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Reactor sizing
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0% found this document useful (0 votes)
89 views40 pagesReactor Sizing Notes
Reactor sizing
Uploaded by
Yash ChorariaCopyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
/ 40
F
\6 0B 2099.
He ae = moles i trned,
Cnlume of fd time?
KINETIes Of HomMoneNntous REACTION
deal _veachor types
“Batch Pua Plow Mixed flow
YN i Hee
| a Bs pn
Fluide pastes Cat
Uniform cone ben wt de. Uniform mixed,
everywhere ih wise game compasition
se suackor,bub no mex of every drut
ait inee
cfeourse Mie Loder ond earxdier
enlestirg Rt) and punofor & of
combinolion = ;
en vara tine we. no overtabii erat.
ee I is oo “Pta foal
o moved Zn singe Fie
Need not be an Rrogerencer __-
Seolated syste
Steady state fle
Diff behween Laminar & orbuloxt Flovs -
a Tn pl flows no vasaatien ef Plato velocity
_B [ete Equablion
aA+bB ——F cel +dD
—% = -_l dN = oiss
Ye _Wolume dima)
The vates_of 7xn_ove EE
Se ee
al ooo ef P)
che vate of - reaction 2° Inefluanced by
_* | Composition — $$ —________________|
ney 4 te pal
frog, yctemb (random Kineb'e enongy of xan)
+ Bi tght_ 2atensity within her Systm —_
+ Mag a
=% = KG = Ke GS
Ke peche oxo vate |
KAA) = pre exponenciall ; factor a frag backer
_£ = Activation. energy i ] J Ear Activation evergs
mac Cneentrakion - per term et yote eqyichien
+ When @ gingle hocliomehfe equatian ond o
a Zrale xate equokion ase deren, Sr az
eck won to
again ‘Yefreseut dtu. \pregress of Hr sucction , 5s eats
ae Single reactien, iy
hon Mote Shae ous hoo Jomebrie. equatien
ord more Shan oe Kinshe embreasion »J¢
Cotlked Kindle sunchion. 1% 08 20822
Multiple reactions
Soutes wn A PRPS
_
Rayelted 1x0 ao and AR ide
Competitive B—-+s gi
Complicated sale mes
A+B —-R
Rt Bor S
ste. Elementary ard avn-clementory yeoctieng
A+B FR
tho “ote of disiopeaxonce of A
~Vy = kKCaCe
* GeRenchtions Gn tel, dita. safe eayaltion
ole Lernentary soodisn.
* non- elementary osadten
Ho+ Gy, —P QB
Ko +Bid6.) | m1Qar
Molecular ty} 0 Reasttsn
—. The no-6f molecuted Snvolved Zn a reackien
ds tte moleculayity of, a reactsa
he powers to Wilh di concenbotions asa
volsed!- tte owlese of tite seaacddion. Tus is
tt Lavo ef moss acten ef
Toke pHa ok (oradluct oF eone of eool-verctoud
bbe ci
= en
K= (ime) Gone)
n= ordex of Ten.
- “Representation af an elementary RN
~ |, MEK GSC
elementary ron ore cPten rebreendial by an
eqtoGi en roving, ba. die wolecuQascty eke
eode coustauk . Date js C aA th b)
y “Ta = REKCR -
- : cae nesesany fo eheoi Fy Ge 7 : .
Reece clstancte
—___.aenstant is offered ___
Bee H Qe 2D —P ST ee 7
. ree eee oe
\ a = Kees ae
el eee 700
—— =—Ye - —% . eee
2B = aniaia
= & a t
t See t=
———. 2n_ gubstitde
|- i a ut
[esaauesaaa ae aaa < ]\Nonelementary Recllion
Whose stiockiometyy does not matelh tts Kinatics
Stivcbiomebry
Ay+ Stl, <— ANHy
i,” K GIDEA Kee fH)
“ee
@ide= vate of Pamation — robe of dussofeannce
ef osnmone, & OMnAo Kier
© Kin Sieg non- elamento:
f,4 = ON
- OP His Kineticg of the steeacttion anda tthiat Hie
reo.ckion GS on ~ elementary we may postulahe
a gelice of clomontam, Bteps de explain the Knahe
fs <=> ant
+8, = — AQ+ &
t+ eS AB uncbseived) ateveredinSes
1D Gime steditaafla : Clee Co bg-r Tas Bo oSShy:
4) Sion andl Polar Substances: Ss pea wy, NY
cHpH, jit
3) Molecules
ArR—>s RSdlernadiateis weaall,
reacfive -
LD, Transition compexes.
Nine Que ——
Grtermadiotiay? > Reduobe
ae 7
a 1 Reaofant —?(Ziter madrobe)
Paglia (6lator madeadS! +Reochau —>Clabempadliote)
: : + \roduk | ” S: fee voLiaad Veen oA media wien
3 + Ry, <> arr
\
Treen ey Dalf ed
ae te fen 5
"2.
BW, SQW Lanattennns Teriuhy
Bee Hy == Bar +H” Pedpagain
Wor Gy << SHBy + By Probupho-
BEY ron alin Rem (piso ante)
A ang — meee deen
= KCatLe) Mi= constant
(Me)
he
Atenas cs Gerad
CA a enzyme) —e R + eneyre
Qk enzyme - din credaion, !
3) Trancitien onmpler ,o% “4
w
@ugd2No > Coe 7M
crn
aA — R*S
ere fone |
ne p +A > AF +A cendtion of energie
molecule
'
\
Ane" A+A Poimakien +o stale fore, |
by cell gion
ph —PR+S_ Shotancous ducmlpesitten |
nko Yoroducks. (9 0g 2092
TESTING KINETIC MODES
Anhese elementary swactions we hystese
dia exlctence a} eitier of 2 types of
intermediates.
Type -1 = Unseen and unmeaawwad nkexmadods ?
Cd is gral and 403 ~o
this js eat steady stati afpproximakien.
“Wpe-2- saneeerias catalyst of anitial cone.
GJ =(el+e) Site
Ossie eitfeble au = =0 ov dint @ as fn
| Quilibrium eee
Neon) ut) romney
hoe K=O
Ke Calle)
45 Tembrokure dependank berm F arake equobien
7 = BCemprtwe) - & (eompesitien)
=k § Concentration) Prehenius lavo
~/R
Ke toe
2 £(+-
Lot = Jn ve E(+ +)
= (nk Vex Sud Yr wa straight ae et |
% large for Sooge valuos Of Oe ten
te igh activation enegy veg ne
- aoruitive. an
- Readtion ig more tomprabee senfitive af
a “ee SEARCHING cor a
Thee axe 3 axcos d Syuealligettion al a sunckion, |
dts thodlgomuby , te Kindics ancl dhe |
machari sac.
MECHANISM |
1). qoupliated sbioddiomabry or enc Stat
foie. suaction cenlitiens or extent ct
*Us alsase evidence of multiple reactions.
& Btiodlometn, Pon Quoged wfPose ;
| veackion O¢ cto eee a
Peer 4B OOOO
No ebrnen} suactions wit. mole culasity
cc tin cthree hove Jean obsowed te
3). The Combasdigon of th utioddiomatric, eapotien
Leis. tha exbestimental Kinetic exprestion con
Suggest iflitor or not webe daaling waist.
_ Ghvichly Sheaking the seaction softs Mould be.
Lauitten Sn tex og ¢ ths acbivities
A= Yue; Ulsa y; se dhe activity Coefficont.
Yer Kate = Ki Gata? (BE
- PD xeackion fay a storclhiometria equafien
A+8 =2R
Overall orci is 2,/ wrt A & ‘vort @
= bpiven dtu swactien, collaf us bth, slafiien
f dic suaction compnin.
eng tJe =O om oe
Gaath;
Se
Date (——!= a
pA + B.'= =
Sote exressi on
| a
_—%n =<
7 oth stn sp i tbh
A+2B =2R+S — _
| of clissopeaxnce of dttbstonce— os_given by _
-% = 1360 [A] [£e) pol 7 7 7
6+ frar ms : :
L mol ye fot = Gnots x4 a .
fal also he 2 Contant, —
rP-3 ms x mol
Seo LC CerFaln wxeaction has a vate given by
i. = 2 005 2 mol/ems- min if a
ne 4s to Ge exbressed un mole/Liter
and “he bee wien fixes fours hak usill be
tte, Value and anifs of ete. constort.
=> -% =o [05 Oy
> 6-019 I
K= ol), (liter) ee
Gitex). Lime Gmorye eamwicneca ram
li se
c= 5x60 _mol
b (literX hy)
~% = 300 mol _ Fr 30065
Gter)Cnr) —
New value of K= Soo hter)
@el)(time ) dh - 2:66Fh elena
ate
| 7 2 | nels:
‘ — dR = = Bs “oR _
aE po
ape kB —
Ge Ce "Coe The rode $e
peel. — Ht
be
a
aR = Co RT van tee
ae -
AG, = AKG
of mote constant oe
4 {| alt
| ; a = AG = i
: 120-829 J
a
a | deg = 0: ie xX Yoox 8.
Ha a OX B66
— | ot
_ _ mol!l-h | Date — /— /—__
sae
_—}— —
tee oy en ae =
i eta ee Steet
| k 5120-2 W/melsh
“| Ke 1w0.9 x el Boxe)
— a opus oe
ke 8.38 x15 Yard: se
4 ee
I aa =i ianaseisssaae eee n ol umn ex eld hi
oe =a Hee
oak Aun 5 elo
» Soe
by dhe Sn Gksen— Pn 189%, BF Dlbear
al Pot dies. ofa clestng se waa,
——____ dapentlonk on Tite fembratue an given by
| Gumbo of links 20 pis) +40 bourbon
ee Gani nk
_ — ao Sp, dhat dha alta
- “tia mushalesRic hata
oe “adiedion-ensigy 2m S/mnot_of Suase |
F __ adote 39 temp range Go—8O—____|
ate |r no dud 0 Ver r
_ 88 460 20 9.995% YR
ee oe Ce
_ BY age Bo B-WOII + O41
AU args a 85583 4 OF x16
at 4-8 Be opag 02 Lp 1 |
yor i a = |
ie, ae
ae
yh — + N20 wt No + Vo
Tye = Ki Los
[+ kKCn,o)
[>> Ko [nod =P Qnd order
\<< Ko PNG) =p ley ovder
NO, zat NO + uh x
Ne Sy io, [NPs Pate + Ip O0
Sager Bue.
chee! 28 coniistont Je sand
eon Loin athe “Vist ovdex droowbeirtion
nee ° wbexton
-2 [aes] = ki (a,05]- & [Noe] no¥|
~a Lees] = eLuog ]+ Ke [wos l[wes a
-a Ose] = #4 (ue) - Cae | Gx stent stale ae
seers so
_|- —_=«iss
“cn let] —Kolvest] =0 -@
(NO™] = Kes/ic,
8 ne + + vate Wor) = —
| on
-_ "coat AT SL
pel * atid enbaray
ejeo
el eisei = “elu Coes]
___ Bg t to wog)
[——————— when Kg>> Ko we can neglect The
Bo Cito.) —.o
AEah KeCNoy)
TA voint become {st Oder
2)2 The ecompesi ten
rawr heirs,
ore sate
8) ST a mechorPem sivfloy db azomettiane dreoupesie
Hf veactant A at Gode
2£en 1 and ioatm Plows a fret
lauo
A+ pe AF a
p* EP Rag
SB consistent Loe tha cboseved) Kinsticn
Difbrent mecharfems can be Ysopeted do eublain
\St ord Kinabicn Co Cain at tig medloutyw
dg correct Sn ¥he Coo A thie ont albernal ves
deaquines odldiitional evidence. ,
~A TAD = KiCal — Ko [oA )(0)
at
~ACet] = QC] - Y Laks ve Cet (A)
at
Sor steady wake
~ at =< gl a -ucAl -O-
a7 [tere CA) = Hela)”
b= ao
| =) = cel = ae
= All _ ele
Ta ge uf "e +*2CA
ye > fa atigh nd odbiden
es ae ae a)
TE ee > Kg =
TE uth Ve conn roy,
Sap = a CA”
: Ae
Tee +t a
pdms GkeCa) a
: ~ OO. EER)
won brevet
e Ahad en? wal
AYE & 2X fie unatoduad curye
2
xX SS RVE
~ ahd - _ylalce) +46 + 6b
Ae). ay, (OLE DS - 603
KBE age = reemiced eb}
ee 2 ce
ee el ee ~¥5 (03
Char Scientis
A+e oS x wit 20 on
x Se BE 7 (e)\-(+05
fra the sete fem Ya in terms of ca S(Esl
vy % and ¥, does
Q) Ist mechanigrn given
and mechanism gren
n - SX = Gd= 4K)
ia Ore Ke,
€-€d -&
Gd= 4 (eI(e.- x3
a=" 60s
aan — 4 Disndharkap eo a
a
AY:
Date __ /—_ /—
Bah Rk Design Copalien
for =
+ Sati-Sanle cberalion ‘
rl -Lesting new | prccesses Shor ave wid been Filly
+ The mmonufocke of “exhonsive paduch, asd
«| Roceases thal aso “ffl do Conved to conkingw.
: _orpouien. oe
— Best re of dh) con convesSong_tthak can be ebbcired
Shee seoaant tin the swockor | im long
i oan
“Hi labor © casts per pax bate, 2 via Bally ef
ee Rom bald te dhate, ond) ita defy
& loxge gede production!
= rag gona nde balance enpafion, :
ye fey!
ot fy NV - .
AN = —
at
A re.
Be = =YpV => dt = _aNa
Vay += N, = Nor Nox = = Nyol (5%) oe eee
| —Yav
|
|
Nai
~My
SSE
—_ > | = O-e=Nao AX 1
| ae a ae i
{ Mods = = Ah = Yay ae
— dts = —thefas _ 3 Continous-Flow reactors re
* Continous — Stived Lank yea:
* Bug - Plow veackor
: baciy ~ bed suactor,
(ar) Class notes
Bote Reaclov clesign Equadiion
~ Srnalt salle ovperakion ‘
testing new \prece ates Gal oo. not been (at, Dovdlped :
- The manufackuxe 4 expensive frwducts
~ Processes hak axe. Ja PRiowtt +o convert to conkinews
orperoHior g.
~ Advantages Of Reef, eonvenion Rat aon be obkereal
Qearfing dea veackiwk Snthe tecnofsy Por long
pena of tiene,
—Disadvankages ef BL (abor ceate he
vasiads ty vets Boe bat. aces
BiGierdty of lange scale \produchlen.
AY Continous Sfirred Sank veachor STP)
Also Known as vob , or back min yeackor Vereoily
uackt for Diguid plane sanctions .
Normally Crpouitid at steady state.
“Pesumed de he pedectly erixal.
“Consequendby tase 28 no ine dofperdonce ox ecivan
Suberdonce af tompredwu, ,concenkmbion ,of
reaction rite Gncido ke CSTR.
Samo ads Whe ert poral. Design custige fora. ese
y,av = aN 7
«fy :
fi
Bic fuav= V4
rsa stab
te -
Ve Volume of content ie quid oh Kn.
y V
% C= Aloo wate
\VO= Vo Cpo -Vln
Th
tt Design equations fer £ Flove Teaco
x Holor nalit al
lice fetees poe Sach Ais at er A a
in tla Syste
fed. oR syslem et en
(fe) - fos ®
fhe Fr Ae *)
= for aad syste , Shir vausrabic flow vote , Vv,
$6 constant and eqpal te \,
- for gpa aytlern , Cho Can be catieuttiBas! How! fa
enkesting ode Rrction, Yro.
~ (Me foubrabuce Fo and dtu Sac gas Sow of
Save ORex gan lar.
Cro = Po Yo,
RT Rt.
CSTR desgn eqcblion
~ Well nfined sulla Hh ace no eadQ
Vastiabions, dn tthe veaclor,
fox Oa gene) Veacths..
At o,® —» oe « ay
V= Gof G2 ive
“th Tedeg-venaked
Y= Fo (Fay Fac)
Se
Vea Fa%
& Wek HW lub ose Plows “‘Rooatoy (TT RP)
= A oyfendbiical pipe aS Nowme 044 ohporollad) ak ead
Sehr .
- Treat of fen Rx gon pore wwooklons E
Concentimiion and Conce quorily jhe ceoalen Tobe A
asy Conbinowly Sle anciad hireobion Horousl
. xeadey Brall but tte Zexo ordlan sea kon,
~ Theve 28 no vadRal vasSation an veadtion vals,
And Ra Teaakox ue Toa flag- How
ys
Va av
Molay Plow + Mielaw Ploworalt| eos abs. Welaoe woe 25)
6} shecies.) [a | Ob Spectea J 2 j
In ak v out ak Viav * termi
Mohortinne Mdes/ om ri
In + Greruxatione Te
Filv 7m ac ee |
~ ag |
=X
filvae - Flv Gon 9
av Sb af,
av “* Cangicten,
+f Leomotadlion
-f\ Se
A
fo
(i
B,
fo, 7
vy ve D
Ve ‘ Ath
iy
( ho
% coal)
fro a
|
\ *
F229
68 04 Anan
D2ing Continous flow eaclors
= Ky = Key (I-74)
pe
#kls) |
L
Siztng - delernine te reactor volume fer
Shecified comersion.
i reackton is cossied ae
oe oe ey
week te denhabign of | |
te gveataat Lie 1S san a |
2 niftle sansa
* Hence resiprocald ate Chr) wa
Foy ryeverible an
A —POQ+c
as XL, Vy —eO The oe
Gain Pre Veto Y Caathi
— fa, = Gye Foe — a
Hide balance on eather 2.2. s
A mole balance en reads \ gives
In — Ouk + Lenwation =o
fo - Al + “Yay, =o
Fo = Feo — Fach
Me Fok,
Yay ae ed
Qn Macher Q
a ee
a eee ee
v= "a =F
The
hee Ene = Fao Xe -%1)
Me G(% x) HEL
oR on 6s 48
L
4,
- et eee ee
oo Abbvoximadiin a umber
CSTR'S din a "a me | Ve
— y
|| Date 6 , el 22 _Gaarhiy
—— | [te ‘thes -more_number of staaslors Loe use
| ond ite volume _2e -acroaiing, So ‘Aha ot
ee te ao shlrlrmrmC—C—C
: fm Gane ha 00a Aci Ye too snuck ax. each
| Yeachoy JB req Pies a. Seber _selulp SN
L 102 dbtinmige
a == Pee CER tn gevfog
| We sow Rat 2 Cste’s § Sn seston gow E
_ total valune > fon a_i CST R foe ta
—_||Same_conversien . TV8s Case Moca | net Cold) trug |
o dor Ro 2 _ lug Plovo Teachors Pn geruen.
= lly. 2 C87 eye loss vane? |
© || When the. fined conc soy Bred Sn bot |
aig at elie nenabe iS samo __|
Land) ucQon Gaathi)
y
af ae rate ga ouplace 2. gf
ere _ Continous?! FR
—Requined to ad)8ve
: ems
[Reootor a > Vy [ee
Ya
jee al
‘Rexckor Qa Ve = eZ)
De Fniti ona
& Shoce time Chddiing time oy_mean, vrecidunce sin
co VAL
Fora PER yo
| t= fe = Cn di ak
Ye %
| oe
lh aCSTR
B4+c
O! 62 63 o& of 0G oF OF OF
_ eas dh 7 —
“heeeforiyhe 1 Nelume cee
ese cB wy eal
CSTR ‘ Y -- Sao00
PER 8 4 {ire
CSte Bf Yoo
-egtR 3 (b dor
Pre Q 2 MMe FH bono
On duty the fovenshizal lot Salo Ixoe