
of an organic, non volatile solute. The molecular solution is formed at the same temperature by
weight of latter is : mixing 46.0 g of ethanol with 16.0 g of metha-
(1) 348.9 (2) 34.89 nol. The mole fraction of methanol in the vapour
(3) 3489 (4) 861.2 is :
(1) 0.467 (2) 0.502
60. If a 6.84% (wt. / vol.) solution of cane-sugar (mol.
wt. 342) is isotonic with 1.52% (wt./vol.) solution (3) 0.513 (4) 0.556
of thiocarbamide, then the molecular wight of 67. A solution of CaCl 2 prepared by dissolving
thiocarbamide is : 0.0112g in 1kg of distilled water. The molal
(1) 152 (2) 76 depression constant of water is 2 K. kg mol–1. The
(3) 60 (4) 180 depression in the freezing point of the solution
61. A solution containing 500 g of a protein per litre is :- (Assuming 100% ionisation of CaCl2).
is isotonic with a solution containing 3.42 g of (1) 0.0006 (2) 0.0002
sucrose per litre. The molecular mass of protein (3) 0.002 (4) 0.003
is 68. A solution has a 1 : 4 mole ratio of pentane to
(1) 5 (2) 146 hexane. The vapour pressures of the pure
(3) 34200 (4) 50000
hydrocarbons at 20°C are 440 mmHg for pentane
62. The osmotic pressure of blood is 7.65 atm. at
and 120 mmHg for hexane. The mole fraction
310 K. an aqueous solution of Glucose that will be
of pentane in the vapour phase would be :-
isotonic with blood is .............wt/Vol :
(1) 0.200 (2) 0.478
(1) 5.41% (2) 54.1%
(3) 0.549 (4) 0.786
(3) 3.5% (4) 4.53%
69. When equimolar equeous solutions of glucose,
63. Which of the following solutions has the highest
normality :- sodium chloride and barium nitrate are compared
the vapour pressure of the solutions will be in the
(1) 8 grams of KOH per litre
following order :-
(2) N phosphoric acid
(1) Glucose > NaCl > Ba(NO3)2
(3) 6 gms of NaOH per 100 ml
(2) Glucose = NaCl = Ba(NO3)2
(4) 0.5 M H2SO4
(3) Ba(NO3)2 > NaCl > Glucose
64. An aqueous solution of glucose is 10% (w/v) in
(4) NaCl > Ba(NO3)2 > Glucose
strength. The volume in which 2 mole of it is
70. 20 gm. of a binary electrolyte (mol. wt. = 100)
dissolved will be :-
are dissolved in 500 g of water. The freezing point
(1) 18 litre (2) 3.6 litre of the solution is –0.74 °C. Kf = 1.86 K molality–1.
(3) 0.9 litre (4) 1.8 litre The degree of ionization of the electrolyte is :
65. An ideal solution was obtained by mixing (1) 50% (2) 75%
(MeOH) methanol and (EtOH) ethanol. If the (3) 100% (4) 0%
partial vapour pressure of methanol and ethanol 71. Which aqueous solution has minimum freezing
are 2.619 K Pa and 4.556 K Pa respectively, the point :
composition of vapour (in terms of mole fraction) (1) 0.01 M NaCl (2) 0.005 M C2H5OH
will be - (3) 0.005 M MgI2 (4) 0.005 M MgSO4
(1) 0.635 MeOH, 0.365 EtOH 72. Which has the minimum freezing point :
(2) 0.365 MeOH, 0.635 EtOH (1) 1 molal NaCl solution
(3) 0.574 MeOH, 0.326 EtOH (2) 1 molal KCl solution
(4) 0.173 MeOH, 0.827 EtOH (3) 1 molal CaCl2 solution
(4) 1 molal urea solution
100 E
 Solution
73. The vapour pressure of a solution in benzene is 80. The relationship between osmotic pressure at
722 mm and that of pure solvent (benzene) is 273 K when 10 g glucose (P1) 10 g urea (P2) and
760 mm. The molality of solution is :- 10 g sucrose (P3) are dissolved in 250 ml of water
(1) 0.128 (2) 0.674
is
(3) 1.28 (4) 6.67
(1) P1 > P2 > P3
74. The following aqueous solution in the correct order
(2) P3 > P1 > P2
of decreasing freezing point is -
(1) 0.2M BaCl2, 0.2M KCl, 0.1M Na2SO4 (3) P2 > P1 > P3
(2) 0.2M KCl, 0.1M Na2SO4, 0.2M BaCl2 (4) P2 > P3 > P1
(3) 0.1M Na2SO4, 0.2M KCl, 0.2M BaCl2 81. A solution containing 10g per litre of urea
(3) 0.1M Na2SO4, 0.2M BaCl2, 0.2M KCl (molecular mass = 60g mol–1) is isotonic with a
75. Which of the following solutions will have highest 5% m/v solution of a nonvolatile solute. The
boiling point ? molecular mass of this nonvolatile solute is :
(1) 1% Glucose in water (2) 1% Sucrose in water (1) 250g mol–1
(3) 1% NaCl in water (4) 1% Urea in water
(2) 300g mol–1
76. Arrange the following aqueous solutions in the
(3) 350g mol–1
order of their increasing boiling points :-
(4) 200g mol–1
(i) 10–4 M NaCl (ii) 10–4 M Urea
–3
(iii) 10 M MgCl2 (iv) 10–2 M NaCl 82. The vapour pressure of pure benzene at a certain
(1) (i) < (ii) < (iv) < (iii) (2) (ii)<(i)=(iii)<(iv) temperature is 640 mm Hg. A non-volatile
non-electrolyte solid and weighing 2.175g is
(3) (ii)<(i)<(iii)<(iv) (4) (iv)<(iii)<(i)=(ii)
added to 39.0 g of benzene. The vapour pressure
77. Among 0.1M solutions of urea,Na 3PO 4 and
of the solution is 600 mm Hg. What is the
Al2(SO4)3 :- molecular weight of the solid substance ?
(a) The vapour pressure and freezing point are the
(1) 6.96 (2) 65.25
lowest for urea
(3) 63.8 (4) None of these
(b) The vapour pressure and freezing point are the
83. The vapour pressure of solution containing 5g
highest for urea
of non-electrolyte in 90g of water at a particular
(c) The elevation in boiling point is the highest for temperature is 2985 Nm– 2. The vapour pressure
Al2(SO4)3 of pure water at that temperature is 3000 Nm– 2.
(d) The depression in freezing point is the highest The molecular weight of the solute is -
for Al2(SO4)3 (1) 180 (2) 90
(1) Only a (2) b & c both (3) 270 (4) 199
(3) b, c and d (4) a, b, c and d
84. The van't Hoff factor for 0.1M Ba(NO3)2 solution
78. A 0.001 molal solution of [Pt(NH3)4Cl4] in water is 2.74. The degree of dissociation is-
had a freezing point depression of 0.0054°C.
(1) 91.3 % (2) 87 %
Kf for water is 1.80, the correct formulation for
(3) 100 % (4) 74 %
the above molecule is :
85. In a 0.2 molal aqueous solution of a weak acid
(1) [Pt(NH3)4Cl3]Cl
HX, the degree of ionization is 0.3. Taking kf for
(2) [Pt(NH3)4Cl2]Cl2
water as 1.85, the freezing point of the solution
(3) Pt(NH3)4Cl]Cl3 will be nearest to –
(4) [Pt(NH3)4Cl4] (1) – 260°C (2) + 0.480°C
79. A solution of urea (mol. mass 60 g mol–1) boils (3) – 0.480°C (4) – 0.360°C
at 100.18°C at the atomospheric pressure. If Kf 86. Aqueous solutions of 0.004M Na 2 SO 4 and
and Kb for water are 1.86 and 0.512 kg mol–1 0.01M Glucose are isotonic. The degree of
respectively, the above solution will freeze at :- dissociation of Na2SO4 is :-
(1) –6.54°C (2) –0.654°C (1) 25% (2) 60%
(3) 6.54°C (4) 0.654°C (3) 75% (4) 85%

E 101
JEE ( Main) - Chemistry
87. 13.44 g of CuCl2 is dissolved in 1 kg of water. 90. The Henry's law constant for the solubility of N2
Determine the elevation in boiling point of the gas in water at 298 K is 1.0 × 105 atm. The mole
solution. [K b = 0.5 Kg mol – 1 , mol. wt. of fraction of N2 in air is 0.8. The number of moles
CuCl2 = 134.1] of N2 from air dissolved in 10 moles of water at
(1) 0.16 (2) 0.052 298 K and 5 atm pressure is :-
(3) 0.1 (4) 0.5 (1) 4 × 10–4
(2) 4 × 10–5
88. 75.2 g phenol is added in (1 kg) of the solvent.
The depression in freezing point is 7. Calculate (3) 5 × 10–4
the percentage association if phenol undergoes (4) 4 × 10–6
dimerisation (Kf = 14). 91. An aqueous solution of oxalic acid dihydrate
(1) 0.75 (2) 75 contains its 6.3 g in 250 ml. The volume of
(3) 0.075 (4) None of these 0.1 N NaOH required to completely neutralize
89. When 20g of naphthoic acid (C 11 H 8 O 2 ) is 10 mL of this solution :-
dissolved in 50g benzene (Kf=1.72K kg mol–1), (1) 4 mL (2) 40 mL
a freezing point depression of 2K is observed.
(3) 20 mL (4) 2 mL
The van't Hoff factor (i) is
(1) 0.5 (2) 1
(3) 2 (4) 3

BRAIN TEASERS ANSWER KEY EXERCISE-II

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans 4 4 3 3 3 3 4 4 2 2 1 4 1 3 3
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans 1 3 4 3 4 1 3 3 2 4 4 3 3 4 3
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans 2 3 3 2 2 3 3 2 2 2 2 1 4 4 3
Que. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans 4 2 2 3 1 2 4 3 1 1 3 4 2 2 2
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans 4 1 3 2 2 3 1 2 1 4 1 3 2 3 3
Que. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans 3 3 2 2 3 2 2 4 2 3 3 1 2 1 1
Que. 91
Ans 2

102 E
 Solution

PREVIOUS YEAR QUESTIONS SOLUTION EXERCISE-III

1. Equimolar solutions of Non-Electrolytes in the 7. At 80°C, the vapour pressure of pure liquid 'A'
same solvent have -
is 520 mm Hg and that of pure liquid 'B' is
[AIIEE-2006]
1000 mm Hg. If a mixture solution of 'A' and
(1) Same freezing point but different boiling
point 'B' boils at 80°C and 1 atm pressure, the
(2) Same boiling point but different freezing amount of 'A' in the mixture is
point
(1 atm = 760 mm Hg) [AIEEE-2008]
(3) Different boiling and different freezing point
(1) 52 mol % (2) 34 mol %
(4) Same boiling and same freezing points
2. 18 g of glucose (C6H12O6) is added to 178.2g (4) 48 mol % (4) 50 mol %
of water. The vapour pressure of this aqueous
8. The vapour pressure of water at 20°C is
solution at 100° C is - [AIEEE-2006]
17.5 mm Hg. If 18 g of glucose (C6H12O6) is
(1) 7.60 Torr (2) 76.00 Torr
added to 178.2 g of water at 20°C, the vapour
(3) 752.40 Torr (4) 759.00 Torr pressure of the resulting solution will be
3. Density of a 2.05 M solution of acetic acid
(1) 17.675 mm Hg [AIEEE-2008]
(CH 3 COOH) in water is 1.02 g/mL. The
(2) 15.750 mm Hg
molality of the solution is - [AIEEE-2006]
(3) 16.500 mm Hg
(1) 3.28 mol kg– 1

(2) 2.28 mol kg– 1 (4) 17.325 mm Hg

(3) 0.44 mol kg– 1 9. Two liquids X and Y form an ideal solution. At
(4) 1.14 mol kg– 1 300 K, vapour pressure of the solution containing
4. A mixture of ethyl alcohol and propyl alcohol 1 mol of X and 3 mol of Y is 550 mm Hg. At
has a vapour pressure of 290 mm at 300 K.
the same temperature, if 1 mol of Y is further
The vapour pressure of propyl alcohol is 200
mm. If the mole fraction of ethyl alcohol is 0.6, added to this solution, vapour pressure of the
its vapour pressure (in mm) at the same solution increases by 10 mm Hg. Vapour
temperature will be [AIEEE-2007]
pressure (in mmHg) of X and Y in their pure states
(1) 350 (2) 300
will be, respectively :- [AIEEE-2009]
(3) 700 (4) 360
(1) 400 and 600
5. If a 5.25% w/v solution of a substance is
(2) 500 and 600
isotonic with a 1.5% w/v solution of urea
(3) 200 and 300
(molar mass = 60 g mol– 1) in the same solvent.
(4) 300 and 400
Then molar mass of the substance will be -
10. A binary liquid solution is prepared by mixing
[AIEEE-2007]
n-heptane and ethanol. Which one of the
(1) 90.0 g mol–1 (2) 115.0 g mol–1 folloowing statements is correct regarding the
(3) 105.0 g mol–1 (4) 210.0 g mol–1 behaviour of the solution ? [AIEEE-2009]
(1) The solution is non-ideal, showing –ve
6. The density (in g mL–1) of a 3.60 M sulphuric
deviation from Raoult's law
acid solution that is 29% H2SO4 (Molar mass = (2) n-heptane shows +ve deviation while ethanol
98 g mol–1) by mass will be - shows –ve deviation from Raoult's law
[AIEEE-2007] (3) The solution formed is an ideal solution.
(4) The solution is non-ideal, showing +ve
(1) 1.64 (2) 1.88
deviation from Raoult's law
(3) 1.22 (4) 1.45

E 103
JEE ( Main) - Chemistry
11. If sodium sulphate is considered to be completely 16. The degree of dissociation (α) of a weak
dissociated into cations and anions in aqueous electrolyte, AxBy is related to van't Hoff factor (i)
solution, the change in freezing point of water
by the expression :-
(∆T f), when 0.01 mol of sodium sulphate is
dissolved in 1 kg of water, is [AIEEE-2011]
(Kf = 1.86 K kg mol–1) :-
[AIEEE-2010] x + y −1 x + y +1
(1) α = (2) α =
(1) 0.0186 K i −1 i −1
(2) 0.0372 K
(3) 0.0558 K
i −1 i −1
(4) 0.0744 K (3) α = (4) α =
(x + y − 1) x + y +1
12. On mixing, heptane and octane form an ideal
solution. At 373 K, the vapour pressures of the 17. The molality of a urea solution in which 0.01g
two liquid components (heptane and octane) are of urea, [(NH2)2CO] is added to 0.3 dm3 of water
105 kPa and 45 kPa respectively. Vapour at STP is :-
pressure of the solution obtained by mixing 25 g
[AIEEE-2011]
of heptane and 35 g of octane will be
(molar mass of heptane = 100 g mol–1 and of (1) 0.555 m (2) 5.55 × 10–4 m
octane = 114 g mol–1) :- (3) 33.3 m (4) 3.33 × 10–2 m
[AIEEE-2010] 18. A 5% w/v solution of cane sugar (molar mass 342)
(1) 144.5 kPa (2) 72.0 kPa is isotonic with 1% w/v of a solution of an unknown
(3) 36.1 kPa (4) 96.2 kPa solute. The molar mass of unknown solute in
13. Dissolving 120 g of urea (mol. wt. 60) in 1000g g/mol is :- [AIEEE-2011]
of water gave a solution of density 1.15 g/mL. (1) 136.2 (2) 171.2
The molarity of the solution is -
(3) 68.4 (4) 34.2
[IIT-2011]
19. A 5.2 molal aqueous solution of methyl alcohol,
(1) 1.78 M (2) 2.00 M
CH3OH, is supplied. What is the mole fraction of
(3) 2.05 M (4) 2.22 M
methyl alcohol in the solution ? [AIEEE-2011]
14. The freezing point (in °C) of a solution containing
0.1 g of K3[Fe(CN)6] (Mol. Wt. 329) in 100 g (1) 0.086 (2) 0.050
of water (Kf = 1.86 K kg mol–1) is - (3) 0.100 (4) 0.190
[IIT-2011] 20. The density of a solution prepared by dissolving
–2 –2
(1) – 2.3 × 10 (2) – 5.7 × 10 120 g of urea (mol. mass = 60 u) in 1000 g of
–3 –2
(3) – 5.7 × 10 (4) – 1.2 × 10 water is 1.15 g/mL. The molarity of this solution
15. Ethylene glycol is used as an antifreeze in a cold is :- [AIEEE-2012]
climate. Mass of ethylene glycol which should be (1) 2.05 M (2) 0.50 M
added to 4 kg of water to prevent it from freezing (3) 1.78 M (4) 1.02 M
at – 6°C will be : 21. Kf for water is 1.86 K kg mol–1. If your automobile
radiator holds 1.0 kg of water, how many grams
(Kf for water = 1.86 K kgmol–1, and molar mass
of ethylene glycol (C2H6O2) must you add to get
of ethylene glycol = 62 gmol–1)
the freezing point of the solution lowered to
[AIEEE-2011]
–2.8°C ? [AIEEE-2012]
(1) 400.00 g (2) 304.60 g (1) 27 g (2) 72 g
(3) 800.00 g (4) 204.30 g (3) 93 g (4) 39 g

104 E
 Solution
22. The freezing point of a 1.00 m aqueous solution 27. 29.2 % (w/w) HCl stock solution has a density
of HF is found to be –1.91°C. The freezing point of 1.25 g mL–1. The molecular weight of HCl is
constant of water, Kf, is 1.86 K kg mol–1. The 36.5g mol–1. The volume (mL) of stock solution
percentage dissociation of HF at this concentration required to prepare a 200 mL solution of 0.4 M
is :- HCl is :-
[AIEEE-2012 (Online)] [IIT-2012]
(1) 2.7% (2) 30%
(1) 4 (2) 2
(3) 10% (4) 5.2%
(3) 8 (4) 12
23. The concentrated sulphuric acid that is available
28. For a dilute solution containing 2.5 g of a non-
commercially is 95% H2SO4 by weight. If the
volatile non-electrolyte solute in 100 g of water,
density of this commerical acid is 1.834 g cm–3, the
the elevation in boiling point at 1 atm pressure
molarity of this solution is :-
is 2°C. Assuming concentration of solute is much
[AIEEE-2012 (Online)]
lower than the concentration of solvent, the
(1) 17.8 M (2) 15.7 M
vapour pressure (mm of Hg) of the solution is
(3) 10.5 M (4) 12.0 M
–1
24. Liquids A and B form an ideal solution. At 30ºC, (take Kb=0.76 K kg mol )

the total vapour pressure of a solution containing [IIT-2012]

1 mol of A and 2 moles of B is 250 mm Hg. The (1) 724 (2) 740
total vapour pressure becomes 300 mm Hg when
(3) 736 (4) 718
1 more mol of A is added to the first solution. The
vapour pressures of pure A and B at the same 29. The molarity of a solution obtained by mixing

temperature are :- 750 mL of 0.5(M)HCl with 250 mL of 2(M)HCl

will be:-
[AIEEE-2012 (Online)]
(1) 450, 150 mm Hg [JEE(Main)-2013]

(2) 250, 300 mm Hg (1) 0.875 M (2) 1.00 M

(3) 125, 150 mm Hg (3) 1.75 M (4) 0.975 M

(4) 150, 450 mm Hg 30. The density of 3M solution of sodium chloride is

25.
–
The ppm level of F in a 500 g sample of a tooth 1.252 g mL–1. The molality of the solution will
–
paste containing 0.2 g F is :- be: (molar mass, NaCl = 58.5 g mol–1)

[AIEEE-2012 (Online)] [JEE(Main)-2013 (Online)]

(1) 250 ppm (2) 200 ppm (1) 2.18 m (2) 3.00 m
(3) 400 ppm (4) 1000 ppm (3) 2.60 m (4) 2.79 m
26. A solution containing 0.85 g of ZnCl2 in 125.0 g 31. A molecule M associates in a given solvent
of water freezes at –0.23ºC. The apparent degree according to the equation M ƒ (M)n. For a certain
of dissociation of the salt is :
concentration of M, the van’t Hoff factor was
(kƒ for water = 1.86 K kg mol–1, atomic mass ; found to be 0.9 and the fraction of associated
Zn = 65.3 and Cl = 35.5) molecules was 0.2. The value of n is :
[AIEEE-2012 (Online)]
[JEE(Main)-2013 (Online)]
(1) 1.36% (2) 2.47%
(1) 2 (2) 4
(3) 73.5% (4) 7.35%
(3) 5 (4) 3

E 105
JEE ( Main) - Chemistry
32. Vapour pressure of pure benzene is 119 torr and 35. Benzene and naphthalene form an ideal solution
that of toluene is 37.0 torr at the same at room temperature. For this process, the true
temperature. Mole fraction of toluene in vapour statement(s) is(are)
phase which is in equilibrium with a solution of [JEE(Advanced)-2013]
benzene and toluene having a mole fraction of
(1) ∆G is positive
toluene 0.50, will be :
(2) ∆Ssystem is positive
[JEE(Main)-2013 (Online)]
(3) ∆Ssurroundings = 0
(1) 0.137 (2) 0.205
(4) ∆H = 0
(3) 0.237 (4) 0.435
36. Consider separate solution of 0.500 M
33. How many grams of methyl alcohol should be
C2H5OH(aq), 0.100 M Mg3(PO4)2(aq), 0.250 M
added to 10 litre tank of water to prevent its
KBr(aq) and 0.125 M Na3PO4(aq) at 25°C. Which
freezing at 268 K ?
statement is true about these solutions, assuming
-1
(Kf for water is 1.86 K kg mol ) all salts to be strong electrolytes ?
[JEE(Main)-2013 (Online)] [JEE(Main)-2014]
(1) 899.04 g (2) 886.02 g (1) 0.125 M Na3PO4 (aq) has the highest osmotic
(3) 868.06 g (4) 880.07 g pressure.
34. 10 mL of 2(M) NaOH solution is added to 200 mL (2) 0.500 M C2H5OH (aq) has the highest osmotic
of 0.5 (M) of NaOH solution. What is the final pressure.
concentration ? (3) They all have the same osmotic pressure.
JEE(MAIN)-2013 (Online)] (4) 0.100 M Mg 3(PO 4) 2 (aq) has the highest
(1) 0.57 (M) (2) 5.7 (VI) osmotic pressure.
(3) 11.4(M) (4) 1.14 (M) 37. The vapour pressure of acetone at 20°C is
185 torr. When 1.2 g of non-volatile substance
was dissolved in 100 g of acetone at 20°C, its
vapour pressure was 183 torr. The molar mass
(g mol–1) of the substance is :
[JEE(Main)-2015]
(1) 128 (2) 488 (3) 32 (4) 64

PREVIOUS YEAR QUESTIONS ANSWER KEY EXERCISE-III

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans 4 3 2 1 4 3 4 4 1 4 3 2 3 1 3
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans 3 2 3 1 1 3 1 1 1 3 3 3 1 1 4
Que. 31 32 33 34 35 36 37
Ans 1 3 3 1 2,3,4 3 4

106 E