MODERN SCHOOL, FARIDABAD
CHEMISTRY ASSIGNMENT,SESSION 2024-25
UNIT- SOLUTIONS,CLASS-XII
MCQ
1. Which among the following is an example of a solid solution?
(a) Copper dissolved in gold
(b) Ethanol dissolved in water
(c) Glucose dissolved in water
(d) Sodium chloride dissolved in water
2. What is the mole fraction of ethylene glycol in a solution containing 20g by mass?
(a) 0.022 (b) 0.054 (c) 0.068 (d) 0.090
3. The solubility of a substance in a solvent depends on
(a) Temperature (b) Pressure
(c) Nature of solute and solvent (d) All of the above
4. Choose the ideal solution from the following.
(a) Carbon disulphide and acetone (b) Phenol and Aniline
(c) Chloroform and Acetone (d) Ethyl iodide and ethyl bromide
5. How is Henry’s constant dependent on temperature?
(a) Directly proportional (b) Inversely proportional
(c) Varies exponentially (d) None of the above
6. In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgSO 4
solution is
(a) the same (b) about twice
(c) about three times (d) about six times
7.0.6ml Acetic acid is dissolved in one litre of water.The value of vant Hoff factor is 1.04. What will be
the degree of dissociation of the acetic acid?
A) 0.01. b)0.02. c) 0.03. d) 0.04
8. If a molecule AB undergoes dimerization in Benzene, its Van’t Hoff factor is found to be 0.60. The
degree of dissociation of AB is
(a) 20% (b) 60% (c) 80% (d) 50%
9.12g of Urea is dissolved in 1L of water and 68.4g sucrose is dissolved in 1L of water. Relative lowering
of vapour pressure of Urea solution is:
(a) Greater than sucrose solution (b) Less than sucrose solution
(c) Double that of sucrose solution (d) Equal to that of sucrose solution
10.Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/lit
will be:
(a) 0.33 (b) 0.666 (c) 0.0033 (d) 3
Assertion and Reason Type Questions
(a) Both Assertion (A) and Reason (R) are the true and Reason (R) is a correct explanation of Assertion (A).
(b) Both Assertion (A) and Reason (R) are the true but Reason (R) is not a correct explanation of Assertion (A).
(c) Assertion (A) is true and Reason (R) is false.
(d) Assertion (A) is false and Reason (R) is true.
11 Assertion: The molarity of a solution in liquid state changes with temperature.
Reason: The volume of a solution changes with a change in temperature.
12. Assertion: When methyl alcohol is added to water, the boiling point of water increases.
Reason: When a volatile solute is added to a volatile solvent elevation in boiling point is observed.
13. Assertion: When NaCl is added to water a depression in the freezing point is observed.
Reason: The lowering of the vapour pressure of a solution causes depression at the freezing point.
14.Assertion: When a solution is separated from the pure solvent by a semi-permeable membrane, the
solvent molecules pass through it from the pure solvent side to the solution side.
Reason: Diffusion of solvent occurs from a region of high concentration solution to a region of low
concentration solution.
Case Based Question
15.Depending upon the nature of the miscible liquids mixed togethe,they form two types of solutions
called ideal and non ideal solutions. Non ideal solution are further classified into two categories one
showing positive deviation from Roult’s law and the other showing negative division from Roults’s law.
However, in each case,such mixture form constant boiling mixture corresponding to a definite
composition, Such mixture are called azeotropes.
a)define an ideal solution
b) What type of liquid form ideal?
c)What type of non ideal solution is formed when ethyl alcohol is mixed with water?
d) when 50ML of liquid A is mixed with 50ML of liquid B total volume of the solution after mixing is
found to be less than 100 ML .What type of non ideal solution is formed?
SHORT QUESTIONS
16.10 g glucose is dissolved in 400 g of solution. Calculate the percentage concentration of the
solution.(2.5%)
17. Calculate the mole fraction of water in C₂H₅OH a solution containing an equal number of
moles of water and C₂H₅OH?(.5)
18.State the unit of ebullioscopic constant (molal boiling point elevation constant.)
19 For a dilute solution containing 2.5 g of a non-volatile non-electrolyte solute in 100 g of water,
the elevation in boiling point at 1 atm pressure is 2℃. Assuming the concentration of solute is much
lower than the concentration of solvent, determine the vapour pressure (mm of Hg) of the solution.
(Given: Kbfor water =0.76Kg Mol⁻¹) (724 mmHg)
20.What is the significance of Henry’s Law constant KH ?
21. Match the items given in Column I with the type of solutions given in Column II.
Column I Column II
(a) Soda water (i) A solution of gas in solid
(b) Sugar solution (ii) A solution of gas in gas
(c) German silver (iii) A solution of solid in liquid
(d) Air (iv) A solution of solid in solid
(e) Hydrogen gas in palladium (v) A solution of gas in liquid
(vi) A solution of liquid in solid
22. Match the terms given in Column I with expressions given in Column II.
Column I Column II
(i) Number of moles of the solute component / Volume of solution in
(a) Mass percentage litres
(b) Volume (ii) Number of moles of a component / Total number of moles of all
percentage the components
(iii) (Volume of the solute component in solution / Total volume of
(c) Mole fraction solution) x 100
(iv) ( Mass of the solute component in solution/ Total mass of the
(d) Molality solution ) x 100
(v) Number of moles of the solute components / Mass of solvent in
(e) Molarity kilograms
Long Question
23 (a) Explain the following phenomena with the help of Henry’s law.
(i) Painful condition known as bends.
(ii) Feeling of weakness and discomfort in breathing at high altitude.
(b) Why does soda water bottle kept at room temperature fizzes on opening?
