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Chemistry Ak

lala

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KASPER UCHIHA
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0% found this document useful (0 votes)
42 views11 pages

Chemistry Ak

lala

Uploaded by

KASPER UCHIHA
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 11

Answer key

CHEMISTRY
CLASS 12
1. D 1
O
LiAlH 4
CH 3 − CH − C − NH 2 ⎯⎯⎯→
Ether
CH 3 − CH − CH 2 − NH 2

2. A 1
Secondary carbocation is more stable than primary carbocation & stability
directly proportional to number of resonating structures
3. A 1
i) C
ii ) B
iii ) A
4. D 1
PCl5 KCN Hydrolysis
CH3OH ⎯⎯⎯
→CH3Cl ⎯⎯⎯
→CH 3CN ⎯⎯⎯⎯→CH 3COOH
5. C 1

t1/2 =
 R0 
2K
4.62  10−2
t1/2 =
2  2.31  10−2
t1/2 = 1 sec
6. B 1
O3
CH3 − CH = CH − CH3 ⎯⎯⎯⎯
Zn/ H O
→ 2CH3 − CHO
2

The mass of CH 3 − CHO is 44u


7. D 1
Calculate oxidation number of Nickel
x + −1( 4 ) = −2
x = +4 − 2
x = +2
Ni  Ar  4s 2 3d 8
Oxidation number is +2 so remove 2 electrons
Ni 2+  Ar 3d 8 4s 0
Fill the electrons coming from ligands. Cl is a weak ligand so electron pairing
does not takes place

Page 1 of 11
Due to presence of unpaired electrons in 3d- orbital the complex is
paramagnetic.
8. B 1
Cellulose is polymer of  − D − glucose
9. B 1
− Ea / RT
K = Ae
− Ea 1
log K =
2.303R T
− Ea
slope =
2.303R
log K

1
T
−1.18 105
Slope = = −6162
2.303  8.314
10. B 1
2+
Ni has two unpaired electrons so
 = n ( n + 2 ) BM
 = 2 ( 2 + 2 ) BM
 = 2.828 BM
11. B 1
LiAIH 4 in ether is not used because I give Azobenzene but not aniline.

12. A 1
Aldehydes & ketones react with 2,4- DNP and give yellow or orange
precipitate.

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13. A 1
Ethylene diamine is a bidentate ligand so it can form chelate complex
14. D 1
For strong electrolytes molar conductivity increases instantly because they
undergo complete.
Reason is true because they all are strong electrolytes.
15. B 1

This reaction indicated presence of six carbons in straight lines.


Reason is true but not correct explanation.

16. D 1
Activation energy directly proportional to temperature.
Reason is correct

17. Solution shows negative deviation from Raoult’s law. 1


+1
(b) 64.50C. Chloroform and acetone form maximum boiling azeotrope so its
boiling point is more than both the components.

Page 3 of 11
OR

18. [FeF6 ]4-has 4 unpaired electrons 1/2


and [Fe(CN)6]4- has zero unpaired electron x4
b. ionization isomerism =2
BaCl2 test: compound 1 gives white ppt of BaSO4 .
AgNO3 test: compound 2 gives yellow white ppt of AgBr

19. A .i. 3F = 3 . 96500


ii. 5F = 5 . 96500
b. ii

+ −
At cathode 2H + 2e → H 2
20. (i) Vinyl chloride is unreactive in nucleophillic substitution reaction 1+
because due to resonanace there is partial double bond character 1

Page 4 of 11
between C = Cl bond which is difficult to break.
(ii) butan-2-ol should be optically active. But the (-) and (+)
enantiomers of butan-2-ol, both exist in equal amounts, so both rotate
the light in opposite directions in equal amounts. So, rotation of both
enantiomers cancel out by each other.

21. (i) RNA contains adenine (A), uracil (U), cytosine (C), and guanine (G). 1
The key difference is that RNA contains uracil (U) instead of thymine
(T), which is found in DNA
(ii) Vitamins are essential for us because they protect us from different
diseases. Every vitamin is specific in its function.
1
The deficiency of vitamin A leads to xerophthalmia (hardening of the
cornea of the eye) and night blindness. The deficiency of vitamin C leads
to scurvy (bleeding gums).

22. Ect 1+
W= 1
96500
3.6  96500
t= = 19300sec
12  1.5 ½
eac
(b) When CuSO4 is electrolysed, copper gets deposited at cathode and oxygen h
gas is released at anode. At cathode reduction of Cu2+ occurs (as it requires
lesser electrode potential than H+)
Cu2+ + 2e- → Cu
At anode oxidation of water occurs (as it requires lesser electrode potential to
get oxidized than SO4 2- )2H2O → O2 + 4H+ + 4e-
23. 1
eac
h

Page 5 of 11
24. 3

25. 3

26. 1
eac
h

27. 1 (a) Melting point order m-dicholrobenzene < o-dicholrobenzene < p- 1


dicholrobenze symmetrical structure and close packing in para isomer
,ortho has a stronger dipole dipole interaction as compared to meta.
Boiling point order o-dicholrobenzene > p-dicholrobenze > m-

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dicholrobenzene
1
(b) 2 chlorobutane has chiral carbon so will give racemic mixture but not
1
2- chloro -2- methylpropane.
28. 3
(a) Zinc chloride ZnCl2 act as electrolyte and combines with NH3, released
from NH4Cl present in the cell to form the complex salt [Zn(NH3)2 Cl2].
Otherwise the pressure developed due to released NH3 would crack the seal of
the cell.
(b)

29. (a) Zero order reaction

(b)
(c)

30. (a) (CH3)3N, N, N–dimethyl methanamine 1


(b)

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1+

(c)
(i)

½
eac
h

(ii)

OR

31. (a) (i)

(ii)

(b)

Page 8 of 11
OR
(a)

(i)

(ii)
(b)

(c) Potassium hexacyanidomanganate (II)

32. a. 1
(i) The reaction of ethanol with acetyl chloride is carried out in the presence of
pyridine . Pyridine is a strong organic base .The function of pyridine is to remove HCl
formed in the reaction.

(ii)As the given alkyl halide is tertiary ,on reaction with sodium methoxide
1
,elimination reaction take place of substitution and hence alkene formed.
(b) The major product formed when 2-cyclohexylchloroethane undergoes
dehydrohalogenation reaction is 1- cyclohexylethene. The reagent which is used to 1
carry out the reaction is ethanolic KOH.
(c)

Page 9 of 11
1

1
OR
(a)
1

1+
1
(b)

(c)

Page 10 of 11
33. 5

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