Science Paper 4
Science Paper 4
3 ,;ner's
Som e tests are mad
9
Tab le 3 .1 show s th ~
on solid P and solution a.
st
e e s, observations and conclusions .
For
Com plete Tabl e 3.1. ·~miner
''l(J
Table 3.1
tests
observations conclusions
(a) Solu tion Q is divid ed
into two porti ons.
A blue litmu s pape r is .... .. ... .... .. .. ··· ···· ··· ..... . ··
··· ·
dipp ed into one portion of blue litmus paper turns red
solu tion Q .
.. .. .... ..... ... ...... ... ....... ... [ 1]
(i) .... · ...... .. ·.... · ...... · .. ·.. .. .. .... ...... ...... ...... ..... .[1] Zn 2+ or Ca 2+ are suspected .
... ······ .... . . .. . . . . . . ... . . . . . [1]
solut ion Q .... .... ....... .. ..... .. .. ...... .. ...... ... .... ........
.... .. ... .. ...... ... .. ... ..... ............ .. ................ ......... (21
© BEC 2017
0569/04/O/N/17
[Turn over
For
Examiner's
11 use
titration 1 titration 2
3
reading after titration I cm
3
reading before titration / cm
3
volume added I cm [3]
3
concentration = .. .... .... .. ... ..... .... ............... . mol I dm [1]
········· ············ ··· ···· ··· ······· ···· ··· ··· ····· ·· ·· ·· ········ ·················· ···· ········ ···· ········· ··· ········· ·· ········· ··· ··· ··· ·· ·
··· ····· ·· ········· ········ ······· ····· ······ ···· ······ ··· ············· ···· ··· ·· ··· ·· ··· ··· ······ ······· ······ ·· ··· ········ ······· ···· ······· ··· ·
··········· ·· ····· ··········· ·· ······· ····· ·· ··· ··· ·· ·········· ···· ·· ·· ········ ····· ····· ·· ··· ···· ···· ··· ·· ·········· ············· ······ ···· ··· ··
······· ··· ············ ···· ·· ··········· ········ ···· ···· ········ ···· ·············· ·· ····· ········ ····· ······· ······ ···· ·· ···· ··· ···· ····· .. ···· ···
······· ·········· ·········· ··········· ······ ········ ··· ···· ········ ···· ····· ····· ··· ··· ········· ··· ··· ······ ·· ·················· ···· ··· ······· ···
··· ······· ··· ···· ··· ······· ····· ····· ·········· ·· ··· ·· ··· ······ ··· ··· ·· ······· ····· ····· ····· ············ ······· ········ ······· ······· ········· ··
················ ···· ·· ····· ··············· ··· ····· ···· . ····· ···· ·· ···· ······· ··· ·························· ···· ················· ·· ·· ··· ··········
··· ·· ················· ·· ·· ········· ············ ··· ·········· ·················· ······· ·················· ·· ··· ·· ·· ····· ···· ···· ···· ········ ····
······· ···· ····· ····· ·... , .., .. .. ....··· ······· ···· ····· ·· ··· ··· ·········· ····· ···· ··· ··· ······· ... .,... ... .. ....... .. ... .. .. ...... ... .. ' '' ' .[4]
© BEC 2017
0569/04/O/N/17
[Turn over
Cl
IC.-6-
( U) L l;.m~ ih<• t w o h,(~51 resulf5 ~coh'l'e """' ., A?taf»O vofumo o f tho •ad u$CG , h o titr 11(11,
"" )-1 rr y1 G
y
1
(h ) Th 1 :ww 1~ ~ ~~ fYfff)ar'X ! ~ ( il l U'k!O ID ttt·t e BQlut:on
• qt, 1t,qr
8.ffl
21
'' )
q
8
25 cm ) of potas, 1um
_______ _ _,._
_,,/
_ _ carbonate soluhorri ..
methyl ornngo
Ftg. 4.1,
1
25
2 2
26
3 3
(i) Use th e burette diagrams to complete Table 4.1.
Table 4.1
titration 1 2 3
volume used/ cm 3
{ii) Using the two best results , calculate the average volume of the acid used for the titration .
{c) This average volume of the acid was mixed with 25 cm 3 of potassium carbonate solution to
obtain potassium chloride solution .
Describe how you would obtain crystals of potassium chloride from the solution .
···· ········· ···· ·· ···· ··· ····· ·· ····· ·· ·· ····· ·· ·· ······· ·· ·· ············ ······· ····· ·· ······ ··· ······· ················· ·· ··· ··· ·· ·· ·· ··············
·· ········· ····· ······················· ····· ········· ······ ·· ·· ······ ···· ·· ···· ········ ·· ·· ··· ····· ·· ····· ··· ··· ····· ·· ······· ······ ·· ··· ······· ·····
···· ······· ··· ··· ········ ···· ·········· ·············· ······· ·· ·· ······ ···· ······· ·· ··· ······· ·· ······ ··· ······ ·· ···· ·· ···· ······· ········ ··· ·· ···· ···
·· ······· ···· ··· ·· ·············· ······ ·· ······ ··· ···· ···· ······· ····· ·· ···· ··· ···· ·· ·· ······•· ···· ··········· ··· ···· ·· ·· ······ ········· ···· ··· ··· ··· ·
.. .... ... .. ... .. .. ....... ... .. ...... ........ ..... ..... ............... ........... .. .... ..... ........... ..... ... .. .... ... ......... ... .. ......... [3]
- \
I
5 (8 ) F 7 Examiner's
Use
how the components of a mixture of sugars war 8 identified.
.tg. 5.1 shows
I I
'
' •
'
•- . . ----•
• • •
mixture sugar sugar sugar sugar
•
.
a
Q P R S
Fig. 5.1
t and label the
(i) On Fig. 5.1, draw an arrow to show the direction of the flow of solven
[2]
startin g line.
{ii) Name the method being used to identify the sugars.
........ .... .. (11
.. .. .... .................... .......................................... ....... .. ............ .. .. ..................
{Iii) Which sugar was not contained in the mixture?
[1]
········································ ·························
(iv) One of the sugars in the mixture was not identified.
What conclusion can be drawn from this statement?
............ [1]
.... .......................................................................... .. ............. .. ....................
Question 5 continues on page 8 overleaf
:!b~liOW6'~; i,:i; [Turri .QV~J
J
.
~
:,
-
-
--
:;
= z
• -
.!
i
ti#
~ :: • i
;:
-.
'8
•
:;,
3
•~ - --
~
!
~ 1 .:
?
0
a
~ -
ta
~
:a i -
2
::
i
c ~
• ;,
ii
i
., I
.I~ For
~ 9 Examiner's
6 Use
Excess
cation. aqueous ammonia was added to four separate solutions, each co ntaining a different
/
, . The cations present were:
iron(III) (Fe3+) copper(II) (Cu 2+)
iron(Il) (Fe2+) calcium (Ca 2+)
Which cation:
(a) formed a permanent dirty green precipitate?
.............................................................................................. ...... ..... ......... ......... .. ... .. .. .. (1)
(b) did not form a precipitate?
........................................................................................ ................................. ..... .. ... .. .(1)
(c) formed a permanent brown precipitate?
................. (1]
······················································································· ···················
i .- ,,
i"? .
\ ,
For
Examine(s
4 Tests 7 Use
were carried
conclusion s made. Cout on a substance, S. Table 4.1 shows the tests, observations and
omplete the table.
~ r----
Table 4.1
I---_
test observation conclusion
(a) S was dissolved in dilute S is a compound
sulphuric acid. of a transition
·················· ······························· metal.
... .................................... ..... (1)
A gas was produced and S contains CO32-
passed through limewater. ················································· ions.
........................... ............... .. (1)
The resulting solution was
divided into two portions
for tests (b) and (c).
(b) (i) To the first portion S probably
contains Cu 2 + ions
aqueous sodium ·················································
hydroxide solution
was added until a ·················································
change was seen.
.. .......................................... (2)
(ii) An excess of sodium
hydroxide was added ··············································· ··
to the mixture from
(b)(i) . . ............................................ (1]
The presence
(c) To the second portion,
Cu 2+ ions is
a few drops of aqueous ················································· of
confirmed.
ammonia were added
until no further change ·················································
was observed.
·················································
.................................... ... ..........
·············································· ···
.... .. ........... ... ............. ... ....... . (3)
(d) What is the name and the formula of S?
name .......................................... ............. .......................... .............................. ...... ..... ..... .
formula ......... ...... ................ .. ................... ....................... ........ .................. ....... .......... .. [2]
@BEC20 11
0569/04/O/N/11 [Turn over
. 8
For
5 Zinc n·tI rate crystals .
are made by following the steps given below. 'rnlner's
"
step 1 Pour 30 cm 3 of dilute nitric . ·into a bea ker.
. . acid
step 2 Add a small amount of zinc oxide.
step 3 Warm and stir the mixture.
step4 Add more zinc oxide until all the acid is used up.
step 5 Remove excess zinc oxide .
step 6 Obtain zinc nitrate crystals from the solution.
(a) (i) Name the apparatus used to measure the acid .
............................................................................ .......................................... ....... [1]
(ii) Name the apparatus used to transfer the small amount of zinc oxide in step 2.
................................................................. .... ......................... .. ............................. [1]
(iii) Why is the mixture warmed in step 3?
........................................... ........................................... ....................................... [1]
(b) How could you show that all of the acid is used up in step 4?
I I 1 1 1 • 1 1 1 I I I I I Io o I I• I I I I 1 1 o I o 1 1 o o o 1 1 1 1 1 1 1 1 •II I I I I I I I •
• • • e • • • • • e I I• I• I I I I I I I I I 11111111 1 o I I I I I I I I I I I IO I I I I I I I I I I I I•• I I I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1
·········· ........................................................................................_.. ............................. ~ ... [2]
(c) Name the method that can be used in step 5.
......................................................... ........ .......... ............... .............................. .. ........... [1]
(d) Describe how zinc nitrate crystals are obtained in step 6 .
······································································ ···················· ···· ··································
........ . ......................... ············································· ···························································
············································· ························································································ ·····
···········--······· .. ···············--····--··· .................................................................................... . [3]
(e) Zinc metal is used instead of zinc oxide. Zinc metal is more reactive than zinc oxide.
Suggest one way how the rate of reaction could be slowed down.
······· .............................................................................................................................. [1]
© SEC 2011 0569/04/O/N/11
7 V
7 Ewmfnor '.•,
U BIJ
(e) Given that R = / · find the resistance of wire Q.
R= [1 J
(f) Wire P and Q are made from the same material.
Will the value of R for wire P be less than, greater than or equal to that of Q.
Explain your answer.
·················································
·····································
··········································· [2]
(g) Name one other variable that must be kept the same for both wires to make a
valid conclusion about the effect of thickness.
.......... ············............. .. [1 J
3 Fig. 3.1 shows some apparatus used in the laboratory.
(
250 :j
ml =!
2s:{
@
=l
ml~ r 500
E ml
)[ ~ r
/f\
LEI
i._
.·______ ,._t~ ___ ---J
)
=1 j
~
j
..J
..J ! .
{~
:l ~
s T u V w
R
Fig. 3.1
(a) Which piece(s) of apparatus
(I)
are beakers, ................ .
3
is capable of measuring accurately 250 cm of water, ................... ..····························
(ii)
3
(iii) is safe for use in boiling 250 cm of water? ............................................................. [3]
(b) Give two precautions taken to obtain an accurate reading when using apparatus R.
1 ·····························································································"···"··············"········"'············ ..
·············································································································································
2 ........................................... ................................................................................................ ..
·········· ··•·"··············"·····"····· .. ··• .......................................... ........... ... ... ................. ........... [2]
0569/04/O/N/12 [Turn over
@ BEG 2012 ~-~~~
~
8
.
een magn esium
4 F'19. 4.1
and exces t e apparatus used to investigate the rate of reaction betw
s d'Is th
show
1u e hydrochloric acid at 30 °c.
· ';'l'}
· ~~ §!!.t;\,,.!l;, dilute hydrochloric acid
magnes1um , ::;;·,~+"
1 ,1/ , .. , , ; . ,,.... - , ,, . .
Fig. 4.1
recorded in Table 4.1.
The volume of hydrogen gas produced was measured and
Table 4.1
3
time / s volume of hydr ogen / cm
0 0
20 19
40 32
60 33
80 43
100 46
120 46
140 46
~
( Of
Examfn111
U !iO
9
II ,
.I
so ~11ttmlllittttttmlf 11111111 I H -~ -
·•-•=i:t:
r·
40
t-ttl7mtttjrtt-Hfflfl·lli-Ufflfflftfffflffl~ttfffifftm+mfffl
30 •~~~m --1 --1 1111-
-HM
- +-_j!-,;-_j_....
.1
':+.-
+-. . ·-- . . L ,_it _ --· ·- - -·- ··· -
1_...1._..LJ
__ I T j j T •
volumeof : :. j{···-1··· ---l+ · ····-•t =.:: .L ~~............. 1--,.
, ·:· -+
1' ' .... ..
hydrogen/c
m3 i -:1, ii
,, - , T,
J. - -
- · - ·-
.
--~_,____,_,_1t·- ~· '-- -'-- ··-
-- '- -
- -i....i-.-++ ......... · , - --+
T
W-
l 1 .l l I I I
I
I
I
I I
II I I I I
I
I
- · I
I l
"T
l
................
onLLLJmmmtr nnnm rmm •111111 I111-11 -
1111 Ir1~hlm
-- -------- -- Jr
;!-ti i 1 1-11I11111 ILI ITT1111lt
-1--
I I
$! I I I I l I I I L ...L ....LL....l......L...L.-J
-t
1 11 1 1 11
r·i -· TTTT - · -
H-l I I I I I 11 H+H+I 11111111
- - - - -
itt
lli±tE
1
;;:
' I
~ ~ : - : : ! : ~-, 1 , , .
i
1 , , • 1 1
"T
t • i
,
alml 111 i 1111 !ff.,.
II : I II I I I I II I I II I I t I I I I I , m
..
1 , , ,
11I
,
I
• 1 ,
I I. I I
I I 1TT 1 I LLU
, :· : · i : : : : I
!. .! '1Jr j1 1 1
•~- ,; I .J_,__
tliW..tl±tn" , _ -1t- ____ _+_. . "[
' i I
I" I I l "_
"" .
,
11-1-~J--'
T
-
.. ' _ ,
• '
10," I
, , "' u, I
. . .. . .... I tttri=-H-
'
~
..L ..
I
r.rrdJ
!
~
- O • L L
I I
! I LlJ..L I l I
2vn 40
Af'I ~(\
60 80 100 120
time Is
(a) Plot the graph of the results on the grid. [2]
(b) Use your graph to determine
(i) the time taken to produce 30 cm 3 of hydrogen gas,
.................................................................................................................. .... .... [1]
(ii) the anomalous reading which should be checked .
[1]
(c) on the same axis, sketch a graph you would get if the same experiment was carried
out at 20 ° C. Label this graph X. [2]
©BEC 2012
~
0569/04/O/N/12
[Turn over
- - - --
r's
10
5 Tes ts were carried out on a solution of salt
R. t the table.
Tab le 5.1 shows tests, observations and I sions drawn. comple e
cone u
Table 5.1 -
conclusions
observations -
tests
(a) (i) a little aqueous ···················································· cu2 .. ions pres ent
ammonia was
added to a ............................................... [2]
portion of
solution R
(ii) excess aqueous ···················································· Cu 2 .. ions pres
ammonia was ent
added ............................................... [21
sulp hate ions
(b) ······································ ···················································· pres
ent
................................. [21 ....... ..................... ................... [1]
(c) State the name and formula of salt R.
name ............................................................
..................................................................
.......
formula ........... ,..........................................
............................................................... . ..... [2]
© BEC 2012 0569/04/O/N/ 12
/'Of
Examiner's
7 US9
3 A sam ple of water
was divided . t was collected and analysed to find the ions it contained. The sample
p rt' s some tests, observations and conclusions
mad e on th in o four O ions. Table 3.1 show
e sample of water.
. the missing test methods, observations and conclusions.
. . g in
Com plete Table 3· 1 bY writin
Table 3.1 '
observation conclusion
test
(a)(i) To the first portion
of the sample, dilute
hydrochloric acid
was added.
........ ....... ....... ....... . [1]
(ii) The gas given off carbonate ions, co/ · ,
was tested with are present
limewater.
.............................. [1]
(b) To a second portion, white precipitate formed
dilute nitric acid and
...... ...... ...... ...... ... [1]
silver nitrate solution
were added.
brown precipitate formed
(c) ······ · ···· ······ ····· ·······
...... ...... ...... ...... [1] ········ ························
precipitate does not ······· ······· ···--· ··--·· · [1)
····························· dissolve
...... ...... ...... ...... [1]
(d) To the fourth portion,
2-
. ...... . ................................. . .... ..... sulphate ions, S04 ,
···················· ·········
not present
····························· ·····························
....... ....... ....... ... [1)
·····························
······ ·· ....... ....... .. [2)
le of water.
(e) Suggest one of the compounds present in the samp
".. ..... ......... ........... ....... (1]
..···· ·.... .... .... ................. ... .............. .. .. .. ... ..... ......
©BEC 2014
~ 0569/04/O/N/14 [Turn over
8 \
4 Fig.
a 4.1 shows
reaction betwaset-up used to collect and measure the volume of gas produced during
een excess dilute hydrochloric acid and calcium.
calcium I r::-.
~ - - - dilute hydrochloric acid
D
Fig. 4.1
Fig. 4.2 shows the gas syringe readings recorded at 1 minute intervals for 5 minutes.
II 'I' II 'I II II30
20 I" II ' 1,-·.<24J:·:::::
, .. · HIME I" II 111 f·~:' "'':."•.•~
II I
40 •.:::.•z
''. ·''I· ·I '. ~ .•··~ . . .,;}
•. '
r.:
1 minute 2 minutes
•• ·1· ••• ,••• ·1· ••• ,.,, 'I" ••
30 40 50
~
.- 0
l ~r,, 111. ~FC~·
3 minutes 4 minutes
··~~·••1••·r==·:~
5 minutes
Fig.4.2
(a) (i) Record the gas syringe readings in Table 4.1.
Table 4.1
time I minutes volume of gas/ cm 3
0 0
1
2
3
4
5
[3]
,A A.f:C. 2014 0569/04/O/N/14
9 For
(ii) Examiner's
Explain Why the readings after 4 minutes and 5 minutes are the same. Use
·· ······ ········· ············· ····· ··· ·· ·· ···· ·· ······· ····· ·· ····· ·· ·· ····· ···· ········ ···· ····· ·· ·· ··· ·
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . .. . .. . .. .. . .. . . . . . .. . . . .. . .. .. . .. . .. . . . . . . .. . . . . . . . . .. . . .. ... . . .. . . [1]
(b) The student was asked to repeat the experiment using the same mass of calcium and
excess dilute hydrochloric acid of the same concentration .
Fig. 4.3 shows the flasks containing the calcium used in both experiments.
experiment 1 repeat experiment
Fig.4.3
(i) Predict the final volume of the gas collected in the repeat experiment.
··········· ·· ····· ········ ···· ···... .. ...... ...... ....... ... ... .. .... .. ..... .. ........ .. ...... ....... ... [1]
(ii) Compare the rate of reaction for the second experiment with that of the first
experiment. Explain your answer.
comparison ..... . : ... ... .... .... .... ... •...... .... .... .. ... ... .... .. ... .. .. ... .... .. .... ... .. ... .. .... .
·· ·· ···························· ·· ················ ·· ··· ···· ··· ····· ···· ········ ··· ··························
explanation · ·· · ·· ·· ··· · ······ ··· ··· · · ···· ···· · ···· · ····· ····. ·· ....... ..... ... .. ...... :: ::::.-.·.·. .-.-.-;~;
··························· ····················· ·········· ·· ·······························
@BEC 2014
ti 0569/04/O/N/14 (Turn over
For
9 Examiner's
(ii) Use
Explain Wh h
Y t e readings after 4 minutes and 5 minutes are the same.
·· ·········· ······ ········ ············ ·· ······· ···· ··· ···· ··· ·································· ···· ····· ·
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . .. . . [1]
(b) The st udent was asked to repeat the experiment using the same mass of calcium and
excess dilute hydrochloric acid of the same concentration.
Fig. 4.3 shows the flasks containing the calcium used in both experiments.
experiment 1 repeat experiment
Fig.4.3
(i) Predict the final volume of the gas collected in the repeat experiment.
............ ................................... ... ... .. ....................... ... ....................... [1]
(ii) Compare the rate of reaction for the second experiment with that of the first
experiment. Explain your answer.
comparison ...... : ........................................................................ ............ .
................... ......... .................................. ....................................................
explanation ............................ ...... .
······················ ··············· ············· ······
...................................................... ................................... ............... [2]
© BEC2014
ti 0569/04/O/N/14 (Turn over
10
5 Name the appara
tus shown in Fig.
5.1.
70
60
50
40
30
20
(b) (c)
10
0
Fig. 5.1
(a) ·· ·· ·· ·· ·· ·· ·· ··
·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ··
·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ··
·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ··
(b) ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ··
·· ·· ·· ·· ··
·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ··
·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ··
·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ··
(c) ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ··
·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ··
·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ·· [3]
·· ·· ·· ·· ·· ·· ·· ·· ·· ·· ··
·· ·· · ·· ·· ·· ·· ·· ·· ·· ··
c, ee c2 01 4 0569/04/O/N/14