CHAPTER Atomic Structure EXERCISE | (JEE MAIN) Fundamental Particles 2. 3. Gases are bad conductors of electricity. Their conductivity may be increased by (a) increasing the pressure as well as potential difference between the electrodes. (b) decreasing the pressure as well as potential difference between the electrodes. (c) decreasing the pressure and/or increasing the potential difference between the electrodes. (@) increasing the pressure and/or decreasing the potential difference between the electrodes. Which of the following is true for cathode ray? (a) Itis not deflected by magnetic field. (b) It is an electromagnetic wave. (©) It emits X-ray, when strikes a metal. (@) It consist all the negative particles present in the atoms, The specific charge of cathode rays (a) depends on the nature of the gas. (b) depends on the material of the dis- charge tube. (©) depends on the potential difference between cathode and anode. (d) is a universal constant. Which of the following is not a funda- mental particle? (a) Electron (©) Neutron (b) Proton (d) X-rays The presence of charge particles in the atoms was first confirmed by (a) Rutherford (b) Thomson (©) Faraday (@) Goldstein From the discharge tube experiment, it is concluded that (a) mass of proton is fractional. (b) matter contains electrons (c) matter contains nucleus. (@) positive rays are heavier than protons, The cathode rays experiment demon- strated that (a) a-particles are the nuclei of He atoms. (b) the e/m ratio for the particles of the cathode rays varies gas to gas, (©) cathode rays are streams of nega- tively charged particles. (d) the mass of an atom is essentially all contained its very small nucleus.132 8. 9% 10. u. 12. = Chapter 13 Which of the following is not the possi- ble path of cathode rays ejecting from the surface of cathode? (b) \ (a) IK. © @ 7 he Cathode rays are made up of electrons. ‘Anode rays are made up of (a) only protons. (b) only nucleus of atoms. (©) positive residue of atoms. (@) only from all the positive particles present in the atoms, Which of the following is incorrect statement? (a) Cathode rays are emitted out from the surface of cathode. (b) Cathode rays travel in straight line. (©) Anode rays are heavier than cathode rays (d) Anode rays are emitted out from the surface of anode. The elm ratio of anode rays produced in the discharge tube, depends on the (a) nature of the gas filled in the tube (b) nature of anode material (©) nature of cathode material (@) alllof these When lithium vapours were filled in the discharge tube for anode rays experiment, the anode rays were found to contain only ions (4 = 7, Z = 3). Each particle of anode ray is, therefore, containing (a) 1 proton only (b) 3 protons and 4 neutrons only (©) 3 protons, 4 neutrons and 2 electrons (@) 3 protons, 3 neutrons and 3 electrons 13. 14. 15. 16. 17. 18, 19, 20. In an oil drop experiment, the following charges (in arbitrary units) were found on a series of oil droplets: 4.5 x 10°", 3.0 x 10", 6.0 x 10, 7.5 x 10", 9.0 x 10°. The charge on electron (in the same unit) should be (a) 3.0x 10" (c) 15x10" (b) 9.0 10°" (d) 1.6x 10" In Wilson cloud chamber experiment, two particles were found to show equal devia- tions butin opposite directions. The names positron and negatron were given to these particles by Anderson, Hence, Negatron is (a) neutron (b) neutrino (©) proton (d) electron Which of the following particle is not deflected in the magnetic field? (a) Electron (b) Proton (©) Neutron (@) Deuteron Which of the following particle have non zero e/m ratio? (a) Neutron (b) Neutrino (c) Positron (d) Neutral meson The e/m ratio is maximum for (a) Nat (b) Alt (©) HW (d) Me™ The potential difference between cathode and anode in a cathode ray tube is V. The speed acquired by the electrons is propor- tional to () W Vv Ov @ WwW The ratio of specific charges of c-particle and deuteron is (a) 1:2 (b) 2:1 © @ 4:1 elm ratio of a particle of charge 2 unit and mass 4 amu is (a) 48 x10 Cikg (c) 4.8 x 10° Cikg (b) 0.5 Chkg, (d) 8x 10 CikgRutherford’s Atomic Models 21. 22. 23. 25. Atoms have void spaces. It was first sug- gested by (a) Rutherford (©) Lenard (b) Thomson (@) Dalton Rutherford’s experiment, which estab- lished the nuclear model of the atom, used a beam of (a) B-particles, which impinged on a metal foil and got absorbed. (b) rays, which impinged on a metal foil and ejected electrons. (©) helium atoms, which impinged on a metal foil and got scattered. (d) helium nuclei, which impinged on a metal foil and got scattered. Which of the following is not a conclu- sion of Rutherford’s atomic model? (a) Most of the part inside an atom is empty. (b) Almost all mass of an atom is con- centrated in the nucleus. (©) The size of nucleus is very small in comparison to the size of atom. (d) Electron revolves round the nucleus in definite orbits. Which of the following is not a correct statement according to Rutherford’s atomic model? (a) 99% of mass of an atom is centred in the nucleus. (b) Most of the part inside the atom is empty. (© The size of nucleus is very small in comparison to the atoms. (4) Electrons revolve round the nucleus, When -particles are sent through a tin metal foil, most of them go straight through the foil as (a) B-particles are much heavier than electron (b) most part of the atom is empty space 21. 29. Atomic Structure * 13.3 (©) B-particles are positively charged (d) B-particles moves with high velocity A proton and a deuteron are projected towards the stationary gold nucleus, in different experiments, with the same speed. The distance of closest approach will be (a) same for both (b) greater for proton (©) greater for deuteron (d) depends on speed ‘Two particles, A and B, having same e/m ratio are projected towards silver nucleus, in different experiments, with the same speed. The distance of closest approach will be (a) same for both (b) greater for A (©) greater for B (d) depends on speed a-particles are projected towards the nucleus of following metals, with the same kinetic energy, Towards which metal, the distance of closest approach will be minimum? 29) 47) 79) 20) In the different experiments, at-particles, proton, deuteron and neutron are pro- jected towards gold nucleus with the same kinetic energy. The distance of clos- est approach will be minimum for (a) a-particle (b) proton (©) deuteron (@) neutron The following charged particles accelerated from rest, through the same potential dif ference, are projected towards gold nucleus in different experiments. The distance of closest approach will be maximum for13.4 * Chapter 13 31. 32. 33. (a) o-particle (b) proton (©) deuteron (d) same for all In the Rutherford scattering experiment, the number of alpha particles scattered at an angle @ = 60° is 36 per minute. The number of alpha particles per minute scattered at angles @ = 90° is (Assume all other conditions to be identical.) (a) 144 (b) 9 (©) 36 (@) 16 If nucleus and atom are considered as perfect spheres with the diameters 4x 10 m and 2 x 10” m, respectively, then the ratio of the volumes of nucleus and atom should be (a) 2x 10%: (©) 1.25x 10:1 (b) 8x 107% (d) 8x10": With what velocity should an o-particle travel towards the nucleus of a copper atoms so as to arrive at a distance 10° m from the nucleus of the copper atom? (4.8 x ¥29x60 = 200, NV, = 6x 10”) (a) 2 10° ms™ (b) 4x 10" ms (c) 2x 10° ms (d) 2 10" ms™ An o-particle accelerated through V volt is fired towards a nucleus. It distance of closest approach is r. If a proton acceler- ated through the same potential is fired towards the same nucleus, the distance of closest approach of the proton will be (@r (b) 2r (©) 12 (@ w4 The distance of closest approach of an a-particle fired towards a nucleus with momentum ‘P’ is r. What will be the distance of closest approach when the momentum of the o-particle is 2P? (@) 2 (b) 4r (©) 12 (@) v4 Planck's Quantum Theory, Photoelectric Effect and Moseley’s Experiment 36. 37. 38. 39, Small packets of light is called (a) proton (b) quanta (©) photon (d) spectrum A radio station emits the radiations of 400 KHz. The metre band of station is, (a) 400 (b) 750 (©) 1333.33 (@) 7.5 Which of the following electromagnetic radiation have greater frequency? (a) X-rays (b) Ultraviolet rays (©) Radio waves (d) Visible rays As its closest approach, the distance between the Mars and the Earth is found to be 60 million km. When the planets are 41. at this closest distance, how long would it take to send a radio massage from a space probe of Mars of Earth? (a) 5s (b) 200s (©) 0.28 (d) 208 Two electromagnetic radiations have wave numbers in the ratio 2:3. Their energies per quanta will be in the ratio (a) 3:2 (b) 9:4 (©) 49 @ 23 A radio station is emitting the radiations of frequency 2 x 10* Hz. If its frequency is doubled, (a) wavelength will be doubled (b) energy per quanta will be doubled (©) wave number will be halved (@) all of these42. 43. 45, 46. 41. The eyes of a certain member of the rep- tile family pass a single visual single to the brain when the visual receptors are stuck by photons of wavelength 662.6 nm. If a total energy of 3.0 x 10 J is required to trap the signal, what is the minimum number of photons that must strike the receptor? (a) 1.0 10° (b) 1.0% 10° (©) 1000 @1 A photon of 400 nm is absorbed by a gas molecule and then the molecule re-emits. ‘two photons. One re-emitted photon has wavelength 500 nm. Assuming that there is no change in the energy of molecule, the wavelength of second re-emitted photon is (a) 100 nm (©) 100 nm (b) 2000 nm (4) 900 nm A green bulb and a red bulb are emitting the radiations with equal power. The cor- rect relation between numbers of photons emitted by the bulbs per second is (a) =m, (b) 1, <1, © m>n, (d) unpredictable A dye emits 50% of the absorbed energy as fluorescence. If the number of quanta absorbed and emitted out is in the ratio 1:2 and it absorbs the radiation of wavelength ‘x’ A, then the wavelength of the emitted radiation will be (@ xA (b) 0.5xA (0) 4xA (d) 0.25%A Wavelength of photon which have energy equal to average of energy of photons with 2, = 4000 A and 2, = 6000 A will be (a) 5000 A (b) 4800 A (©) 9600 A (a) 2400 A Bond dissociation on energy of Br, is 200 kJ/mole. The longest wavelength of photon that can break this bond would be (N, x he = 0.12) 49. 51. 52. 53. Atomic Structure * 13.5 (b) 1.2x10%m (d@) 12x 107m (a) 6.0 105m (©) 6.0x 107m Wavelength of photon having energy 1 eV would be (a) 1.24% 104m (b) 1.24 10m (c) 1.24 10% m (d) 1.24% 10°m In the emission of photoelectrons, the number of photoelectrons emitted per unit time depends upon (a) energy of the incident radiation (b) intensity of the incident radiation (©) frequency of the incident radiation (d) wavelength of the incident radiation Radiations of frequency, v, are incident on a photosensitive metal, The maximum kinetic energy of photoelectrons is £. When the frequency of the incident radi- ations is doubled, what is the maximum kinetic energy of the photoelectrons? (a) 2E (b) EI2 (©) E+hv (d) E-hv A. photo sensitive surface is receiving light of wavelength 5000 A at the rate of 10° J/s. The number of photons received per second is (a) 25x10" (© 25x10" (b) 3.0.x 10 (d) 2.5% 10° In order to increase the kinetic energy of ejected photoelectrons, there should be an increase in (@) intensity of radiation (b) wavelength of radiation (©) frequency of radiation (d) both wavelength and intensity of radiation The threshold wavelength for ejection of electrons from a metal is 330 nm, The work function for the photoelectric emis- sion from the metal is (h = 6.6 x 10™ J-s)136 * Chapter 13 (a) 1.2« 10°F (b) 6.0 10°F (©) 12«10"F (a) 26:21 (©) 16:25 (b) 4:5 (a) 25:16 2 55. The wavelength of the K, line for an ele- eo Hsu ment of atomie number 37 is 4. What is 54. The ratio of wavelengths of the wavelength of k, line for the element K,-characteristic X-rays produced when of atomic number 29? iron (Z = 26) and scandium (Z = 21) are (aa (b) 2% used as anticathode, is (© a @ Na Bohr's Atomic Model 56. Bohr's model may be applied to 62. The ratio of circumference of third and (a) Na! ion (b) He atom second orbits of He’ ion is (c) Be* ion (d) C* ion (a) 3:2 (b) 2:3 57. If the radius of first orbit of H-atom is Ce @ 49 x A, then the radius of the second orbit 63, If the mass of electron is doubled, the of Li* ion will be ax speed of electron revolving round Li’ (a) xA (b) 3A nucleus will ox (a) remain same oa 4rd (b) be doubled i (©) be halved 58. According to Bohr model, the radius of Ne ion in ground state should be (4) be quadrupled (a) 0.529 A (b) 0.0529 A 64. What is the orbit number of the He" ion (©) 529A (@) 529A in which electron have speed =a 59. The ratio of spacing between the third and times the speed of light? i fourth orbit to the spacing between sixth a aye and seventh orbit of H-atom is i Fi f ia i @ 7:13 (b) 13:7 2 (©) 16:49 @ 1 65. The speed of electron revolving in the 60. What would be the approximate quantum fourth{orbit{oftalliydrogen ike atomior number, n, for a circular orbit of hydro- ome Oe Sree Sioa Ono gen, 1 x 10cm in diameter? (a) H, (b) He, (a) 31 (b) 43 (© Li* (d) Be (© 40 (@) 39 66. Escape velocity for earth is 11.2 kmis, 61. If the mass of electron is doubled, the The orbit number for H-atom in which radius of first orbit of H-atom becomes approximately (a) 0.529 (b) 0.265 A (©) 1.058 A (d) 032A speed of electron is about 19.54 times the escape velocity is fa) 4 () 10 (b) 8 (d) infinite67. 68. 69, 70. n. nR. 2B. The ratio of the speed of the electron in the ground state of hydrogen atom to the speed of light in vacuum is (a) Ll (© 1:137 (b) 1:100 (d) 2:3 An electron revolves round Li” nucleus at a distance of 1.587 A. The speed of electron should be (a) 2.188 x 10° m/s (b) 6.564 x 10° m/s (©) 7.293 x 10° mis (d) 7.293 x 10° mis How much distance an electron revolving in 3" orbit of He* ion will travel in one second (a) 1.458 x 10° m (b) 3.28 x 10°m_ (©) 4.862 x 10° m (@) 2.917 x 10° m The ratio of time taken by electron in revolutions round the H-nucleus in the second and third orbits is (a) 2:3 (b) 4:8 (c) 8:27 (a) 27:8 For hydrogen atom, the number of revo- lutions of the electron per second in the orbit of quantum number, », is propor- tional to (@) (b) vn (d) Ow Which of the following is not a permis- sible value of angular momentum of elec- tron in H-atom? @ist 054 © © (© 1.254 (4) all of these X If an electron in H-atom jumps from one orbit to other, its angular momentum doubles. The distance of electron from 14. 5. 6. 71. 8. 29. Atomic Structure "© 13.7 nucleus becomes times the initial distance, (a) 2 (b) 4 1 1 au ay 1 OF OF The angular momentum of electron revolving in the second orbit of H-atom is ‘x’ Js. The angular momentum of electron in the second orbit of He* ion should be (a) xs (b) 2x Fs (©) 05x 5s @) axds The angular momentum of electron revolving round nucleus of H-atom is directly proportional to (@)r ( r" () r? @r What is the angular speed of an electron revolving in the third orbit of He*ion? (a) 6.12 10% s* (b) 1.63 10s (©) 1.92% 10s! (@) 1.95 10%s" The force of attraction on electron by the nucleus is directly proportional to @ a o 2 i” oF @ 5 The K.E. of electron in He* will be maxi- mum in (a) third orbit (b) first orbit (©) seventh orbit (d) infinite orbit As the orbit number increases, the K.E. and PE. for an electron: (a) both increases (b) both decreases (©) K.E. increases but PE. decreases (d) PE. increases but K.E. decreases138 * Chapter 13 80. 81. 82. 83. 86. The ratio of energies of first excited state of He* ion and ground state of H-atom is (a) 1 (b) 4:1 (© 14 (d) 16:1 For which atom or ion, the energy level of the second excited state is 13.6 eV? @H (b) He* © Li* @ Li The orbit from which when electron will jump in other orbit, energy may be absorbed but not emitted out, will be (a) first orbit (b) second orbit (c) seventh orbit (d) infinite orbit Inthe Bohr’s model of the hydrogen atom, let r, v and E represent the orbit radius, speed of an electron and the total energy of the electron, respectively. Which of following relation is proportional to the orbit number 7? @ vr (@ lV (b) IE @) rE The ratio of potential energy of electron in the third orbit of Li? ion to the kinetic energy of electron in the fourth orbit of He’ ion should be (a) 81 (b) -8:1 (© 161 (@) 1 Which of the following quantity for an electron revolving round the H-nucleus is independent to the mass of electron? (@) distance from nucleus (b) KE (© PE (@) speed The potential energy of electron revolv- ing in the ground state of H atom is (@) -13.6eV (b) -6.8 eV (©) -27.2eV (@) Zero 1. 92. 93. An electron is revolving round the nucleus of He’ ion with speed 2.188 x 10° m/s. The potential energy of the electron is (a) -13.6eV (b) -6.8 eV (©) -27.2eV (@) Zero As the orbit number increases, the differ- cence in two consecutive energy levels (a) remain constant © (©) decreases (@) is unpredictable The amount of energy released when an electron jumps from the seventh excited state to the first excited state in He’ ion is (a) 13.32eV (b) 53.28 eV (©) 12.75ev (d) 26.08 ev The energy different will be minimum for which of the following energy levels of H-atom? (a) n=2andn=3 (b) n=3andn=4 (©) n=1andn=2 (@) n=1andn=4 For which transition in H-atom, the amount of energy released will be maximum? (a) n=4ton (b) n=Ston (©) m=2ton=1 (@) How much energy is needed for an elec- tron revolving in the second orbit of He’ ion, in order double its angular momentum? (a) 40.8 eV (b) 2.55 eV (© 10.2eV (d) 12.09 ev The ionization energy of a hypothetical atom is 50 eV. If this atom obey Bohr’s atomic model, the energy of electron in its fifth orbit will be (a) 1250eV (c) 2eV ton (b) +2eV (d) +1250eVAtomic Structure * 13.9 94. Anelectron revolving round H-nucleus in 97. Electromagnetic radiations of wavelength ground state absorbs 10.2 eV energy. Its 240 nm are just sufficient to ionize sodium angular momentum increases by atom, The ionization energy of sodium h h (in kJ/mol) is OF ies (a) 5.167 (b) 498.58 a i (©) 118.83 (@) 51.67 © — @) 98. The ionization energy of He-atom in T 4an ground state may be 95. The ionization energy of He ion is (a) 13.6eV (b) 54.4eV x eV, The ionization energy of Be™ ion (c) 108.8eV (d) 27.0eV should be 99. The binding energy for the third electron Oe ©) 2rev in the ground state of Li-atom should be ov @ av (a) 108.8 eV (b) 122.4eV 96. The excitation energy of an electron from rey CEE GY second orbit to third orbit of a hydrogen- 100. Suppose that means were available like atom or ion with +Ze nuclear charge is for stripping 29 electrons from Zn in 47.2 eV. If the energy of H-atom in lowest, vapours of this metal. The ionization energy state is -13.6 eV, the value of Z is energy for the last electron is, (a4 (b) 5 (a) 11.5keV (b) 12.24 keV © 6 @7 (© 13.6eV (d) 408 ev Spectrum 101. Suppose the mass of electron decreased by 25%. How will it affect the Rydberg constant? (a) It remains unchanged. (b) It becomes one-fourth. (©) It reduces to 75% of its original value. (d) It is doubled. 102. The charge on the electron and proton is reduced to half, Let the present value of the Rydberg constant is R. What will be the new value of the Rydberg constant? R R @s oF R R OF OG 103. Rydberg is (a) also called Rydberg constant and is the universal constant. 104. 105. (b) unit of wavelength and one Rydberg equals 1.09 x 107 m, (©) unit of wave number and one Rydberg equals 1.09 x 10’ m“, (@) unit of energy and one Rydberg equals 13.6 eV. For the same electronic transition in the following atom or ion, the frequency of the emitted radiation will be maximum for (a) H-atom: (b) D-atom (c) Het ion (@) Li ion An electron jumps from the fourth orbit to the first orbit in a H-atom. The num- ber of photons liberated out will be @ 1 (b) 2 © 3 @ 613.10 106. 107. 108. 109. 110. ii. = Chapter 13 The wavelength of radiation emitted out in the transition n= 4 to n= 1 in Li*ionis 135R 16 OG ©) B5R 16R 135 © Bs (d) TOR What is the frequency of the second line of the Paschen series in the spectrum of He’ ion? 64 RC 64R @ Ss ) 5 225 225C © GR © Gr What is the wave number of the radiation of lowest frequency in the Lyman series of the spectrum of Li* ion? 4 2IR @ & 27RC lara © oR ‘The wavelength of a spectral line obtained by an electronic transition is inversely proportional to (a) Number of transit electrons (b) Nuclear charge of the atom (©) Energy difference of the related energy levels (d) Speed of the transit electron In H-atom, wave number ratio is 108:7 is for (a) first Lyman and first Balmer transition (b) first. Lyman and first Brackett transition (©) first. Lyman and first Paschen transition (@) first Lyman and. second Balmer transition Wave number of the first line in the Balmer series of Be is 2.5 x 10° cm”. Wave number of the second line of the Paschen series of Li is 112. 113. 14. 115. (a) 7.2 10° em (b) 7.2 10° cm™ (©) 7.2 10cm" (d) 1.8 x 10%cm™ When an electron jumps from nth orbit to 1* orbit, in an imaginary atom obey- ing Bohr’s model, it emit two radiations of wavelengths 400 nm and 300 nm. The frequency of radiation emitted out in the transition n =n to n=1 will be (a) 75x10" Hz (b) 1.0.x 10" Hz (c) 8.75 x 10" Hz (d) 1,75 x 10" Hz The given diagram indicates the energy levels of a certain atom. When the system moves from 2E level to E level, a photon of wavelength 2 is emitted. The wave- length of the photon emitted during its transition from 4£/3 level to E level 2E AED e— (a) M3 (b) 314 (©) 443 (@) 3 What transition in the hydrogen spectrum would have the same wavelength as the Balmer transition n = 4 to n = 2 of He" spectrum? (@) n=4t0n (b) n=4ton=1 () ton (@) n=3t0n Number of possible spectral lines in the bracket series in hydrogen spectrum, when electrons present in the ninth excited state return to the ground state, is (a) 36 (b) 45 © 5 @6Heisenberg’s Uncertainty Principle 116. The uncertainty in measuring speed of a particle is zero. Uncertainty in measuring its position will be (a) zero (b) z ot (d) infinite 4am 117. Uncertainty in measuring speed of a par- ticle is numerically equal to uncertainty in measuring its position. The value of these uncertainties will be (a) equal to ph 4mm (b) less than | 4am (© greater than | o 4am (d) (a) or (c) 118. If uncertainty in position and momen- tum of a particle is numerically equal, then the minimum uncertainty in speed of the particle is Atomic Structure = 13.11 1 : © oF & © fi (d) ens © mVn 119. The mass of a particle is 10 g and its diameter is 10 cm. If its speed is 10% cm/s with 0,0001% uncertainty in measurement, the minimum uncertainty in its position is (a) 5.28 10% m (b) 5.28 x 107m (©) 5.28% 10% m (@) 5.2810? m ih © Woe 120. Uncertainty in the position of an elec- tron (mass = 9.1 x 10°" kg) moving with a velocity 300 m/s, accurate up to 0.001%, will be (= 6.3 x 10 Js) (a) 5.76x 10? m (b) 1.92x 107 m (©) 384x107? m (d) 19.2 107% m De-Broglie’s Equation 121. The ratio of de-Broglie wavelength of electron and proton moving with the same speed is about (a) 1836:1 (b) 1:1836 © (d) 1:2 122. An electron makes five crests during one revolution round H-nucleus. The electron belongs from the (a) first orbit (©) fifth orbit (b) fourth orbit (d) sixth orbit 123. The circumference of the third orbit of He’ ion is xm. The de-Broglie wavelength of electron revolving in this orbit will be (a) ym (b) 3xm © 5m (@ 9xm 124. The momentum of a photon of wave- length 6626 nm will be (a) 10% kg ms" (©) 10"kgm"* 125. If 2 be the de-Broglie wavelength of a thermal neutron at 27°C. The wavelength of the same neutron at 927°C is (a) (b) 0.5% (©) 2% (d) 0.252 (b) 10°*kg ms (@) zero13.42 = Chapter 13 Quantum Numbers 126. The energy of different orbitals in an atom or ion having only one electron, depends on (a) nonly (b) mand /only (©) n, land m only (@) nm, L.mands 127. The size of an orbital is given by (a) principal quantum number (b) azimuthal quantum number (©) magnetic quantum number (@) spin quantum number 128. The types and number of orbitals belong- ing from the fifth orbit are, respectively, (a) 5,25 (b) 25,5 © 4,16 (@) 5,5 129. The electron in the same orbital may be identified with the quantum number (@n (b) 7 (m @s 130. The orbital angular momentum of an electron is 2s orbital is A a) +=. — (b) 0 @) 45-55 ) A A (c) —— (d) [2 — Ox @ 2 131. The orbital angular momentum of a 4p electron will be h h a) 4.— (by) v2. @ 455 ) 25. A A —— i © Ver @ 2a 132. The probability of finding P, electron is zero in (a) XY-plane (b) ¥Z-plane (©) XZ-plane (d) Y-axis 133, The quantum number which determines the shape of the orbital is 134. 135. 136. 137. 138. 139. 140. (a) Magnetic quantum no. (b) Azimuthal quantum no. (©) Principal quantum no. (d) Spin quantum no. Orbital with maximum symmetry is (a) p-orbital (b) s-orbital (©) d,,-orbital (d) d,-orbital In presence of external magnetic field, p-orbital is (a) 3-fold degenerate (b) 5-fold degenerate (©) 7-fold degenerate (@) non-degenerate The number of orbitals of g-type (a5 () 7 (©) 9 qd) Which of the following orbital does not exist according to quantum theory? (a) Sg (b) 4f (©) sh (@) 6h Which of the following set of quantum numbers is permissible? (a) 4,1,42,41/2 — (b) 4,2,-1, 41/2 () 4,0,0,1 (d) 4,4,42, 172 Number of orbitals represented by 1 = 2and m=+2is (@1 (b) 2 © 3 @4 The quantum numbers +1/2 and -1/2 for the electron spin represent (a) rotation of the electron in clock- wise and anticlockwise direction, respectively. (b) rotation of the electron in anti- clockwise and clockwise direction, respectively (©) magnetic moment of the electron pointing up and down, respectively. (d) two quantum mechanical spin states which have no classical analogue.Schrodinger's Equation 141. The number of nodal planes in 2p, orbital is (a) zero (b) 1 © 2 (@) infinite 142. Which orbital is represented by the com- plete wave function, Wi.” Atomic Structure = 13.13 143. Number of nodal surface in 5s orbital is (a) 5 (b) 4 (©) 3 do 144, The orbital having two nodal surfaces is (a) Is (b) 2s (c) 3s (d) 2p 145. The number of radial nodes of 3s, 3p and 3d electrons are, respectively, (a) 4s (b) 3p (©) 4p (d) 4d (a) 0,1,2 (b) 2,1,0 (©) 2,2,2 @ 1,35 Electronic Configuration 146. The process of successive addition of (a) 5 (b) 3 protons to the nucleus followed by an © 8 @ 2 addition of the same number of electrons to the available orbitals in the sequence 1S The number of orbitals having (+ D of increasing energy to obtain the elec- tronic configuration of many electronic (a9 (b) 8 configuration of many electron atom, is a4 (d) 10 known as 151. The total number of orbital for (n+) =4 is. (a) Pauli’s exclusion principle (4 (b) 16 (b) Hund’s rule (©) 32 @9 (©) Heisenberg's uncertainty principal (@ Aufbau principle 147. When the value of azimuthal quantum number is 3, the maximum and minimum values of spin multiplicity are (@) 1.8 (b) 81 (©) 6,1 (d) 7,0 148. A completely filled d-orbital (d”) is of (a) Spherical symmetry (b) Octahedral symmetry (©) Tetrahedral symmetry (@) Unsymmetry 149. An atom have d’ configuration. The max- imum number of electrons in the same spin is 152. Which of the following configuration is violating Pauli’s exclusion principle? 2s 2p offi of ffl eft] ith (d) (b) and (c)13.44 = Chapter 13 153. 154, 155. 156. 157. If there are three possible values (-1/2, 0, +1/2) for the spin quantum number, then the maximum capacity of second orbit will become of (a) 8 electrons (b) 6 electrons (c) 12 electrons (d) 27 electrons The electrons, identified by quantum numbers 1 and /, @ n=4, (i) n=4,1=0 Gil) n=3,1=2 iv) n=3,/=1 can be placed in order of increasing energy, from the lowest to highest, as (a) v B, 1 x 10% moles of ‘B’ were formed on absorption of 6.626 x 10” erg at 360 nm. ‘The quantum efficiency (molecules of ‘B” formed per photon) is (@) 1.0 © 05 (b) 0.25 (d) 2.0 Light of wavelength, 2, falls on a metal having work function he/A,. Photoelectric effect will take place only if (a) 22% (b) AE 2%y (©) AS Ay (d) AS AY2 Light of wavelength, 2, strikes a metal surface with intensity X and the metal emits Y electrons per second of maxi- mum kinetic energy Z, What will happen to Yand Zif Xis halved? (a) Ywill behalved and Z will be doubled (b) ¥ will be doubled and Z will be halved2. 2. 23. (©) Y will be halved and Z will remain the same (d) Y will remain same and Z will be halved Photoelectric emission is observed from a metal surface for frequencies v, and ¥, of the incident radiation (», > ¥,). If maximum kinetic energies of the pho- toelectrons in the two cases are in the ratio 1:K, then the threshold frequency for the metal is given by Ky, ~ K Ky,-v, K-1 (b) @ Photons of frequency, v, fall on metal sur- face for which the threshold of frequency is vy, Then. (a) All ejected electrons have the same kinetic energy, Atv ~ v (b) The ejected electrons have a distribu- tion of kinetic energy from zero to hv =). (©) The most energetic electron has kinetic energy hv. (d) The average kinetic energy of ejected electrons is hv ¥,) If Ay is the threshold wavelength for photoelectric emission from a metal surface, ) is the wavelength of light fall- ing on the surface of metal and m is the mass of electron, then the maximum speed of ejected electrons is given by © [266 -a m © [2a] m 25. Atomic Structure = 13.19 Which of the following graphs is correct for the photoelectric effect? (a) { K.E. of Emiued > Electrons . of Emiued —> Electrons K.E. of Emiued > Electrons @ K.E. of Emitted > Electrons The wavelength of —K,-characteristic X-rays produced is A, when cathode rays strike on a metal of atomic num- ber Z. What should be the atomic num- ber of metal such that it can produce the K ,-characteristie X-rays of wavelength 42? Zz Zz @ | ©) 5 Zl @ (@ 2Z-1 2 Two carbon discs, 1.0 g each, are 1.0 em apart have equal and opposite charges. If force of attraction between them13.20 = Chapter 13 21. 28. 29. 30. 31. 32. is 10° N, the ratio of excess electrons to the total atoms on the negatively charged disc is (N, = 6 x 10”) (a) 2.4% 10771 (©) 10.2.4 (b) 107:2.4 (a) 2.4:107 The radius of the hydrogen atom in its ground state is 5.3 x 10""m. After collision with an electron it is found to have a radius of 21.2 x 10m. The principal quantum number of final state of the atom is (a) 2 (b) 3 o4 (@) 16 For which orbit in He* ion, the cireumfer- ence is 26.5 A? (a) 2 (b) 3 o4 (@) 16 The radius of the second orbit of H-atom is equal to the radius of (a) second orbit of He*ion (b) third orbit of Li? ion (0) fourth orbit of He’ ion (d) fourth orbit of Be*ion As the orbit number increases, the dis- tance between two consecutive orbits (r= radius of first orbit) (a) increases by 2r, (b) increases by (2m — 1)r,, where n is lower orbit number (©) increases by Qn — 1)r,, where n is higher orbit number (d) remains constant The ratio of the areas within the electron orbits for the first excited state to the ground state for the hydrogen atom is, (@ 2:1 (b) 4:1 (© 8:1 (@) 16:1 When an electron jumps from the second orbit to fourth orbit, its distance from nucleus increases by 2.116 A. The atom or ion should be (a) Hatom (©) Li* ion (b) He’ ion (d) Be* ion 33. 35. 37. What is the distance travelled by an electron revolving in the second orbit of Be’ ion, in 100 revolutions? (a) 3.32 10m (b) 5.29 10m (c) 6.64 10% m (@) 1.16% 10% m Which of the following cannot be circumference of an orbit in H-atom? (r= radius of the first orbit) (a) 2nr, (b) 4nr, (c) 8nrq (d) 18nr, The speed of electron revolving round H-nucleus is 0.547 x 10° m/s. The distance of electron from nucleus is (a) 2.116 A (b) 4.761 A (c) 8.464 (a) 0.529 The speed of electron in H-atom is directly proportional to () vr @r © Wr @) Wr The ratio of the speed of the electron in the first Bohr orbit of hydrogen and the speed of light is equal to (where e, hand ¢ have their usual meanings) (a) 2nhele* (b) ecl2nh © ehi2nc @) ee, he In the Bohr’s atomic model, the electro- static force of attraction between nuclear charge (Z,) and electron of charge ¢ is balanced by the centripetal force act- ing towards the centre of atom. If €, be the permittivity of vacuum and r be the radius of orbit in which electron is revolving, the speed of electron is Ze ® \(Gne.) mr (Gne,ymr ) ee (©) y(4ne,) mrZ e* @ — [(ane,) mr39, 40. 4. 42. 43. If an electron is revolving round the nucleus of He*ion at a distance of 4.0 A, the magnitude of centripetal force on electron by the nucleus is (a) 2.88 x 10°N (b) 2.88 x 107.N (©) 1.152x 10" N (d) 1.44x 10°N The time period of revolution in the third orbit of Li* ion is x second. The time period of revolution in the second orbit of He’ ion, should be @ xs 3xs 2 8 © 3x8 @ 3x8 In two hydrogen atoms A and B, the elec- trons are revolving round the nucleus in circular orbits of radius r and 4r, respec- tively. The ratio of times taken by them to complete one revolution is (@) 12 (b) 1:4 (© 18 (d) 1:64 The time period of revolution of electron in H-atom is directly proportional to @)r (b) 7? or @? The average life time of an electron in an excited state of hydrogen atom is about 10° s, How many revolutions does an electron in the m = 2 state make before dropping to the n= 1 state? (a) 10° (b) 8.33 x 10° (©) 6.67% 107 (d) 1.04% 108 According to Maxwell’s theory of elec- trodynamics, an electron going in a circle should emit radiation of frequency equal to its frequency of revolution. What should be the wavelength of the radia- tion emitted by a hydrogen atom in the ground state if this rule is followed? (a) 4500 nm (b) 450 nm (©) 45nm (@ 45m 45. 41. 49. Atomic Structure = 13.21 The angular momentum of electron in Bohr’s orbit is J, What will be the K.E. of electron in that Bohr’s orbit? wv (b) — r £ oF inetic energy of an electron in the second Bohr orbit of a hydrogen atom is (a, is the Bohr radius) We We ai b) ® 4n'ma, ®) 16n*ma? R Re = d oS © 32n?ma? @ 64n'ma? The ionization energy of a hydrogen-like atom is 14.4 eV, The amount of energy released when electron jumps from the fourth orbit to the first orbit in this atom, is (a) 13.5eV (b) 10.8 eV (©) 0.9eV (d) 12.75 eV The radius of first orbit of H-atoms is 0.529 A. The radius of first orbit of D-atoms should be (a) exactly 0.529 A (b) slightly less than 0.529 A (c) slightly greater than 0.529 A (@) 1.058 A The ionization energy of H-atoms is 13.6 eV. The ionization energy of deuterium atom should be (a) exactly 13.6 eV (b) slightly less than 13.6 eV (©) slightly greater than 13.6 eV (@) 27.2eV ‘An antiproton has the mass of a proton but a charge of -e. If a proton and an antiproton orbited each other, how far apart would they be in ground state of such a system? Mass of a proton is 1836 times the mass of an electron.13.22 = Chapter 13 51. 52. 53. (a) 0.058 pm (b) 0.029 pm (©) 0.014 pm (@) 194,25 nm A lithium atom has three electrons. Assume the following simple picture of the atom, Two electrons move close to the nucleus making up a spherical cloud around it and the third moves outside this cloud in a circular orbit. Bohr’s model can be used for the motion of this third electron but 1 = 1 state is not available to it. The ionization energy of lithium in ground state, using the above picture, is (a) 13.6eV (b) 10.2eV (© 34eV (@) Ls1ev An electron in a hydrogen atom in its ground state absorbs 1.5 times as much energy as the minimum required for it to escape from the atom. What is the speed of the emitted electron? (a) 1.55 x 10° m/s (b) 2.68 x 10° m/s (©) 2.19 x 10° m/s (d) 1.02 x 10° mis Sodium atoms emit a spectral line with a wavelength in the yellow, 589.6 nm. What is the approximate difference in energy between the two energy levels involved in the emission of this spectral line? (a) 3.37x 10°F (b) 2.1eV (0) 48.35 kcal/mol (@) all of these A certain molecule has an energy level diagram for its vibrational energy in which two levels are 0.0141 eV apart The wavelength of the emitted line for the molecule as it falls from one of these levels to the other, is about (a) 88 um (b) 88 mm (©) 174.84m (@) 88 nm 55. 56. 37. In a discharge tube, there are only two hydrogen atoms, If the electrons in both atoms are de-exciting from 4" orbit, the minimum and maximum number of spec- tral lines should, respectively, be (@) 1,4 (b) 4,1 (©) 3.4 @ 1.6 Electrons are de-exciting from the fifth orbit in hydrogen atoms but the first orbit is not available for them. The maximum number of spectral lines should be (a) 10 (b) 6 © 15 @ 3 From a hydrogen discharge tube, only three photons are picked up. The energies of these three photons were 10.2, 12.1 and 1,9 eV. These photons are coming from (a) only one atoms (b) two atoms (©) three atoms (d) two or more atoms When electron jumps from the fourth orbit to the second orbit in He" ion, the radiation emitted out will fall in (@) ultraviolet region (b) visible region (c) infrared region (@) radio wave region When electrons are de-exciting to the ground state from n® orbit of hydrogen atoms, 15 spectral lines are formed. The shortest wavelength among these will be ul 900 au ead fa) 3 (b) TR 35 35 =R d) = © % © ser Rydberg given the equation for all vis- ible radiation in the hydrogen spectrum as =<" The value of k in terms of n-4 Rydberg constant is61. 62. 63. 65, R 4 Ss (a) 4R OF 4 oe) = aR © R (d) ‘The wavelengths of the first Lyman lines of hydrogen, He" and Li® ions are Ay, Ay, 4. The ratio of these wavelengths is (a) b4:9 (b) 9:4:1 (©) 36:9:4 (d) 6:3:2 An excited hydrogen atom emits a photon of wavelength A in returning to the ground state. If R is the Rydberg con- stant, then the quantum number 1 of the excited state is (@ VAR (b) VAR=1 aR © Vip (@) JAROR=1) Suppose that in any Bohr atom or ion, orbits are only in even numbers like 2, 4, 6, .... The maximum wavelength of radiation emitted in the visible region of H-spectrum should be @ 4 w 4 36 16 Ea) a) 16 © 3R © SR The wavelength of first line of Lyman series of H-atom is 1216 A. What will be the wavelength of first line of Lyman series in 10 time ionized sodium atom (Z=11) (a) 1216A (b) 12.16 A (©) 10A (d@) 0A In a sample of hydrogen atoms, all the atoms are in a particular excited state. If the emission spectrum of this sample has only 4 spectral lines in the visible region, then the total number of spectral lines in IR region possible from that state is 67. Atomic Structure = 13.23 (a) 6 (b) 5 () 7 (d) 15 Imagine an atom made up of a station- ary proton and a hypothetical particle of double the mass of electron but having the same charge as the electron. Apply Bohr atomic model and consider all pos- sible transitions of this hypothetical par- ticle directly to the first excited state. The longest wavelength photon that will be emitted has wavelength (given in terms of Rydberg constant R for the hydrogen atom) equal to 9 36 (a) R (b) oR 18 4 ©) R (d) R Which of the following expression repre- sent the wave number of spectral lines in Balmer series (if 1 is the principal quan- tum number of higher energy level)? RU 4) @ 2-4) Wn py Rea 2yn+2) me R(n=2)(n+2) an? ) Rn=Den+) 4n* The energy emitted when electron of 1.0 g atom of hydrogen undergo transition giv- ing the spectral lines of lowest energy in visible region of its atomic spectra is (a) 301.22 ky (b) 328 KI (©) 984 KS (4) 182.22 kJ ( © @ A series of lines in the spectrum of atomic hydrogen lines at wavelength 656.46, 486.27, 434.17, 410.29 nm. What is the wavelength of next line in this series? (a) 397.12nm, (b) 407.83 nm (©) 389.01 nm (@) 360.54 nm13.24 = Chapter 13 10. n. R. BB. 14. To what series does the spectral line of atomic hydrogen belong if its wave num- ber is equal to the difference between the wave numbers of the following two lines of the Balmer series: 486.1 and 410.2 nm? (a) Lyman series (b) Balmer series (©) Paschen series (d) Brackett series The value of Rydberg constant R, if He” ions are known to have the wavelength difference between the first (of the long- est wavelength) lines of the Balmer and Lyman series equal to 132 nm, is (a) 2.07 x 10! m* (b) 1.11 x 107m” (©) 9x 10% m™ (d) 1.936 x 10’ m™! The wavelength of the first line of the He* ion spectral series whose interval between the extreme lines is 2.725 x 10° m* is (R= 1.09 x 10’ my (a) 471,82nm (b) 4718.2 nm (©) 1019.37 nm (@) 165.14 nm The binding energy of an electron in the ground state of hydrogen-like ions in whose spectrum, the third line the Balmer series is equal to 108.5 nm, is (a) 13.6eV (b) 54.4eV (©) 1224eV (@) 144ev A stationary He" ion emitted a photon corresponding to the first line of the Lyman series. That photon liberated a photoelectron from a stationary hydro- gen atom in the ground state. The velocity of the photoelectron is (a) 3.1.x 10° m/s (b) 3.1 10° m/s (©) 9.56 x 10" mis (d) 9.56 x 10° mis 15. 16. 8. 2”. A single electron species in energy level (orbit number 1) with energy X was provided with excess of energy so that it jumps to higher energy level with energy Y. If it can emit radiations of six different wavelengths on de-excitement between these two energy levels, then the correct relation is @ = n— 1 Sa142 o 13 Fa148 When an electron de-excites from higher orbit in H-atom, two radiations are emit- ted out in Paschen and Lyman series. The wavelength of radiation emitted out in Lyman series is 8R 3R o> oO 4 9 © 3R ®O oR If the radius of first Bohr orbit is x unit, then de-Broglie wavelength of electron in the third orbit is (a) 2nx unit (©) 9x unit (b) 6nx unit (d) 18nx unit If E,, E,and E, are the kinetic energies of an electron, an o-particle and a proton, with same de-Broglie wavelength, then (a) E,>E,>E, (b) E,> E,>E, (©) E,>E,>E () E,=E,=E, A proton and an o-particle are accel- erated through the same potential difference. The ratio of their de-Broglie wavelengths is, (@) 1: (©) V2: (b) 2:1 (d@) 22:180. 81. 82. 83. The de-Broglie wavelength of a vehicle moving with velocity v is 4. Its load is changed so that the velocity as well as kinetic energy is doubled. What will be the new de-Broglie wavelength? (@) a (b) 22 © 4a (@) 2 When accelerated electrons are directed against an anticathode in an X-ray tube, the radiation obtained has a continuous spectrum with a wavelength minimum, a. - 124x1o* age used for accelerating the electrons. Yin for V= 5x 10° Vis (a) 0.124 nm (©) 2.48 nm m, where V is the volt- (b) 0.248 nm (@) 1.24nm The dynamic mass (in kg) of the photon with a wavelength corresponding to the series limit of the Balmer transitions of the He* ion is (a) 4.2210 (b) 2.24 x 10 (©) 2.42 x 10° (@) 4.2210 An electron is continuously accelerated in a vacuum tube by the application of a potential difference. If its de-Broglie wavelength decreases by 1% over a path length of em, its kinetic energy (a) increases by 1% (b) increases by 2% (©) decreases by 2% (d) increases by 0.5% Assume that the uncertainty in the posi- tion of a particle is equal to its de-Broglie wavelength. The minimum uncertainly in its velocity is equal to (a) 0.25 times its velocity © (b) F times its velocity (0) x times its velocity 4 (a) = times its velocity 85. Atomic Structure = 13.25 What should be the increase in kinetic energy, of electron in order to decrease its de-Broglie wavelength from 100 nm to 50 nm? (a) 0.451 keV (b) 4.51 «10 ev. (©) 4.51107 ev (A) 0.0451 ev An o-particle is accelerated from rest through a potential difference of 6.0V. Its de-Broglie wavelength is (a) 5A (c) 414.64 The de-Broglie wavelength of electron of He’ ion is 3.329 A. If the photon emit- ted upon de-excitation of this He* ion is made to hit H-atom in its ground state so as to liberate electron from it, what will be the de-Broglie wavelength of photo- electron? (a) 2.348 A (b) 1.917 (©) 3.329 (d) 1.66.4 Photoelectrons are liberated by ultra- violet light of wavelength 3000 A from a metallic surface for which the photoelec- tric threshold is 4000 A. The de-Broglie wavelength of electrons emitted with maximum kinetic energy is (a) 1000A (b) 42.43 A (©) 1205A (d) 354A The minimum uncertainty in de-Broglie wavelength of an electron accelerated from rest by a potential difference of 6.0, if the uncertainty in measuring the (b) 4.15 pm. (@) Som 1 position is —nm, is x (a) 625A. (b) 6.0A (©) 0.625 (@) 0.3125A A photon of 2.55 eV is emitted out by an electronic transition in hydrogen atom. ‘The change in de-Broglie wavelength of the electron is13.26 = Chapter 13 oO. 92. 93. 95. 96. 97. (@) 332A (b) 498A (©) 6.64 (d) 9.96 A The orbital angular momentum of 2p- and 3p-orbitals (a) are same (b) are different, more for 2p-orbital (©) are different, more for 3p-orbital (@) depends on the type of atom or ion Which of the following energy level may bring absorption of photon but never emission of photon? (a) 3d (b) 2p © Is (d) 28 An electron that has the quantum num- bers n=3 and m=2 (a) must have spin quantum number value, +1/2 (b) must have (c) must have (d) must have /= 2 If an electron has spin quantum number of + %and magnetic quantum number of =1, it eannot be present in (a) s-orbital (b) p-orbital (©) d-orbital (@) Forbital Inwhich of the following orbital, electron will be closer to the nucleus? (a) 65 (b) af (©) Sd (d) 6p In the absence of external magnetic field, d-orbital is (a) 3-fold degenerate (b) S-fold degenerate (0) 7-fold degenerate (d) non-degenerate 30rd Lor 2 The following electronic transitions occur when Lithium atoms are sprayed into a hot flame; 28 2p33d3p 4s 3p, which of these transition would result in the emission of light? 98. (a) I, Wand IV (b) Mand V (©) IIL, IV and V (d) alll of these steps Possible set of quantum numbers for which; n=4,/=3 and s= +3 is (a) 14 (b) 7 (©) 5 (d) 10 Which of the following graph represents the radial probability function of 3d elec- tron? fa) 4n2R? > (b) nr? R2 > © 4m? R2 > @) 4m? R2 > 100. The wave function of 1s orbital of sia 1 fe H-atom is: y =—=|—]| e°*, where vr (<) a, = Bohr radius, The probability of find- ing the electrons at a distance ‘r from the nucleus is given by101. 102. 103. 104, (@) y=wdr (b) fy*4nrtdr (©) w4nr'dr (d) wed For an electron in a hydrogen atom, the wave function is given by yy, = (wy2)e"™, where a, is the radius of first Bohr’s orbit and r is the distance from the nucleus with which probability of finding electron varies. What will be the ratio of probabilities of finding electrons at the nucleus to first Bohr’s orbit a,? (a) 0 (b) e oe @4 If n and / are, respectively, the principal and azimuthal quantum numbers, then the expression for calculating the total ‘number of electrons in any energy level is (a) Y2Q/+), (b) ¥ 22/41) (© > 22l+1 a @) ¥ 22/4) Which of the following element will have same number of electrons in s-as well as p-type of orbitals? (a) Fe(Z=26) (b) Mg (Z= 12) (c) Ne(Z=10) (@) Ar(Z=18) Electronic configuration of an element is Is!,2s!, 2p? Itis (a) ground state configuration of B(Z=5) (b) excited state configuration of B (© ground state configuration of C* ion (Z=6) (d) impossible configuration 105. 106. 107. 108. 109. Atomic Structure = 13.27 Number of electrons having m = 0 for sodium atom is (a) 2 (b) 5 ©@7 (d) 3 The magnitude of the orbital angular momentum of an electron is given by L = V5 hin, How many orbitals of this kind are possible, belonging to an orbit? @4 (b) 5 © @9 What is the most probable distance of a Is electron in a He" ion. The wave function for Is orbital is given by we 2 ] 2% where a, = radius of Ta: first Bohr’s orbit in H-atom = 52.9 pm. (a) 52.9 pm (b) 13.25 pm (© 6.61 pm (@) 26.45 pm The average and the most probable dis- tance from the nucleus for 1s electron in hydrogen atom are, respectively (a, is the first Bohr radius.) (a) a, a, (b) a,, 1:54, (©) 15a,,4, (d) 1.Sa,, 1.5a, For an atom or ion having single electron, compare the energies of the following orbitals: S, = a spherically symmetrical orbital having two spherical nodes. S,=an orbital which is double dumb-bell and has no radial node. S, = an orbital with orbital angular momentum zero and three radial nodes. S,=an orbital having one planar and one radial node. (a) S,=S,=S,=S, (b) S,=S;=S,S,>S,>8, @ 8,<8, n (d) Coloumbie force of attraction on the electron a nt 4 5. 6. As an electron jumps from the fourth orbit to the second orbit in Be* ion, its (a) K.E. increases (b) speed increases (©) frequency of revolution increases (d) PE. decreases Which of the following statement(s) is/are correct about the Boht model of hydrogen atom? (a) The acceleration of the electron in the n =2 orbit is more than that in the n=1 orbit, (b) The angular momentum of the elec- tron in then n= 2 orbit is more than that in the n= 1 orbit. (©) The kinetic energy of electron in the n= 2 orbit is less than in the n= 1 orbit, (d) The centripetal force on electron in ‘n= 2 orbit is more than that in the n=1 orbit, The frequency of certain line of the Lyman series (1, = 4 to m, = 1) of the atomic spectrum of hydrogen can satisfy the following conditions: (a) Itis the sum of the frequencies of a Lyman line and a Balmer line. (b) Itis the sum of the frequencies of a certain Lyman line, a Balmer line and a Brackett line. (©) It is the sum of the frequencies of a Lyman line, a Balmer line and a Paschen line. (d) It is the sum of the frequencies of a Lyman and a Paschen line.7. A sample of hydrogen atoms in ground state is exposed to electromagnetic radia- tions of 1028 A. The wavelengths of the induced radiation(s) is/are (a) 1028 A (b) 1218.4 A (c) 6579.2 (a) 19044 8. Some hydrogen-like atoms in ground state absorbs ‘n’ photons having same energy and on de-excitement, it emits exactly ‘n’ photons. The energy of absorbed photon may be (a) 91.8eV (©) 48.4eV (b) 40.8 eV (d) 54.4eV 9. Which of the following statement(s) is/are correct? (a) The ratio of the radii of the first three Bohr orbits of hydrogen atom is 1:8:27. (b) The ratio of magnitude of total energy:kinetic energy:potential energy for electron in any orbit of hydrogen atom is 1:1:2. (©) The frequency of a green light is 6 x 10 Hz, then its wavelength is 500 nm. (@) The ratio of de-Broglie wave- length of a H-atom, He-atom and CH,-molecule moving with equal kinetic energy is 4:2:1 10. When photons of energy 4.25 eV strike the surface of a metal ‘A’, the ejected photoelectrons have maximum. kinetic energy, T, (in eV) and de-Broglie wave- length, ,. The maximum kinetic energy of photoelectrons liberated from another ‘metal ‘B’ by photons of energy 4.20 eV is T, (= Ty ~ 1.50 eV). If the de-Broglie wave length of these photoelectrons is 2 (= 2a), then (a) the work function of ‘A's 2.25 eV (b) the work function of *B’ is 3.70 eV (©) T,=2.00eV (@) T,=2.75eV i. 12. 13. 14. Atomic Structure ™ 13.29 Which of the following suggested de- Broglie wavelengths is not possible for the electron in a Bohr orbit of the hydrogen atom? (a) 3.20A (b) 4.98 A (©) 9.96A (d) 6.64 The magnitude of spin angular momen- tum of an electron is given by @ { eH} sh On Ba 220 A an (b) © @ Which of the following is/are true information(s)? (a) 3s orbital is spherically symmetrical with two nodes. (b) dy,» orbitals has lobes of electron density Y-axis, (©) The radial probability curve of 13, 3p and Sd have one, two and three regions of maximum probability. (d) 3d, has zero electron density in XY-plane. XY¥-plane along X- and Correct statement(s) regarding 3p, orbital is/are (a) Angular part of wave funetion is independent of angles @ and @. (b) Number of maxima in 4m7R%(r) vs. reurve is 2 (©) XZ plane is the nodal plane. (@) Magnetic quantum number must be=1, The angular part of the wave function depends on the quantum numbers @n () £ (© m @s18. Which is/are correct for sodium atom, in the ground state? (a) There is only one unpaired electrons. (b) There are five pairs of electrons. (©) 6electrons are in one spin and other 5 in opposite spin. (@) There are ten electrons in the same spin 13.30 = Chapter 13 16. The electronic configuration of carbon 19. Select the correct statement(s) among the atom in the excited state is 1s? 2s! 2p’, following Which of the following is/are incorrect (a) Outside any orbital, the probability statement(s) about it? of finding electron is zero. (a) The number of unpaired electron is 4. (b) For single electronic atom or ion, the (b) There are five electrons in the same most probable distance of electron in spin. an orbital having no radial node is (©) There are only two unpaired electrons. . from the nucleus, where a, is (d) The spin of all p-electrons are similar. a the first Bohr radius. Which of the following statement(s) is (©) The average distance of electron (are) correct? (belonging from the same orbit) (a) The electronic configuration of Cr from the nucleus decreases with is [Ar] 3d°4s' (Atomic Number of the increase in the value of angular Cr=24), momentum quantum number for the (b) The magnetic quantum number may orbital, have a negative value. (d) The angular wave function of any (©) In silver atom, 23 electrons have a s-orbital is independent from @ and 6. spin of one type and 24 of the oppo- site type 20. Among the following, select the correct (d) The oxidation state of nitrogen in information(s) HN, is-3. (a) The opposite lobes in any d-orbital have the same sign of wave function. (b) 1s orbital is the only orbital for which the sign of wave function does not have radial as well as angular depend- ency. (©) The number of radial nodes is always greater than that of angular nodes. (@) All the orbitals belonging from an orbit have the same number of total nodes Section C (Comprehensions) Comprehension | ‘Three laser guns labelled as I, IT and ILI have power 2, 3 and 5 W (not necessary in the same order) are used to produce photocurrent from metal plate. Number of photons emitted by laser guns are 4 x 10", 5 x 10" and 9 x 10" per second. Metal plate have threshold energy 4.5 x 10"” J. Neither the power nor the number of photons emitted by a particular laser gun is known and it is known that all capable photons emit a photoelectron. 1. Minimum possible wavelength of emitted (a) V680 A (b) V30 A photoelectron is (©) V480 A (a) Vi20 AAtomic Structure = 13.31 2. Minimum photocurrent which must be 3. Ratio of maximum to minimum photo- passed through the circuit is current which can be passed through the (a) 2.88.4 (b) 144A circuit is (©) 2.08 A (d) 0.644 (a) 5:4 (b) 9:5 (c) 9:4 (d) 9:2 Comprehension Il Let us assume a different atomic model in which electron revolves around the nucleus (proton) at a separation r under the action of force which is different form electrostatic force of attraction. The potential energy between an electron and the proton due to this force is given by U=—Klr*, where k is a constant. This hypothetical atom is obeying Bohr’s quantization condition. 4. The radius of n® Bohr’s orbit is ale t © v= = @) r= ven 4n'mdkm cf 2 Phi Qn @ v=" ) rat vk 8x?°mvkm 4n 6. The total energy of the electron in the © relive n® orbit is =ntht TE-— ft @r SE Ji ® 128n'mek Wl nht 5. The speed of dato n the n® orbit is () TE.= Derntk n @ v=" nth’ T.E.=—— > 81° mk © Botan 2h athe ) Y= a 81? mvkn OE 6 mt Comprehension It A hydrogen-like atom (atomic number Z) is in a higher excited state of quantum number n. This excited atom can make a transition to the first excited state by successively emitting two photons of energies 10.20 and 17.00 eV, respectively. Alternatively, the atom from the same excited state can make a transition to the second excited state by successively emitting two photons of energies 4.25 and 5.9 eV, respectively. 7. The value of ‘n’ is 9. How much energy will be emitted when @ 4 () 5 an electron in this atom moves from 6 @7 (n+1) to ground state? (a) 114.75 ev 8. The value of Z is eatTiTisey (@) 2 () 3 (©) 119.9eV o4 @> (a) 122.7401332 Chapter 13 Comprehension IV A certain gas of identical hydrogen-like atoms has all its atoms in a particular upper energy level. The atoms make transition to a higher level when a monochromatic radiation, having wavelength 1654 A, is incident on it. Subsequently, the atoms emit radiation of only three different photon energies. 10. The initial energy level of atoms was 12, The atom/ion is (a) n=1 (b) (a) H (b) D © (d) (c) Hey (d) Li? 11. The final energy level of atoms is 13. The energy of photon required to remove (@) (b) electron from higher energy level is © @ (a) 6.04eV (b) 13.6eV (©) 27.2eV (d) 36.8 eV Comprehension V A gas of identical H-like atom has some atoms in the lowest (ground) energy level ‘A’ and some atoms in a particular upper (excited) energy level ‘B’ and there are no atoms in any other energy level. The atoms of the gas make transition to a higher energy level by absorbing monochromatic light of photon ‘energy 2.7 eV. Subsequently, the atoms emit radiation of only six different photons energies. Some of ‘the emitted photons have energy 2.7 eV. Some have more and some have less than 2.7 eV. The principal quantum number of — 16. Theminimum energy of emitted photon is initially excited level ‘B’is (a) 02ev (@1 (b) 2 (b) 13.5eV @3 q@) 4 (c) 6.7eV 15. The ionization energy for gas atoms is Ca) Ore (a) 3.4eV (b) 12.8eV (© 1440 (@) 13.6eV Comprehension VI A muon is an unstable elementary particle whose mass is 207m, and whose charge is either +e or -e. A negative muon (I) can be captured by a proton to form a muonic atom. This atom follows Bohr’s quantization condition. Answer the following, neglecting reduced mass effect. 17. What is the radius of the first Bohr orbit 19. What is the wavelength of the photon of this atom? emitted when muon drops from second (a) 52.9 pm (b) 0.256 pm orbit to the ground state in this atom? (©) 0.256 nm (d@) 10.9 nm (a) 2.53 x 10° m (b) 1.22 107m (c) 5.91 x10" m (d) 2.8510"? m What is the ionization energy of the atom? (a) 13.6eV (b) 0.066 ev (©) 0.583 MeV (d) 2.82 keVAtomic Structure = 13.33 Comprehension VII A sample of H-atoms contains all atoms in ground state. If the atoms are irradiated by photons of x A, the atoms get excited to a particular energy level. When these atoms de-excites, they emit the radiations of six different photon energies. 20. What is the value of x? (a) 2.453 x 10" Hz (a) 978.6 (b) 0,098 (b) 3.066 x 10" Hz (©) 1032 (a) 1223 (©) 5.912x 10" Hz (4) 1.081 x 10" H 21. What is the orbit number for the excited eee state? 24. What are the wavelengths of all infrared @ 6 3 radiations coming out? (4 (d) 2 (a) 1887.3 nm, 4077.5 nm en — () 1887.3 nm Ne (©) 122.3nm, 103.2. nm, 97.9 nm emitted radiations? toieaaeen ingame (a) 978.6A (b) 1223 A 25. What are the wavelengths of all visible (c) 18,872.87 nm radiations coming out? (@) 18,872.87 A (a) 660.5 nm, 489.3 nm b) 660.5 nm, 489.3 nm, 436.9 nm 23. What is the maximum frequency among He 6605 un, 489.3 ‘am, 4369 mm, emitted radiations? soem (d) 660.5 nm, 436.9 nm Comprehension Vill When a sample of hydrogen atoms is irradiated by electromagnetic radiations of suitable wave length, all the electrons jump from the ground state to the fifth orbit. As the electrons cannot remain perma- nently in the fifth orbit, they de-excites to the ground state making one or more than one transitions. Each transition results the emission of an electromagnetic radiation of a particular wave length. When these radiations pass through a prism, they deviate with different angles resulting in the spectral lines. 26. What is the maximum number of spectral (@ 5 (b) 6 lines, if the sample is containing only one (7 @ 10 atom? 29, What is the maximum number of spectral (a) 5 (b) 4 lines, if the sample contains infinite o6 @) 10 number of atoms? 27. What is the maximum number of spectral (a) 5 (b) 6 lines, if the sample is containing only two (7 (@) 10 atoms? atoms 30. What should be the minimum number (a) 5 (b) 6 of hydrogen atoms in the sample to get a ©7 (@ 10 maximum of 10 spectral lines? 28. What is the maximum number of spec- (a) 1 (b) 6 tral lines, if the sample is containing only (©) 8 (@) 10 three atoms?