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Batch Code : Date of Practice:
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Level - I, II & III
Chemistry – Gaseous State Sheet – 1
QP Code : 611982.0
Important Instructions
Attempt all the Questions
1. There are THREE Sections in this sheet Level I, Level II & Level III.
2. Level I has 30 questions and carries +2 for correct answer and -1 for wrong answer.
3. Level II has 20 questions and carries +4 for correct answer and -1 for wrong answer.
4. Level III has 10 questions and carries +6 for correct answer and NO NEGATIVE for wrong answer.
5. There is NO Marks for unanswered questions.
All the best....
No. of Questions No. of No. of
Total No. of Expected
Attempted Questions Question Negative Marks
Questions Score
confidently Guessed s Left
Correct Incorrect Correct Incorrect Attempted Guessed
CMPC - 03 2
SECTION I
PART A
Single Answer Questions
1. The physical state of a substance is largely determined by :-
(A) Temperature (B) pressure (C) Both (D) None
2. A gas is at 1 atm and 27°C and what will be temperature (K) when the gas is expanded to 0.25atm
(A) 50 (B) 75 (C) 100 (D) 125
3. For matter, in which state the molecules have least energy?
(A) Liquids (B) solids (C) gases (D) plasma state
4. Among the following molecules, dispersion forces are seen in
(A) CO2 (B) HF (C) NH3 (D) HCl
5. Which of the following does not determine the translational kinetic energy of an ideal gas?
(A) Temperature (B) Amount of gas
(C) number of moles of gas (D) pressure of gas
6. The volume of gas at 273.15o C is
(A) 1 (B) (C) Zero (D) 1.5
7. At very low pressures all gases shows Z =? & behaves as
(A) 0, real gas (B) 1, real gas (C) 0, Ideal gas (D) 1, Ideal gas
8. Boyle’s law deviates at
(A) high pressure (B) low pressure (C) high temperature (D) low temperature
9. The deviation from ideal behavior can be measured in terms of which factor?
(A) Reducing (B) Elongation (C) Compressibility (D) True
10. For matter, in which state the molecules are more compressible?
(A) gas (B) solids (C) liquids (D) plasma
11. Dispersion forces are interparticle forces among:-
(A) monoatomic molecules (B) Non-polar molecules
(C) Both (D) None
12. What is the plot for ‘V’ vs ‘P’ at constant Temperature?
(A) (B)
V
V
P P
(C) (D)
V V
P P
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CMPC - 03 3
13.
H2 From the graph, which gas is easier
to liquefy?
O2
CO2
Z=
Ideal gas
compressibility
factor
‘P’
(bar)
(A) H2 (B) O2 (C) CO2 (D) None
14. 5gm of He at 80.6 K is subjected to a pressure change from 1 atm to 2 atm. The final volume of the gas is
3
20dm . Calculate the change in volume of the gas.
3 3 3 3
(A) 20dm (B) 40dm (C) 30dm (D) 60dm
15. At constant temperature ( 27o C), the graph log P ‘vs’ log (V1 ) cuts an intercept on y-axis at ‘2’. Find the no. of
moles of gas. (pressure in atm & volume in litre).
(A) 2 (B) 4 (C) 3 (D) 6
16. A gas at 80.6 o F is compressed to reduce to half of its volume. At what temperature (Kelvin) will it become half
of its initial volume? C
9
5
F 32
(A) 300K (B) 450K (C) 600K (D) 150K
17. For gases which follows ideal gas law, which graph is correct
(A) (B) (C) (D)
PV
P V
PV
T
P V
P
18. Ideal gas equation is combination of
(A) boyle’s law, Avagadro’s law, Gay Lusac’s law
(B) Avagadro’s law, Charle’s law, Dalton’s law of partial pressures
(C) Avagadro’s law, Charle’s law, Boyle’s law
(D) None of them
19. An open bulb containing air at 19 o C was cooled to -39.4 o C by how much no. of moles of gaseous molecules
increased?
(A) 10% (B) 20% (C) 25% (D) 30%
20. On Same Temperature & pressure, the sequence of rate of diffusion will be
(A) CO2 H2 N2 O2 (B) O2 N2 CO2 H2
(C) N2 H2 O2 CO2 (D) H2 N2 O2 CO2
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CMPC - 03 4
21. In kinetic molecular model, the pressure of a gas is
(A) based on Vanderwaal’s force present in the gas
(B) The result of collision of molecules with the wall of the container
(C) Both (A) & (B)
(D) None of them
22. According to Guldberg’s rule, the critical temperature of water is (K):-
(A) 32 (373) (B) 32 (373) (C) 52 (373) (D) 52 (373)
23. Which of the following is true?
-2 -2
(A) 1 pascal.sec = 10 Nm . sec (B) 1pascal.sec = 100 dyne cm sec
-2
(C) 1 pascal.sec = 1 Nm . sec (D) None of them
24. The drops of a liquid are spherical
(A) due to gravity (B) Viscosity
(C) maximum surface Tension (D) All of them
25. Vrms : vmp are having ratio of
(A) 1 : 2 (B) 2: 3 (C) 3: 2 (D) 1 :1
26. A gas is at 3 atm & 300 K. If the pressure is increased to 8 times, by how much temperature will be changed ,
keeping volume constant
(A) increased by 4 times (B) decreased by 8 times
(C) increased by 8 times (D) No change in temperature
27. 32gm of SO2 occupies Volume of 175ml at 300 K & 50 atm pressure. What is Compressibility factor of gas
(A) 0.5 (B) 1 (C) 0.711 (D) 1.4
28. For Vanderwaal’s modified equation, volume correction Factor (b) will be equal to
(A) volume of single molecule (B) twice of volume of single molecule
(C) Thrice of volume of single molecule (D) Four times of volume of single molecule
29. Under similar conditions, which are the following gases diffuses as 4 times quickly as O2
(A) Ne (B) H2 (C) CO2 (D) N2
30.
T3
T2
P The order of temperature (Boyle’s law) graphically
T1
1/V
(A) T3 T2 T1 (B) T2 T1 T3 (C) T1 T2 T3 (D) T3 T2 T1
SECTION II
PART A
Single Answer Questions
1. What will be volume occupied by 7g N2 at 27°C and 760mm Hg
(A) 4 L (B) 6 L (C) 8 L (D) 5 L
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CMPC - 03 5
2. 10g of ethane are confined in a bulb of 1 litre capacity. The bulb is so weak that it will burst if the pressure
exceeds 10 atm. At what temperature will be the pressure of gas reach the bursting value?
(A) 365.4 °C (B) 92°C (C) 92 K (D) It will not burst
3. What would be the percentage change in pressure for a 5% increase in volume of gas at constant
temperature?
(A) 5.26% (B) -5.26% (C) 4.76% (D) -4.76%
4. Calculate the density of CO2 at 100°C& 800 mm Hg pressure
3
(A) 1 g/L (B) 1.051 g/L C) 1.512g/L D) 1000 kg/m
5. A gas occupies 0.418 litre at 740 mm of Hg and 27°C, and weighs 3g. Calculate the new pressure of gas if the
weight of gas is increased to 7.5g and temperature becomes 280 K, keeping the volume as constant.
(A) 2.27 atm (B) 4 atm (C) 2 atm (C) 3 atm
6. 32g each of CH4 and O2 are mixed in empty container of one litre at 27°C. what will be total pressure
(A) 50 atm (B) 63 atm (C) 73 atm (D) 1 atm
7. The density of a gas at STP is 2.68 g/L. This gas is
(A)COS (B) NO2 (C) Kr (D) CO2
3
8. 20dm of SO2 diffuses through a porous partition in 60 second. What volume be O2 will diffuse under similar
Conditions in 30 second.
3 3 3 3
(A) 1.414 dm (B) 14.14 dm (C) 141.4 dm (D) 0.1414 dm
9. The V D of gas is 11.2. The volume occupied by 11.2 g of this gas at NTP is
(A) 11.2 L (B) 1L (C) 22.4 L (D) 2 L
10. An evacuated glass vessel weighs 50.0 g when empty, 148.0g when filled with a liquid of density 0.98 g/mL and
50.5 g when filled with an ideal gas at 760 mm Hg at 300 K. Determine the molecular weight of the gas.
(A) 1.23 (B) 100 (C) 10 (D) 123
11. What weight of hydrogen at STP could be contained in a vessel that holds 3.36 L of O2 gas at STP?
(A) 0.30g (B) 1g (C) 1.5g (D) 2g
12. When an open vessel is heated from 300 K to 500 K, what percentage of the gas will escape out?
(A) 20 (B) 60 (C) 40 (D) 80
13. An under water bubble with a radius of 0.5cm at the bottom of tank where the temperature is 5°C and pressure
is 3atm rises to the surface, where temperature is 25°C and pressure is 1atm. What will be the radius of bubble
when it reaches to surface?
(A) 0.74 cm (B) 7.4 cm (C) 5 cm (D) 10 cm
14. The rates of diffusion of two gases A & B are in the ratio 1:4. If the ratio of their masses present in the mixture
is 2:3, calculate the ratio of their mole fraction
(A) 24:1 (B) 1:24 (C) 1:16 (D) 16:1
15. A 4:1 molar mixture of He and CH4 is contained in a vessel at 20 bar pressure. Due to a hole in the vessel, the
gas mixture leaks out. What is the composition of the mixture effusing out initially?
(A) 1:1 (B) 2:1 (C) 3:1 (D) 8:1
-1
16. Calculate root mean square speed of O2 if its density is 0.0081g L at 1atm
(A) 100 m/sec (B) 200 m/sec (C) 300 m/sec (D) 400 m/sec
-1
17. Calculate molecular diameter of He from its Vander Waal’s constant b=24 mL mol
°
(A) 1.355 A° (B) 0.338 A° (C) 2.71 A° (D) 1.92 A
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CMPC - 03 6
18. The compressibility factor for a given real gas is 0.927 at 273K and 100atm. How much gas is required to fill a
gas cylinder of 100 litre capacity under given conditions (Mol weight of gas is 30)
(A) 14.4 kg (B) 10 kg (C) 1 kg (D) 5 kg
19. The relative rates of effusion of O2 to CH4 through a container containing O2 and CH4 in 3 : 2 mass ratio will
be:
3 2 3 3 3
(A) (B) (C) (D)
4 4 2 2 2 2
20. A flask is of a capacity of one litre. What volume of air will escape from the flask if it is heated from 27°C to
37°C? Assume pressure is constant.
(A) 1 L (B) 8.033 L (C) 33.3 mL (D) 88.8 mL
SECTION III
PART A
Single Answer Questions
1. A spherical balloon of 12cm diameter is to be filled with hydrogen at STP from a cylinder containing the gas at
o
20atm and 27 C. If the cylinder can hold 3.42L of water. Calculate the no. of balloon that can be filled up?
(A) 51 (B) 65 (C) 62 (D) 58
2. An evacuated glass vessel weighs 50 g. When empty, 144 g when filled with liquid of density 0.47 g mL1 and
50.5 g when filled with an ideal gas at 760 mm Hg at 300 K. The molar mass of ideal gas is:
(A) 61.5 (B) 130.98 (C) 123.75 (D) 47.87
3. Which of the following graph is consistent with ideal gas behaviour?
(A) (B)
P1
P2 > P1
T1 >T2
P2
P
V
T1
T2
V
T(K)
(C) (D)
T2>T1 T2>T1
T2
T2
T1
P PV
T1
1/V P
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CMPC - 03 7
3
4. How many moles of nitrogen are present in 200cm sample of the gas at a pressure of 1atm and a
temperature of 27°C?
(A) 0.08 mol (B) 0.008 mol (C) 0.076 mol (D) 0.007 mol
5. Calculate the volume occupied by 7g of acetylene gas at 47°C and 740mm pressure
(A) 7.72 lit (B) 6.97 lit (C) 7.25 lit (D) 6.52 lit
6. What mass of calcium carbonate decomposed to produce 1.8L of CO2 gas at 0.72 bar and 300K.
(A) 5.268 g (B) 5.628 g (C) 5.862 g (D) 5.682 g
7. Dalton’s law of partial pressures is not applicable to
(A) Mixture of H2 and CO2 (B) Mixture of NH3 and HCl
(C) Mixture of H2 and N2 (D) none
8. A mixture of 80ml of H2 and 80 ml of O2 is allowed to effuse through an effusion meter till the residual gas
occupies 150ml. What is the composition of residual gas?
(A) 76mL,74mL (B) 73mL, 77mL (C) 75mL,75mL (D) 72mL,78mL
23 -19 3
9. Calculate the pressure exerted by 10 gas particles each of mass 10 g in a container of volume of 7dm . The
7 -1
root mean square speed is 10 cms
(A) 5.12 x1012 pa (B) 4.52 x1012 pa (C) 4.76 x1012 pa (D) 5.54 x1012 pa
10. The compressibility factor of gases is less than unity at STP. Therefore
(A) Vm>22.4 L (B) Vm<22.4 L (C) Vm=22.4 L (D) Vm=4.8L
**********
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CMPC - 03 8
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