SAMPLE PAPER SESSION ENDING 2019-20
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Class XI
Subject: Chemistry
SA SA Long
T
V -I -II answe
o
Unit S (2 (3 r
Title/ chapter t
No. A ma ma questi
a
(1mark) rks rks ons
l
) ) (5)
Some Basic
1 Concepts of 2(1) 1(1) - -
Chemistry
2 Structure of Atom 4(1) - 1(3) -
15
Classification of
Elements and
3 2(1) 1(2) - -
Periodicity in
Properties
Chemical Bonding
4 and Molecular 1(1) 1(2) 1(5)
Structure
States of Matter:
5 1(1) 1(2) - -
Gases and Liquids 21
Chemical
6 1(1) - 1(3) -
Thermodynamics
7 Equilibrium 1(1) - - 1(5)
8 Redox Reactions 2(1) - 1(3) -
9 Hydrogen 2(1) 1(2) - -
16
10 s -Block Elements 2(1) 1(2) - -
11 p -Block Elements - - 1(3) -
Organic Chemistry:
Some basic
12 1(1) - 1(3) -
Principles and
Techniques
13 Hydrocarbons 1(1) 1(2)- 1(3) 1(5) 18
Environmental
14 1(3) -
Chemistry
20(1) 7(2) 7(3) 3(5) 70
SAMPLE PAPER (2019 -20)
CLASS : XI
SUBJECT : CHEMISTRY
Time allowed: 3 hours
M.Marks : 70
General Instruction:-
(1) All questions are compulsory.
(2) Question no. 1 to 20 are VSA / objective type questions and carry 1 mark each.
(3) Question no. 21 to 27 are short answer questions and carry 2 marks each.
(4) Question no 28 to 34 are also short answer questions and carry 3 marks each.
(5) Question no. 35 to 37 are long answer questions and carry 5 marks each.
(6) Use log tables if necessary. Use of calculators not allowed.
1 Out of ice and water which one is heavier? Why 1
OR
Perhydrol is the trade name of which chemical species.
2 What happens when quick lime is heated with silica write chemical 1
reaction only?
OR
A solution of sodium carbonate is alkaline. Why?
3 Write the Law of Chemical Equilibrium. 1
OR
Define buffer solutions.
4 What is the oxidation state of K in KO2 ? 1
5 Write IUPAC names of the given organic compound: 1
(CH3)3CCH2C(CH3)3.
6 Give IUPAC name of the element with atomic no.117. 1
OR
Write an example of amphoteric oxide.
7 Give the orbital designation if a) n=3 & l=2 1
8 Condition of spontaneity is 1
(a) ∆ H<O (b) ∆G<O (c) ∆ S<O (d) ∆U<O
9 Give the number of node in 3d. 1
10 Write Pauli’s exclusion principle. 1
11 The hybridisation state of ClF3 is 1
(a) SP3 (b) SP3d (c) SP3d2 (d) Sp3d3
12 Give the % of carbon in C2H5OH. 1
13 Which is more concentrated? 1M or 1m for aqueous solutions. 1
14 The element have atomic number 23, So It’s group is…………. 1
15 Write the relation between pressure density and molar mass of an ideal 1
gas.
16 Which is not showing ideal gas relationship; 1
(a) PV=nRT (b) P=CRT (c) PV=w/mRT (d) P=dRT
17 Write name of radioactive isotopes of Hydrogen. 1
18 The pH of aqueous solution of NaCl is; 1
(a) 5 (b) 6 (c) 7 (d) 4
19 Which is more covalent; AlCl3 or MgCl2? 1
OR
Which is more soluble in water? AlCl3 or MgCl2?
20 Number of pi electrons in benzene; 1
(a) 5 (b) 6 (c) 3 (d) 4
OR
Write Huckel’s rule.
21 A compound contains 4.07 % hydrogen, 24.27 % carbon and 71.65 % 2
chlorine. Its molar masses 98.96 g. What are its empirical and
molecular formulas?
22 Give suitable reason for the following statement: 2
i) NaCl has higher boiling point than KCl.
ii) Alkali metals are good reducing agent.
OR
Write the chemical reaction involved in following:
i) Sodium metal is dropped in water?
ii) Sodium peroxide is dissolved in water
23 What do you understand by (i) electron-deficient, and (ii) electron-rich 2
compounds of hydrogen? Explain with suitable examples.
24 Why the electron gain enthalpy of chlorine is higher than fluorine? 2
25 Why para nitro phenol have higher boiling point than ortho nitro 2
phenol.
26 Write any one chemical reaction for following name reaction: 2
i) Wurtz reaction
ii) Friedel craft alkylation.
OR
Distinguish between following pair of compound on the basis of
chemical test [any one].
i) Ethane & Ethene
ii) Benzene &Ethene
27 What will be the pressure of the gaseous mixture when 0.5 L of H2 at 2
0.8 bar and 2.0 L of dioxygen (O2) at 0.7 bar are introduced in a 1L
vessel at 27°C?
28 what do you mean by Green Chemistry? Write any 2 use of Green 3
Chemistry in day-to-day Life.
29 Give reasons for following: 3
(i) [SiF6]-2 is known whereas [SiCl6]–2 not known.
(ii) Diamond is covalent, yet it has high melting point.
(iii) CO is poisonous.
30 Define entropy and find the sign of ∆ H and ∆ S (positive or negative) 3
for the reaction
Cl2(g)---------→2Cl(g)
31 (a) Write the electronic configuration of Cu. 3
(b) Explain the significance of Heisenberg’s uncertainty principle.
32 Balance the redox reaction in acidic medium; 3
Cr2O72- + SO2 -----------→ Cr3+ + SO42- +H2O
33 Complete the following reactions: 3
C6H5OH + Zn → _______ + _________
C6H6 + Cl2 Anhy AlCl3 ________ + ___________
C6H5COONa+ Soda lime heat ______ + __________
34 Define following : 3
(i) Positive Resonance Effect (+R effect)
(ii) Hyper conjugation
(iii)Differential Extraction
OR
(i)Why an organic liquid vaporizes at a temperature below its boiling
point in its steam
distillation?
(ii) Why is it necessary to use acetic acid and not sulphuric acid for
acidification of sodium
extract for testing Sulphur by lead acetate test?
(iii) Write the method of preparation of lassagine’s extract
35 (i) Define following terms: 5
(a) Lattice enthalpy (b) Bond Order
(ii) Draw the shape and write the hybridisation of following
(a) ClF3 (b) SF4(c) XeF4
OR
(i) what you mean by term ‘Hybridisation’. Write important conditions
for hybridization.
(ii) Compare the relative stability of the following species with the
help of M.O diagrams and
indicate their magnetic properties;
O2 , O2
+ O2
- (superoxide
36 (i) Define Homogenous Equilibrium. 5
(ii) Derive relation between Kp and Kc.
(ii) PCl5, PCl3 and Cl2 are at equilibrium at 500 K and having
concentration 1.59M PCl3, 1.59M
Cl2 and 1.41 M PCl5. Calculate Kc for the reaction, PCl5⇌ PCl3+ Cl2
OR
(i) write Brönsted-Lowry theory of acid base.
(ii) The species: H2O, HCO3-, HSO4 -and NH3 can act both as
Bronsted acids and bases.
For each case give the corresponding conjugate acid and conjugate
base.
(iii) Derive Ionization Constants for a Weak Di-basic Acid.
37 (i) Why is benzene extra ordinarily stable though it contains three 5
double bonds?
(ii)How would you convert the following compounds into benzene?
(a) Ethyne (b) Hexane
Write chemical equation in each.
OR
(i) Why is Wurtz reaction not preferred for the preparation of alkanes
containing odd number of carbon atoms? Illustrate your answer by
taking one example.
(ii) Write chemical equations for the following hydrocarbons:
(a) combustion reaction of Butane
(b) Addition of HBr on Propene in the presence of Peroxide
(c) Hydration of ethyne
SAMPLE PAPER SESSION ENDING 2019-20
MARKING SCHEME
1 Water due to high density 1
OR
hydrogen peroxide
2 CaO + SiO2 → CaSiO3 1
OR
NaOH is stronger base than carbonic acid(weak acid)
3 at a given temperature, the product of concentrations of the reaction products 1
raised to the respective stoichiometric coefficient in the balanced chemical
equation divided by the product of concentrations of the reactants raised to
their individual stoichiometric coefficients has a constant value. This is known
as the Equilibrium Law or Law of Chemical Equilibrium.
Or
Correct definition
4 +1. 1
5 2, 2, 4, 4-Tetramethylpentane 1
6 Ununseptium 1
OR
Any amphoteric oxide
7 3d 1
8 Option b 1
9 2 1
10 Correct definition 1
11 Sp3d 1
12 12/44*100=27.2% 1
13 1M 1
14 5 1
15 P=dRT/m 1
16 Option d 1
17 Tritium 1
18 Option c 1
19 AlCl3 1
OR
MgCl2
20 Option b 1
21 2
22 i) NaCl has high Lattice enthalpy 2
ii) low ionisation enthalpy
OR
NaOH& H2 is formed
NaOH& H2O2 is formed
23 i) electron-deficient: has too few electrons for writing its conventional Lewis 2
structure. Ex Diborane (B2H6)
(iii) electron-rich: Electron-rich hydrides have excess electrons which are
present as lone pairs. Elements of group 15-17 form such compounds. (NH3
has 1- lone pair, H2O – 2 and HF –3 lone pairs)
24 Correct explanation of electron-electron repulsion 2
25 It is due to intermolecular hydrogen bonding in para nitro phenol and 2
intramolecular hydrogen bonding in ortho nitro phenol
26 2RX + Na (dry ether) → R-R + 2NaX 2
C6H6 + RX (Anhy AlCl3) → C6H5R + HX
Or2
i)Bayer’s test or any other
ii) Bayer’s test or any other
27 P= P1V1+P2V2/V 2
P= 0.8 x 0.5 + 2 x 0.7 / 1
Calculation
P = 1.8 bar or any other method
28 Correct explanation/definition 3
29 i). six large chloride ions cannot be accommodated around Si4+ due to 3
limitation of its size.
(ii) Diamond has a three-dimensional network involving strong C—C bonds,
which are very difficult to break and, in turn has high melting point
(iii) It is deadly poisonous due to higher stability of its haemoglobin complex
as compared to that of oxy-haemoglobin complex
30 Correct definition and change in entropy and enthalpy will be positive. 3
31 Correct electronic configuration and correct significance. 3
32 Cr2O72- + 3 SO2 +2H+ -----------→ 2Cr3+ +3 SO42- + H2O 3
33 i) Benzene & Zinc oxide 3
(ii) Chlorobenzene & HCl
(iii) Benzene & sodium carbonate
34 (i) Positive Resonance Effect (+R effect): the transfer of electrons is away 3
from an atom or substituent group attached to the conjugated system.
(ii) Hyper conjugation: delocalisation of ᵟ electrons of C—H bond of an alkyl
group directly attached to an atom of unsaturated system or to an atom with an
unshared p orbital.
(iii) Differential Extraction: Extraction of compound takes place based on
difference in solubility
OR
(i) In steam distillation the mixture boils when sum of vapour pressure of
water and organic liquid becomes equal to atmospheric pressure. And the
vapour pressure of water is high therefore
(ii) if sulphuric acid is used lead acetate itself react with sulphuric acid to form
white ppt of lead sulphate
35 (i) (a) The Lattice Enthalpy of an ionic solid is defined as the energy required 5
to completely
separate one mole of a solid ionic compound into gaseous constituent ions.
(b) Bond Order is given by the number of bonds between the two atoms in a
molecule
(ii) (a) T shaped sp3d (b) See Saw sp3d (c) Square planer sp3d2
OR
(i) the atomic orbitals combine to form new set of equivalent orbitals known
as hybrid orbitals.
Unlike pure orbitals, the hybrid orbitals are used in bond formation. The
phenomenon is known
as hybridisation.
Important conditions for hybridisation
(i) The orbitals present in the valence shell of the atom are hybridised.
(ii) The orbitals undergoing hybridisation should have almost equal energy.
(iii) Promotion of electron is not essential condition prior to hybridisation.
(iv) It is not necessary that only half filled orbitals participate in hybridisation.
In
some cases, even filled orbitals of valence shell take part in hybridisation.
(ii) MO’s for all the molecules,
36 (i) all the reactants and products are in the same phase. 5
(ii) Derivation
(iii) Writing correct formula, value in formula, calculation, result
Kc= 1.79
OR
(i) According to Brönsted-Lowry theory, acid is a substance that is capable of
donating a
hydrogen ion H+ and bases are substances capable of accepting a hydrogen
ion, H+. In
short, acids are proton donors and bases are proton acceptors.
(ii) Correct conjugate acid(H3O+, H2CO3, H2SO4 and NH4) and conjugate
base(HO-, CO3--, SO4-- andNH2-)
(ii) Derivation with all stapes
37 i) The presence of delocalised π electrons in benzene makes it more stable. 5
explanation by diagram
(ii)
(i) For a hydrocarbon of odd no of carbon, we have to take different types of
halo-alkanes, by
which a mixture of products will form.
(iii) Correct reactions
