e i a CH cin Beni Out-of-phase stretch In-phase stretch eed clan egjoew Ip fae m0 Sa ce fe CH2 Wag, CH Twist CHz Rock TABLE 6.1 Selected Group Frequencies: Aliphatics Sse Intensities* Group Assignment Frequency (cm) IR R CH; RCH, ooph. str? ai doo mph np 2975-2950 vs vs a sph. str, Cy 2885-2860 vs vs o ‘oph. bend 1470-1440 ms ms eZ iph. bend 1380-1370 m vw R-CH(CHs)2 bend-bend 1385-1380 m vw 4 ‘bend-open. 1373-1365 m awe RICH) bbend-bend 1395-1385 = = ‘bend-open 1373-1365 ng! ae iph. str. + 2935-2915 ms an bend overtone 2875-2855 m = iph. str 2850-2815 aa fe ipph. bend 1450-1430 Ea = iph. str 2825-2765 rn " iph. bend 1380-1365, Fe Be Dugc quét bang CamScanner2936-2915 an o.phist. Ps vs RCH = ch i phoste ¥ a ‘ 2920-280 er ey Fermi resonance «le obs 2 1475-1445 ms A . bend » be 1305-1295 2 . iph. tis » (CHy-s ‘ . 726-720 ee oe (Cs Ue his sn (O=C-CH aa Me . rs a 1445-1405 a m pent ony 1390-1340, = m oa ort 13001220, uy a cH RCH CH bend 1360-1320 4 O=C-H CHste + 2900-2800 m mr a rk overtone 270-2695 ont oe 5 CH rock 1410-1380 m 2 trong, m= medium,» = weak, = very, br = broad, car, = variable, ~~ 270 gh st oualphane strech ih str = npls stretch, r= rock Lom 2 the an gang segments of te long cain CH) group, he Raman active CH outpace tec bad is af 2900-2850 cm (2883 coin polyetilene). The gauche segment hae this at 2936-2916 cm in the Ramon. TABLE 63. Selected Group Frequencies: Triple Bonds, Cumulated Double Bonds, Conjugated Aliphatics and Aromatics Group Assignment Frequency(em) IRR Triple CC=C-H CHste 3340-3267 5 w Bonds eB C=Cst. 2140-2100 w Fs CH wag 710-578 shew c-C=C-c CaC ste, 2245-2100 - : CH,-C=N CaNste 2260-2240 mos 1440-1405 2235-2185, 2170-2135) Dugc quét bang CamScanner£63 Selected Group Frequencies: peer ecnng esne Triple Bonds, Cumulated Double Bonds, Conjugated Aliphatics and. pe reac lon devon eI Ee je Intensities signment Honoka) ee Se oe CCC oph. ste 11900 ~owW Double =N=C-0 3 re NCO oph str. 2300-2250 wow aa GN=c=s NCS oph. str 2200-2000 v3 Bu es C=C mono, cis, 1,1 C=C str? 1660-1630. m s Alkane Subst. C=C trans, tr, tetra CC st? 1680-1665 wos (C=CH-R mono, cis, trans CH str. 3020-2995 m m (C=CH, mono, 1,1 CH, oph str 3080-3075, m m J CH, iph. str 3000-2980 m s : CHy bend 1420-1400 w m R-CH=CHy rans CHiph wag 995-965 s w % =CHi wag? 910-905 5 w =CH wag? ‘900-885, s w =CHiph. wag 980-965 s - =CHiph. wag 730-650 mo =I wag 840-750 Aromatics CHste. 3100-3000 quadrant st. 1620-1585 2 quadrant str. 1590-1565 q semicircle st. 1525-1470 var ow a semicircle ste. 1465-1400 m vw | mono, meta, 135 2,46 radial iph ste 1010-990 ww 8 | meta, 124 & 13,5 lone H wag, 935-810, m - para and 1,24 2 adj. H wag 1880-795 s = ‘meta and 1,23 Bad). H wag, 825-750 s = ‘ortho and mono 4 & 5 adj. H wag 800-725 2 e ‘mono, meta, 13.5 ring out-ofsplane bend 710-665 s - para ring in-plane bend. mono ring in-plane bend m= medium, w = weak, 0 = very, br = broad, oar. = variable, Ten doers C=C frequencies 10-50 on™ (eg, N=C-CH=CH 1607 cm") vdsitents ler the ~CH tog frequencies (6, R-OCH=CHy 813 cm) and electron witrvers ise them (eg. {, 960 on”) Dugc quét bang CamScannerVv bonyls incies: Carbony TABLE 6.10 Selected Group Freque! ery co Frequency (m”") is Gop ee Saat \-1720 = C=O str. Dee R-CO-H 1710-1685 s w conj-CO-H c=Ostr pans oa R-CO-R C=O str. a conj-CO-R C=Ostr, 1700-1670 a conj-CO-con} C=O str, 1680-1640 & H-CO-O-R C=O str, 1725-1720 Z i R-CO-O-R C=O str 1750-1735 s ee Conj-CO-O-R C=O0str. 1735-1715 s me y lactones C=O str. 1795-1760 s un R-+CO-OH dimer C=Ooph. str 1720-1680 s os “ C =Oiph. str. 1670-1630 = m R-CO-N C=Oste 1695-1630 s m R-CO-C C=Ostr. 1810-1775 s m R-CO-O-CO-R C =Oiph. str 1825-1815 s m i C=O oph. str. 1755-1745 ms m Cyclic anhydride C=O iph. str. 1870-1845 m s - C=O oph. str. 1800-1775 s mw R-COz CO; oph. str. 1650-1540 s w Op iph. str, w = weak, 0 = very, br = broad, var, 1450-1360. Dugc quét bang CamScanner— 4 £6.11 Selected Group Frequencies: Alcohols and Ethers Go8 soup Assignment Frequency (cm IR ES oH R-OH-O. OH str 3400-3200 a a r O=C-OH dimer OH str 3200-2600) owe = . OH wag 960-875 oe = P-OH™O OH ste ‘2800-2100 sbr ww S-OH-0 OF str. 3100-2200 og ce co CH,-O-CH, COC oph. str 1270-1060, o 3 COC iph. ste 1140-800 zn # c=C-0-CH, COC oph. ste 1225-1200 6 2 ‘Ar-O-Cy Ar-O str 1310-1210 : iy a O-chh ste. 1050-1010. = = cH.-OH COs. 1090-1000 Q aoe 5 CO ste 900-800 mes el ee cre ec TABLE 6.11 Selected Group Frequencies: Alcohols and Ethers—cont'd Group Assignment Frequency (em™’) R.CH-OH CO ste, 1150-1075 m mw 5 CO ste, 900-800 mw s RsC-OH Ost 1210-1100 s mw a C-Ost. 800-750 mw 2 Ar-OH CO ste, 1260-1180 s w 0=C-0-C CO str 1300-1140 s 0=C-OH C-Ostr. 1300-1200 s w ring iph. str, 1270-1245, ring oph. str. 935-880 ring o:ph. str. 880-830 Dugc quét bang CamScannertrogen Compounds TABLE 6.12 Selected Group Frequencies: NiNO8S Tntensines? eae R wD) Grup, ‘Assignment Frequency fem” ” ao, Nib oph st 3500-3300 a F NH iph st 3100-3200 a NH bend 1630-1590 a w cB NH; wag 900-600 on es Cly-NH-Ch, NHste 3450-3250 cat a ct C-N-C oph. str. 1150-1125 a = Ar-NH2 CON str. 1380-1260 ce CoNHE Ni st 3200-2700 G i 5 NEY oph. bend 1625-1560 ew ad ‘ NH; iph. bend 1550-1505 ad is "TABLE 6:12 Sclected Group Frequencies: Nitrogen Compounds—conrd , a nisi Group: Assignment Frequency (em~") R E; NHS x" NHb ste, 3000-2700 aoe a fn NH, bend 1620-1560 mw a (GNH*~X~ ‘NH str, 2700-2300 s a O-C-NH: NH oph. st. 375-2050 : w - NH ph ste 3285-3180 s w . NH bend 1660-1620 Pe « oO =c-NH-C Nite 3320-370 ms w . CNHstr bend 1570-1515 ms 7 O=C-NH-C ale NHste 3200-3100 ms w >can CaNste 1650-1630 mw ms >C=N-OH OF st. 3300-3150 s w - N-Oste 1000-900 s s NO? oph. ste. 1600-1530 : mw NOs iph. ste 1380-1910 : vs NOs oph. st 1555-1485, F - NOs iph. ste 1357-1318 : vs NO; oph str 1640-1600 s mw Opi ph. ste 1235-1220 . s N-Oste 870-840 : . s-trans N =O str. 1681-1640 s s seis N =O str 1625-1600 s s Dugc quét bang CamScanner{15S Grp Reqs Gnome Com vs fei? IR bands (cm~") ‘Raman bands (em~") e. 3100's, 1410s 3100 w, 1410 w es 2170 vs, 1300 m, 1210 m 2170 m, 1300s, 1260 5 \ aa 2060 vs 2060 s ey 2100 m_ 2080 5 Oe 1450 vs, 880 m, 710 w 1065 5. ome 1650 m, 1320 vs 1270 m, 1030s Noe 1390 vs, 830 m, 720 w 1040s Noe 1270 vs, 820 w 1320s oe 1130 vs, 620 m 980s oe 1240 vs, 1040 m, 870 m 1040 s, 870 m Sais 980 vs 980s PO. 1030 vs, 570m 940s (SiOz). 100 vs, 470 m = eS 660 vs, 540 vs = ‘5 = strong, m = medium, w = weak, v = very, ~ = 2210. , — =p daw ding we phi dee o coohoc Dugc quét bang CamScannerCyclohexane Isooctane 00-{ ee 500 2000 1600-1600 1400 1200 ‘foo ‘300600400 ‘Wavenumbers(em™) 7 Dugc quét bang CamScanneri aes sao RR ers My pol fe Cy 2 nid TR 8G Kesh, Women neytin fa Eke CCHS) cis-aHeptene trans-3-Heptene Seu ooo goo 2000 1800 1e00" 7400«1200° ~1000 800 600400 ‘Wavenumbers(em") n-Dibuty| ether “3000-2500 -—<2000—*1800 «+1600 14001200 ‘Wavenumber (cmt) 9 port W Sughl 2 (Cle 0h) 9p: fey kt CC-O,€-H,-- ) Dugc quét bang CamScanner100 ye00 1600 1400 1200 Wavenumber(er™) 2000 3500. 3000 2500 bend Sad) Ar ~e Hi ph wad ig Ser. St. 01,9 ph bend cr) Dugc quét bang CamScannere- a m at B8aa8 Acetonitrile ‘Acrylonitrile 0 2000 1800 1600 1400 1200 1000 600600400 ‘Wavenumber(cr") 11 Dugc quét bang CamScannergp nar & = 169 xl can 9 ahie “ Le Veehn Chive ‘Acetone 120 ae ® = st 7 seins wo eo 2 s 3 axe 2 a 0.08 + < Dugc quét bang CamScannerore Dhan a Palmitic acid PN ee ag 7600 1400 1200 1000 800 600 400 3500 3000 2500 2000 1800 13, Dugc quét bang CamScanneras Dimethyl formamide Dugc quét bang CamScanner050 0.40 Ra 030 1 920 0.10 0.00 {Butyl alcohol 3500 3000 2500 2000 1800 1600 1400 1200 Wevenumber(em-") 4-Hexadecanol 7000 800 600 400 S cuychan BU ph rock cco © axyetaepiting aan Sane chan 2500 2000 1800 1600 1400. ‘Wavenumber(em*) a5) Dugc quét bang CamScanner _Sodium carbonate ‘Sodium bicarbonate 1a 081 1081 72 2500 2000 1800 1600 1400 1200 Wavenumber (em=1) 16 1000 800 600 Dugc quét bang CamScannerpure phan tir: CAHN Yay = SOW? A Y (cont. ae " 240D9 254Uer p-3t) Palm) Cm) Cae H Cn ph sb) = 16 4 ew > 1B (m) 1 ROM, Hy. berclig : ) 3 _ Ayo un! 30 20 3500 3000 2500-2000 +1400 ©1600 1400 ©1200 ©1000 800 600-400 ‘Wavenumber (err) Hop chat 2: Cong thie phan tt’: CHO yy 7 2 100 -| ee Neat/cap film 2000 1800 1600 1400 1200. Wavenumber (cm-1) 7 Dugc quét bang CamScanner eas21phat oy GMO Vi = Hap chat 3: Céng thife phan tt = money a a a ee picd ba his exe 0 06 OF 7 2 phal ocd eae Ain ke RG), R(x) » C06") ty 9 AMD eho (Rey 18 Bod Gq hy os Cth, (CH, 6,2 OD ° a ~ fare Oa ° 7 (Ab ee ano Wd — tee do. et AB) sat tip eobea Dugc quét bang CamScannerDuc quét bang CamScanner