Safety Data Sheet
Hazardous Chemical, Dangerous Goods
1. MATERIAL AND SUPPLY COMPANY IDENTIFICATION
Product name: RocX Mine Mark
Synonyms Product Code
Not Available UGEONVFO,
UGEONVFP,
Recommended use: Marker spray UGEONVFR,
UGEONVO,
Supplier: Dynamics G-Ex Pty Ltd. UGEONVR,
ABN: 53 153 273 431 UGEONVW,
Street Address: 37 Langton Road, GYMPIE UGEONVY
QLD 4570 WA 6105
Australia
Telephone: +61 7 5482 6649
Emergency telephone number: +61 7 5482 6649 (Mon-Fri, 7am-5pm AEST)
2. HAZARDS IDENTIFICATION
This material is hazardous according to health criteria of Safe Work Australia.
Signal Word
Warning
Hazard Classifications
Skin Corrosion/Irritation – Category 2
Serious Eye Damage/Irritation – Category 2A
Carcinogenicity – Category 2
Specific Target Organ Toxicity (Single Exposure) – Category 3 Narcotic Effects
Hazard Statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer .
Prevention Precautionary Statements
P102 Keep out of reach of children.
P103 Read label before use.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust, fume, gas, mist, vapours or spray.
P264 Wash hands, face and all exposed skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P281 Use personal protective equipment as required.
Response Precautionary Statements
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Safety Data Sheet
P101 If medical advice is needed, have product container or label at hand.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTRE or doctor/physician if you feel unwell.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.
Storage Precautionary Statements
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
Disposal Precautionary Statement
P501 Dispose of contents/container in accordance with local, regional, national
and international regulations.
Poison Schedule: Not Applicable
DANGEROUS GOOD CLASSIFICATION
Classified as Dangerous Goods by the criteria of the "Australian Code for the Transport of Dangerous Goods
by Road & Rail" and the "New Zealand NZS5433: Transport of Dangerous Goods on Land".
Dangerous Goods Class: 2.2
Subrisk 1: 6.1
3. COMPOSITION INFORMATION
CHEMICAL ENTITY CAS NO PROPORTION
Methane, dichloro- 75-09-2 30 - 60 %
Ethylene glycol mono butylether 111-76-2 1 - 10 %
Ethane, 1,1,1,2-tetrafluoro- 811-97-2 12 - 15 %
Carbon dioxide 124-38-9 1-3%
Ingredients determined to be Non-Hazardous - Balance
____________
100%
4. FIRST AID MEASURES
If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia 131 126, New Zealand 0800
764 766).
Inhalation: Remove victim from exposure - avoid becoming a casualty. Remove contaminated clothing and
loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until
fully recovered. Seek medical advice if effects persist.
Skin Contact: If skin or hair contact occurs, immediately remove contaminated clothing and flush skin and hair
with running water. Continue flushing with water until advised to stop by the Poisons Information Centre or a
Doctor; or for 15 minutes and transport to Doctor or Hospital.
Eye Contact: If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue flushing
until advised to stop by the Poisons Information Centre or a Doctor; or for at least 15 minutes and transport to
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Safety Data Sheet
Doctor or Hospital.
Ingestion: Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water to drink. Never
give anything by the mouth to an unconscious patient. If vomiting occurs give further water. Seek medical advice.
PPE for First Aiders: Wear safety shoes, overalls, gloves, chemical goggles, respirator. Use with adequate
ventilation. If inhalation risk exists wear organic vapour/particulate respirator meeting the requirements of AS/NZS
1715 and AS/NZS 1716. Available information suggests that gloves made from nitrile rubber should be suitable
for intermittent contact. However, due to variations in glove construction and local conditions, the user should
make a final assessment. Always wash hands before smoking, eating, drinking or using the toilet. Wash
contaminated clothing and other protective equipment before storing or re-using.
Notes to Physician: Treat symptomatically.
5. FIRE FIGHTING MEASURES
Hazchem Code: 2YE
Suitable Extinguishing Media: If material is involved in a fire use water fog (or if unavailable fine water
spray), alcohol resistant foam, standard foam, dry agent (carbon dioxide, dry chemical powder).
Specific Hazards: Non-combustible material.
Firefighting Further Advice: Not applicable.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILLS
Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of gas. If safe to do so,
isolate the leak. Increase ventilation to assist with dispersion.
LARGE SPILLS
Clear area of all unprotected personnel. If safe to do so, isolate the leak. Increase ventilation to assist with
dispersion. If contamination of crops, sewers or waterways has occurred, advise local emergency services.
Dangerous Goods - Initial Emergency Response Guide No: 49
7. HANDLING AND STORAGE
Handling: Avoid eye contact and skin contact. Avoid inhalation of vapour, mist or aerosols.
Storage: Store in a cool, dry, well-ventilated place and out of direct sunlight. Store away from foodstuffs. Store
away from incompatible materials described in Section 10. Store away from sources of heat and/or ignition.
Store locked up. Keep containers closed when not in use - check regularly for leaks.
This material is classified as a Division 2.2 Non Flammable, Non Toxi Gas, Division 6.1 Toxic Substance as per
the criteria of the "Australian Code for the Transport of Dangerous Goods by Road & Rail" and/or the "New
Zealand NZS5433: Transport of Dangerous Goods on Land" and must be stored in accordance with the relevant
regulations.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
National occupational exposure limits:
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TWA STEL NOTICES
ppm mg/m3 ppm mg/m3
1,1,1,2-Tetrafluoroethane 1000 4240 - - -
2-Butoxyethanol 20 96.9 50 242 Sk
Carbon dioxide 5000 9000 30000 54000 -
Methylene chloride 50 174 - - Sk
As published by Safe Work Australia.
TWA - The time-weighted average airborne concentration over an eight-hour working day, for a five-day working
week over an entire working life.
STEL (Short Term Exposure Limit) - the average airborne concentration over a 15 minute period which should
not be exceeded at any time during a normal eight-hour workday.
‘Sk’ Notice – absorption through the skin may be a significant source of exposure. The exposure standard is
invalidated if such contact should occur.
These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These exposure standards should not be used as
fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative
toxicity.
If the directions for use on the product label are followed, exposure of individuals using the product should not
exceed the above standard. The standard was created for workers who are routinely, potentially exposed during
product manufacture.
Biological Limit Values: As per the "National Model Regulations for the Control of Workplace Hazardous
Substances (Safe Work Australia)" the ingredients in this material do not have a Biological Limit Allocated.
Engineering Measures: Ensure ventilation is adequate to maintain air concentrations below Exposure
Standards. Use only in well ventilated areas. Use with local exhaust ventilation or while wearing appropriate
respirator. Vapour heavier than air - prevent concentration in hollows or sumps. Do NOT enter confined spaces
where vapour may have collected.
Personal Protection Equipment: SAFETY SHOES, OVERALLS, GLOVES, CHEMICAL GOGGLES,
RESPIRATOR.
Personal protective equipment (PPE) must be suitable for the nature of the work and any hazard associated with
the work as identified by the risk assessment conducted.
Wear safety shoes, overalls, gloves, chemical goggles, respirator. Use with adequate ventilation. If inhalation risk
exists wear organic vapour/particulate respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716.
Available information suggests that gloves made from nitrile rubber should be suitable for intermittent contact.
However, due to variations in glove construction and local conditions, the user should make a final assessment.
Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other
protective equipment before storing or re-using.
Hygiene Measures: Keep away from food, drink and animal feeding stuffs. When using do not eat, drink or
smoke. Wash hands prior to eating, drinking or smoking. Avoid contact with clothing. Avoid eye contact and skin
contact. Avoid inhalation of vapour, mist or aerosols. Ensure that eyewash stations and safety showers are close
to the workstation location.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form: Aerosol
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Safety Data Sheet
Colour: Various colours
Odour: Characteristic
Solubility: Insoluble in water
Specific Gravity: 1.1
Relative Vapour Density (air=1): >1
Vapour Pressure (20 °C): N Av
Flash Point (°C): N App
Flammability Limits (%): N Av
Autoignition Temperature (°C): N Av
Melting Point/Range (°C): N Av
Boiling Point/Range (°C): 40
pH: N App
Viscosity: N App
Total VOC (g/Litre): N Av
(Typical values only - consult specification sheet)
N Av = Not available, N App = Not applicable
10. STABILITY AND REACTIVITY
Chemical stability: This material is thermally stable when stored and used as directed.
Conditions to avoid: Elevated temperatures and sources of ignition.
Incompatible materials: Oxidising agents.
Hazardous decomposition products: Carbon dioxide and carbon monoxide.
Hazardous reactions: No known hazardous reactions.
11. TOXICOLOGICAL INFORMATION
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the
product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:
Acute Effects
Inhalation: Material may be an irritant to mucous membranes and respiratory tract. Inhalation of vapour can
result in headaches, dizziness and possible nausea. Inhalation of high concentrations can produce central
nervous system depression, which can lead to loss of co-ordination, impaired judgement and if exposure is
prolonged, unconsciousness.
Skin contact: Contact with skin will result in irritation.
Ingestion: Swallowing can result in nausea, vomiting and irritation of the gastrointestinal tract.
Eye contact: An eye irritant.
Acute Toxicity
Inhalation: This material has been classified as non-hazardous. Acute toxicity estimate (based on ingredients):
LC50 > 20,000 ppm
Skin contact: This material has been classified as non-hazardous. Acute toxicity estimate (based on
ingredients): >2,000 mg/Kg bw
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Ingestion: This material has been classified as non-hazardous. Acute toxicity estimate (based on ingredients):
>2,000 mg/Kg bw
Corrosion/Irritancy: Eye: this material has been classified as a Category 2A Hazard (reversible effects to eyes).
Skin: this material has been classified as a Category 2 Hazard (reversible effects to skin).
Sensitisation: Inhalation: this material has been classified as not a respiratory sensitiser. Skin: this material has
been classified as not a skin sensitiser.
Aspiration hazard: This material has been classified as non-hazardous.
Specific target organ toxicity (single exposure): This material has been classified as a Category 3 Hazard.
Exposure via inhalation may result in depression of the central nervous system.
Chronic Toxicity
Mutagenicity: This material has been classified as non-hazardous.
Carcinogenicity: This material has been classified as a Category 2 Hazard.
Reproductive toxicity (including via lactation): This material has been classified as non-hazardous.
Specific target organ toxicity (repeat exposure): This material has been classified as non-hazardous.
12. ECOLOGICAL INFORMATION
Avoid contaminating waterways.
Acute aquatic hazard: This material has been classified as non-hazardous. Acute toxicity estimate (based on
ingredients): >100 mg/L
Long-term aquatic hazard: This material has been classified as a Category Chronic 3 Hazard. Non-rapidly or
rapidly degradable substance for which there are adequate chronic toxicity data available OR in the absence of
chronic toxicity data, Acute toxicity estimate (based on ingredients): 10 - 100 mg/L, where the substance is not
rapidly degradable and/or BCF ≥ 500 and/or log Kow ≥ 4.
Ecotoxicity: No information available.
Persistence and degradability: No information available.
Bioaccumulative potential: No information available.
Mobility: No information available.
13. DISPOSAL CONSIDERATIONS
Persons conducting disposal, recycling or reclamation activities should ensure that appropriate personal
protection equipment is used, see "Section 8. Exposure Controls and Personal Protection" of this SDS.
If possible material and its container should be recycled. If material or container cannot be recycled, dispose in
accordance with local, regional, national and international Regulations.
14. TRANSPORT INFORMATION
ROAD AND RAIL TRANSPORT
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Classified as Dangerous Goods by the criteria of the “Australian Code for the Transport of Dangerous Goods by
Road & Rail" and the "New Zealand NZS5433: Transport of Dangerous Goods on Land".
UN No: 1950
Dangerous Goods Class: 2.2
Subrisk 1: 6.1
Packing Group: None
Hazchem Code: 2YE
Emergency Response Guide No: 49
Proper Shipping Name: AEROSOLS
Segregation Dangerous Goods: Not to be loaded with explosives (Class 1), spontaneously combustible
substances (Class 4.2), or organic peroxides (Class 5.2). Exemptions may apply.
MARINE TRANSPORT
Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code)
for transport by sea.
UN No: 1950
Dangerous Goods Class: 2.2
Subrisk 1: 6.1
Packing Group: None
Proper Shipping Name: AEROSOLS
AIR TRANSPORT
Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA)
Dangerous Goods Regulations for transport by air.
UN No: 1950
Dangerous Goods Class: 2.2
Subrisk 1: 6.1
Packing Group: None
Proper Shipping Name: AEROSOLS, NON-FLAMMABLE, CONTAINING
SUBSTANCES IN DIVISION 6.1, PACKING GROUP III
15. REGULATORY INFORMATION
This material is not subject to the following international agreements:
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Montreal Protocol (Ozone depleting substances)
The Stockholm Convention (Persistent Organic Pollutants)
The Rotterdam Convention (Prior Informed Consent)
International Convention for the Prevention of Pollution from Ships (MARPOL)
This material is subject to the following international agreements:
Basel Convention (Hazardous Waste)
• Wastes from production, formulation and use of inks, dyes, pigments, paints, lacquers, varnish
• Halogenated organic solvents
This material/constituent(s) is covered by the following requirements:
• All components of this product are listed on or exempt from the Australian Inventory of Industrial
Chemicals (AIIC).
16. OTHER INFORMATION
Reason for issue: Revised
This Safety Data Sheet has been prepared by Chemical Data Services Pty Ltd on behalf of its client.
Safety Data Sheets are updated frequently. Please ensure that you have a current copy.
This information was prepared in good faith from the best information available at the time of issue. It is based
on the present level of research and to this extent we believe it is accurate. However, no guarantee of accuracy
is made or implied and since conditions of use are beyond our control, all information relevant to usage is
offered without warranty. The manufacturer will not be held responsible for any unauthorised use of this
information or for any modified or altered versions.
If clarification or further information is needed to ensure that an appropriate assessment can be made, the user
should contact this company.
Our responsibility for product as sold is subject to our standard terms and conditions, a copy of which is sent to
our customers and is also available upon request.
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