Army Public School & College (Boys) Ordnance Road
Rawalpindi
CHEMISTRY HSSC-I
PRACTICAL EXAMINATION
Note: Attempt all questions and answer the questions within the provided spaces.
Question no 1:
Purpose of this experiment is to find the value of X in 6.93 g of given FeSO4.xH2O solution per dm3.
Apparatus used:
Burette, pipette, funnel, conical flask, beakers, iron stand.
Chemical used:
0.1 M KMnO4, H2SO4,
Distilled water, solution of 6.93g of FeSO4.xH2O in 1 dm3
10cm3 FeSO4.xH2O required volume for V2 of KMnO4 in cm3
See on the figure given below and record the observations in table.
i. Observation Table: [02]
Exp No. Initial Reading Final Reading Volume of KMnO4 used
1
2
3
Mean volume of KMnO4 used = ______ cm3
ii. How will you identify the end point of the reaction? [01]
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iii. Why indicator is not used in this experiment? [01]
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iv. Chemical Equations: [01]
2KMnO4 + 3H2SO4 K2SO4 + 2MnO4 + 3H2O + 5[O]
2FeSO4 + H2SO4 + [O] Fe2(SO4)3 + H2O
Write Overall Reaction:
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v. Calculations: [01]
Find n1 of FeSO4.xH2O and n2 of KMnO4 from chemical equation
n1= ………………. n2=………………..
You are advised to show full working in all parts of calculations.
Calculate the molarity of FeSO4.xH2O by using formula: [01]
M 1V 1 M 2V 2
=
n1 n2
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a. Calculate mass of FeSO4.xH2O per dm3 after titration [01]
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b. Calculate the value of x by using formula [01]
Amount in g/dm3 dissolved = Molarity x Mol. wt. of FeSO4.xH2O
(Fe=56, S=32, O=16, H=1)
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Result:
The value of X= ________________
Question 2: Encircle the correct option. [06]
1. Ratio of distance travelled by solut and distance travelled by solvent front is:
a. Theoretical yield
b. Retardation factor
c. Limiting factor
d. Polarity
2. The product of molar concentration of ions in equilibrium with solid salt is:
a. Equilibrium constant
b. Solubility constant
c. Common ion
d. Solubility product
3. Lead and Cadmium are colorless liquids. They can be separated by process:
a. Thin Layer chromatography
b. Paper chromatography
c. Titration
d. Reacting with carbon dioxide
4. In the Ink Chromatography which of the solvent is used:
a. Water
b. Ethanol
c. Hexane and water
d. Chloroform and methanol
5. In the titration of NaOH and sulphuric acid which of the following in the heat of
neutralization.
a. -57.3KJ
b. -114.6KJ
c. +57.3KJ
d. +114.6KJ
6. Heat of Neutralization of hydrochloric acid and sodium hydroxide is measured by:
a. Titration
b. Calorimetry
c. Hydrogenation
d. Reacting with water
Army Public School & College (Boys) Ordnance Road
Rawalpindi
CHEMISTRY HSSC-I
PRACTICAL EXAMINATION
Note: Attempt all questions and answer the questions within the provided spaces.
Question no 1:
Purpose of this experiment is to standardize the KMnO4 solution with standard solution of
Na2C2O4.
Apparatus used:
Burette, pipette, funnel, conical flask, beakers, iron stand.
Chemical used:
0.05 M Na2C2O4, 1M H2SO4,
Distilled water, solution of KMnO4 heat
10cm3 Na2C2O4 required volume for V2 of KMnO4 in cm3
See on the figure given below and record the observations in table.
i. Observation Table: [02]
Exp No. Initial Reading Final Reading Volume of KMnO4 used
1
2
3
Mean volume of KMnO4 used =_________ cm3
ii. How will you identify the end point of the reaction? [01]
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iii. Why is meant by the term self indicator? [01]
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iv. Chemical Equations: [02]
2KMnO4 + 3H2SO4 K2SO4 + MnSO4 + H2O + 5[O]
[O] + Na2C2O4 + H2SO4 Na2SO4 + 2CO2 + H2O
Write Overall Reaction:
_____________________________________________________________________________
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v. Calculations: [01]
Find n1 of Na2C2O4 and n2 of KMnO4 from chemical equation
n1= ………………. n2=………………..
You are advised to show full working in all parts of calculations. [02]
Calculate the molarity of KMnO4 by using formula:
M 1V 1 M 2V 2
=
n1 n2
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Result:
Molarity = _____________________
Question 2: Encircle the correct option. [06]
1. Rf value is:
a. Rhesus factor
b. Retardation factor
c. Relative formula
d. Reference factor
2. KCl can be purified by adding which of the following to KCl solution?
a. NaBr
b. KBr
c. HBr
d. HCl
3. Lead and Cadmium are colorless liquids. Their spots can be identified by applying:
a. Hydrogen peroxide
b. Hydrogen sulphide
c. Hydrogen chloride
d. Carbon dioxide
4. In the Ink Chromatography which of the solvent is used:
a. Water
b. Ethanol
c. Hexane and water
d. Chloroform and methanol
5. In the titration of KMnO4 and Oxalic acid which of the following indicator is used?
a. Bromothymol blue
b. Phenolphthalein
c. Methyl Orange
d. KMnO4
6. The process used to standardize given solution is:
a. Titration
b. Calorimetry
c. Hydrogenation
d. Sulphonation
Army Public School & College (Boys) Ordnance Road
Rawalpindi
CHEMISTRY HSSC-I
PRACTICAL BASED ASSESSMENT (Work Sheet)
Note: Attempt all questions and answer the questions within the provided spaces.
Question no 1:
The given solution contains 6gms of Na2CO3 dissolved per dm3 . Determine the
Percentage Purity of the Sample Solution by Volumetric Method.
Apparatus used:
Burette, pipette, tripod stand, corks, funnel, iron stand etc.
Chemical used:
Methyl orange, Na2CO3, 0.1M HCl,
Distilled water, solution of 6g of Na2CO3 in 1dm3
10cm3 Na2CO3 required volume V2 of HCl in cm3
Standard solution:
0.1M HCl
Indicator:
Methyl orange
End point:
Appearance of light pink colour
i. Read the following statements about readings calculated in burette in three times
repeated experiment and fill the given table, also calculate mean volume of HCl and write in
given space.
In experiment no.1 volume used was from 40cm3 to 30cm3
In experiment no.2 volume used was from 30cm3 to 25m3
In experiment no.3 volume used was from 25cm3 to 15cm3 [02]
Exp.no Initial readings(cm3) Final readings(cm3) Average volume(cm3)
1.
2.
3.
Mean volume of HCl used= _________ cm3
ii. Why we use indicator? [01]
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iii. Balance the given equation. [01]
Na2CO3 + HCl NaCl + water + CO2
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iv. Write the following from above equation. [01]
n1 = _______________ n2 = _________________
v. Calculate the molarity of Na2CO3 by using formula: [02]
M 1V 1 M 2V 2
=
n1 n2
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vi. Calculate mass of sodium carbonate per dm3. [01]
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vii. Calculate percentage purity of sodium carbonate after calculating mass. [01]
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Question 2: Encircle the correct option. [06]
1. Components of ink can be separated by the process:
a. Titration
b. Stoichiometry
c. Chromatography
d. Hydration
2. To purify MgCl2 which of the following will be added to the solution of MgCl 2 ?
a. Magnesium carbonate
b. Hydrogen chloride
c. Hydrogen oxide
d. Magnesium metal
3. Lead and Cadmium are colorless liquids. They can be separated by process of paper
chromatography, which of the following can be used to identify the spots?
a. Chlorine gas
b. Nitrous oxide
c. Hydride of oxygen
d. Hydride of sulphur
4. Which of the following apparatus is not used in titration?
a. Funnel
b. Burette
c. Test tube
d. Flask
5. In the titration of KMnO4 and Mohr’s salt which of the following indicator is used?
a. Bromothymol blue
b. Phenolphthalein
c. Methyl Orange
d. KMnO4
6. The molarity of unknown substances can be calculated by the process of:
a. Titration
b. Calorimetry
c. Hydrogenation
d. Chlorination
Army Public School & College (Boys) Ordnance Road
Rawalpindi
CHEMISTRY HSSC-I
PRACTICAL BASED ASSESSMENT (Work Sheet)
Note: Attempt all questions and answer the questions within the provided spaces.
Question no 1:
Determine the Value of X by Volumetric Method of (COOH)2. XH2O, if 6.3g of it dissolved in
1dm3
Apparatus used:
Burette, pipette, tripod stand, corks, funnel, iron stand etc.
Chemical used:
Oxalic acid, Potassium permanganate [2.5]
Name the apparatus can be used in this experiment in the given observation
table.
i. Observation Table:
Sr. # Apparatus name
1
2
3
ii. Instruction
You are advised to write the procedure of titration. [2.5]
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iii. Write balance chemical equation between Potassium permanganate and oxalic acid. [01]
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Q#2: Complete for the value of x.
𝟏𝟎𝟎 × 𝐰𝐭 𝐨𝐟 𝐇𝟐𝐎/ x = 𝐇𝟐𝐎%
a. Write name of some indicators use in titration. [01]
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b. Give the possible placement of acid and base in titration. [01]
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c. Which is the value of x in this process; also write the value of x in sodium carbonate? [01]
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Q no 2 Encircle the correct Answer from the following [06]
1. Which of the following is used as an indicator in the titration of a strong acid and a
weak base?
a. Phenolphthalein
b. Thymol blue
c. Fluorescein
d. Methyl orange
2. A difference between strong and weak acid is
a. presence and absence of halogen ions
b. negative and positive pH
c. complete and partial ionization
d. proton donation and electron acceptance
3. Which of the following is a buffer solution?
a. H2SO4 + CuSO4
b. CH3COOH + CH3COONH4
c. NaCl + NaOH
d. CH3COONa + CH3COOH
4. In an acid-base titration, which of the following indicators is commonly used to
detect the endpoint when titrating a strong acid with a strong base?
a. Phenolphthalein
b. Bromothymol blue
c. Methyl orange
d. Litmus paper
5. Which solution would you place in a burette
a. Standard solution
b. Unknown concentration solution
c. Indicator
d. none of the above
6. Rock salt can be purified by common ionic effects which of the following will give
precipitates
a. Rock salt solution +HNO3
b. Rock Salt Solution +HCl
c. Rock Salt Solution +H2SO4
d. Rock salt Solution +KCl
