Structure/Geometry of the Following Molecules/Ions
are Given on Pages Shown Against Each Species
Group 1 (IA) -
H2 -495, 559; H 24 -560; Li,-560;H-569
Group 2 (II A)
Be2 - 560; BeF, -512: BeCL, - 506
Group 13 (III A)
B, - 560: BF3 - 513. 564: BCI 3 - 508; B0 13-- 514: BH4 - 517; BF4- - 452; R3N1H6
(Borazine or borazole) - 930: BN - 930
Group 14 (IV A)
(i) C,- 561; CH - 510: CO - 453, 536, 563, 568; CO,- 538; C22 (Acetylide ion) - 990; C
(Allylide ion)-99I; C0 12 - 539; SnCl2 -515
Group 15 (VA)
(1) N, -487, 499, 561; N 2 4 - 569; NH 3 - 497, 519; NH 4 +- 453, 518;
PF5 -523; NF-3 - 564; NH, - NH, or N,H4 - 1063; HN 3 - 1064, 1065; N 3-- 567, 1064,1086;
(ii) N20 - 1073, 1089, 1090; NO - 563. 1073; NO 4 (Nitrosoniuin ion) - 563, 1097:
N,03 -1074: NO2 - 1074, 1091, 1096; NO,4 -566, 1096; N 2 04 - 1074; N 2 05 - 1075
(iii)H,N,O, and N 2 0, 2 - 1083; HNOI - 1083: NO, - 566. 1083, 1096; HNO 3 - 1084;
NO3 - 564,1084; HNO 4 - 1084;
(iv)N(CH3 ) 3 (Trimethylamine) and N (Si H 3 ) 3 (Trisilylamine) - 1084; NH, (Amide ion)
- 1085; N2H54 (Hydrazinium ion) and N,H62 (Hydrazoniunl ion) - 1088
(v)P,O3 or P406 - 1105; P205 or P4010 - 1107;
(vi)H3 PO, - 1117; H3P0 1 -1117: H3 PO4 - 1117, 1125; H 4P,06 - 1118; H4P,07 - 1118;
I-1P03 - 1118; [(P0 1 ) 3 ] 3- - 1124: [(PO3 )4] - 1124; [(PO 3 )]" - 1124; H3P05 - 1119; H4P2 08 -
1119;
(vii) PCI 1 - 1120; PCI 3 - 1121; [PC1414- 1121: [PC1 6 1 - 1121; [PBr4 ] 4 - 1127; [ P141'-
1127; POd 3 - 1121
Group 16 (VIA)
(i) 0, - 487, 499, 562; 0; (Superoxide ion) - 562; O, 2 (Peroxide ion) - 569; 0 - 569; 03
-452, 542; S8 - 1131; H20 -496, 520; H304 -453; 1-1,0, -451.
040 -
(ii) SF, - 525, 564; SF-6 - 529: SC12 - 1136; S2CI I - 1137
(iii) so -452, 544, 1138; SO (Gaseous) -452, 547. 1140; SO., (Solid) - 549; S0 3 (Solid (x,
and r forms) - 1141; ScO., (Solid) - 1138; 0 2F., - 1137
(iv) F12SO4 - 1161; S- 564: 5- 452, 1161; H 2S20 3 - 1165; S 2 O - 1165; S2O-
1166: HS,O6 - 1168; S,O -1168; II,S 306 . S.,O . H 2S406, S 4 O. H 2S SO6, S 5 oj. H7S606.
S6 0- 1171, 1172; H7SOS. HSO5 - 1174; S-,S2Oj-1175
(v) SOCl2 - 1176: SO,C17 - 1177
Group 17 ('/11 A)
(i)F2-497.562;HF-495: 1-IFZ-1l98
(ii) ICI - 522; CIF3 - 526; IF5 - 530; IF., - 533
(iii) 1255; ICI-52l; 1F -526; I-528; ICI - - 528; LBr- 1282; ICI - - 1282
(iv)02F2 - 1137;C1 2 0- 1223;C102 - 1224; C1,O6 - 1238; C1 20.,- 1225;12O4- 1237; 1205
1238; 1409 - 1237
(v) C10- 1227; CIO- - 1234; ClO- 1234: ClO - 1236; BrO -564, 1282; CaOCl 2 or
Ca (OCI) Cl (Breaching powder) - 1.231
(vi) CN (Cyanide ion)- 1255; NC (Isocynide ion)- 1255 ;OCN (Cyanate oroxycyanide ion)
- 1255; N CO (Isocyanate ion) - 1255; SCN- (Thiocyanate ion) - 1255; NCS (Isothiocyanate ion) -
1255; C N 0 (Fulminate ion) - 1255
Group 18 (Zero)
He -560; Ne2 -562: Xc03 - 564; Xe04 - 1281; XeF, - 528; XeF4 -531, 564: XeF6 -534;
XeOF4 - 1276: XeOF, - 1282; XeO1 F, - 1282; XeO.,F, - 1282; XeO2F4 - 1282
MM
