DNVPS Fuel Testing Procedures Part 1
DNVPS Fuel Testing Procedures Part 1
Revision 3 : JULY 12
Introduction
Overview of the DNVPS Samples
Procedures For Sampling
Sampling
Sampling Kit
Sampling Device
Safety Considerations During Sampling
Request to Witness Sampling Form
Continuous-Drip Sampling
Dividing the Sample Evenly
Sealing the Bottles
Insert Sample into Ziplock Bag
Sample for Supplier
Ship's Retained Sample
MARPOL Annex VI Sample
Dispatching the Samples
Order Sampling Supplies
Thank you for choosing DNV Petroleum Services (DNVPS) as your fuel management partner. We are committed to
providing you with the best possible marine fuel management solutions.
DNVPS introduced the Fuel quality testing (FQT) service in 1980 to meet the needs of a maritime community seriously
concerned about the quality of bunkers supplied in ports worldwide. Over the years, the problems encountered by
shipowners and operators in the procurement and use of marine fuels have not diminished. You must safeguard your
vessels by ensuring the bunkers received are not used until tested.
DNVPS fulfils the requirements of an independent international testing service which is credible both to shipowners
and suppliers alike. We operate five wholly-owned and ISO 17025 accredited laboratories strategically located in
Singapore, Rotterdam, Fujairah, Houston and Oslo so that fuel samples from your ships will reach the appropriate
DNVPS lab in the shortest possible time. This in turn facilitates fast turnaround of test results and prompts technical
advice.
Spanning different time zones and linked by a Wide Area Network, DNVPS laboratories and technical team provide
24-hour support. And as soon as the test results of your fuel samples are available, you can download them directly from
DataAccess, our online service.
DNVPS has thus far tested more than 1 million marine fuel samples in our FQT programme. Our substantial market
share is well supported by an extensive monitoring network which allows us to spot fuel quality problems in bunkering
ports around the world. You will be immediately notified of these problems through our Bunker Alert service,
exclusively available to members of the DNV FQT Programme.
Fully compliant with MARPOL Annex VI requirements, the DNV FQT programme ensures that ship operators adhere
to approved procedures, documentation and sampling equipment (sample bottles, seals, line samplers and cubitainers).
Besides FQT, DNVPS also provides a whole range of other products and services, such as sampling kits; line samplers;
technical seminars; fuel system checks (FSC); blend optimization programme (BOP); bunker quantity surveys (BQS);
bunker quality statistics (including FuelWise, a 'live' data service available on the Internet); BunkerMaster, a bunker
management software offering a suite of calculation tools and information updates catering to current bunker
requirements and industry practices; and Total Fuel Management solutions, a consulting service helping ship
operators optimise fuel efficiency and savings.
In addition, DNVPS is also in the forefront of developing extended analytical services for marine fuels, including
ignition and combustion services as well as advanced investigative testing for detecting chemical wastes and other
contaminants. These services are all conducted in-house, and we also have access to other testing services available
throughout DNV, such as the materials laboratories in Singapore and Oslo.
As you embark on the DNV FQT Programme, please go through this Instruction Manual in detail, so that your vessels
can fully enjoy the benefits we offer.
Overview of DNVPS Samples
The diagram below describes the purpose of the different fuel oil samples to be taken under the DNV Fuel Quality
Testing and Fuel System Check programmes, as well as the associated labels accompanying these samples.
Please note that each sample must be duly-filled and attached with security seals and the respective service labels.
Sample to Lab Ship's retained Supplier's sample MARPOL Annex FSC sample
sample VI sample
This sample is to This sample is to This sample is
be provided with This sample is to be provided with This sample is to for checking the
the FQT sample be provided with the FQT sample be kept onboard efficiency of the
the FQT sample in the event the
bottle label and bottle label and supplier does not fuel pre-treatment
security seal and is bottle label and security seal and is system (see Fuel
provide a MARPOL
to be sent to DNVPS security seal and to be given to the System Check on
sample or it is not
laboratory for fuel is to be retained supplier. taken as per the page 15). Affix the
quality testing. on board. guidelines in MEPC FSC sample bottle
If the supplier 182(59). If the label and security
The bottle is to be In the event of a declines or discards supplier does fulfil seal to this sample,
placed in Ziplock quality dispute, the the sample, make this obligations which is to be sent
sample may be and provides a
bag and carton sure that this is to the DNVPS
required sent to a compliant sample
together with Chief recorded in the to the ship, then laboratory for
Engineers form and laboratory for testing ship's log. testing.
this is the official
copy of Bunker in the presence of MARPOL sample
Delivery Note and the parties involved and the “DNVPS Place the bottle in
sent to the appropriate in the dispute. MARPOL” sample a Ziplock bag before
DNVPS laboratory can be used for putting it in the FSC
in accordance with commercial purposes carton box provided.
these instructions. or discarded. Dispatch the sample
to the appropriate
The sample is to
be provided with DNVPS laboratory
MARPOL bottle in accordance with
label and security given instructions.
seal. It is to be
stored, recorded in
inventory log or
otherwise treated as
an official MARPOL
sample log.
SAMPLING
The importance of proper sampling cannot be over-emphasised, as the analysis results will only be as good as the samples
submitted.
Please ensure that all staff involved are fully conversant with both the sampling procedure recommended in this
instruction manual and your company's fuel management practices.
DNVPS advocates Custody Transfer Sampling, which is also a requirement under the Code of Practice for Bunkering
(SS600). If the fuel has been purchased on FOB terms and delivered by barge or at the tank terminal, the DNVPS
recommended location for Custody Transfer Sampling is on the ship's bunker manifold. Note that Resolution MEPC
182(59) referred to in Annex VI of MARPOL 73/78, also specifies that the representative sample is to be taken at the
ship manifold. If for any reason the sample cannot be taken at the ship manifold, such reasons should be recorded.
In order to obtain a representative sample of the fuel delivered to the ship, the sample has to be drawn continuously
throughout the entire bunkering process. To achieve this, DNVPS strongly recommends the use of a DNVPS
continuous drip line sampler, together with clean DNVPS cubitainers. The DNVPS line sampler can be sealed to
prevent tampering during the sampling operation. Please note that the use of a continuous drip or auto-sampler is
required by Resolution MEPC 182(59).
Sampling Kit
The sampling kit contains :-
Sampling bottles with caps
IATA approved FQT shipping cartons
IATA approved Fuel System Check carton
Security seals
Ziplock bags
Labels for FQT Sample Bottles
Labels for FSC sample bottles
Labels for MARPOL sample bottles
“For receipt only - source unknown” stamp
“For volume and temperature only” stamp
Sampling Device
Please ensure that your vessel has a proper sampling
device installed at the point of Custody Transfer, ie. at the
ship's bunker manifold. The sampling device and
collection container must also be clean and ready for use.
As a routine, clean the sampling device immediately after
every bunkering to minimise the possibility of
contamination by remaining fuel oil or cleaning solvents.
If your vessel is not fitted with a proper sampling device, it
may not be possible to take a representative sample as
required by Annex VI of MARPOL 73/78.
Safety Considerations During Sampling
The following safety precautions should be taken during any sampling:
Invite the supplier's representative to witness the sampling procedures. Complete a 'Request to Witness Sampling'
form and ensure that it is signed by both parties. Give the top copy to the supplier's representative. Retain the blue
copy for your file.
If the supplier declines to attend the witnessing of sampling, you must note this in the ship's log-book there and
then. Such a record can serve as contemporaneous evidence should a fuel quality dispute later arise. Please ensure
that full information about the barge, cargo officer, supplier, time, date and circumstances etc, are recorded.
IMPORTANT
If this sample is eventually sent for testing, all parties
involved or their representatives must be present to witness
the breaking of the seals and the testing process.
If there are technical reasons as to why a sample cannot be taken at the receiving ship's manifold (e.g. vacuum
problems and/or extreme weather conditions), then such reasons should be recorded in the ship's log book and
the sample taken at e.g. barge manifold.
IMPORTANT
This MARPOL Annex VI sample should be kept onboard in a safe location until the fuel bunkered has been
substantially consumed, but in any case for a period of at least 12 month after the fuel delivery. The sample is only to
be handed over to a port or flag state authority.
In such an event, a receipt should be requested and the action recorded in a sample inventory log.
In case the supplier has also provided a MARPOL sample but which is not taken in accordance with the requirements of
MARPOL Annex VI, it is recommended that both samples are handed over to the port or flag state authority together
with documentation highlighting any discrepancy (Notification).
Note that IMO has interpreted that it is the actual sulphur content in fuel that is to be specified in the BDN and that
terms like “less than” or “max” are not acceptable.
Sometimes these documents are prepared before the delivery and may not reflect the 'facts' of the delivery. We strongly
recommend that you do not sign the BDN or any sample labels from the supplier before the bunkering is completed.
Volume Deliveries
Normally, the terms and conditions of sale state that the quantity of fuel delivered will be determined by shore meters or
measurement of barge outturn.
With the enforcement of the ECAs as defined in Annex VI of MARPOL 73/78, as well as the 0.1% maximum fuel
sulphur limit for ships at berth in EU community ports under the EU Directive 2005/33/EC, verifying bunkered
quantity of low sulphur fuel is increasingly important. This is because Port State Control inspectors may
scrutinize fuel inventory records in order to ascertain that the ship has used the correct fuel within an ECA or
an EU Community Port.
In either case the chief engineer or ship representative should attend to witness opening meter readings or barge
soundings and temperature. On completion of the delivery the ship representative should also attend to determine the
'actual' volume delivered. The volume recorded on the BDN should be at standard temperature - calculated by referring
to ASTM Petroleum Table 54B.
To convert from volume to weight it is necessary to determine the density of the fuel and, by reference to ASTM Table 56,
multiply the volume at standard temperature by the weight factor. DNVPS finds that the density on the BDN is often
overstated, resulting in an overstatement of weight delivered.
Receivers of fuel are advised to indicate on the BDN “For Volume at Observed Temperature Only”.
The rubber stamp is provided for your use.
Please ensure that a copy of the BDN is enclosed with your sample in order for us to evaluate the DNVPS density
determination against the supplier's statement.
General Guidelines
Disputes arising from poor quality fuel deliveries can be complex and what may seem to be a simple case can become very
convoluted with respect to documentation, samples and alleged damages.
A fuel quality dispute can develop at any time, and investigators will need to compile an accurate report if the claim is to
be successful. We stress the need for good routine record-keeping onboard the vessel as 'after the fact' accounting is
difficult and confusing. The DNVPS system will provide support in such cases but the chief engineer, by following the
guidelines listed here, will improve the chances of success :
1. Keep a daily record of fuel quantities held onboard in each tank. Record transfers of fuel by date and amount
transferred from tank to tank.
2. Keep careful records of oil bunker deliveries, recording quantity in all tanks before and after delivery.
3. Whenever possible, do not mix fuel from different deliveries and always load into empty tanks.
5. Retain suppliers' samples and samples taken by ship staff for a minimum period of six months. Ensure that they
are correctly labelled, sealed and stored in a safe location.
6. Retain the MARPOL Annex VI sample until the fuel has been substantially consumed, but in any case for a
minimum of 12 months. Ensure that the sample is correctly labelled as per MARPOL Annex VI requirements, sealed
and stored in a safe location.
7. Ensure that BDNs are in accordance with MARPOL Annex VI requirements. Keep copies of all BDNs readily
available onboard for a minimum of 3 years.
8. Keep good records on main engine and auxiliary inspections and repairs.
9. Ensure that engine room or machinery log books record temperatures and pressures, so that abnormal conditions
can be recognised and related to a particular period.
10. In case of damages, compile a statement or record of events which should include date, times, damages and costs
(including manhours and spare parts). Also retain broken or damaged parts for future inspection. Photographs of
damages may also prove useful.
11. If problems are encountered, samples of the fuel in use should be drawn from the fuel system as detailed below.
Tank Sampling
Ideally, to evaluate the quality of fuel stored in a tank, the following samples should be obtained :
a) Top sample - taken at approximately 6 inches below the surface of the oil.
b) Upper sample - taken from the middle of the upper one-third of the tank's contents.
c) Middle sample - taken from the middle of the tank's contents.
d) Lower sample - taken from the middle of the lower one-third of the tank's contents.
e) Bottom sample - taken from the bottom surface of the tank.
The above samples should not be mixed together but submitted for analysis as individual samples. The label on each
bottle must record the date, the sample type and tank location.
Sampling devices designed for such sampling should be used. If sampling equipment is available onboard, ensure that it
is thoroughly cleaned before use. In some cases, due to limited access to tanks, it is not possible to obtain tank samples as
described above. Under these circumstances, a sample may be taken at the fuel transfer pump as described below.
If the suction or discharge lines of the pump contain oil from previous transfers, start the pump and run it for a sufficient
period to empty the lines. After this, start sampling by taking a continuous-drip or stream of oil into a clean cubitainer.
Continue to collect the sample until the tank is empty, during which time you should have adjusted the sample flow to
collect some five litres of oil. If an empty tank is not available, take a continuous-drip sample from the transfer pump
discharge during circulation of the oil back to the same tank.
Thoroughly mix the 5-litre sample and pour one litre into a DNVPS bottle. Mark the sample as 'Continuous-drip - Fuel
tank contents during discharge' together with the tank number.
DO NOT
a. take the sample from tank bottom drain valves. These will probably contain high levels of water and sediment
which will not be representative.
Sampling from a fuel system when a problematic fuel is loaded will also help indicate the efficiency of the treatment plant
and thus assist the crew in taking preventive action, if needed.
Sampling before and after separators is also considered the only feasible condition and performance monitoring of the
fuel.
Periodic sampling from the fuel treatment system will also identify such problems as water ingress from ballast systems,
leaking heating coils and cargo contamination. A good fuel management system would include such sampling and
analysis at least once a year.
The DNVPS Fuel System Check (FSC) can assist your ship in this regard. Further information and detailed instructions
for fuel system check sampling is provided in page 11 of this Instruction Manual.
Sludge Samples
Sludge samples taken from tanks, purifiers and pipelines can provide useful information, but without fuel samples taken
at the same time, the analysis results cannot be put into context. Thus, it is important to submit both sludge and fuel
samples. It must be accepted that sludge samples may contain high amounts of water and sediment accumulated over a
period of time from several bunker deliveries.
In addition, DNVPS now offers a catfines (Al+Si) size distribution screening as a value-added service to the FSC
programme.
ISO 8217 : 2010 specifies the required properties for fuels at the time and place of custody transfer. It is presumed that
quality will not deteriorate in storage on board and that there will be adequate treatment before use.
Experience gained by DNVPS and its customers since the introduction of the DNV Fuel Quality Testing programme,
coupled with studies and research, confirms that fuel treatment systems are not always operated at optimum efficiency.
Fuel contamination may also occur in the ship's fuel system and tanks due to e.g. defective steam heating coils or
seawater/cargo ingress resulting from badly located or damaged vent pipes.
Efficient centrifuge operation is essential for the removal of heavy fuel oil contaminants. With the FSC programme,
malfunctions and defects in the centrifuges can be identified.
For example, the latest edition of ISO 8217, the most commonly referred to marine fuel specification in the market,
indicates 60 mg/kg Aluminium + Silicon (Al+Si) as the maximum amount of catalytic fines (catfines) particles
permitted in an RMG380 fuel as delivered. However, major marine engine manufacturers recommend less than 15
mg/kg Al+Si at the engine inlet. Hence, assuming a delivered fuel contains 50mg/kg Al+Si, the fuel treatment plant
has to operate at an efficiency level capable of removing 70 per cent of these highly abrasive materials, in order to meet
the engine manufacturers' requirement.
The purpose of the FSC programme is to monitor the shipboard fuel system, i.e. the ' gap' between the ship's manifold
and the engine, in a systematic manner. This is achieved by analysing samples drawn from key locations to assess the total
fuel oil system operational condition.
In order to secure representative samples, it is recommended that the sampling locations are fitted with sampling cocks
or valves. A connecting pipe may extend to a convenient position for sample collection. A facility should be provided to
allow for the flushing of the connection back to the system or to a waste tank. Samples should NOT be drawn from tank
drains.
A recommended set of Fuel System Check samples consists of one sample taken from each of the following locations
(see fig. 1):
A. Transfer Pump Discharge L. After Service Tank (Before Fuel Heaters)
B. Before Separator (s) M. Before Main Engine - See Safety Note
C. After Separator (s)
As a minimum before and after separator samples should be drawn and forwarded to the laboratory for analysis.
Clarifier Homogeniser
Clarifier
Purifiers in
Parallel
Clarifier
Purifiers in
Parallel
Purifiers in Purifiers in
Series Series Notes
(2) Two Purifiers in Parallel followed in Series by One Clarifier = E11 + E12 + F1
(3) Two Purifiers in parallel with each with followed by a Clarifier in series = E11 +
F11 + E12 + F12
(5) If there are more than two Purifiers in parallel, Identify samples from third as
E13, fourth E14, etc.
= Sample code to be entered on label & forms. Additionally please (6) Sample from a Purifier which is centrifuging the Service Tank back to the
indicate your own identification for any equipment/tanks that are in Settling Tank should be identified as E51. Not normally required, will be
duplicate/parallel/series etc. requested if necessary.
Sampling Procedure
For the assessment of the analysis results to be as meaningful as possible, the samples should be drawn at around the same
time. Routine and requested sample sets should be taken when the fuel from the last bunkering has displaced the fuel oil
from the previous delivery.
When samples are being taken before and after the separators, the condition should be allowed to stabilize after
adjustments have been made to e.g. the fuel oil flow rate, before drawing samples. The before/after separator samples
should preferably be taken at the same point of time. Time for sampling should be the discharge interval, divided by two.
For instance, if discharge interval is set to two hours, the samples should be taken one hour after a discharge. First the
separator inlet sample is taken, and immediately after that, the sample of the cleaned oil at the separator outlet should be
taken.
For safety reasons it is not recommended to take samples from the booster system. Safety precautions should be taken if
such samples nevertheless are to be drawn because the fuel oil at this point has an elevated temperature and is kept under
relatively high pressure.
All sampling equipment should be clean and in good order. Oil, sludge, water, cleaning solvents etc, from previous
samplings can cause erroneous analysis results.
1. The sample bottles from the FQT sampling kit should be used.
3. Ensure the lines are flushed through before drawing the sample.
4. The samples may be filled directly into the plastic sample bottles,
except for samples taken from the booster system, where it is
recommended to use a closed container that can withstand the
elevated temperature.
5. The plastic bottle cap should be firmly fastened after sample has
cooled to avoid leakage.
Please refer to page 4 of this Instruction Manual for safety considerations during sampling .
Pack the FSC samples in the FSC cardboard transportation box. Alternatively, if only one FSC sample is taken (not
recommended), or if more than three FSC samples are being forwarded to the laboratory, the IATA carton boxes
provided for the bunker delivery samples may be used.
In order to assess the onboard treatment efficiency, the following parameters will be measured:
• Water - Used to monitor if any settling of water has taken place and/or if there is any water contamination; for
example, from steam heating coils or leaking solenoid valves on the separators.
• Sodium - High Sodium can cause increased corrosion of the high pressure parts of the fuel system and to exhaust
valves as well as increased deposits in the post-combustion spaces. Sodium is also an indicator of whether water in fuel
oil is fresh or salty.
• Aluminium + Silicon - These abrasive particles, otherwise known as “cat fines” can cause significant damage to an
engine. Areas such as fuel injectors and the liners and piston rings can be subject to high wear rates if the “cat fines”
content is not reduced to a satisfactory level as recommended by your engine manufacturer(s).
• Iron - If present, this would most likely be in the form of Iron Oxide (Rust) and as such would be removed by the
separator(s).
• Total Sediment Potential (TSP) - This parameter is used to assess and indicate the stability and cleanliness of a fuel.
Fuels with high sediment content can cause increased sludge problems in the separators and filters.
In addition the test parameters density, sulphur and vanadium are used as “fingerprint parameters” in order to confirm
that the tested results correspond with the parameters of the bunkered fuel oil.
The analysis report for the Fuel System Check samples will be sent to designated recipients in the same manner as the test
results from the fuel analysis samples.
Density
Density is expressed in kilograms per cubic metre (kg/m³) at 15˚C. Density mainly affects specific energy, ignition
quality and fuel separation. Conventional separators can remove water and to some extent solid particles from heavy
fuel oils with densities up to 991kg/m³ @15˚C. Separators of newer design can clean heavy fuel oils with densities up to
1010kg/m³ @15˚C. An important issue is to ensure that the correct separation flow rate and temperature are used in
order to achieve an efficient reduction of water, catalytic fines, sodium and sediments from the heavy fuel. Further, the
exact density must be known in order to verify the weight of the fuel based on the received volume.
Viscosity
Viscosity is expressed in mm²/s (centistokes, or cSt) at a stated temperature. This is a measure of a fluid's resistance to
flow. The kinematic viscosity is measured by the time for a fixed volume of oil to flow through a capillary tube.
Viscosity is not actually a measurement of heavy fuel oil quality. The user of the fuel will need to be aware of the viscosity in
order to set heaters correctly, prior to pumping and cleaning or treating the fuel, and before injection into the main
engine. This is because heavy fuel oil must be heated to reach the correct injection viscosity to ensure optimized
combustion and engine performance.
If the viscosity of the fuel is too high, the heating plant may not be capable of raising the fuel to the correct temperature.
In extreme cases, transfer of the fuel onboard may be very difficult and the engine could suffer poor performance and
possibly damages if insufficient heating is applied prior to injection.
Heavy fuel oils are also generally priced and ordered according to viscosity.
Water
Water content is expressed as per cent by volume. Water reduces the specific energy of fuel oil, thereby increasing
consumption and reducing fuel economy. Water may cause corrosion in the fuel system. The sodium chloride (salt) in
sea-water can also promote corrosion by giving rise to the formation of sodium-vanadium compounds during
combustion (high temperature corrosion). The water content in heavy fuel oils is low during production; thus the
presence of water in bunker oil is usually due to external contamination.
Separation of water from fuel oil can be a slow process, particularly if the difference in density is small or if the water is
present as minute drops. Separation of water drops is also inhibited by various small-particle impurities, such as dust,
sand and rust. The resulting emulsion clogs filters and affects efficient centrifuging.
Sulphur
The sulphur level in fuel contributes to sulphur oxide emissions and thus air pollution. Currently Annex VI of
MARPOL 73/78 includes a worldwide 4.50% maximum sulphur limit in marine fuels which will be further reduced to
3.50% by January 1, 2012. In the Emission Control Areas (ECAs), the maximum sulphur limit is 1.00%. Other local
requirements may apply eg. in Europe and California.
Sulphur compounds may corrode cylinder liners and piston rings. The sulphur dioxide generated by combustion may
cause corrosion in exhaust passages at low temperatures.
Engines designed for operation on high sulphur fuels use special lubricants to minimise the effects of sulphur. The
sulphur content of a fuel affects the energy available.
Sediment
All fuels contain sediment consisting of hydrocarbon sludges and extraneous materials. The Total Sediment Test is
designed to determine the quantity of non-fluid material in the fuel by a hot filtration method.
Ash
Ash represents the incombustible components of fuel oil. These components may have their origin in the fuel or may
have been introduced by poor house keeping. High ash levels can cause wear in the fuel injection system, deposits on
cylinder components and resultant wear. In addition, some ashes are corrosive and may stick on to exhaust valves. High
ash levels may also reduce the efficiency and cause damage to turbochargers.
Catalytic Fines
Small particles of the catalyst (aluminium and silica oxides) used in the refinery process are sometimes carried over
into the residual fuel. They are of irregular shape, porous and extremely hard. Some degree of removal may be
achieved by settling and centrifuging onboard the ship. Due to their abrasive nature, they can lead to rapid wear of fuel
injection system components and cylinder rings/liners.
ISO 8217 : 2010 prescribes a maximum level of 60 mg/kg aluminium + silicon in high viscosity (40mg/kg and below
for the lower viscosity grades) fuels as delivered to vessels. However, fuel deliveries with levels of aluminium and silicon
far in excess of this value have been recorded and severe engine damages have been attributed to such high catalytic
fine levels. Note that a single separator may not be capable of handling aluminium + silicon levels above 50mg/kg in
order to reduce the aluminium + silicon contents to an acceptable level at main engine inlet. We therefore recommend
operating two or more separators in parallel or series, depending on type, when the tested level is in the 50-80 mg/kg
range. DNVPS recommends taking FSC samples when the tested level exceeds 40 mg/kg.
Elements
Fuel oils contain many metals, of which the most common are vanadium, nickel, iron and sodium. Vanadium and
sodium are potentially most harmful as they may lead to high temperature corrosion. The worst situation is when the
ratio of vanadium to sodium is approximately 3:1. Sodium salts are water-soluble and can be removed with water during
treatment. Without presence of water, sodium cannot be removed. Vanadium, however, is oil soluble and cannot be
removed by onboard fuel treatment equipment.
If present, calcium, zinc and phosphorous are indications of used lube oil (ULO) in the fuel. Although according to
DNVPS' knowledge and information small amounts of ULO do not have any adverse impact on fuel oil treatment and
calculation, ULO may increase the particulate emission and increase the risk of exhaust gasway fouling.
Flash Point
The flash point is expressed in degrees centigrade. Safe transport and storage requires that the flash point of the fuel
oil is known. A flash point minimum of 60°C is prescribed for use onboard ships in the machinery spaces. This
minimum temperature is stated in the rules of classification societies and legislated by most governments.
Pour point is only relevant for storage and handling of the fuel and neither impacts the ignition nor the combustion.
Specific energy
The heat released during combustion of a fuel may be termed specific energy or heat of combustion. The energy
content of a fuel may be measured by calorimetry but usually the energy is calculated to find the gross specific energy
or the net specific energy.
Specific energy decreases with increasing density, sulphur, ash and water.
Oxidation stability
Oxidation stability of a marine distillate product refers to its resistance to oxidation and is therefore a measure of its
potential service or storage life. Oxidation occurs when the fuels degrade on contact with oxygen. In ISO 8217 marine
fuel specification, oxidation stability testing is applicable only to marine distillate products and conducted according
to the ISO 12205 test method, with a maximum limit of 25g/m3. For the DMB distillate grade, oxidation stability
testing cannot be conducted (and therefore not applicable) if the product is not bright and clear.
Lubricity
In ISO 8217, lubricity testing is conducted on marine distillates to determine their ability to reduce friction between
the moving parts in a ship engine. Lubricity testing [corrected wear scar diameter (wsd 1.4) at 60 degrees Celsius] is
conducted according to the ISO 12156-1 test method and applicable only for distillate products with fuel sulphur
content below 500 mg/kg (0.050 mass %).
Acid number
Acid Number (AN) is a measure of the total acidic constituents in a marine fuel sample. Although there is no
recognised correlation between Acid Number and the corrosivity of a marine fuel product, AN test (ASTM D664) is
nevertheless an important parameter for assessing the potential acid contamination of marine fuel products. While a
small quantity of weak acids in naturally occurring form may be tolerated, strong acids are not expected to be present
in marine fuels. In ISO 8217, the maximum AN limit is 0.5 mg KOH/g for marine distillates and 2.5 mg KOH/g for
residual fuel oil products.
Chemical contaminants
During the past years, several cases of chemical contamination of residual fuels have been found. Such contamination
damaged engine fuel pumps, blocked filters, overloaded centrifuges, and caused fouling of exhaust gasways.
As looking for special contaminants is both time consuming and expensive it is usually not done as part of a routine
fuel analysis. Only when a ship reports problems related to operation on a specific fuel, will the lab look for chemical
contaminants.
During the past years, components such as carboxylic acids, solvents, polymers, and shale oil have been found to cause
damage. Unfortunately, it is not always possible to find the component responsible for the damage. Finding the source
of the problem is often the key to filing a complaint against the bunker supplier, for which reason DNVPS takes
chemical contaminants very seriously.
DNVPS is currently offering a GCMS (Gas Chromatography Mass Spectrometry) headspace program which assists ship
operators in finding possible contaminants.
MARPOL Annex VI Services
Based on clients' requests, DNVPS has further developed a service where owners can submit fuel oil samples for
verification of compliance with the sulphur content requirements of Annex VI to MARPOL 73/78. The service is
available for marine fuel oils, diesel oils and gas oils.
- Low sulphur fuel is anticipated to come at a premium compared to normal sulphur fuel, i.e. there is a commercial
interest in verifying that the fuel quality is in accordance with the specification.
- It is considered preferable to verify the actual sulphur content in advance as opposed to testing on the order of the port
state control. Verification in advance represents an opportunity to be pro-active, i.e. notify flag states and port states
of any failure on the part of the supplier in delivering MARPOL Annex VI compliant fuels.
- Prior verification could limit potential problems in case the vessel is using lubrication oils with a TBN adapted to low
sulphur fuel oils only.
- It serves as a means to limit the emission of sulphur oxides within the ECAs, i.e. fulfil the ship's obligation towards
safeguarding the environment.
The time required for this change-over will deviate depending on the tank and piping system configuration onboard.
Although change-over from one fuel quality to another is nothing new onboard ships, MARPOL Annex VI has specific
requirements for the completion of such a change-over. It is therefore recommended that additional focus should be put
on the development of proper procedures as MARPOL Annex VI is a statutory requirement subject to statutory surveys
and controls.
In order to verify whether the change-over procedures developed comply with the requirements of MARPOL Annex VI,
DNVPS has developed a service where owners can take in-system samples before and upon completion of change-over
and submit them to DNVPS for testing.
Such verification can be carried out without low sulphur fuel being onboard, as long as fuel oils of different grades are
used.
DNVPS will test submitted samples in order to determine whether complete change-over between fuel grades has been
achieved. The results of the tests will enable owners to adjust the change-over procedures to ensure future
compliance.
Sampling Points:
The sampling points depend on the fuel tank and piping system configuration onboard. The following sampling points
are however recommended:
3. Fuel supply piping immediately before each engine and boiler burner arrangement:
-In order to confirm that complete change-over of fuel oil supplied to engines and boilers has been achieved.
-Alternatively consider taking similar samples in return oil piping from engines and boiler burner arrangement.
In order to limit the number of samples taken, one could limit the scope to the service tank outlet or from the common
supply piping to main engine(s), auxiliary engines and boiler(s). However one needs to bear in mind that this will not
necessarily reflect the quality of the fuel being consumed in the respective engine/boiler.
Please ensure that at the time of sampling, safety precautions are taken due to potential hazards if sampling is carried out
from the pressurised fuel oil booster system(s).
Sampling Equipment:
For ease of sampling, we strongly recommend that the sampling points are provided with sampling cocks or valves. A
connecting pipe may extend to a convenient position for sample collection. Ideally, a facility might be provided to allow
for the flushing of the connection back to the system or to a waste tank.
All sampling equipment should be clean and in good order. Oil, sludge, water, cleaning solvents etc, from previous
samplings can cause erroneous analysis results.
Sampling Procedures:
One sample should be taken at each specified sampling point:
- Before commencement of change-over.
- Immediately upon completion of change-over, which is considered the official time to be recorded in the ship's
logs as per MARPOL Annex VI requirements
2. Ensure that each sample bottle is provided with a red FSC label and
mark each label clearly before sampling to prevent mix-up as follows:
“FUEL CHANGE-OVER”
-whether sample is taken before or upon completion of change over. Fill the sample bottle. Make sure each
bottle is clearly marked to prevent mix-up.
-Sampling point location.
3. Ensure the lines are flushed through before drawing the sample.
4. The sample may be filled directly into the plastic sample bottles.
5. The plastic bottle cap should be firmly fastened after sample has
cooled to avoid leakage.
Fasten the bottle cap
securely to prevent leakage.
6. Complete the FSC sample record form as provided in this manual.
The original should be sent with the samples, together with other
relevant documentation. The copy is for the ship's file.
7. Pack the samples in the Fuel System Check carton box. Attach the
laboratory address labels according to our Air Courier Directory.
Please instruct your agent to fill out the required customs declarations and contact the nearest courier service listed in
our Air Courier Directory.
By agreement with DNVPS, the sample boxes will be forwarded by our international network of courier agencies. The
ship agent should be instructed to request pick-up and dispatch according to page 7 of this Instruction Manual. Pro
Forma invoices, as enclosed in this manual, should be filled out and attached to the sample box.
Verification Frequency:
The above comprehensive sampling is considered necessary in connection with development of change-over
procedures. It is however recommended that periodic verification of procedures are carried out, but with a reduced
scope incorporating sampling from settling and service tank(s) outlets only.
Due to uncertainty with respect to availability of low sulphur fuel oil, certain owners have indicated that they intend
to blend fuel onboard to meet the low sulphur requirements.
To limit the above uncertainties, DNVPS offers its Blend Optimisation Programme (BOP). This programme will enable
owners engaging in onboard blending to optimise the composition of blended marine fuels to ensure that the most
economic blends are used; that the blends meet the engine manufacturers' requirements to fuel oil quality; and that the
risk of blend incompatibility, which can lead to severe sludging and potential operating problems, is reduced.
The Blend Optimisation Programme will consider the critical specifications of the blend components and the non-linear
viscosity blending characteristics. The programme will provide the technical expertise and experience to determine
optimum blend composition and will also verify whether the blend components are compatible.
By submitting a representative sample of each blend component, the Blend Optimisation Programme will undertake the
following:
- Fuel quality testing of the blend components
- Compatibility check of the blend components
- Calculation of the resultant blend viscosity
- Recommendations on optimum blend composition to meet engine fuel specifications and correct injection temperature
- Technical advice on the overall fuel quality
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Email: [email protected] Email: [email protected]
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foundation with the objective of safeguarding life, property and the environment. DNV comprises
300 offices in 100 countries, with 9,000 employees.
All rights reserved; no part of this publication may be reproduced without the written permission of DNV Petroleum Services. DNVPS/FQTK_IM/V2R3/0712