KELANTAN MATRICULATION COLLEGE

CHEMISTRY 1 SK015
SESSION 2021/2022
PRACTICE TO PERFECT A (SET 4)

1. How many nitrogen atoms are present in 32 dm3 of nitrogen gas at STP?
a. 1.7 x 1024 atoms
b. 7.5 x 1023 atoms
c. 1.5 x 1024 atoms
d. 3.0 x 1024 atoms

2. Which of the following does not have the same number of electrons as in a
sulphide ion, S2- ?
a. Ar
b. H2O
c. Sc3+
d. Cl-

3. When 69.0g of lead were heated in excess oxygen,79.6g of an oxide of lead were
obtained. What is the empirical formula of the oxide?
[Relative atomic mass: O=16 Pb = 207]
a. PbO
b. PbO2
c. Pb2O3
d. Pb3O4

4. The chemical equation for the reaction between KIO3 and Na2SO3 is shown
below.
KIO3 + Na2SO3 KIO + 2Na2SO4
Which of the following statements about this reaction is correct?
a. KIO3 is the oxidising agent.
b. Na2SO3 is reduced to Na2SO4.
c. The oxidation number of iodine decrease from +1 to -1.
d. The oxidation number of sulphur increase from +2 to+4.

5. Which of the following contains 1 mol of particles stated?

a. Chlorine molecules in 35.5 of chlorine gas
b. Electrons in 1g of hydrogen atom
c. Hydrogen ions in 1dm3 of 1 mol dm-3 aqueous sulphuric acid
d. Nitrogen atoms in 22.4 dm3 of nitrogen gas at s.t.p

6. Which of the following chlorine compounds contain the same number of atoms
as the number of atoms in two moles of chlorine gas?
I 2 mol hydrogen chloride
 II 1 mol chlorous acid, HClO2
III 2 mol chlorine monoxide, Cl2O
a. I only
b. I and II
c. II and III
d. I,II and III

7. Hydrochloric acid is used in the production of batteries, photoflash bulbs and

fireworks. What is the mole fraction of hydrogen chloride in hydrochloric acid
which contains 42% HCl by mass?
a. 0.11
b. 0.26
c. 0.33
d. 0.44

8. Aspirin is produced from salicyclic acid as follows:

C7H6O3 + CH COOCOCH C9H8O4 + CH3COOH
3 3
salicyclic acid aspirin

If the percentage yield of the production is only 80%, calculate the actual yiels of
aspirin if 5.0g of salicyclic acid is used.
[ Ar: H = 1, C = 12, O = 16]
a. 3.0 g
b. 5.2 g
c. 4.8 g
d. 6.4 g

9. Choose the electronic configuration that fail to obey the Hund’s rule for an atom
at its ground state:
a.

1s 2s 2p
b.

1s 2s 2p
c.

1s 2s 2p
d.

1s 2s 2p

10. The energy required to excite an electron from n=3 to n= 5 is

 I. Equal to the amount of energy when an electron falls from n=5 to
n=3.
II. Less than the energy required to excite an electron from n=2 to n=3
III. The same energy as the energy required to excite an electron from
n=2 to n=4.
a. I only
b. I and II
c. II and III
d. I, II, III

11. The electronic configuration of cation , A5+ is 1s2 2s2 2p6 3s2 3p6. What would be
the electronic configuration for A?
a. 1s2 2s2 2p6 3s2 3p5
b. 1s2 2s2 2p6 3s2 3p1
c. 1s2 2s2 2p6 3s2 3p6 3d5
d. 1s2 2s2 2p6 3s2 3p6 4s2 3d3

12. Given below are orbitals that occupied by valence electron of an atom Z:

z
z

y
x
x y

I II
z z

x y x y

III IV

z z

x y x y

V VI
 For orbital I and II its fully filled by electrons. While for orbital III, IV, V and VI
its half filled by electron. Choose the CORRECT electronic configuration for
valence electron of an atom Z.
a. ns2 nd10
b. ns2 nd5
c. ns2 nd6
d. ns1 nd5

13. CH3F and CF4 are same molecule geometry

a. Square planer
b. Tetrahedral
c. See Saw
d. T Shaped

14. Below are the list of physical properties of metallic compounds except

a. Malleability
b. Ductility
c. Amorphous
d. Thermal conductivity

15. Why aluminium has higher boiling point than sodium?

a. Size of atom Na is smaller than Al

b. No of valance Na is greater than Al
c. Charge of ion Al is greater than ion Na
d. The attraction of cation towards the electron sea is stronger for Na compared to
Al

16. The most plausible lewis structure of chlorate ion, ClO3- are obeys except
a. 2 double bond
b. 2 lone pair for centre atom
c. Trigonal pyramidal
d. 0 and -1 formal charge for O

17. For species NH4+, NH3 and NH2–, identify their molecular shapes.
a. Distorted tetrahedral, T-shaped, Linear
b. Square planar , Trigonal pyramidal, Linear
c. Tetrahedral, Trigonal planar, V-Shaped
d. Tetrahedral, Trigonal pyramidal, V-shaped

18. Consider the molecules BCl3 and ICl3. What is the hybridisation of the central
atom in both molecules?
a. sp3 and sp3d
b. sp2 and sp3d
c. sp3 and sp3d2
d. sp2 and sp3d2
19. Predict the polarity the compounds PCl3 and POCl3 respectively
a. Polar and non polar
b. Non polar and polar
c. Both are polar
d. Both are non polar

20. A piston-cylinder holds 7.00 g of CO2 at 160 oC and 110 kPa. How many grams
of CO2 will it hold at 27 oC under the same pressure?

a. 5.2
b. 0.231
c. 10.1
d. 32

21. 2 moles of hydrogen gas are allowed to react with 1 mole of nitrogen gas in a
30 L container at 25oC.
N2 (g) + 3H2 (g) → 2NH3 (g) . If all hydrogen gas are converted to ammonia,
what is the total pressure after the reaction is completed.

a. 0.272
b. 1.359
c. 1.087
d. 1.666

22. Give the conditions that cause real gases to deviate from ideal behavior.

a. High temperature and low pressure

b. High pressure and temperature
c. Low pressure and temperature
d. High pressure and low temperature

23. Which of the following equilibrium reactions will shift to the right if the pressure
is increased at a fixed temperature?

a. PCl5(g) PCl3(g) + Cl2(g)

b. O2(g) + 2F2(g) 2F2O(g)
c. Fe2O3(s) + 3CO(g) 2Fe(s) + 3CO2(g)
d. NH4HS(s) NH3(s) + H2S(g)

24. At 237oC, Kp for the reaction PCl 5(g) PCl 3(g) + Cl2(g)
is 985 atm. What is Kc for the reaction?

a. 1.93
b. 3.86
c. 23.5
d. 50.6
25. When a mixture of 1 mole of nitrogen and 3 moles of hydrogen is allowed to
react until equilibrium is attained, the total pressure is p.
N2(g) + 3H2(g) 2NH3(g)
Under these condition, 50% of nitrogen has reacted. What is the partial pressure
of ammonia in the equilibrium mixture?
a. p
3
b. 3
p
c. p
4
d. 4
P

26. Which of the following given rank is in order of increasing acid strength?
I : HNO2 Ka = 4.5 x 10-4
II : HCN Ka = 4.9 x 10-10
III : C6H5COOH Ka = 6.3 x 10-5

a. II<I<III
b. II<III<I
c. I<II<III
d. III<I<II

27. C6H5COO- ion is the conjugate base of benzoic acid C6H5COOH (Ka = 6.5 x 10-
5
). What is the value of the base ionisation equilibrium constant, Kb for
C6H5COO- ?

a. 6.5 x 10-5
b. 5.3 x 10-5
c. 1.5 x 10-10
d. 6.5 x 10-10

28. A solution is prepared by mixing 500 mL of 0.10 M NaOCl and 500 mL of 0.20
M HOCl. What is pH of this solution?
[Ka HOCl = 3.2 x 10-8]

a. 7.00
b. 4.10
c. 7.49
d. 7.19

29. Consider a solution which is 0.10 M in CH3COOH and 0.20 M in CH3COONa.

Which of the following statements is true?

a. If a small amount of NaOH is added, the pH decreases very slightly.

b. If NaOH is added, the OH- ions react with the CH3COO- ions.
c. If a small amount of HCl is added, the pH decreases very slightly.
 d. If HCl is added, the H+ ions react with CH3COOH ions.

30. If 100. mL of 0.025 M NaCl is mixed with 150. mL of 0.0015 M Pb(NO3)2, will
a precipitate form?
(Ksp PbCl2 = 1.6 × 10-5)

a. No, because Qsp > Ksp.

b. Yes, because Qsp > Ksp
c. Yes, because Qsp < Ksp.
d. No, because Qsp < Ksp

Disediakan Oleh :

SITI AFIZA HJ BASIR

KHAIRUL ASWARI AB RAHMAN
NOOR NAJIHAH KAMARUDDIN