SAFETY DATA SHEET

(in accordance with Regulation (EU) 2015/830)

REPLENISHER RD1
Version 1 Date of compilation: 02/02/2017 Page 1 of 9
Version 2 (replaces version 1) Revision date: 26/02/2021 Print date: 05/08/2021

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING.

1.1 Product identifier.

Product Name: REPLENISHER RD1

Product Code: REDEV001

1.2 Relevant identified uses of the substance or mixture and uses advised against.

Direct use replenisher for CTP Thermal and CTcP UV positive plates.

Uses advised against:

Uses other than those recommended.

1.3 Details of the supplier of the safety data sheet.

Company: Platea Graphic SL

Address: C/ Joan Fernandez I Comas 3
City: 08940 Barcelona
Province: Barcelona
Telephone: (+34)934457553
Fax: (+34)934457553
E-mail: [email protected]
Web: www.plateatc.com

1.4 Emergency telephone number: USA, CAN:1-800-535-5053 / EU: 1-352-323-3500 (Available 24 hours)

SECTION 2: HAZARDS IDENTIFICATION.

2.1 Classification of the substance or mixture.

In accordance with Regulation (EU) No 1272/2008:
Eye Dam. 1 : Causes serious eye damage.

2.2 Label elements.

.
.

Labelling in accordance with Regulation (EU) No 1272/2008:

Pictograms:

Signal Word:
Danger
H statements:
H318 Causes serious eye damage.

P statements:
P264 Wash with clean water and soap thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or
shower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P501 Dispose of contents/container in accordance with current regulations on hazardous waste.

Contains:
disodium metasilicate

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 SAFETY DATA SHEET
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2.3 Other hazards.

The product may have the following additional risks:
The mixture / substance does not meet the criteria to be considered PBT or vPvB according to Regulation (EC) No.
1907/2006 (REACH), Annex XIII.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS.

3.1 Substances.
Not Applicable.

3.2 Mixtures.
Substances posing a danger to health or the environment in accordance with the Regulation (EC) No. 1272/2008, assigned a
Community exposure limit in the workplace, and classified as PBT/vPvB or included in the Candidate List:

(*)Classification - Regulation (EC)

No 1272/2008
Identifiers Name Concentrate specific
Classification concentration
limit
Index No: 014-010- Eye Dam. 1,
00-8 H318 - Met.
CAS No: 6834-92-0 Corr. 1, H290 -
disodium metasilicate 5 - 20 % -
EC No: 229-912-9 STOT SE 3,
Registration No: 01- H335 - Skin
2119449811-37-XXXX Corr. 1B, H314
(*)The complete text of the H phrases is given in section 16 of this Safety Data Sheet.

SECTION 4: FIRST AID MEASURES.

4.1 Description of first aid measures.

In case of doubt or when symptoms of feeling unwell persist, get medical attention. Never administer anything orally to persons
who are unconscious.

Inhalation.
Take the victim into open air; keep them warm and calm. If breathing is irregular or stops, perform artificial respiration.

Eye contact.
Wash eyes with plenty of clean and cool water for at least 10 minutes while pulling eyelids up, and seek medical assistance. Do
not let the person to rub the affected eye.

Skin contact.
Remove contaminated clothing. Wash skin vigorously with water and soap or a suitable skin cleaner. NEVER use solvents or
thinners.

Ingestion.
If accidentally ingested, seek immediate medical attention. Keep calm. NEVER induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed.
Corrosive Product, contact with eyes or skin can cause burns; ingestion or inhalation can cause internal damage, if this occurs
immediate medical assistance is required.
Contact with eyes may cause irreversible damage.

4.3 Indication of any immediate medical attention and special treatment needed.
Request immediate medical attention. Never administer anything orally to persons who are unconscious. Do not induce vomiting.
If the person vomits, clear the respiratory tract. Cover the affected area with a dry sterile bandage. Protect the affected area from
pressure or friction.

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 SAFETY DATA SHEET
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SECTION 5: FIREFIGHTING MEASURES.

The product is NOT classified as flammable, in case of fire the following measures should be taken:

5.1 Extinguishing media.

Suitable extinguishing media:
Extinguisher powder or CO2. In case of more serious fires, also alcohol-resistant foam and water spray.

Unsuitable extinguishing media:

Do not use a direct stream of water to extinguish. In the presence of electrical voltage, you cannot use water or foam as
extinguishing media.

5.2 Special hazards arising from the substance or mixture.

Special risks.
Fire can cause thick, black smoke. As a result of thermal decomposition, dangerous products can form: carbon monoxide, carbon
dioxide. Exposure to combustion or decomposition products can be harmful to your health.

5.3 Advice for firefighters.

Use water to cool tanks, cisterns, or containers close to the heat source or fire. Take wind direction into account. Prevent the
products used to fight the fire from going into drains, sewers, or waterways.

Fire protection equipment.

According to the size of the fire, it may be necessary to use protective suits against the heat, individual breathing equipment,
gloves, protective goggles or facemasks, and boots.

SECTION 6: ACCIDENTAL RELEASE MEASURES.

6.1 Personal precautions, protective equipment and emergency procedures.

For exposure control and individual protection measures, see section 8.

6.2 Environmental precautions.

Prevent the contamination of drains, surface or subterranean waters, and the ground.

6.3 Methods and material for containment and cleaning up.

Contain and collect spillage with inert absorbent material (earth, sand, vermiculite, Kieselguhr...) and clean the area immediately
with a suitable decontaminant.
Deposit waste in closed and suitable containers for disposal, in compliance with local and national regulations

6.4 Reference to other sections.

For exposure control and individual protection measures, see section 8.
For later elimination of waste, follow the recommendations under section 13.

SECTION 7: HANDLING AND STORAGE.

7.1 Precautions for safe handling.

For personal protection, see section 8.
In the application area, smoking, eating, and drinking must be prohibited.
Follow legislation on occupational health and safety.
Never use pressure to empty the containers. They are not pressure-resistant containers. Keep the product in containers made of
a material identical to the original.

7.2 Conditions for safe storage, including any incompatibilities.

Store according to local legislation. Observe indications on the label. Store the containers between 5 and 25º C, in a dry and
well-ventilated place, far from sources of heat and direct solar light. Keep far away from ignition points. Keep away from
oxidising agents and from highly acidic or alkaline materials. Do not smoke. Prevent the entry of non-authorised persons. Once
the containers are open, they must be carefully closed and placed vertically to prevent spills.
The product is not affected by Directive 2012/18/EU (SEVESO III).

7.3 Specific end use(s).

No specific use.

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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION.

8.1 Control parameters.

The product does NOT contain substances with Professional Exposure Environmental Limit Values.The product does NOT contain
substances with Biological Limit Values.
Concentration levels DNEL/DMEL:

Name DNEL/DMEL Type Value

DNEL Inhalation, Long-term, Systemic effects 6,22
(Workers) (mg/m³)
DNEL (General Inhalation, Long-term, Systemic effects 1,55
population) (mg/m3)
DNEL Dermal, Long-term, Systemic effects 1,49
disodium metasilicate
(Workers) (mg/kg
CAS No: 6834-92-0
bw/day)
EC No: 229-912-9
DNEL (General Dermal, Long-term, Systemic effects 0,74
population) (mg/m3)
DNEL (General Oral, Long-term, Systemic effects 0,74
population) (mg/kg
bw/day)

DNEL: Derived No Effect Level, level of exposure to the substance below which adverse effects are not anticipated.
DMEL: Derived Minimal Effect Level, exposure level corresponding to a low risk, that risk should be considered a tolerable
minimum.
Concentration levels PNEC:

Name Details Value

aqua (freshwater) 7,5 (mg/l)
disodium metasilicate
aqua (marine water) 1 (mg/l)
CAS No: 6834-92-0
aqua (intermittent releases) 7,5 (mg/l)
EC No: 229-912-9
STP 1000 (mg/l)

PNEC: Predicted No Effect Concentration, concentration of the substance below which adverse effects are not expected in the
environmental compartment.

8.2 Exposure controls.

Measures of a technical nature:

Provide adequate ventilation, which can be achieved by using good local exhaust-ventilation and a good general exhaust system.

Concentration: 100 %
Uses: Direct use replenisher for CTP Thermal and CTcP UV positive plates.
Breathing protection:
If the recommended technical measures are observed, no individual protection equipment is necessary.
Hand protection:
PPE: Non-disposable protective gloves against chemicals.
«CE» marking, category III. Check the list of chemicals for which the glove has
Characteristics:
been tested.
CEN standards: EN 374-1, En 374-2, EN 374-3, EN 420
A schedule for the periodical replacement of gloves should be established in order to guarantee their
Maintenance: replacement before pollutants permeate them. The use of contaminated gloves could be more dangerous
than not using gloves, since the pollutant can gradually accumulate in the glove's material.
They are to be replaced whenever tears, cracks or deformations are observed or when exterior dirt could
Observations:
reduce their strength.
Breakthrough time Material thickness
Material: PVC (polyvinyl chloride) > 480 0,35
(min.): (mm):
Eye protection:
PPE: Protective goggles with built-in frame.
«CE» marking, category II. Eye protector with built-in frame for protection against
Characteristics:
dust, smoke, fog and vapour.
CEN standards: EN 165, EN 166, EN 167, EN 168

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Visibility through lenses should be ideal. Therefore, these parts should be cleaned daily. Protectors should
Maintenance:
be disinfected periodically following the manufacturer's instructions.
Some signs of wear and tear include: yellow colouring of the lenses, superficial scratching of the lenses,
Observations:
scraping etc.
Skin protection:
PPE: Chemical protective clothing
«CE» marking, category III. Clothing should fit properly. The level of protection
Characteristics: must be set according to a test parameter called BT (Breakthrough Time), which
indicates how long it takes for the chemical to pass through the material.
CEN standards: EN 464,EN 340, EN 943-1, EN 943-2, EN ISO 6529, EN ISO 6530, EN 13034
In order to guarantee uniform protection, follow the washing and maintenance instructions provided by
Maintenance:
the manufacturer.
The protective clothing's design should facilitate correct positioning, staying in place without moving for
Observations: the period of use expected, bearing in mind environmental factors as well as any movement or position
the user might adopt while carrying out the activity.
PPE: Anti-static safety footwear against chemicals.
«CE» marking, category III. Check the list of chemicals against which the footwear
Characteristics:
is resistant.
EN ISO 13287, EN 13832-1, EN 13832-2, EN 13832-3, EN ISO 20344, EN ISO
CEN standards:
20345
For correct maintenance of this kind of safety footwear, it is necessary to observe the instructions
Maintenance: specified by the manufacturer. The footwear should be replaced as soon as any sign of damage is
observed.
The footwear should be cleaned regularly and dried when damp, although it should not be placed too
Observations:
close to a source of heat in order to avoid any sharp changes in temperature.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES.

9.1 Information on basic physical and chemical properties.

Appearance:Liquid
Colour: colorless
Odour:characteristic
Odour threshold:N.A./N.A.
pH:13
Melting point: N.A./N.A.
Boiling Point: >90 ºC
Flash point: >60 ºC
Evaporation rate: N.A./N.A.
Inflammability (solid, gas): inorganic mixture. Pyrophoricity is not a concern based on chemical structure and experience in
handling and use.
Lower Explosive Limit: N.A./N.A.
Upper Explosive Limit: N.A./N.A.
Vapour pressure: 23,24 mmHg
Vapour density:N.A./N.A.
Density (20ºC):1,085 g/cm3
Solubility:N.A./N.A.
Liposolubility: N.A./N.A.
Hydrosolubility: soluble
Partition coefficient (n-octanol/water): inorganic mixture
Auto-ignition temperature: Soluble silicates do not spontaneously ignite in contact with air.
Decomposition temperature: N.A./N.A.
Viscosity: N.A./N.A.
Explosive properties: non explosive. There are no chemical groups associated with explosive properties, therefore, according to
REACH, Annex VII, 7.11, column 2, the study is not necessary.
Oxidizing properties: non oxidising. Based on the chemical structure, the mixture is unable to exothermically react with
combustible materials. According to REACH, Annex VII, 7.13, column 2, the study does not need to be carried out.

N.A./N.A.= Not Available/Not Applicable due to the nature of the product

9.2 Other information.

Dropping point: N.A./N.A.
Blink: N.A./N.A.
Kinematic viscosity: N.A./N.A.

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The mixture is not corrosive to metals: silicates in aqueous solution form a protective film that inhibits metal corrosion, contains
corrosion inhibitors.
N.A./N.A.= Not Available/Not Applicable due to the nature of the product

SECTION 10: STABILITY AND REACTIVITY.

10.1 Reactivity.
The product does not present hazards by their reactivity.

10.2 Chemical stability.

Unstable in contact with:
- Acids.

10.3 Possibility of hazardous reactions.

Neutralization can occur on contact with acids.

10.4 Conditions to avoid.

- Avoid contact with acids.

10.5 Incompatible materials.

Avoid the following materials:
- Acids.

10.6 Hazardous decomposition products.

Depending on conditions of use, can be generated the following products:
- Corrosive vapors or gases.

SECTION 11: TOXICOLOGICAL INFORMATION.

11.1 Information on toxicological effects.

Splatters in the eyes can cause irritation and reversible damage.

Toxicological information about the substances present in the composition.

Acute toxicity
Name
Type Test Kind Value
LD50 Rat 1152 mg/kg bw [1]

Oral [1] Saiwai K, Ito T, Saito S, Hiraga K, Iwahara S (1980).

Safety|of the metal scavengers sodium metasilicate and
disodium metasilicate sodium|polyphosphate. Internal Report Toho University.
LD50 Rat > 5000 mg/kg bw [1]
Dermal
[1] study report, 2004.
LC50 Rat > 2.06 mg/l air (4 h) [1]
Inhalation
CAS No: 6834-92-0 EC No: 229-912-9
[1] study report, 2004.
a) acute toxicity;
Not conclusive data for classification.

b) skin corrosion/irritation;
Non-corrosive and non-irritating by dermal contact.
OECD 404 method, rabbit.

c) serious eye damage/irritation;

Product classified:
Serious eye damage, Category 1: Causes serious eye damage.

d) respiratory or skin sensitisation;

Not conclusive data for classification.

e) germ cell mutagenicity;

Not conclusive data for classification.

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f) carcinogenicity;
Not conclusive data for classification.

g) reproductive toxicity;
Not conclusive data for classification.

h) STOT-single exposure;
Based on available data, the classification criteria are not met.

i) STOT-repeated exposure;
Not conclusive data for classification.

j) aspiration hazard;
Not conclusive data for classification.

SECTION 12: ECOLOGICAL INFORMATION.

12.1 Toxicity.

Ecotoxicity
Name
Type Test Kind Value
Brachydanio rerio
LC100 250 mg/L (96 h h h) [1]
(Danio rerio)
Fish
[1] Richterich K and Muehlberg B (2001). Silicic acid,
disodium|salt. Fish, acute toxicity. Final Report R-0100922,
disodium metasilicate
Henkel|KGaA.
EC50 Daphnia Magna 1700 mg/l (48 h) [1]
Aquatic
invertebrates
[1] study report 1997
Aquatic plants
CAS No: 6834-92-0 EC No: 229-912-9

12.2 Persistence and degradability.

No information is available regarding the biodegradability of the substances present.

No information is available on the degradability of the substances present.No information is available about persistence and
degradability of the product.

12.3 Bioaccumulative potential.

No information is available regarding the bioaccumulation of the substances present.

12.4 Mobility in soil.

No information is available about the mobility in soil.
The product must not be allowed to go into sewers or waterways.
Prevent penetration into the ground.

12.5 Results of PBT and vPvB assessment.

No information is available about the results of PBT and vPvB assessment of the product.

12.6 Other adverse effects.

No information is available about other adverse effects for the environment.

SECTION 13: DISPOSAL CONSIDERATIONS.

13.1 Waste treatment methods.

Do not dump into sewers or waterways. Waste and empty containers must be handled and eliminated according to current,
local/national legislation.

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Follow the provisions of Directive 2008/98/EC regarding waste management.

Waste classification according to the European Waste Catalogue:

06 WASTES FROM INORGANIC CHEMICAL PROCESSES
06 02 wastes from the MFSU of bases
06 02 99 wastes not otherwise specified

SECTION 14: TRANSPORT INFORMATION.

Transportation is not dangerous. In case of road accident causing the product’s spillage, proceed in accordance with point 6.

14.1 UN number.
Transportation is not dangerous.

14.2 UN proper shipping name.

Description:
ADR: Not classified as hazardous for transport.
IMDG: Not classified as hazardous for transport.
ICAO/IATA: Not classified as hazardous for transport.

14.3 Transport hazard class(es).

Transportation is not dangerous.

14.4 Packing group.

Transportation is not dangerous.

14.5 Environmental hazards.

Transportation is not dangerous.

14.6 Special precautions for user.

Transportation is not dangerous.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code.
Transportation is not dangerous.

SECTION 15: REGULATORY INFORMATION.

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture.
The product is not affected by the Regulation (EC) No 1005/2009 of the European Parliament and of the Council of 16 September
2009 on substances that deplete the ozone layer.

Volatile organic compound (VOC)

VOC content (p/p): 0 %
VOC content: 0 g/l

The product is not affected by Directive 2012/18/EU (SEVESO III).

The product is not affected by Regulation (EU) No 528/2012 concerning the making available on the market and use of biocidal
products.
The product is not affected by the procedure established Regulation (EU) No 649/2012, concerning the export and import of
dangerous chemicals.

Kind of pollutant to water (Germany): WGK 1: Slightly hazardous to water. (Autoclassified according to the AwSV Regulations)

15.2 Chemical safety assessment.

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

SECTION 16: OTHER INFORMATION.

Complete text of the H phrases that appear in section 3:

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H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.

Classification codes:

Eye Dam. 1 : Serious eye damage, Category 1

Met. Corr. 1 : Corrosive to metals, Category 1
STOT SE 3 : Specific target organ toxicity following a single exposure, Category 3
Skin Corr. 1B : Skin Corrosive, Category 1B

Modifications compared to the previous version:

Section 2: product classification
Section 3: classification of substances
Section 7: storage
Section 9: physical and chemical properties
Section 11: toxicological information
Section 13: Waste Classification

Classification and procedure used to derive the classification for mixtures according to Regulation (EC)
1272/2008 [CLP]:
Physical hazards On basis of test data/calculation
Health hazards Calculation method
Environmental hazards Calculation method

It is advisable to carry out basic training with regard to health and safety at work in order to handle this product correctly.

Abbreviations and acronyms used:

AwSV: Facility Regulations for handling substances that are hazardous for the water.
CEN: European Committee for Standardization.
DMEL: Derived Minimal Effect Level, exposure level corresponding to a low risk, that risk should be
considered a tolerable minimum.
DNEL: Derived No Effect Level, level of exposure to the substance below which adverse effects are not
anticipated.
EC50: Half maximal effective concentration.
PPE: Personal protection equipment.
LC50: Lethal concentration, 50%.
LD50: Lethal dose, 50%.
PNEC: Predicted No Effect Concentration, concentration of the substance below which adverse effects are
not expected in the environmental compartment.
WGK: Water hazard classes.

Key literature references and sources for data:

http://eur-lex.europa.eu/homepage.html
http://echa.europa.eu/
Regulation (EU) 2015/830.
Regulation (EC) No 1907/2006.
Regulation (EU) No 1272/2008.

The information given in this Safety Data Sheet has been drafted in accordance with COMMISSION REGULATION (EU) 2015/830
of 28 May 2015 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council
Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC.

The information in this Safety Data Sheet on the Preparation is based on current knowledge and on current EC and national
laws, as far as the working conditions of the users is beyond our knowledge and control. The product must not be used for
purposes other than those that are specified without first having written instructions on how to handle. It is always the
responsibility of the user to take the appropriate measures in order to comply with the requirements established by current
legislation. The information contained in this Safety Sheet only states a description of the safety requirements for the
preparation, and it must not be considered as a guarantee of its properties.

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