Dr.
Catherine Tan
Polymers
(IGCSE Chemistry Syllabus 2016-2018)
Macromolecules
o Small molecules (monomers) join together to form a long, large molecules
o Different macromolecules have different linkage
o Condensation polymerization: small molecules join together by losing small molecule
(e.g. water) as byproduct
Condensation polymer – Natural Polymer
Monomer Functional Linkage Natural Structure
group(s) Macromolecule
involved
Glucose -OH Glycosidic Starch
Amino -NH2 and Amide Protein
acids -COOH
Fatty -OH and Ester Fats/Lipids
acids and -COOH
glycerol
1
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Dr. Catherine Tan
Condensation polymer – Synthetic Polymer
Monomer Functional Linkage Synthetic Structure
group(s) Macromolecule
involved
1,6- -NH2 and Amide Nylon
diaminohexane -COCl -CONH
&
Hexan-1,6-
dioyl chloride
#uses: ropes,
fishing nets
Benzene-1,4, -COOH Ester Terylene
dicarboxylic and -OH -COO
acid
& ethane-1,2-
diol
#uses: clothing,
thread
2
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Dr. Catherine Tan
o Addition polymerization: small molecules which consist of C=C double bond join
together without losing any molecule
Addition polymer
Monomer Polymer Structure Uses
Ethene Polyethene Plastic bags,
gloves, bowls
Chloroethene Polychloroethene Water pipes,
(PVC) hoses
Propene Polypropene Crates, ropes
Tetrafluoroethene Polytetrafluoroethene Non-stick
(Teflon) frying pans,
windscreen
wiper
3
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Dr. Catherine Tan
o Pollution from plastics
- Choke birds
- Kill aquatic animals
- Cause flooding
- Visual pollution
4
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