Sec: Sr.

IIT-CO-SC Date: 02-05-21

Time: 3 HRS Max.Marks:186
Name of the Student: ___________________ H.T. NO:

2016_PAPER-I
02-05-21_Sr.IIT-CO-SC_GTA-7_ Syllabus
MATHS:

TOTAL SYLLABUS

PHYSICS:

TOTAL SYLLABUS

CHEMISTRY:

TOTAL SYLLABUS
Narayana IIT Academy 02-05-21_Sr.IIT-CO-SC_JEE-ADV_(2016_P1)_GTA-7_Q.P

JEE-ADVANCE-2016-P1-Model
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 5) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 6 – 13) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 14 – 18) Questions with Integer Answer Type 3 0 5 15
Total 18 62
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 23) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 24 – 31) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 32 – 36) Questions with Integer Answer Type 3 0 5 15
Total 18 62
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 41) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 42 – 49) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 50 – 54) Questions with Integer Answer Type 3 0 5 15
Total 18 62
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PHYSICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.

1. An air chamber of volume ‘v’ and pressure ‘p’ has a neck area of cross- section ‘A’ into which a ball of
mass ‘m’ just fits and can move up and down without friction. When the ball is pressed down a little
and released it executes S.H.M. The time period of oscillations of the ball is (assuming pressure –
volume variations to be isothermal). ( p0 = atm pressure).

mv 2 mv p0 mv 2 mv
(A) 2 (B) (C) 2 (D)
pA A p pA A p  p0

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2. A ramp is constructed in parabolic shape such that the height y of any point on its surface is given in
x2
terms of points horizontal distance x from the bottom of the ramp by y  . A block of granite is to
2L
set on the ramp, the co-efficient of static friction is 0.8. The maximum x coordinate x m at which the
block can be placed on the ramp and remain at rest if L  10m is
(A) 2m (B) 4m (C) 8m (D) 10m

3. A metal block of heat capacity 80 J / 0 C is placed in a room at 200 C is heated electrically. The heater
is switched off when the temperature reaches 300 C . The temperature of the block rises at a rate of
20 c / s just after the heater is switched on and falls at the rate of 0.20 C / s just after the heater is
switched off. Assume Newton’s law of cooling to hold. Find the power radiated by the block when the
temperature of the block is 250 C .
(A) 2 W (B) 4 W (C) 8 W (D) 32 W

4. In the arrangement as shown, mB  3m, density of liquid is  and density of block B is 2  . The
system is released from rest so that block B moves up when in liquid and moves down when
completely out of liquid with the same acceleration. Find the mass of block A.

7 9 9
(A) m (B) 2m (C) m (D) m
4 2 4

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5. Two parallel resistance less rails are connected by an inductor of inductance L at one end as shown in
the figure. A magnetic field B exists in the space which is perpendicular to the plane of the rails. Now a
conductor of length and mass m is placed transverse on the rails and given an impulse J towards the
rightward direction. Then choose the correct option.

(A) Velocity of the conductor is half of the initial velocity after a displacement of the conductor
3J2L
d
4B2 2m
(B) Current flowing through the inductor at the instant when velocity of the conductor is half of the
3J2
initial velocity is i 
2Lm
(C) Velocity of the conductor is half of the initial velocity after a displacement of the conductor
3J2L
d
B2 2m
(D) Current flowing through the inductor at the instant when velocity of the conductor is half of the
3J2
initial velocity is i 
mL

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SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases
6. A particle of mass m is bound by the linear potential U  kr , where k is a constant and r  0 . It is
moving in a circular orbit of radius r0 about the origin.
3kr0
(A) Its mechanical energy is
2
(B) The speed is independent of value of radius
(C) The angular speed is independent of value of radius
kr0
(D) Its mechanical energy is
2

7. In the circuit shown, switch S1 is initially open and switch S 2 is initially closed. At time t  0, S1
closed and at time t  0.25Sec, S2 is opened. The voltage across the inductor, VL
1H

S1
S2
20
10V
5

(left switch is S1 and right switch is S2 )

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(A) Just after switch S1 is closed, VL  10V
(B) Just before switch S2 is opened VL  10 / eV
(C) Just after switch S 2 is opened, VL   40  50 / e V
(D) Just after switch S 2 is opened, VL   60  50 / e V

8. A hollow, conducting spherical shell of inner radius R1 and outer radius R 2 encloses a charge q
inside, which is located at a distance d (d  R1 ) from the centre of the spheres. (assume potential to
be zero at infinity)

kq kq
(A) The potential at the centre of the shell is 
d R1
kq
(B) The potential of the shell is
R2
kq kq kq
(C) The potential outside the shell at a distance R from the center is  
R d R1
kq kq kq
(D) The potential at the centre of the shell is  
d R1 R2

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9. The first overtone of an open organ pipe (of length L0 ) beats with the first overtone of a closed organ
Pipe(of length Lc ) with a beat frequency of 10 Hz. The fundamental frequency of the closed pipe is
110 Hz. If the speed of sound is 330 m / s . Then
 33   33 
(A) Lc  0.75m (B) Lo    m or   m
 34   35 
 33   33   33 
(C) Lo    m or 1m (D) Lo    m or   m
 32   32   34 

10. In a one-dimensional collision between two identical particles A and B, B is stationary and A has
momentum p before impact. During impact, B gives impulse J to A.
(A) The total momentum of the ‘A plus B’ system is p before and after the impact and  p  J  during
the impact.
(B) During the impact, A gives impulse J to B.
2J
(C) The coefficient of restitution is – 1.
p
J
(D) The coefficient of restitution is  1 .
p

11. A gas undergoes a process in which its pressure ‘P’ and volume ‘V’ are related as VP n  constant. The
bulk modulus of the gas in this process cannot be equal to
P
(A) nP (B) P1/n (C) (D) P n
n

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12. In figure the uniform gate weighs 300N and is 3m wide and 2m high. It is supported by a hinge at the
bottom left corner and a horizontal cable at the top left corner, as shown. (Take g  10 m / s 2 )

(A) The tension in cable is 225N

(B) The tension in cable is 125N
(C) The vertical force that the hinge exerts on the gate is 300N
(D) The vertical force that the hinge exerts on the gate is 150N

13. A particle is projected from ground from point A near the bottom of a wedge. At the same time
wedge(sufficiently long) is also moved with same speed towards right as shown, then
g 10m / s 2

10 3m / s
10 3m / s 60º
30º
A
(A) Particle can never collide the wedge.
(B) Particle will collide the wedge after 2 sec.
(C) Maximum height attained by the particle is 11.25 m from the ground.
(D) Height of point on the wedge where particle strikes is 10m.
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SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
14. A cylindrical vessel is divided in two parts by a fixed partition which is perfectly heat conducting. The
wall and piston are thermally insulated from surroundings. The left side contains 0.5 moles of gas with
Cv  2 R at temperature of 300 K. The right side contains 4 moles of mixture of gas with
Cv  1.75R at same temperature of 300 K. The piston compresses slowly the right side from volume
V
of V0 to 0 . Find the total change in internal energy of gases. If U  n  10 J , fill n in OMR Sheet
4
4
25
(Take: R  S .I .unit )
3

15. A parallel paraxial beam of light is incident on the arrangement as shown.  A  3 / 2, B  4 / 3 , the two
spherical surfaces are very close and each has a radius of curvature 10 cm. If the distance between the
point of entry and the point where the rays are focused is n cm, find the value of 5n / 2

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16. In an LRC series circuit at resonance current in the circuit 4 2 A . If now frequency of the source is
changed such that now current lags the applied voltage by 450 in the circuit, find the new value of
current in the circuit ( in A)

17. One end of a long iron chain of linear mass density  is fixed to a sphere of mass m and specific
density 1/3 while the other end is free. The sphere along with the chain is immersed in a deep lake. If
specific density of iron is 7, the height h above the bed of the lake at which the sphere will float in
equilibrium is (Assume that the part of the chain lying on the bottom of the lake exerts negligible
xm
forces on the upper part of the chain) . Find x=?
3

18. A glass plate of area A and mass m is hinged along one of its sides. At what speed the air should be
blown on its upper surface and parallel to it to hold the plate horizontal? Assume that the air below the
mg
lower surface is at rest. The density of air is  . Give the answer in multiples of
18. A

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CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.

19. The energy levels of a hypothetical one electron atom are given below.
No.of orbit Energy of the orbit
n 0ev
n 5 0.80ev
n4 1.45ev
n 3 3.08ev
n2 5.30ev
n 1  15.6ev
Pick the incorrect statement from the following.
(A) ionization potential of the atom is 15.6ev
(B) wave length corresponding to the electronic transition n  3 to n  2 is the longest wave length of
the series terminating at n  2
(C) wave length corresponding to the electronic transition n  to n  2 is the shortest wave length of
the series terminating at n  2
(D) wave length corresponding to the electronic transition n  to n  1 is the longest wave length
among all the possible transitions

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20. When one mole of an ideal gas is reversibly changed from ‘30K’ to ‘300K’ in a closed container then
what is the change in its entropy?
2.303R 3 r
(A) (B) 2.303 R (C) R (D)
   1 2 2.303R

21. Of the following which is a step-growth polymer?

(A) Bakelite (B) Polyethylene (C) Teflon (D) PVC

22. The following are some statements related to VA group hydrides. Incorrect statement is:
(A) Reducing property increases from NH 3 to BiH 3 .
(B) Tendency to donate lone pair increases from NH 3 to BiH 3 .
(C) Thermal stability of hydrides decreases from NH 3 to BiH 3 .
(D) Bond angle of hydrides decreases from NH 3 to BiH 3 .

23. Which statement is correct for the following complexes?


1. Co  en 2 Cl2  , 2. Co  NH3 3 Cl3  , 3. Co  H2O 4 Cl2  Cl .
(A) 1, 2 complexes can show both geometrical and optical isomerism
(B) 1, 2 complexes can show geometrical and optical isomerism
(C) 1, 2, 3 complexes can show geometrical isomerism and optical isomerism is shown by cis forms of
2 and 3.
(D) 1, 2, 3 complexes can show geometrical isomerism, cis form of complex 1 shows optical
isomerism.

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SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases

O O
K2Cr2O7 / H 
24. Consider the following reaction: A 

The starting substance ‘A’ can be
NH2 OH NH2 OH

NH2 NH2 CH3 OH

(A) (B) (C) (D)

25. Which of the following reactions involve hydride ion shift?

o o
()

2 H  C  H 
OH
 H  C  O  CH 3  OH
(A)
O O
()
O H /
2CH 3  C  H   CH 3  CH  CH  C  H
(B)
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o o

Al  oEt 
2CH 3  C  H 
3
 CH 3  C  O  CH 2CH 3
(C)
OH O
Al  OCMe 

O
3 3

CH3-C-CH3
(D)

26. The mean lives of a radioactive substance are 1620 years and 405 years of   emission and  -
3
emission respectively. Find out the time during which th of a sample will decay if it is decaying both
4
by   emission and   emission simultaneously.
2.303 N 
(A)  1620  log  o  (B) 449.24 years.
5  N
2.303 N 
(C) 44.924 years (D)  log  o 
2025  N 

27. Which of the following reagents cannot be used for differentiation between glucose and fructose?
(A) Lucas reagent (B) Br2 / H 2O
(C) Tollen’s reagent (D) NaHCO3  aq 

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28. A substance ‘A’ may react to give different products in two different paths:
(1) A 
K1
 B  C (2) A  K2
D  E
Both these reactions paths are of first order and have identical frequency factor. ln K is plotted against
1/T for (1) and (2):

lnk 2
1

1/T
Select the correct statements among following
(A) activation energy of reaction (1) is greater than that of (2)
(B) Activation energy of reaction (2) is greater than that of (1)
(C) B and C are kinetically favorable products
(D) D and E are kinetically favorable products

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29. Consider the following sequence
O O O CH3
O

OH 
H

Step I

CH3CHO
Step II 
H2O

Step III
H3C O H3C O H3C O

O O CH3
HO
CH
CH3 H


Step IV
H3C O H3C O
Which of following statement(s) is/are correct for above reaction sequence?
(A) Step I is acid-base reaction
(B) Step II is nucleophilic addition reaction
(C) Step III is acid base reaction
(D) Step IV is elimination reaction

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30. Observe the following experiments:
AgNO3 Na 2SO3

   
 
 
 
 

Na 2SO3 AgNO3

(I) (II)
The correct statement(s) about set up (I) and (II) is/are:
(A) In set up (I) initially no precipitate is formed but on addition of excess of reagent and followed by
boiling gives greyish black ppt.
(B) In set up (II) initially a white precipitate is formed as well as on boiling gives grayish black ppt
(C) In set up (I) the precipitate formed with excess AgNO3 which is soluble ammonia solution.
(D) In set up (II) the precipitate is soluble is dilute nitric acid and gives gas with suffocating smell of
burning sulphur.

31. Which of the following statement(s) is/are correct?

(A) Cationic part of Cl2O6 is planar
(B) N SiH3 3 is more basic than N  CH3 3
(C) HNO2and HClO3 both disproportionate on heating
(D) NO2and ClO2 both are sp 2 hybridised

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SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases

32. Total no. of stereo isomers possible for the compound CH3  CH  CH  CH  CH  CH  CH  ph

33. 0.5 molal NaCl and 0.8 molal urea solutions are found to be isotonic at 270 c , then Degree of
dissociation of NaCl under these conditions is reported as z 10% .What is the value of z?

34. In IL saturated solution of AgCl  Ksp AgCl  1.6 1010  ,0.1 mol of CuCl  Ksp CuCl  1106  is
added. The resultant concentration of Ag  in the solution is 1.6 10 x The value of ‘x’ is______

35. Consider the following extraction process:

Wolframite
(impurity)
Cassiterite step  I
+ 

wolframite
step  II m etal  M   m etal oxide(M O 2 ) im purity
Cassiterite 

Wolramite Step  III

(impurity)

Step  IV
Step V
99.98% Pure metal (M )   99.5% Pure metal (M )  purer metal(M )

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The number of correct statement(s) among the following is
(1) The flow chart represents extraction of tin
(2) Step-I is levigation
(3) Step-II is carbon reduction
(4) Step-III is poling
(5) Step-IV is liquation
(6) Step-V is electro refining

36. How many of the following reactions evolve a paramagnetic gas?

(a) Fe  80%conc HNO3 
(b) Cu  dil.HNO3 
(c) Zn  dil HNO3 
(d) Pb  dil HNO3 
(e) Zn  NaOH 
(f)  NH4 2 SO4  NaOH 
(g) KO2  H2O 

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MATHEMATICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.

37. If the quadratic equation 4 x2  2  a  c  1 x  ac  b  0,  a  b  c  then

(A) both roots are greater than a (B) both roots are less than c
c a c a
(C) both roots be between   and   (D) exactly one of the root is between   and  
2 2 2 2

38. If Z1  1 , Z 2  2, Z3  3 and 9Z1Z2  Z 2 Z3  4Z3 Z1  12 then Z1  Z 2  Z3 

(A) 2 (B) 3 (C) 4 (D) 6

2 2 2 2
 3  2  1  4 16m
39. If the sum of the first ten terms of the series 1    2    3   42   4   ..... is then m
 5  5  5  5 5
is equal to
(A) 102 (B) 101 (C) 100 (D) 99

40. If each of the lines 5x  8 y  13 and 4 x  y  3 contains a diameter of the circle

x2  y 2  2  a 2  7a  11 x  2  a 2  6a  6  y  b3  1  0 then
(A) a  1 and b   1,1 (B) a  2 and b   ,1
(C) a  5 and b   1,1 (D) a  5 and b   ,1

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41. Let A   x1 , x2 ,...x7 . Let ‘f’ be bijective mapping from A to A. Let ‘ n1 ’ be number of functions ‘f’
such that f  xi   xi holds for at least one ‘ i ’ and ‘ n2 ’ be number of functions ‘f’ such that f  xi   xi
for i  1, 2,3 and no restriction on remaining elements. Then, which of the following is true?
(A) n1  n2  40 (B) n2  n1  30
(C) n2  n1  362 (D) n1  n2  2871

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases

42. If the ellipse x2   2 y 2   2 a 2 ,  2  1 is confocal with the hyperbola x 2  y 2  a 2 , then

(A) ratio of eccentricities of ellipse and hyperbola is 1: 3
(B) ratio of major axis of ellipse and transverse axis of hyperbola in 3 :1
(C) the ellipse and hyperbola cuts each other orthogonally
(D) ratio of latustrectum of ellipse and hyperabola is 1 : 3

43. If f and g are two strictly monotonic functions such that 2f 1  g  2   4 and 2f  9   g 10   20 and

 
 x 2g f  x 3  1 f '  x 3  1  3x 2  dx  0
2

0 
Which of the following is /are true

 g  x  dx  12  g  x  dx  24 g 1  x  dx  356 g 1  x  dx  168
10 10 20 20
(A)
2
(B)
2
(C) 
4
(D) 
4

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Narayana IIT Academy 02-05-21_Sr.IIT-CO-SC_JEE-ADV_(2016_P1)_GTA-7_Q.P
f  t  dt   t f  x  t  dt  1  e x  x  R
x x
44. Let f be a differentiable function on R and satisfy the 0 0
Which of the following is/are correct
(A) f  0   f '  0   f  2   1  e2
(B) f  0   f '  0   f  2   2  e2
1
(C) Area enclosed by y  f  x  , y  0, x  0 and x  2 is
e
2 2
(D) Area enclosed by y  f  x  , y  0, x  0 and x  2 is  2
e e

 e2tx  2tx  1  g2  x   x 4
45. If g  x   Lim tan   and L  Lim ; which of the following is/are true
t 0
 2t 2  x 0 x8
g  Lx  4 g  Lx  25
(B)  L  1
2
(A) L  (C) Lim 2
 (D) Lim 
3 x 0 x 9 x 0 x2 9
(where { } and [ ] are fractional part function and Greatest Integral Function respectively )

46. A certain coin is tossed with probability of showing head being p. let q denotes the probability that
when the coin is tossed four times the number of heads obtained is even then which of the following
is/are true ?
(A) there is no value of p, if q  1/ 4
(B) there is exactly one value of p, if q  3 / 4
(C) there are exactly two values of p, if q  3 / 5
(D) there are exactly four values of p if q  4 / 5
47. Consider f  x   x 2 sin 2   2x cos   1,   n, n  I
Then which of the following is/are true ?

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Narayana IIT Academy 02-05-21_Sr.IIT-CO-SC_JEE-ADV_(2016_P1)_GTA-7_Q.P
(A) Both roots of f  x  , are of opposite sign
 
(B) For    ,   , 1 lies between the roots of f ( x)  0
2 
x2 1
(C) Locus of vertex of f  x  is 2   1
y x
x2 1
(D) Locus of vertex of f  x  is 2   1
y y
x 1 y z  2
48. The equation of the plane which is equally inclined to the lines   and
2 2 1
x3 y 4 z
  and passing through the origin is/are
8 1 4
(A) 14 x  5 y  7 z  0 (B) 2 x  7 y  z  0
(C) 3x  4 y  z  0 (D) x  2 y  5z  0
49. Let ‘O’ be origin and the curve y  x  9 meets the x-axis and y-axis respectively at A and B.
Which of the following is/ are correct
(A) The abscissa of the point where the tangent at B intersect the curve again is 36  18 2
(B) Normal at A to the curve is x + 9 = 0
15
(C) Tangent at B meets the tangent at A at   , such that    = 
2
33
(D) The area of quadrilateral formed by the tangents at A and B and the co-ordinate axes is square
4
units
SECTION – III
(INTEGER ANSWER TYPE)
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This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases

 /2  /2  /2

 cos( sin  cos(2 sin x) dx and I 3   cos( sin x) dx , then

2 2
50. Suppose I1 = x) dx ; I2 =
0 0 0

I1  I 2  I 3 

51. The angle bisector of angle C of ABC , meets the side AB and its circumcircle at the points D & E
respectively. If AB  6 , then the maximum value of (CD) (DE) is……

52. Let A and B are two square idempotent matrices such that AB + BA, AB – BA are null matrices, then
the sum of squares of the possible values det (A – B) is

2i  j 2i  j
53. A unit vector r has equal length of projections along the vectors , and k . If r.
5 5

i  j  k  is positive, then number of such vectors r will be

3
54. Let f be continuous periodic function with period 3, such that 0 f  x  dx  1 . Then the value of
8

4 f  2 x  dx

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Narayana IIT Academy 02-05-21_Sr.IIT-CO-SC_JEE-ADV_(2016_P1)_GTA-7_Q.P

BRANCH: SURAT

MATHS PHYSICS CHEMISTRY CHEMISTRY

KULDIP MISHRA PRINCE PUNDIR SUMIT LUNIA SANKET GAJJAR

82382 85251 99402 13029 90995 09500 99983 26903

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