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47 The solids sodium chloride and sodium iodide both react with concentrated sulfuric acid at room temperature. With NaCl, the products are NaHSO, and HCI. With Nal, the products are NaHSO,, HI, I,, SO,, H,0, S and H,S. What is the explanation for this difference in products? A Chloride ions will displace iodine from the solution. B Hydrogen chloride is more volatile than hydrogen iodide. ©) Iodide ions are better reducing agents than chloride ions. D Sulfuric acid is able to act as a dehydrating agent with Nal. Scanned with CamScanner OIN 161 13/012, OIN 16/P14/012 41.18 9 of a metalic element needs 300 cm? of oxygen for complete reaction, at 298 K and 1 alm pressure, to form an oxide which contains O?- ions. What could be the identity ofthis metalic element? A calcium B magnesium © potassium 3D sodium Scanned with CamScanner 414, MAJ 08/P1/Q1, OIN 12/13/09 in the Basic Oxygen steel-making process the P,O,o impurity is removed by reacting it with calcium oxide. The only product of this reaction is the salt calcium phosphate, Cas(POx)2. In this reaction, how many moles of calcium oxide react with one mole of xs? Ad B15 c 3 Scanned with CamScanner 23. MA 14/P11/Q40, O/N 10/P12/Q39 Use of the Data Bookiet is relevant to this question. In an organic synthesis, a 62% yield of product is achieved. Which conversions are consistent with this information? 1 74.00 g of butan-2-ol —> 44.64 g of butanone 2 74.00 g of butan-1-ol —> 54.56 g of butanoic acid 3 74.00 g of 2-methylpropan-1-ol —> 54.56 g of 2-methylpropanaic acid A B c D 1,2and3 Tand2 2and3 1only are only are only are is correct correct correct correct Scanned with CamScanner 42. MJ 13/P14/Q2, ON O2/PIIAQ1 ‘Aminture of 10 cm? of methane and 10 om? of ethane was sparked with an excess of oxygen. After cooling to room temperature, the residual gas was passed through aqueous potassium hydroxide. All gas volumes wore measured al the same temperature and pressure ‘What volume of gas was absorbed by the alkali? A 15cm? B 20cm? © @) 200m? D 40cm? Scanned with CamScanner a. IN 10/P13/022, OIN 10/P11/021, OIN 13/P13/Q28 Compound X reacts with ethanoic acid in the presence of an H* catalyst to produce the compound below. HOH 9° ° Ito I H,c—C—C—c—o—C—CH, HOH What is the molecular formula of compound x? A C:HeO2 B GaHeOs © CHO (DD CuHaO. Scanned with CamScanner 48. OIN 09/P12/Q18, OIN 09/P11/Q19, M/J 13/P13/Q18, MJ OB/P1/Q18, In an historically famous experiment Wahler heated ‘inorganic’ ammonium eyanato in the absence of ir. The only product of the reaction was ‘organic’ urea, CO(NH,)2, No other products were formed in the reaction, ‘What is the formula of the cyanate jon present in ammonium cyanate? ‘A CNO- B CNO® © CO D NO Scanned with CamScanner 53, OIN 16/P 11/016, MiJ 13/P11/Q16, OIN 16/P13/016 Magnesium nitrate, Mg(NO3), wil decompose when heated to give a white solid and a mixture of gases. One of the gases released is an oxide of nitrogen, X. 7.4 g of anhydrous magnesium nitrate is heated until no further reaction takes place. What mass of X is produced? A 15q B 23g c 30g (D469 Scanned with CamScanner 57. OIN 15/P12/Q16, Mid 04/P 11018 Use of the Data Booklet is relevant fo this question, Brine is concentrated aqueous sodium chloride. In the commercial electrolysis of brine, the products are chlorine, hydrogen and sodium hydroxide. ‘What is the maximum yield of each of these products when 58.5 kg of sodium chloride are electrolysed as brine? yield of yield of yield of sodium chlorinevkg | _hydrogen’kg | “hydroxide/kg Qs j i B 35.5 2 40 c 71 1 40 D 71 2 80 OIN 15/P12/013, Md 12/P111014, MY 12/P13/Q15, Use of the Data Booklet is relevant to this question ‘he reaction between aluminium powder and anhydrous barium nitrate (8 used'as the propellant in some fireworks. ‘The metal oxides and nitrogen are the only products. Which volume of nifogen, measured under room condltios, is pred ced jwhen 0.783 9 of anhydrous barium nitrate reacts with an excess of aluminium?’ A 46.8 cur 'B. 120en CC _93.6eme: D 144m? Scanned with CamScanner 86, OIN 17/P12/Q16, Mid 14/P12/Q19 Use of the Data Bookiet is relevant to this question. In an experiment, 0.125 mol of chlorine gas, Gla, is reacted with an excess of cold aqueous sodium hydroxide. One of the products is a compound of sodium, oxygen, and chlorine. Which mass of this product is formed? A 9319 B 13.39 Cc. 18.69 D 2669 Scanned with CamScanner 97, MJ 16/P13/Q15, Mid 13/P13/Q12 Anhydrous magnesium nitrate, Mg(NOs)2 , will decompose when heated, giving a white solid and a mixture of two gases X and Y. Yis oxygen. Whats the ratio M28sol Xreleased massof Yreleased 4 1 4 4 az 8 ter c Ta > 3a Scanned with CamScanner 38. O/N 15/P13/Q9, O/N 15/P11/Q9 Hexamine is a crystalline solid used as a fuel in portable stoves. The diagram shows its skeletal structure. or { bo What is the empirical formula of hexamine? A CHN CsHeNe C CaHaNa Do CeHiNg Scanned with CamScanner 4, MJ 13/P12/Q3, OJN 10/P13/Q3, O/N 10/P11/Q6, O/N 05/P1/Q2 Which ion has more electrons than protons and more protons than neutrons? IH= 1H, D="H,O="O] A D- B H.0 c oD “Dy oO Scanned with CamScanner 48, MU 15/P11/031, O/N 12/P12/Q32, OIN 12/P11/032 Use of the Data Booklet is relevant to this question. The isotope **Te is radioactive and has been found in lobsters and seaweed adjacent to nuclear fuel reprocessing plants. ‘Which statements are correct about an atom of To? 1 thas 13 more neutrons than protons. 2 Ithas 43 protons. 3 Ithas 99 nucleons. A! B c D 1,2and3 tand2 2and3 tonly are only are only are is correct correct, correct correct Scanned with CamScanner 29. OIN 16/P11/Q13, O/N 16/P13/Q13 The diagram shows the melting points of eight elements with consecutive atomic numbers. Which element could be sodium? melting point/K > atnmic number Scanned with CamScanner 4. O/N 15/P11/Q1, ON 15/P13/Q1, O/N 12/P13/Q7, O/N 03/P1/Q5, The table gives the successive ionisation energies for an element X. What could be the formula of a chloride of X? A XC Bo XCh Ast 2nd 3rd 4th 5th 6th ionisation energy/kJmot | 950 | 1800 | 2700 | 4800 | 6000 | 12300 & xc, D xc Scanned with CamScanner 91. O/N 12/P12/Q9, O/N 12/P11/Q9, M/J 07/P1/Q3 John Dalton’s atomic theory, published in 1808, contained four predictions about atoms. Which of his predictions is still considered to be correct? All atoms are very small in size. B All the atoms of a particular element have the same mass. C All the atoms of one element are different in mass from all the atoms of other slepens To Naatam ean he enlit inta cimnilar narte Scanned with CamScanner 3. O/N 12/P13/Q11, M/J 04/P1/Q20 Which molecule is planar? CrCl B CoH, C Coty D NF, 4. OIN 12/P11/Q13, M/J 16/P11/Q12, O/N 12/P12/Q13 Why is the ionic radius of a chloride ion larger than the ionic radius of a sodium ion? ‘A Achioride ion has one more occupied electron shell than a sodium ion. B c D Chlorine has a higher proton number than sodium. lonic radius increases regularly across the third period. Sodium is a metal, chlorine is a non-metal. Scanned with CamScanner 14. MiJ 16/P12/Q13 Solid aluminium chloride sublimes at 178°C. Which structure best represents the species in the vapour at this temperature? Cl Ci Cl cl cl A Nn ty” c Nar 4NZ7™ | cl Cl cl Cl ci Cl cl B “i SW D AP*(CI-). SN TS ° Ci Cl Cl Scanned with CamScanner 7. OIN 16/P11/Q6, O/N 16/P13/06 Histamine is produced in the body to help fight infection. Its shape allows it to fit into receptors which expand blood vessels, smallest largest bond angle ————*_ bond angle * x y z B y x z c y z x D z y x histamine What are the bond angles x, y and zin histamine, from the smallest to the largest? Scanned with CamScanner 29, OIN 12/P13/Q21, Mid 15/P13/Q21 The diagram shows a molecule that has o bonds and z bonds, i Zew CH,=CH—CH, ~O—CH,—cH How many c bonds are present in this molecule? A 15 B17 ce. 18 D 21 Scanned with CamScanner 32. M/J 17/P11/Q5, M/J 12/P12/Q10 Which molecule has the largest overall dipole? H CHy cl \ f c A = o=C. 7 \ H CH; Ci CH; HC, cl Bo ond D Ya’ \ ZN CHs cl CHs Scanned with CamScanner

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