MUZZA HIGH SCHOOL, KABEMBE.
S5 CHEMISTRY PAPER 2
1 HOUR AND 30 MINUTES
ATTEMPT ALL QUESTIONS
1. (a) Write down the statements of the kinetic theory of gases (04 marks)
(b) Explain the causes for the deviation of real gases from ideality. (04 marks)
(c) A gas Q contains 30.43% nitrogen and the rest being oxygen.
0.23g of Q occupied 154.11cm3 at 150oC and 840mmHg.
(Molar gas constant R = 8.314 Jmol-1K-1)
(i) Determine the empirical formula of Q (03 marks)
(ii) Determine the molecular formula of Q (05 marks)
(d) When a mixture of Q and oxygen was bubbled through water, a
compound Y was formed.
(i) Identify (01 mark)
(ii) Write equation for the reaction leading to the formation of (01 mark)
e) Explain the term an ideal gas (02 marks)
2. (a) Define the following terms
a. Homogous series
b. Functional group
c. Isomerism (01 mark@)
(b) An organic compound P contains carbon, hydrogen and oxygen in the ratio of 4:9:1
(i) Write the molecular formula of P ( 0.5 mark)
(ii) Write the names and structure formulae of all possible isomers P
(6.5marks)
(c) State the Thomas Graham’s law of gaseous effusion ( 0 1 mark)
(d) Two pieces of cotton wool, one soaked in an amine and the other in concentrated
hydrochloric acid were placed at the opposite end of a1m glass tube. After some time,
a white ring was formed at 0.52m from the end containing the amine.
(i) Calculate the molecular mass of the amine.
(03marks)
(ii) Determine the molecular formula. (02 marks)
3. (a) Define the following terms as used in periodicity
(i) First ionization energy
(ii) Electron affinity
(iii) Electronegativity
(iv) Atomic radius (01 mark @)
(b) The atomic number and atomic radius of elements in period 3 of the periodic table
are shown below;
ELEMENT Na Mg Al Si P S Cl
ATOMIC 11 12 13 14 15 16 17
NUMBER
ATOMIC 0.156 0.136 0.125 0.117 0.110 0.104 0.091
RADIUS
a) Plot a graph of atomic radius against atomic number. (04 marks)
b) Explain the shape of the graph you have drawn in (a) above. (06 marks)
c) Explain the general trend of the variation of ionization energy;
• Down any group (05 marks)
• Across any period (05 marks)
END
“CHEMISTRY IS NEVER A MYSTERY”
THE TEACHER OPENS THE DOOR ITS UP TO YOU TO ENTER.
