SUMMARY OF QUESTIONS ASKED IN PREVIOUS BOARD EXAMS

1 SOLID STATE
(1) Distinguish between crystalline solid and amorphous solid. (March 2013, 2014, 2017) (2)
(2) Gold occurs as face centered cube and has a density of 19.30 kg dm3. Calculate atomic radius of gold.
(Molar mass of Au = 197) [Ans. r= 144 pm] (March 2013) (2)
(3) Calculate the number of atoms present in 2 gram of crystal which has face-centered cubic (fcc) crystal lattice
having edge length of 100 pm and density 10 gcm. [Ans. 8 x 1023 atoms] (Oct. 2013) (3)
(4) What are Schottky defect and Frenkel defect? (Oct. 2013) (2)
(5) Face centered cubic crystal lattice of copper has density of 8.966 gcm3, Calculate the volume of
the unit cell. Given molar mass of copperis 63.5 g-mol-! and Avogadro number N, is 6.022 x 102.
[Ans. 4.702 x 1023 cm (March 2014) (3)
(6) Aunit cellof iron crystal has edge length 288 pm and density 7.86 g.cm3. Find the number of atoms per unit
cell and type of the crystal lattice. [ Given: Molar mass of iron = 56 g- mot';
Avogadro's Number, N, = 6. 022 x 1023.] [Ans. 2, Type-bcc] (Oct. 2014) (3)
(7) Explain impurity defect in stainless steel with diagram. (March 2015) (2)
(8) Niobium crystallises as body centered cube (BCC) and has density of 8.55 kg/dm°.
Calculate the atomicradius of niobium. (Given: Atomic mass of niobium= 93). (Ans. 0.143 nm](March 2015) (3)
(9) Silver crystallises in F.C.C. (face-centered cubic crystal) structure. The edge length of the
unit cell is found to be 408.7 pm. Calculate density of the unit cell.
[Given : Molar mass of silver is 108 g. mot l1. [Ans. 10.51 gcm-] (Oct. 2015) (3)
(10) What is ferromagnetism? Iron (Z = 26) is strongly ferromagnetic. Explain. (March 2016) (2)
(11) Silver crystallises in FCC structure. If density of silver is 10.51 g.cms, calculate the volume of unit cell.
[Atomic mass of silver (Ag) = 108 g. mot'] [Ans. 68.24 x 10-24 cm3 (March 2016) (3)
(12) A face centered cube (FCC) consists of how many atoms? Explain. (July 2016) (2)
(13) Determine the density of Cesium chloride which crystallizes in BCC type structure with the edge length
412.1 pm. The atomic masses of Cs and C1 are 133 and 35.5 respectively. Predict the co-ordination number of
Cst ion if ro,t = 1.69 Åand = r-= 1.81 ¢. [Ans. 4 gcm; C.N. = 8] (July 2016) (3)
(14) Calculate the percentage efficiency of packing in case of simple cubic cell. [Ans. 52.4 %] (March 2017) (2)
(15) Calculate the number of atoms in a unit cell of a metal crystallising in face centered cubic structure.
[Ans. 4 atoms] (March 2017) (2)
(16) Classify the following molecular solids into different types:
(a) Ammonium phosphate (b) Brass (c) S, molecule (d) Diamond.s S(July 2017) (2)
(17) A metal crystallises into two cubic faces namely face centered (FCC) and body centered (BCC,.
whose unit cell edge lengths are 3.5 Å and 3.0 ¢ respectively. Find the ratio of the densities of
FCC and BCC. [Ans. d, :d, = 1.26] (July 201 7) (3)
(18) Ionic solids are hard and brittle. Explain. (March 2018) (2)
cell is 2.8 Åand
(19) The density of iron crystal is 8.54 gram cm3, If the edge length of unit
cell.
atomic mass is 56 gram mol-!, find the number of atoms in the unit
2.017s 21
[Given: Avogadro's number = 6.022 x 1023, 1 Å=1 x10-8 cm] [Ans. Z = (March 2018) (3)
(20) Classify the following molecular solids into different types:
(a) HC1(b) CO, (c) Solid ice (d) SO, (July 2018) (2)
(21) The density of silver having atomic mass 107.8 gram mol is 10.8gram cm°. If the edge length of cubic unit
the unit cell.
cell is 4.05 x 10-8 cm, find the number of silver atoms in
(N, =6.022 x 1023, 1¢ =1o8 cm) [Ans. Z= 4.009 4] (July 2018)(3)
number of anions in hexagonal closed packed structure?
(22) What is the ratio of octahedral holes to the
[Ans. 1: 1] (March 2019) (1)
crystalline solids and amorphous solids. (March 2019) (3)
(e3) Define Anisotropy. Distinguish between cubic crystal. nUuly2019) (1)
length in body centered
(44) Give the relation between radius of atom and edge
molecule (iv) Brass.
O) Classify the following solids : (1) Diamond (ii) NaCl (1l1) P4 (July 2019) (3)
What is Schottky defect?
(c) Diamond (d) NaCI (March 2020) (2)
Classify the following into different types: (a) Silver (b) P, of 7.86 g cm,Determine the type
Unit cell of a metal has edge length of 288 pm and density[Ans. bcc] (March 2020) (3)
56g mol)
Of crystal lattice. (Atomic mass of metal = simple cubic crystal lattice? (Sept. 202 1) (1)
What is the coordination number of atoms in What is the number of
structure.
(29) A compound forms hexagonal close packed (hcp)
Total voids formed in 0.4 mol of it?
(1) Octahedral voids (1i Tetrahedral voids (lii) (Sept. 202 1) (3)
[Ans. (1) 2.4098 x 10°; (H) 4.818 x 1023; (ili) 7.227 x 1023:1
(305)
 306 UTTAM's XII Chemistry Papers Solution.
(30) Write the consequences of Schottky defect with reasons. (March 2022) (2)
(31) Gold crystallises into face -centred cubic cells, The edge length of unit cell is 4.08 x 10- cm.
Calculate the density of gold.[Molar mass of gold - 197 gmol-'|[Ans. 19.27 x 10kg dm} (March 2022) (2)
(32) Explain metal deficiency defect with example. (March 2022) (2)
(33) Distinguish between Schottky and Frenkel defect. (July 2022) (2)
(34) Calculate the number of atoms and unit cell present in 0.5 g of Niobium if it forms
body centred cubic structure, The density of Niobium is 8.55ofgunit em'cells
and=edge length of unit cell is 330.6 pm.
1.62 x 10211
[Ans. No. of atoms = 3.25 x 1021, No. (July 2022) (2)
(35) Explain the following terms: (a) Substitutional impurity defect (b) Interstitial impurity defect. (March 2023) 12
(36) Silver crystallizes in fee structure. If edge length of unit cellis 400 pm,gcm-3,]
calculate density of silver.
(Atomic mass of Ag = 108). [Ans.The density of silver (p) = 11.20 (March 2023) (2)
(37) Write the number of particles present in FCC per unit cell. (July 2023) (1)
(38) An element with molar mass 27 g/molforms cubic unit cell with edge length of 405 pm If density of
the element is 2.7 g/em³ what is the nature of cubic unit cell? (Ans. n=4, : fcc (July 2023) (3)
(39) Define isomorphism. (July 2023) (1)
(40) Derive the relationship between molar mass, density of the substance and unit cell edge length. (March 2024) 12
(41) Predict the type of cubic lattice of a solid element having edge length of 400 pm and
density is 6.25 g/ml. (Atomic mass of element = 60). [Ans. n = 4, :. fcc (March 2024) (2)
2 SOLUTIONS

(1) Derive the relationship between relative lowering of vapour pressure and molar mass of
non-volatile solute. (March 2013, 2017) (2)
(2) Define osmosis. (March 2013) (1)
(3) What is boiling point? (March 2013) (1)
(4) State Henry's law. How does solubility ofa gas in water varies with the temperature? (Oct. 2013; July 2017) (2)
(5) Define Isotonic solution'. (March 2009, Oct. 2013) (1)
(6) Calculate the amount of CaCl,2 (van't Hoff factor, i =2.47) dissolved in 2.5 L solution so that
itsosmotic pressure at 300K is 0.75 atmosphere.
[Given: Molar mass of CaCl, is 11l g. mot',R = 0.082 L. atm K' mot!.] [Ans. W= 3.425 g] (March 2014) (3)
(7) Explain, why do aquatic animals prefer to stay at lower level of water during summer? . (March 2014) (2)
(8) A solution containing 0.73 g of camphor (molar mass 152 g.mol-) in 36.8 g of
acetone (boiling point 56.3°C) boils at 56.55°C. A solution of 0.564 g of
unknown compound in the same weight of acetone boils at 56.46°C. Calculate the molar mass
of the unknown compound. [Ans. 183.5 gmol-] (Oct. 2014) (3)
(9) Defne van't Hoff factor. How is it related to the degree of dissociation? (Oct. 2014) (2)
(10) Define: Cryoscopic constant. (Oct. 2014, July 2018) (1)
(11) Derive van't Hoff general solution equation. (March 2015, 2019; July 2017) (2)
(12) 1.0 x 10-3 kg of ureawhen dissolved in 0.0985 kg of a solvent, decreases freezing point
of the solvent by 0.211 K. 1.6 x10-3 kg of another non-electrolyte solute when dissolved
in 0.086 g of the same solvent depresses the freezing point by 0.34 K. Calculate the
molar mass of the another solute. (Given: Molar mass of urea = 60] [Ans. 68.28 g-mol-] (March 2015) (3)
(13) Define ebullioscopic constant. Write its unit. (Oct 2015) (2)
(14) What is the effect of temperature on solubility of gas in a liquid? (Oct 2015) (2)
(15) Defne boiling point.Write the formula to determine molar mass of a solute using freezing point
depression method. (March 2016) (2)
(16) The vapour pressure of pure benzene is 640 mm of Hg. 2.175 x 103 kg of non-volatile
solute is added to 39 gram of benzene, the vapour pressure of solution is 600 mm of Hg.
Calculate molar mass of solute. [C = 12, H= 1]. [Ans. 69.6 x 10- kg] (March 2016) (3)
(17) Why is molality of a solution independent of temperature? (March 2016) (1)
(18) Define: (a) Osmosis (b) Freezing point. (July 2016) (2)
(19) 3.795 gof sulphur is dissolved in 100 g of CS,. This solution boils at 319.81 K. What is the molecular
formula of sulphur in solution? The boiling point of CS, is 319.45 K.
[Given that K, for Cs, - 2.42 Kkg mol-! and atomic mass of S = 32.) [Ans. S,] (July 2016) (3)
(20) State Henry's law. (July 2016) (1)
(21) A solution of a substance having mass 1.8 x 103 kg has the osmotic pressure
of 0.52 atm at 280K. Calculate the molar mass of the substance used.
[Volume = ldm³, R= 8.314 JK-' mot!] [Ans. 79.49 g-mol-] (March 2017) (2)
 307
Summary of Board Questions
(22) The boiling point of benzene is 353.23 K. When 1.80 gram of non-volatile solute was dissolved in
90 gram of benzene. The boiling point is raised to 354.11 K. Calculate the molar mass of solute.
|K, for benzene = 2.53 K mot} [Ans. 57.5 g- mol-1] (March 2017) (2)
(23) State Henry's Law. How does solubility of a gas in water varies with temperature? (July 2017) (2)
(24) Define: (a) Molality (b) Osmotic pressure. (July 2017) (2)
(25) An organic substance (M = 169 gram mol) is dissolved in 2000 cm³ of water. Its osmotic pressure
at 12°C was found to be 0.54 atm. If R=0.0821 Latmn. Kl mol1, calculate the mass of
[Ans. 7.796 gl (July 2017) (2)
the solute.
(26) Derive the relation between elevation of boiling point and molar mass of solute. (March 2018) (2)
(March 2018) (1)
(27) Define: Semipermeable membrane.
(28) (a) State Henry's law
Calculate the number of
(b) 22.22 gram of urea was dissolved in 300 grams of water.
moles of urea and molality of the urea solution.
0.1234 mol kg] (March 2018) (2)
(Given: Molar mass of urea - 60 gram mot') [Ans. 0.3703 mol; (July 2018; March 2019) (2)
solute.
(29) Derive van't Hoff general solution equation for n' moles of Calculate the
point of pure benzene is 278.4 K.
(30) What is freezing point of a liquid? The freezing
freezing point of the solution when 2.0 gram of a solute having molecular weight 100 gram is
277.376 K] (July 2018) (3)
added to 100 gram of benzene. [K, for benzene = 5. 12 kg mot| [Ans. T=
(31) Define the following terms: (March 2019) (3)
(i) Isotonic solution (ii) Hypertonic solution (iii) Hypotonic solution.
constant and
(32) Define osmotic pressure. Write mnathematical expression between cryoscopic (July 2019) (2)
molar mass of solute.
(33) Derive n= CRT. (July 2019) (2)
(34) Define the following: (i) Molality (ii) Mole fraction. (July 2019) (2)
(35) What is the concentration of dissolved oxygen at 50°C under pressure of one atmosphere
if partial pressure of oxygen at 50°C is 0.14 atm.
(Henry's law constant for oxygen= 1.3 x 10-8 mol dm-3 atm-') [Ans. 1.82 x 10-4 mol- dm-3] (March 202O) (1)
(36) Define: (a) Molality (b) Osmotic pressure. (March 2020) (2)
(37) Derive the mathematical expression between molar mass of a non -volatile solute and
elevation of boiling point. State and explain van't Hoff- Avogadro's law. (March 2020) (4)
(38) Define 'Cryoscopic constant'. Derive the relation between elevation of boiling point and
molar mass of solute. (Sept. 202 1) (3)
(39) What is the molar mass of a solute if a solution prepared by dissolving 0.822 g of it in
0.3 dm of water has an osmotic pressure of 0.196 atm. at 298 K? [Ans. 341.9 gmol-'] (Sept. 202 1) (3)
(40) Derive an expression to calculate molar mass of non volatile solute by osmotic pressure
measurement. (March 2022) (2)
(41) Henry's law constant for CH,Br, is 0.159 mol dm-3 bar- at 25°C.
What is solubility of CH,Br, in water at same temperature and partial pressure of 0.164 bar ?
[Ans. 0.026 mol dm-3| (March 2022) (2)
(42) Define the following terms: (i) Isotonic solution (ii) Osmosis. (March 2022) (2)
(43) Define: (i) Osmotic pressure (ii) Ebullioscopic constant. (July 2022) (2)
point of 271 K. Calculate freezing point of
(*) 5%% aqueous solution of cane sugar has freezing (July 2022) (2)
K]
S% glucose solution. (Molar mass of cane sugar = 342 g mol-] [Ans. 269.2 solute
TO) The normal boiling point of ethyl acetate is 77.06 °C. A solution of 50g of non-volatile
K, for ethyl acetate is
n 150g of ethyl acetate boils at 84.27°C. Evaluate the molar mass of solute if (July 2022) (2)
2.77 Kkg mol-'. [Ans. 128 g mol]
(46) Write the SI unit of cryoscopic constant. (March 2023) (1)
(47) Define osmosis. How will you determine molar mass of non-volatile solute by elevation of
(March 2023) (3)
boiling point.
O) Calculate the mole fraction of solute, if the vapour pressure of pure benzene at certain temperature is
in benzene is 600 mm Hg.
TO mmn Hg and vapour pressure of solution of a solute [Ans. Mole fraction = 0.0621 (March 2023) (2)
non-volatile solute in
he normal boiling point of ethyi acetate is 77.06°C. A solution of 50 g of a
for ethyl acetate is
150 g of ethyl acetate boils at 84.27°C. Evaluate the molar mass of solute if K,
2.77°C kg mol-. [Ans. M, = 12.8 g mol-] (July 2023) (2)
Define: Ebullioscopic constant. Derive the relation between freezing point depression and
molar mass of (July 2023) (3)
solute. (March 2024) (1)
o1) Write the condition of reverse osmosis.
308
UTTAMs Chernistry Papers Soution
XIl in
(52) Henry's constant for CH,Br, is 0.159 mol dn-3-bar at 25'C. Calculate its solubility
0.164 bar
water at 25'C, if its partial pressure is [Ans. S -
(53)What is osmotic pressure ? How will you determine molar mass of 0.0260 mol L-]
solute frorm osrnotic pressure? (March 2024) (2)
3 (March 2024) (31
IONIC EQUILIBRIA
(1) Derive the relationship between pH and pOH.
12 solubility
Define Solubility product. Derive the relationship between solubility and (Sept. 202 1, March 2022) (2)
product for Pbl,.
I Calculate the pH of buffer solution composed of 0.01 M weak base BOH and (Sept. 2021) (3)
0.02 Mof its salt BA. (K, - 1.8 x 10-5for weak basel [Ans. pH - 13.95]
enH of solution is 3.12. Calculate the (March 2022) (3)
concentration of H,0* ion. [Ans. 7.568 x 10- M1
(5) Derive an expression of Ostwald's dilution law for weak acid. Jhuty 2022) (2)
i6) Defne: Acidic buffer solution. Write the relationship between solubility
and solubility Jhuly 2022) (2)
for PbCl, product
mAweak monobasic acid is 10% dissociated in 0.05 M solution. What is (March 2023) (3)
percent dissociation in 0.15 M soluticn 2
[Ans. % dissociation - 5.74%] (March 2023) (2)
(S) Derive Ostwald's dilution law equation for weak acid.
(9) Define: Buffer solution. Write any four applications of buffer Jhuly 2023) (2)
solution. Jhuty 2023) (3)
(10) Explain buffer action of sodium acetate - acetic acid buffer.
(11) Define acids and bases according to Bronsted -LowTy theory. Derive (March 2024) (2)
between pH and OH. relationship
(March 2024) (3)
4 CHEMICAL THERMODYNAMICS
(1) Prove that AH = AU+ AnRT. What is the condition under which
AU= AH? March 2013) (2)
(2) 300 mol of perfect gas occupies 13L at 320 K. Calculate the work done in
joules when the gas expands
(a) isothermally against a constant external pressure of 0.20 atm.
(b) isothermal and reversible process.
(c) into vacuum until the volume of gas is increased by 3L.. (R= 8.314 J motK)
[Ans. (a) -60.78 J (b) -165.8 J (c) 0] (March 2013) (2)
(3) Explain with reason sign conventions of AS in the following reactions:
() Nag t 3H2g
(ü) CO2e 2NH3g (March 2013) (2)
(4) Calculate AH° for the following reaction:
2H,BO3aq) > B,0sj) + 3H,0,
Given that: (a) H,BO3ag) + HBO2ag) t H,On: AH = -0.02 kJ
(b) H,B,079) 2B,O3) t H,Op H, =17.3 kJ
(e) H,B,07s) t H,O ’4HBO2ag, AH, - - 11.58 kJ [Ans. AH° -+14.40 kJ] (Oet. 2013) (3)
(5) What are the conditions for spontaneous and non- spontaneous reactions in terms of
free energy change? Define entropy. (Oct. 2013) (2)
(6) Derive the relation AH - AU = AnRT. (Oct. 2013) (2)
(7) Derive a relation between AH and AU for a chemical reaction. March 2014) (2)
(8) One mole of agas expands by 3L against a constant pressure of3 atmosphere. Calculate the work done in -
(a) L. atmosphere (b) Joules (c) Calories. (Ans. (a)-90L-atm (b) -911.7 J (c) - 217.98 cal. ] March 2014) (3)
(9) Derive the relation between AG° and equilibrium constant (K) for the reaction
aA + bB cC t dD March 2014) (2)
(10) What is the value of AS.for the following reaction at 298K?
6c02 t 6H,O, +CH,Oss) t 602g.
Given that, AG® =2879 kJ moll as =-210 J K' mol, [Ans. -9.451 kJ] (Oet. 2014) (3)
(11) State and explain Hess's law of constant heat summation. (Oct. 2014; July 2018; March 2020) (2)
(12) Derive the equation:W =- Pea AV. (March 2015) (3)
(13) Define the following terms: (a) Enthalpy of fusion (b) Enthalpy of atomization. March 2015) (2)
(14) Determine whether the reactions with the following AH and AS values are spontaneous or non-spontaneous.
State whether the reactions are exothermic or endothermic.
la) AH= -110 kJ, AS= +40 JK at 400 K (b) AH=+ 40 kJ, AS = -120 JK at 250 K.
[Ans. (a) spontaneous and exothermic (b) non- spontaneous and endothermic] (March 2015) (3)
(15) Write one statement of first law of thermodynamics and its mathematical expression. (Mareh 2015) (2)
 16) Derive an
expression for maximum work in isothermal reversible 309
expansion of two moles of an ideal gas.
(17) The equilibrium constant K, for the
Ha t Lyle reaction (Oct. 2015) (2)
2H1,, is 130 at 510 K. Calculate AG for
2Hl Ha tL the following reaction at the same
/Given:R8.314
I18) State: (a) Second Iaw of JK mot |Ans. AG-20490 J] temperature.
thermodynamics in terms of entropy (Oet. 2015) (3)
(b) Third law of
(19) Write mathematical thermodynamics. (Oet. 2015) (2)
equations of first law of
process (b) Isochoric process. thermodynamics for the following processes:
(a) Adiabatic
(20) Define Enthalpy of sublimation. How is it (March 2016) (3)
related to enthalpy of fusion and enthalpy of
(21) Calculate C- Cl bond enthaply from
vaporization?
following (March 2016) (2)
CH,Cl Clae reaction:
CH,CtHCI AH104 kJ ifC- H, Ci - Cl andH-CI bond enthalpies
are 414, 243 and 431 kJ-mol
(22) Explain the respectively. | Ans. 330 kJ mo]
relationship between Gibb's standard energy change of the reaction and equilibrium (March 2016) (3)
July 2016)
constant.
(23) Calculate the standard enthalpy of the reaction, (2)
2Cephite)t 3Hae +CHeid : AH" - ? from the following, AH° values:
7
+3H,Ou : AH" =-1560 kJ

(D) Ha : AH°=-285.8 kJ
(c) Cjraphite) +O2g
(24) Define the term 'enthalpy'.
CO2( :AH°--393.5 kJ. [Ans. AHO -84.4 kJ] July 2016) (3)
What will happen to the internal energy if work is done by
the system?
(25) Calculate AH° for the reaction between ethene and
water to form ethyl
(March 2017) (2)
alcohol from the following data :
AH°C,H_OH - 1368 kJ ; AH°C,H4j -1410 kJ.
Does the calculated AH" represent the enthalpy of formation of liquid
ethanol ?
[Ans. AH =42 kJ, is not enthalpy of formation of liquid
(26) Derive an expression for maximum work. ethanol.] (March 2017) (3)
(27) Write the mathematical expression of the first law of March 2017) (2)
(a) Isothermal (b) Adiabatic (c) Isochoric (d) Isobaric.thermodynamics
for the following processes
(28) Calculate the standard enthalpy of combustion of July 2017) (2)
CH,COOH,, from the following data:
4,H°(CO,) = 393.3 kJ mol; A,H° (H,O) =- 285.8 kJ mol; 4,H° (CH,cOOH) =- 483.2 kJ mol!
[Ans. AH° =-875 kJ mol-.J (July 2017) (3)
(29) Distinguish between isothermal process and adiabatic process.
(30) State third law of thermodynamics. Give its two uses. July 2017) (2)
(31) Calculate the internal energy at 298K for the formation of one mole of (March 2018) (2)
ammonia, if the enthalpy change at
constant pressure is -42.0 kJ mol. (Given: R= 8.314 JK mol-) [Ans. -39.523 kJ] (March 2018) (3)
(32) Define: (a) Enthalpy of atomization (b) Enthalpy of vaporization. (March 2018) (2)
(33) 5 moles of helium expand isothermally and reversibly from a pressure 40 x 105 Nm² to 4 x 105 Nm at 300 K.
Calculate the work done, change in internal energy and heat absorbed during the expansion.
(R-8.314 JKl mol') [Ans. W,,may - -28.720 kJ, AU = 0, q = 287.720 kJ] July 2018) (3)
(34) State and explain Hess's law of constant heat summation. July 2018; March 2020; 2022) (2)
(35) Write the features of reversible procesS. uly 2018) (2)
(36) Write the conditions for maximum work done by the system. (March 2019) (2)
(o7 Calculate the work done in the following reaction at 50°C. State whether work is done
on the system or by the system.
1
+SOaol [Ans. W=+1.343 kJ; Work is done on the systemn. 1
SOz122)
o8) The standard enthalpy of combustion of formaldehyde A, H° =- 571 kJ.
(March 2019) (3)

How much heat willbe evolved in the formation of 22 gof Co,? [Ans. 285.5 kJ] (March 2019) (3)
(39) Conversion of carbon into carbon dioxide can not perform the work. Give reason. (July 2019) (1)
H0) Define the term enthalpy. Classify the following properties into intensive and extensive properties:
() Pressure (ii) Density (l) Work (iv) Heat. uly 2019) (3)
 310
the work done by
the following chemical
reaction:
UTTAM'S XIl Chemistry Papers Solution
(41) Caleulate 373 K
2NH, 2N,O + 4H,O
StateNO,)
whether the work is done on the system or by the system.
(Ans. Wm-18,62 kJ, work is done by the aystem. 1
(42) For the reaction:
N,O,l -2NO, AH" +57,24 kJ, Agº175,8 JK-, (July 2019) (2)
t what temperature the reaction will be spontaneous ?
JAns. T >325.6 K, the reaction will be spontaneous, I
43) Deâne: (a) Reversible process (b) Standard enthalpy of combustion,. (March 2020) (2)
Caleulate the enthalpy change for the reaction: N 3H) 2NH
The bond enthalpies are:
NN H-H NH
Bond
AH°in kJ mol 946 435 389 |Ans. AH--83 kJ |
AA) In a Darticular reaction, 2 kJ of heat is released by the system and6 k.J of workis (March 2020) (2)
done on the system, Caleulate AU,
|Ans. AUm +4 kJ]
(45) Caleulate the standard enthalpy of N,Hat H, + 2NH) (Sept. 2021) (2)
i AH°N-H) 389 kJ mol, AH°(H-H) 435 kJ mol, AH' (N-N) - 159 kJ mol!,
[Ans, -184 kJ] (Sept. 2021) (3)
(46) Define: ()Intensive property (ii) Enthalpy of sublimation.
2moles of an ideal gas are expanded isothermally and
reversibly from 20L to 30L at 300 K.
Calculate the work done. (R- 8.314 JK- mot!)
(47) One mole of an ideal gas is expanded isothermally and [Ans. 2023 J] (Sept. 2021) (4)
Calculate the work done in the process. reversibly form 10 Lto 15 Lat 300 K.
[Ans, -1.0115 kJ] (March 2022) (2)
(48) Calculate the standard enthalpy of formation of
3
CH,OH, from the following data:
() CH,OHutzi0 + CO2l9 + 2H,0,; AH° =- 726 kJ mol-1
() Ct O2i8) CO2(R : AH'=-393 kJ mol-l
1
(iü) Hg2218 AH =- 286 kJ mol-1
[Ans. A,H -239 kJ mol-'. ] (March 2022; July 2022) (3)
(49) Write the mathematical equation for the first law of thermodynamics for
() Isothermal process (ii) Adiabatic process. (March 2022) (2)
(50) Define the relationship between AH and AU for gas phase reaction. (July 2022) (2)
(51) Write the correct condition of spontaneity in terms of Gibb's energy. (March 2023) (1)
(52) Define extensive property. Calculate the work done during the expansion of 2 moles of an ideal gas from 10 dm
to 20 dm at 298 K in vacuum. [Ans. Work done = 0, Free expansion.] (March 2023) (2)
(53) 2000 mmol of an ideal gas expanded isothermally and reversibly from 20 L to 30 Lat 300K, calculate the work
done in the process (R= 8.314 JK mol). [Ans. W, max =-2023.08 J.] (March 2023) (3)
(54) Derive relationship between AH and AU for gaseous reaction. (March 2023) (2)
(55) Three moles of an ideal gas are expanded isothermally from 15 dm³ to 20 dm at constant external
pressure of 1.2 bar. Estimate the amount of work in Joules. [Ans. W=-600 J] (July 2023) (1)
(56) Calculate the standard enthalpy of the reaction:
SiO29) t 3C(graphite) SiCp +2COg
From the following reactions,
(i) Si +O2e +SiOs)2CO,;; A,H°= -911 kJ
4,H = -221 kJ
(ii) 2°(graphite) +O28)
(iü) Si, +Clgraphite) + SiCjs) ; AH = -65.3 kJ [Ans. A,H° = + 624.7 kJ] (July 2023) (3)
(57) Write any two statements of first law of thermodynamics.
For a certain reaction AH° is -224 kJ and AS° is -153 JK-'. At what temperature the change over from
spontaneous to non-spontaneous will occur? [Ans. Reaction is spontaneous below 1464 K] (July 2023) (4)
(58) Write the sign convention of work done during expansion of gas. (March 2024) (1)
(59) Derive and expression for maximum work obtainable during isothermal reversible expansion of
an ideal gas from initial volume (V,) to final volume (V,). (March 2024) (2)
(60) Calculate the standard enthalpy of combustion of methane, if the standard enthalpy of formation
of methane, carbon dioxide and water are -74.8, - 393.5 and-285.8 k J moll respectively.
[Ans. AH°= - 890.3 kJ ] (March 2024) (3)
(61) Define: () Extensive and Intensive properties (ii) Isobaric and Adiabatic processes. (March 2024) (2)
Summary of Board Questions 311

5 ELECTROCHEMISTRY
I) State Kohlrausch Law and write mathematical expression of nolar conductivity of the given solution at
infinite dilution. (March 2013) (2)
(2) Write the cell reactions in lead storage battery during discharge. (March 2013) (2)
(3) In the electrolysis of AgNO, solution 0.7 gof Ag is deposited after a certain period of time.
Calculate the quantity of electricity required in coloumb.[Molar mass of Ag is 107.9 g mot)
|Ans. 626.1 coulomb] (March 2013) (2)
(4) Write electrode reaction and net cell reaction for fuel cell. Caleulate e.m.f. of the following cel at 25 C:
Zn lZn (0.1 M) | Cuo(0.5 M) |Cu
Standard reduction potential (SRP) of Zn and Cu are -0.76 Vand 0.334 Vrespectively. (Oct. 2013) (2)
[Ans. E,el 1.114 V]
(Oct. 2013) (2)
(5) State and explain Faraday's second law of electrolysis.
15002
(6) Resistance and conductivity of a cell containing 0.001 M KCl solution at 298K are (March 2014) (2)
and 1.46 x10 S.cm- respectively. What is the cell constant ? [Ans. 0.219 crn]
(March 2014) (2)
(7) State the first and second law of electrolysis. (Oct. 2014) (2)
(8) Write any four' applications of electrochemical series.
is an intensive
(9) With the help of the equation, AG0= - nFEOa explain that cell potential
property. (Oct. 2014) (2)
(10) How much electricity in terms of Faraday is required to produce:
(a) 20 g of Ca from molten CaCl, (b) 40 g of Al from molten Al,0,
(Given: Molar mass of Calcium and Aluminium are 40g.mot' and 27g.mot' respectively.)
[Ans. (a) 1F (b) 4.4 F] (Oct. 2014) (2)
I11) Draw neat and labelled diagram of dry cell. (March 2015) (2)
12) Arrange the following reducing agents in the order of increasing strength under standard state
conditions. Justify the answer.
Element Al Cus Cag) Nig
- 1.66 V 0.34 V 1.36 V -0.26 V (March 2015) (2)
(13) Calculate Eell and AG for the following at 28°C:
Mgs + Sn2* (0.04M) + Mg (0.06M) + Sn, Ell = 2.23 V.
Is the reaction spontaneous? [Ans. Ecel =2.224 V; G=-429.2 kJ] (March 2015) (3)
(14) Can copper sulphate solution be stored in an iron vessel ? Explain. (Oct. 2015) (2)
(15) Resistance of conductivitycell filled with 0.1 MKCl solution is 10 ohms, calculate the conductivity and molar
conductivity of 0.02 MKCl solution. (Given : Conductivity of 0. 1MKCl solution is 1.29 Sm'.]
[Ans. k, = 0.00248 S- cm-, A= 124 S-cm² mol-1,] (Oct. 2015) (3)
(16) Define Molar conductivity. (March 2016) (1)
(17) Define cell constant. Drawa neat and well labelled diagram of primary reference electrode. (March 2016) (3)
(18) Conductivity of asolution is 6.23 x 10-5 r'cm and its resistance is 13710 2. If the electrodes
are 0.7 cm apart, calculate the cross-sectional area of electrode. [Ans. a =0.82 cm?] (March 2016) (3)
(19) Write Nernst equation and explain the terms involved. (July 2016) (2)
(20) The conductivity of 0.02 M AgN0, at 25°C is 2.428 x 10- 9l cm-!,
What is its molar conductivity? [Ans. A= 121.4 ' cm² mol-] (July 2016) (2)
(21) What are fuel cells? Write cathode and anode reaction in a fuel cell. (March 2017) (2)
(22) 0.05 MNaOH solution offered a resistance of 31.6 Win a conductivity cell at 298 K.
Ifthe cell constant of the cell is 0.367 cm-', Calculate the molar conductivity of NaOH solution.
[Ans. A= 232.2 Ql cm² mol-11 (March 2017) (3)
(23) State Faraday's first law of electrolysis. (March 2017) (1)
(24) Construct a labelled diagram for the following cell:
Zn|Zn2 (1 M) | H (1 M)| H,(g, 1atm) | Pt (July 2017) (2)
(25) Write the cell representation and calculate equilibrium constant for the following redox reaction:
N + 2Ag (1 M) ao(1 M) + 2Ag, at 25°C ; EN =-0.25 Vand E0A=0.799 V
[Ans. k =2.754 x 10351 (July 2017) (3)
(26) Drawa neat and labelled diagram of leadstorage battery. (March 2018) (2)
(27) Define: Reference electrode. (March 2018) (1)
l48] How many faradays of electricity are required to produce 13 gram of aluminium from aluminium chloride
solution? (Given: molar mass of Al= 27.0 gram mot) [Ans. 1.444 F] (March 2018) (3)
312 UTTAM's XII Chemistry Papers Solution
Mg?*| Mg half cell and Agt|Ag half cell and
Represent a cell consisting of write the cell reaction.
(29)
0.799 V, E°M -2.37 V)
(30) (EO,
How much quantity of electricity in coulomb is required to deposit 1.346 x 103 kg of Ag in 3.5 (July
minutes2018) (2)
(Given: Molar mass of Ag is 108 x 103 kg mot})
AgNO, solution?
from
[Ans. Q = 1214 coulomb]
(31) Define resistivity. (July 2018) (3)
(31) ny faradays of electricity are required to produce 6 gof Mg from MgCi,? [Ans, 0.50 F] (March (July 2018) (1)
solution at 25°C is 2230-1 cm-l
2019) (21
ia2 The molar conductivityof 0.05 M BaCl,
What is its conductivity? [Ans, k = 0.01 159-cm-1
series. Write its applications. (March 2019) (2)
(34) Define electrochemical (March 2019) (3)
35) The molar conductivity of 0.02 MHClsolution is 407.2 'cm² mol- at 25°C. Calculate its conductivity
[Ans. 8.144 x 10-3 9cm-1 (July 2019) (2)
(36) Draw a neat labelled diagram of H, -0, Fuel cell.
(July 2019) (2)
i37) Draw a neat labelled diagram of standard hydrogen electrode. (July2019) (2)
(38) The standard e.m.f. of the following cell is 0.463 V
Cu |Cu*,(aq) ||Ag* (ag)
|ABel
(1M) (1 M)

If the standard potential of Ag electrode is 0.800 V, what is the standard potential of Cu electrode ?
[Ans. Eº,Cu = 0.337 V] (March 2020) (1)
(39) Write the cell reaction and calculate E® cell of the following electrochemical cell:
Al,|A13 (ag) ||Zn2+ lag) |Znag)
(1 M) (1 M)
E,,
Al =- 1.66 V, E°,, = -0.76 V. [Ans. EO cell0.90 V] (March 2020) (2)
(40) Define terms: (a) Electrochemical series (b) Corrosion.
Write two applications of electrochemical series. (March 2020) (3)
2.303 RT
(41) Write the value of. in Nernst equation. (Sept. 2021) (1)
F
(42) The molar conductivity of 0.01 Macetic acid at 25°C is 18 9-1 cm² mol-l, Calculate its degree of dissociation in
0.01 M solution and dissociation constant, if the molar conductivity of acetic acid at zero concentration
is 400 cm² mol-!. [Ans, a =0.015; K,= 2.025 x10-5] (Sept. 2021) (2)
(43) State Kohlrausch law of independent migration of ions. Write and explain two applications of
electrochemical series. Write unit of cellconstant (Sept. 202 1) (4)
(44) How many moles of electrons are required for reduction of 2 moles of Zn 2+ to Zn?
How many faraday of electricity will be required? [Ans. 4 moles; 4 faraday] (March 2022) (2)
(45) Define reference electrode. Write the functions of salt bridge.
Draw neat, labelled diagram of standard hydrogen electrode (SHE). (March 2022) (4)
(46) Write relation between molar conductivity and conductivity of solution. (uly 2022) (1)
(47) Write cell representation of standard hydrogen electrode. (July 2022) (1)
(48) State Kohlraush Law of independent migration of ions. Write one application of
Kohlraush Law of independent migration of ions. (July 2022) (1)
(49) What is reference electrode ? (March 2023) (1)
(50) Calculate the molar conductivity for 0.5 M BaCl, if its conductivity at 298 K is 0.01 Q-l cm-!,
[Ans. A, = 20 21 cm² mol] (March 2023) (1)
(50) Calculate standard Gibb's energy change at 25° C for the cell reaction:
Cd, +Sn20(ag +Cq2® Po +Sngi Ec =-0.403 V, E'sn =-0.136 V. [Ans. AGº=- 51.53 kJ] (March 2023) (2)
(52) Draw labelled diagram of H,-O, fuel cell. Write two applications of fuel cell. (March 2023) (3)
(53) Write the unit of cell constant. (July 2023) (1)
(54) What is the mass of Cu metal produced at the cathode during the passage of 5 ampere current through
CusO, solution for 6000 seconds. Molar mass of Cu is 63.5 g mol-l. [Ans. W =9,872 g] (July 2023) (2)
(55) Describe the construction and working of Standard Hydrogen Electrode. Write any two difficulties
in setting SHE. (July 2023) (4)
(56) Write SI unit of molar conductivity. (March 2024) (1)
(57) Calculate the time required to deposit 2.4 g of Cu, when 2.03 Aof current passed through CuSO, solution.
(At. mass of Cu = 63.5 g' mol-l) [Ans. t = 3593 sec] (March 2024) (2)
IK8) Defneelectrochemical series and write its two applications. (March 2024) (3)
(59) Write the cellreaction during discharging of lead accumulator. (March 2024) (1)
 313

Questions
Summary of Board
CHEMICAL KINETICS
6
molecularity and order of the reaction. 2014) (2)
(1) Distinguish between Oct. 2008, 2009, 2010, 2013,
(March 2008, 2009, 2011, 2020;
reaction:
(2) Consider the d(80,,2 x10-2 M/s.
time t,
2 ng) + 2SO,n at particular dt
same time?
Whatare the values of the following at the
d[1| d|S,0,| -d[,1
(b dt (March 2013) (3)
(a) - dt
dt
10-2 M/s (b) 1.1 x 10-2 M/s (e) 1lx 10-2 M/s]
[Ans. (a) 3.3 x of which rate constant
becormes
energy. Calculate activation energy for a reaction
R8.314 JK motl)
(3) Define activation changes from 30°Cto50°C. (Given (Oct.2013) (3)
four times when temperature |Ans.E, - 56,4 kJ mol-!.1
following reaction: (March 2014) (1)
(4) Write molecularity of the reaction:
2NO,+O2lg 2NO2) according to the following equationfollows first order
decomposition of N,Osie at 320K
(5) The 1

N,Osie 2NO212 2i0 60 minutes, 0.20 x 10 mol. L1,

concentration of N,Osita is 1.24 x 102 mol. L-! and after (March 2014) (3)
The initial [Ans. k = 0.0304 min-|
reaction at 320 K.
Calculate the rate constant of the reaction. (March 2014) (2)
period and rate constant for first order
(6) Derive the relation between half-life according to the first order rate law.
(7) Sucrose decomposes in acid solution to give glucose and fructose after 8 hours.
Calculate fraction of sucrose which will remain
The half life of the reaction is 3 hours. [Ans. 0.1576] (Oct. 2014; March 2015) (3)
constant for a first order reaction. (March 2015, 2017) (2)
(8) Derive the relation between half life and rate reaction. (Oct. 2015) (2)
Instantaneous rate of
(9) Define: (a)Average rate of reaction (b)
(10) Ammonia and oxygen react at high temperature as:
4NHs +50219 3.6 x 10-3 mol L-, s-1
In an experiment, rate of formation of NO,, is
of water.
Calculate: (a) Rate of disappearance of ammonia. (b) Rate of formation
[Ans. (a) 3.6 x 10- mol·L-l.s (b) 5.4 x 10-3 mol·L -. l] (Oct. 2015) (3)
(March 2016) (1)
(11) Define Zero order reaction'.
energy of a reaction. (March 2016) (2)
(12) Explain graphical method to determine activation
compound remains unreacted in 45 minutes.
(13) In a first order reaction x’y, 40% of the given sample of
Calculate rate constant of the reaction. [Ans. 0.02036 min-1 (March 2016) (2)
0.58 s at 313 K and 0.045 s-! at 293 K.
(14) The rate constant of a first order reaction are
What is the energy of activation for the reaction? [Ans. 96.85 kJ mol-!] July 2016) (3)
(15) Write the Nernst equation and explain the terms involve. July 2016) (2)
(16) In the Arrhenius equation for a first order reaction, the values of A' and E.'are 4 x 1013 sec-l
and 98.6kJ mol respectively. At what temperature will its half life period be 10 minutes?
R=8.314 JK-' mot] [Ans. T = 311.5 K] (March 2017) (3)
(17) The rate law for the reaction
2H, t 2NO +2H,0, is given by rate =K[H,] |NO?
The reaction occurs in the following two steps:
(a) H, + 2NO,
(b) N,O+H210
What is the rate of N.O in the mechanism ?What is the molecularity of the elementary steps? (uly 2017) (2)
(18) From the following data for the liquid phase reaction A- B, determine the order of reaction and calculate its
rate constant:
t/s 600 1200 1800
[A]/mol L1 0.624 0.446 0.318 0.226[Ans. First order; 5.6 x10-* s-'] (July 2017) (3)
(19) Acertain reaction occurs in the following steps:
(1) C t Oge
(i) Clo, +Oe Clt O28
la) What is the molecularity of each of the elementary steps?
(b) Identify the reaction intermediate and write the chemical equation for overall reaction. (March 2018) (2)
 UTTAM's XII Chemistry Papers Solution
314 products is first order in each of the reactants.
reaction A + B
(20) The
the rate of
reaction change if the concentration of Ais increased by factor 3?
(a) How does changein the rate of reaction if the concentration of Ais halved and concentration
the
(b) What is doubled?IAns. (a) The rate of reaction is increased by factor 3
ofB is (b) The rate of reaction remains unchanged.]
reaction.
(March 2018) (2)
Define the order of chemical
(21) following reactions:
the overall order of the
Bind
+ Cclj + HCl Rate - kjCHCI,| [CL,|
(a) CHCl_jg) +Clje k|NOo]' (o,| [Ans. (a) 2 (b) 31
(b) 2NO,@ +Oe 2NO@) Rate (Juty 2018) (2)
reaction A + product,80 % of the given sarmple of compound decomposes
(22) In a first order half life period of thereaction ? [Ans. 17.22 min-j
in 40 min. What is the (July 2018) (3)
variations,
(23) Write Arrhenius equation. Derive an expression for temperature (March 2019) (3)
reaction, A Bis 5.4 x 10 Ms- when AJ is 0.3M.
(24) The rate of a first order
Calculate the rate constant of the reaction. [Ans. 1.8 x 10-5s-] (March 2019) (1)
195) The half life period of a first order reaction is 6.0 h. Calculate the rate constant. (March 2019) (1)
(26) The half life of first order reaction is 6.0 hours. How long it will take for the concentration of
reactant to decrease from 0.8 M to 0.25 M. [Ans. t - 10.07 hours] (Jhuly 2019) (3)
(27) For a certain second order reaction energy of activation is 240 kJ mol-. Calculate its rate constant
at 1023 Kif the rate constant at 923 is 0.0113 m-! s-.[R= 8.314 JK mot|]
[Ans. 0.24 M-! s-lj (huly 2019) (3)
(28) Defne elementary reaction. (Jhuty 2019) (1)
(29) A reaction occurs by the following mechanism:
() NO2 + F2g NO,Fg +Fg
() F+ NO2g)
ldentify the intermediate and write net reaction. (July 2019) (1)
2020) (1)
(30) Write the mathematical relation between half life of zero order reaction and its rate constant. (March
(31) Define instantaneous rate of reaction. Explain pseudo first order reaction with
suitable example. (March 2020) (3)
(32) Define isomorphism. Derive integrated law expression for first order reaction. (Sept. 2021) (4)
(Sept. 2021) (2)
(33) What is pseudo - first order reaction ? Explain with suitable example.
2.303 RT (Sept. 202 1) (2)
(34) Write the value of. in Nernst equation.
F
life and
(35) Define half life of first order reaction. Obtain the expression for half (March 2022) (3)
rate constant of the first order reaction.
(36) ldentify the molecularity of following elementary reaction: (September 202 1) (1)
NOtOsg three times the time required for 90%
(37) Show that time required for 99.9% completion of a first order reaction is (July 2022) (1)
completion.
(38) A chemical reaction occurs in the following steps:
) NOg+ Fzg + NO,F +Fe (slow)
(ii) Fg t NO2g (fast)
(a) Write the equation of overall reaction.
(b) Write down rate law.
July 2022) (3)
(c) Identify the reaction intermediate.
(39) What is Pseudo first order reaction? Derive integrated rate law equation for zero order reaction.(March 2023/(3)
(40) Show that time required for 99.9% completion of a first order reaction is three times the time required for 90%
(March 2023) (2)
completion. (July 2023) (2)
(41) Derive integrated rate law for zero order reaction.
(42) Write Arrhenius equation. Derive an expression to determine activation energy for two
different termperatures T, and T, (July 2023) (3)
(43) For the reaction A+B +P. If B] is doubled at constant [AJ, therate of reaction doubled.
If (A] is triple and (B] is doubled, the rate of reaction increases bya factor of 6.
Calculate the rate law equation. [Ans. rate = k[A|' |B|1 (March 2024) (3)
(44) Derive the relation between half life period and rate constant for first order reaction. (March 2024) (2)
(45) Write two uses of neon. (March 2024) (1)
 315
Questions
Summary of Board
18
7 ELEMENTS OF GROUPS 16, 17 AND
following reagents on ammonia ? (March 2013) (3)
(1) What is the action of the (c) Na metal
(a) Excess of air
(b) Excess of chlorine
reference to group 16:
following properties with
(2) Explain the trends in the (b) Density (March 2013) (4)
radii
(a) Atomic radii and ionic (d) Electronegativity
(c) lonisation enthalpy
(Cl) on the following:
(3) What is the action of chlorine (b) Hot and concentrated
caustic soda.
(Oct. 2013) (3)
(a) Cold and dilute caustic soda.
(Oct. 2013) (2)
(c) Potassium bromide solution.
uses of neon (Z = 10). (March 2014) (1)
(4) Write electronic configuration and two
Write resonating structures of ozone. 17 with reference to:
(5)
behaviour of fiuorine with the other elements of group (March 2014) (3)
(6) Describe anomalous Polyhalide ions.
(b) Oxidation state (c) reference to
(a) Hydrogen bonding compared with other elements of group 16 with
oxygen as (Oct. 2014) (3)
(7) Describe anomalous behaviour of (c) Hydrides
(a) Magnetic property (b) Oxidation state
(Oct. 2014) (2)
(8) Draw the structure of:
(a) Orthophosphoric acid (b) Pyrophosphoric acid (March 2015) (2)
sulphur dioxide.
(9) Explain the structure of of the following compounds:
formulae and structures
(10) Write molecular (b) Peroxy monosulphuric
acid
(a) Dithíonic acid (March 2015) (4)
(d) Dithionous acid
(c) Pyrosulphuric acid (b) Chlorine pentafluoride. (2)
(a) Chlorine trifuoride
(11) Draw structures of:
(12) What is the action of dioxygen on : (Oct. 2015) (3)
(a)Calcium (b) Iron (c) Carbon disulphide?
(13) Write four' uses of hydrochloric acid.
Write chemical formula of the following oxoacids of chlorine: Perchloric acid. (Oct. 2015) (4)
acid (d)
(a) Hypochlorous acid (b) Chlorous acid (c) Chloric July 2016) (2)
with (a) Fe (b) CaF, ?
(14) What happens when dilute sulphuric acid is treated containing chlorine? (July 2016) (2)
jar
(15) What happens when thin copper leaves are thrown in July 201 6) (2)
(16) H,O is liquid while H,S is gas at room temperature. Explain.
(17) Write the electronic configuration of thefollowing elements :
(b) Krypton (Z - 36) (March 2017) (2)
(a) Sulphur (Z- 16)
Write any two' uses of cach of the following: (a) HsO, b) Chlorine (March 2017) (2)
(18)
(19) What is the action of concentrated sulphuric acid on the following: (July2017) (3)
(a) Phosphorous pentachloride (b) Copper (c) Potassium chlorate. with respect to:
(20) Arrange the following oxyacids of chlorine: HCIO, HCIO,, HCIO, and HCIO,
(a) Increasing order of thermal stability (b) Increasing order of oxidising power. (July 2017) (2)
(21) Write balanced chemical equations for the following
Action of ozone on hydrogen peroxide. (March 2018) (1)
(22) Write the molecular and structural formulace of:
(b) Dithionous acid (March 2018) (2)
(a) Thiosulphuric acid
(23) Draw the structure of IF, Write its geometry and the type of hybridization. (March 2018) (2)
(24) Explain the following with the help of balanced chemical equation:
(a) Bleaching action of SO
(b) Dehydration of formic acid by concentrated H,SO,
(c) Burning of benzene in presence of exxcess of dioxygen. (July 2018) (3)
(25) Write structure and molecular formula for sulphurous acid. (July 2018) (1)
(26) Write any four points of difference between fuorine and other halogens. (July 2018) (2)
(27) Explain the following properties of group 16 elements:
() Electronegativity (iü) Melting and boiling points
(i) Metallic character (iv) Allotropy (March 2019) (4)
) What are oxides? Write different types of oxides with one example each. (March 2019) (4)
Write the name of an inert gas element used in the treatment of cancer by radiotherapy. July 2019) (1)
(30) The layer of ozone acts as a protective umbrella. Explain. (July 2019) (2)
316
each of the following: (a) Helium (b) Neon.
UTTAM's XIlChemistry Papers Solution
(31) Write two uses of
(32) Draw the structure of sulphurous acid, Explain why nitrogen does not form (March 2020) (2)
pentahalides.
(33) Explain
interhalogen compound, (March 2020) (3)
How is oxygen prepared from the following compounda?
(a) KCIO, (b) PbO,
A) Write the name of interhalogen compound of chlorine which has square pyramidal (March 2020) (4)
structure.
aK) Draw the structure of sulphurous acid. Write two uses of helium. (Sept. 2021) (1)
BA Write chemical equations involved during manufacture of sulphurice scid by (Sept. 2021) (2)
contact process. Write two Uses of sulphur dioxide,
a What is the action of concentrated H,80, on: (i)CaF, (1) Cane sugar. (Sept. 2021) (3)
What is nucleotide? Write reaction for the preparation of polyacrylonitrile (PAN).
nR) What is the action of selenium on magnesium metal ? (Sept. 2021) (4)
i30) Explain the trends in the following atomic properties of group 16 elements: (March 2022) (1)
) Atomic radii (i) lonisation enthalpy (i) Electronegativity (iv)
a0) Write chemicalcomposition of haematite. Write the names and Electron gain enthalpy. (March 2022) (2)
configurations of first two elements of group 17. electronic
(41) Write chemical equation for preparation of sulphur dioxide from sulphur. (March 2022) (3)
Write uses of sulphur.
142) What is the action of chlorine on the following: (March 2022) (2)
() NH, (exCess) (ii) phosphorus ? (July 2022) (2)
(43) What happens when:
() Ethene reacts with iodine
monochloride
(i) Sulphur dioxide is oxidised in presence of V,0,
(ii) Cu heated with concentrated H,SO,.
(July 2022) (3)
(44) What are interhalogen compounds ? Write two uses of neon. (July 2022) (2)
(45) Write the chemical composition of cryolite. (March 2023) (1)
(46) Give reason: Group 16h elements have lower ionisation enthalpy compared to group 15th elements,(0March 2023) (1)
(47) Given reason: Bleaching action of ozone is also called dry bleach. (March 2023) (1)
(48) Write two uses of dioxygen. (March 2023) (1)
(48) Draw structures of the following compounds:
(a) Chloric acid (b) Peroxy disulphuric acid. (March 2023) (2)
(49) Explain anomalous behaviour of oxygen in group 16 with respect to:
(1) Atomicity (ii) Magnetic property (iil) Oxidation state. (March 2023) (3)
(50) Write the name of radioactive element in group 16. (July 2023) (1)
(51) Why fluorine shows anomalous behaviour? (July 2023) (2)
(52) Write molecular formula and structure of:
(a) Sulphuric acid (b) Peroxy monosulphuric acid (c) Thiosulphuric acid July 2023) (3)
(53) What are interhalogen compounds?
Write any two general characteristics of interhalogen compoundss (July 2023) (2)
(54) The compounds of Tif* ions are colourless due to (March 2024) (1)
(55) What are interhalogen compounds ? Write the chemical reaction, when chlorine reacts
with dry slaked lime. (March 2024) (2)
(56) Arrange the following in the increasing order of the property mentioned.
4) HOCI, HCIO, HCIO, HCIO, (acidic strength)
(11) ME, MCI, MBr, MI (ionic character)
(4) HF, HCI, HBr, HI(thermal stability) (March 2024) (3)
(57) Draw the structure of peroxymonosulphuric acid. (March 2024) (1)
8 TRANSITION AND INNER TRANSITION ELEMENTS

(1) Write the different oxidation states of manganese. Why +2 oxidation state of manganese
is more stable? (March 2013) (3)
(2) Explain the following terms: (1) Smelting (i1) Flux. (March 2013) (2)
(3) Write observed electronic configuration of elements from first transition series having
half flled d-orbitals. (Oct. 2013) (2)
(4) What is lanthanoid contraction? Explain the cause and effects of lanthanoid contraction. (Oct. 2013) (3)
 317

Questions (Mareh 2014) 2)

Summary of Board actinoids in periodie table? (Mureh 2014) (2)
What are lanthanoids? What is the position of '?
(5) ronsting
How does it differ from
(6) What in 'calcination '? ofthe following ores: (oct 2014) (2)
(7) Write chemical formula Corundum,
(e) Magnetite (d)
(a) Calamine (b) Haematite
compounds? Why do these compounds have
higher melting points (Mareh 2016} (2)
(8) What are interstitial (Mareh 2016) (a)
metals?
than correnponding pure
contraction, Explain its effects, extraction
(9) Definelanthanoid involved in the zoneof reduction in blast furnace during (Mareh 2016) (2)
(10) Write the reactions
of iron. (0et. 2016) (3)
What is the position of iron (Z-26) in periodie table? 2019) 2)
(11) stablethan Fe2? 0ot. 2016; Huly 2016,
Explain why in Femore (March 2008, 2010, (00t 2016) (2)
Distinguish between Lanthanoides and Actinoides. (Mareh 2016) (2)
(12) Electrometallurgy.
(13) Define: (a) Hydrometallury (b) ore of iron and zine esch. (March 2016) (2)
Write the names and chenical formulae of any one number Se 21, TI 22) (March 2016} (3)
(14) while T coloured? (Atomte actinoids,
(15) Why is Se colourless elementa? Distinguish between
lanthanoids and (March 2016} (1)
(16) What are fblock Interstitial compoundn, (March 2017) 2)
(17) Explain the term - of transition metal ions,
are related to the colouroxidation stable?
(18) Write the factors which of iron, Why stateof manganese is rmore (March 2017) (3)
different oxidation states
(19) Write the while
(Given: Z of Mn -25.) 57) forns La" ion,
What is lanthanoid contraction? Explain, why lanthanum (Z - (uly 2017) (3)
(20) 2017) (2)
cerium (Z- 58) forms Ce"ion? in the extraction of pure metals from their ores. (huly
various steps involved
(21) Mention the names of carbon on the following metal oxide:
(22) What is theaction of (March 2018) (1
Fe,O, in blast furnace. (July 2018) (2)
elements?
(23) What are d' and f block
on lanthanoids?
(24) What is the action of the following (July 2018) (3)
(a) Water (b) Sulphur, heat (c) Nitrogen, heat.table. What is the action of sulphur
(25) Explain the position of actinoids in the periodic
on lanthanoids? Calculate the magnetic moment of divalent ion in aqueous solutíon if
(March 2019) (4)
its atomic number is 24. of KMUO,. July 2019) (3)
(26) Write a note on Lanthanoid contraction. Write two uses (July 2019) (3)
(27) Explain Bessermization process. (March 2020) (1)
(28) What is electrometallurgy? (March 2020) (2)
ore of zinc.
(29) Write the name and chemical formula of one (March 2020) (3)
(30) Define flux. Write a note on leaching process.
are most of the
(31) Write the general electronic configuration of lanthanoids. Why (March 2020) (3)
compounds of transition metals coloured ?
configuration.
(32) Iron exhibits +2 and +3oxidation states. Write their electronic (Sept. 202 1) (2)
Which will be more stable ? Why ?
(33) Why La(OH), is the strongest base, while Lu(OH), is the weakest base?
transition metals and compounds. (Sept. 2021) (3)
Write two applications of catalytic properties of (Sept. 2021) (1)
(34) Write the chemical formula of Haematite.
(35) Define mineral. (Sept. 202 1) (1)
with
(36) Calculate spin only magnetic morment of divalent cation of transition mnetal (March 2022) (4)
atornic number 25, Salts of Ti4* are colourless. Give reason. (March 2022) (1)
(37) What is a Lanthanoid contraction?
(38) Write the molecular formula of the following minerals: (July 2022) (2)
(4) Chalcopyrite (14) Calamine.
actinoids. (July 2022) (3)
o) What is a Lanthanoid contraction? Write similarities between lanthanoids and
(40) Give electronicconfiguration of Gd (Z- 64). (March 2023) (1)
(41) Distinguish between lanthanides and actinides. (March 2023) (2)
) What are interstitial compounds? Give the classification of alloys with examples. (March 2023) (3)
(93) Why do d -block elements form coloured compounds? (July 2023) (2)
Which alloy is used in Fischer Tropsch process in the synthesis of gasoline? (March 2022; July 2023) (1)
(45) Define: Gangue. (July 2023) (1)
T) Write different oxidation states of manganese. Why +2 oxidation state of manganese is
more stable? (July 2023) (3)
 UTTAM's XII Chemistry Pupers Solution
318
Lanthanide
contraction. Write the balanced chemical equations when acidifiedI K,Cr,0,
Define
(47) reactswith H,S. (March 2024) (2)
potassium dichromate from chromite ore. (Mareh 2024) (3)
the preparation of elements
(48) Write of transuranium (March 2024) (1)
the atomic numbers
4Q) Wite
coORDINATION COMPOUNDS
formulae of fthe following compounds:
(1) Write the hexanitro-N-cobaltate (t)
(a) Sodium
Tetraaquodichlorochromium (I) chloride.
(b) tetracyanoaurate (I) ion. Mareh 2013) (3)
(c) Potassium electroplating.
2 Wite applications of co-ordination compounds in medicine and (Oet. 2013) (2)
(3) What is effective atomic number (EAN)?
Calculate EAN of cobalt (Z = 27) in (Co(NHJJ and of zinc (Z -30) in Zn(NH)] so, (March 2014) (3)
J4) Classify the following ligands into monodentate and polydentate -
(a)Ammonia (b) Carbon monoxide
(c) Ethyiene diamine (d) Ethylene diamine tetra acetate ion. (Oct. 2014) (2)
(5) On the basis of valence bond theory explain the nature of bonding in [CoF,J ion.
(March 2015) (3)
Write the IUPAC name of [Co(NONH.
(6) Explain cationic complexes and anionic complexes of co-ordinationation compounds. (Oet. 2015) (2)
(7) Ilustrate with example, the difference between a double salt and a co-ordination compound. March 2016) (2)
(8) Explain the terms- Ligand. (March 2016) (1)
(9) Write the formula of Tetraminodichloroplatinum (IV) chloride. (March 2016) (1)
(10) Define ligand. Write four postulates of Werner's theory. Jhuly 2016) (3)
(11) What is 'effective atomic number EAN)?
Calculate the effective atomic number of the central metal atom in the following compounds:
(a) K;Fe(CN)E (b) Cr(C0)
(March 201 7) (3)
Fe (Z = 26) Cr (Z = 24)
uly 2017) (3)
(12) How ligands are classifed? Explain with suitable examples. Mareh 2018) (2)
(Z of Co = 27)
(13) Explain the geometry of (Co( NHJJ on the basis of hybridisation. (March 2018) (1)
(14) Write the formula of the complex Copper (lI) hexacyanoferrate(1). uly 2018) (2)
(15) Write the formula for pentaammine chlorocobalt (I) sulphate. uly 2018) (2)
hybridisation [At. No. Cu =29).
(16) Explain the geometry of [CuNH)J on the basis of atomic number of
(17) What is effective atomic number? Calculate effective March 2019) (3)
copper (Z=29) in [Cu(NH)LP. (March 2019) (1)
(18) What is Nesslert's reagent.
uly 20I9) (1)
(19) Write IUPAC name of Pt(en),Cl,j** complex. Cu = 29) (March 2020) (2)
(20) Calculate the effective atomic number (E.A.N) of copper in [Cu(NHJ|2*. (Z of (Sept. 2021) (2)
(21) What are bidentate Ligands ? Give one example. (Sept. 2021) (1)
(22) Write two applications of coordinate compounds. (Sept. 2021) (1)
(23) Write IUPAC name of Fe(CO)] complex.
(24) Write the name of isomerism in the following complexes: (March 2022) (1)
[CuNH)J[PrCi,]and Pr[(NHJ).|CuCl;] (March 2022) (2)
(25) Explain monodentate and ambidentate ligands with example. (March 2022) (3)
(26) Explain cationic, anionic and neutral sphere complexes with example. uly 2022) (1)
(27) Calculate effective atomic number of Co*s in (Co(NH)JS* complex. uly 2022) (2)
(28) Explain homoleptic and heterolepticcomplexes with examples. uly 2022) (2)
(29) Write two postulates of Werner theory of coordinate complexes. (March 2023) (1)
(30) Write the name of platinum complex used in the treatment of cancer. (Mareh 2023) (1)
(31) Define: Distereoisomers.
(32) Give cis and trans isomers of (Co(NH),Cl,]e. (Mareh 2023) (1)
(33) Explain formation of (CoF,Jecomplex with respect to:
(Mareh 2023) (3)
4) Hybridisation (ti) Magnetic properties (ii) Inner / outer complex (iv) Geometry. Muly 2023) (2)
(34) Write four postulates of Werner theory of coordination complexes.
(35) On the basis of valence bond theory explain the nature of bonding in [NijC))² complex ion. Muly 2023) (3)
(36) Define:lonisation isomer. uly 2023) (1)
(37) Calculate effectíve atomic number of [Co(NHJJt ion. (Mareh 2024) (1)
 (March 2024) (3)
Questions complexes.
Board -ordination (March 2024) (2)
Summary of theory of co complexes:
postulates of Werner
hexadentate ligand.
geometry of following
L38) Write the name of a electrons and
Write of unpaired
the number
(39) Mention ( )[Ni(CN,)|2 HALOGEN DERIVATIVES
()(NiCl))2- attack of (March 2013) (2)
10 readily with
displacement reactions
p-nitrochlorobenzene undergo
(1) Why does
nucleophilic OH- ion ? equations for the action of (March 2013) (3)
balanced chemical on propan-2-ol.
(2) Write
(a) Phosphorus trichloride a peroxide.
styrene in the presence of diagram
(Oct. 2013) (4)
bromide on profile (March 2014) (3)
(b) Hydrogen propanoate. labelled energy
Methyl bromide on silver acid. Draw a neat, (March 2014) (2)
(c)
optical activity of lactic
(3) Explain reaction mechanism. acid.
for SN' activity oflactic (Oct.2014) (3)
the optical mechanisms. 5-Tribromobenzene.
(4) Discuss
Distinguishbetween SN' and
SN?
3-dimethylbutane (c) 1, 3, (March 2015) (2)
(5) structures of - 1-lodo-2,
(6) Write the
3-Chloro-3-ethylhex-1-ene (b)environmental effects. (Oct. 2015) (2)
(a) Write its
of DDT. (Oct. 2015) (4)
(7) Draw structure following reaction:
and B'in the B' 2016) (2)
(8) ldentify 'A' HBr 4 alc. KOH bromomethane. diphenyl? March
hydrolysis of into (March 2016) (1)
CH,
CH, -CH - mechanism of alkaline chlorobenzene converted
Discuss the aniline? How is (March 2016) (2)
(9) from
chlorobezene prepared (2)
(10) How is
Explain the term - Optical
activity.
1-bromopropane and
2-bromopropane? (July 2016, 2018)
(11) into
propene converted
(12) How is Sandmeyer's reaction.
note on
(13) Write a the reactions.
Identify 'A' and B' and rewrite
(14)
CH,
-NH, NaNO, Cu,Br, (B) + N,1
’ (A)
HBr, 273 K
(a) (July 2O16) (2)
2H,0
> (A) + (B) + 2KBr +
Alcoholic KOH
CH,
(b) H,C - CH, CH - (March 2017) (1)
Br diagram.
racemic mixture. tert-butyl bromide with energy profile (March 201 7) (3)
(15) Define of
Explain the mechanism of alkaline hydrolysis (July 2O1 7) (4)
(16)
lactic acid.
optical activity. Explain optical activity of
(17) Define
the following reaction:dry ether (July 2017) (2)
(18) Identify A and B in + B+ Mg(Br)OH
dry ether A + CO, H/H,0 (March 2018) (2)
CH, - Br + Mg tert-butylbromide.
mechanism for alkaline hydrolysis of
(19) Explain only reaction following reaction and rewrite the complete
reaction:
(20) Identify 'A' and B' in the (March 2018) (2)
Na + B
A
CH, -CH, -Br + AgCN C,H,OH
reaction:
following reaction and rewrite complete
(21) Identify A and B from the (huly 2018) (2)
dry ether A H,0 + B + MgCl(OH)
+ Mg
chemical reaction:
(22) Complete and rewrite the followingaq. alkali (July 2018) (1)
?
1- Chloro -2, 4-dinitrobenzene 368 K, H
ethyl bromide:
(23) What is the action of the following on
(4) Alcoholic solution of potassium hydroxide
(4) Moist silver oxide (March 2019) (3)
(1) Silver acetate? (March 2019) (1)
(24) Define Enantiomers. (March 2019) (1)
(25) What is Grignard reagent?
 UTTAM's XIIChemistry Papers Solution
320
iodic acid in the preparation of ethyl iodide from ethane.
the role of
(26) Explainacid is optically inactive. Why? July 2019) (3)
Dilactic
reaction for preparation of Grignard's reagent. (huly 2019) (1)
(27) Writethe
conversion of 2. bromobutane into unsaturated hydrocarbon by using alcoholic KOH. uly 2019) (1)
(28) Write
optical activity. How many optical isomers are possible for glucose? (March 2020) (2)
(29) Define chemical reactions of fchlorobenzene with respect to:
(30) Write the Acetylation (c) Nitration,
(a) Sulphonation (b) the following on chlorobenzene? (March 2020) (3)
action of
(31) What is the
) Methyl chloride in presence of anhydrous AlCL,
() Fuming H,S0, (Bept. 2021) (2)
bromomethane.
(22) ExDlain SN? reaction mechanism for alkaline hydrolysis of (Sept. 2021) (3)
nitrite.
133) Write the product formed when alkyl halide reacts with silver (March 2022) (1)
on ethyl bromide?
(34) Whatis the action of the following
() Na in dry ether (ii) Mg in dry ether. (March 2022) (2)
(35) Write chemical reactions for the following conversions:
)Ethyl bromide to ethyl methyl ether () Ethyl bromide to ethene
() Bromobenzene to toluene. (iv) Chlorobenzene to biphenyl. (March 2022) (4)
(36) Convert ethyl bromide to: ()Ethyl iodide (ii) Ethyl fluoride. (huly 2022) (2)
(37) Write four salient features of S,yl mechanism. (huly 2022) (2)
(38) Write the structure of the product formed when chlorobenzene is treated with sodium metal
in the presence of dry ether. (March 2023) (1)
(39) Write the chemical reactions for the following:
(a) Chlorobenzene is heated with fuming H,SO,
(b) Ethyl bromide is heated with silver acetate. (March 2023) (2)
(40) Explain dehydrohalogenation reaction of 2-chlorobutane.
Write use and environmental effect of CFC. (March 2023) (3)
(41) What is Grignard reagent? How it is prepared? (July 2023) (2)
(42) Explain optical activity of 2 -chlorobutane. (July 2023) (3)
(43) Write the use and environmental effect of methylene chloride. (July 2023) (1)
AgCN +? (March 2024) (1")
(44) Complete the reaction CH,CH,CI alc. A
(45) What is the action of the following on ethyl bromide ?
(a) silver nitrite (b) Mg in dry ether (c) alcoholic sodium hydroxide. (March 2024) (3)
11
ALCOHOLS, PHENOLS AND ETHERS
(1) How is ethanol prepared from methanal by using Grignard reagent? (March 2013) (2)
3-methylbutan-2-ol. (March 2013) (3)
(2) Explain the mnechanism of action of hydroiodic acid on
(3) How is phenol converted into the following?
(c) Picric acid. (Oct. 2013) (3)
(a) Benzene (b) Benzoquinone
acid ? (Oct. 2013) (2)
(4) How is methoxy benzene prepared fromn carbolic compound
(5) Write the structural formula and IUPAC names of all possible isomers of the
(March 2014) (4)
with molecular formula C,H,0. Write two' uses of phenol.
(March 2014) (1)
(6) How is methoxyethane prepared from methyl iodide.
(7) What is the action of the following reagents on phenol
(a) Bromine in CS, at low temperature (b) Conc. H,S0, at room temperature. (Oct. 2014) (2)
(8) Write the structure and IUPAC name of all the metamerism represented by formula C,H,,0. (Oct. 2014) (3)
(9) How is carbolic acid prepared from the following compounds:
(4) Aniline (1i) Chlorobenzene and steam at 698K? (March 2015) (2)
(10) Mention two' physical properties of carbolic acid. (March 2015) (1)
(11) How are the following compunds prepared? (Oct. 2015) (2)
(a) Benzyl alcohol from benzyl chloride. (b) Propan -1-ol from propanal.
(12) How is carbolic acid prepared from chlorobenzene? What is the action of bromine water on
carbolic acids? Write chemical test to distinguish between carbolic acid and alcohol. (Oct. 2015) (3)
(13) Write the reactions involved in dehydration of 1", 2° and 3" alcohols. (March 201 6) (2)
(14) What is metamerism ? Explain metamerism with suitable examples of ethers. (March 2016) (2)
(15) What is metamerism? Write the structure and IUPAC name of 'methyl-n-propyl ether.
What is the action of hot HI on it? (July 2016) (3)
 321

SmaryBxar Questions
out?
following conversions carried
I16) How are the
into 2-methvlbutanoic acid.
() 2-Methvlbutan-1-ol
Benroic acid hu ly 2016) (3)
() Phenvlethene into March 201 7) (2)
metanitrobennoic acid.
(BR) Benzoic acid into prepared from benzene sulphonic acid? March 2017) (2)
(17) Deine carbolic acid.
How carbolic acid is
esterification process ? ly 201I7 (3)
prepared by continuous 2-methyipropan-2-ol from Grignard's reagent?
(18) How is diethvl ether
ethanol. propan-2-ol and huly 2017; Jhuly 2023) 2)
(19) How willyou prepare
from cumene? equuation for the
(20) How is phenol prepared bennene sulphonic acid ? Write a chemical arch 2018) 3)
will you prepare carbolic acid from
(21) How on phenol. March 2018) (2)
action of neutral ferric chloride ethane?
boiling point than
(22) Why ethanol has higher cumene? What happens when phenol is
heated Fhuly 2018) (3)
preparation of phenol from
Wnte a
(23) wìth inc dust? (b) hot HI huly 2018) (2
methyl ether ? [a) cold HI DMarch 2019) (1)
the following on isopropvi
(24) What is the action of
(25) What are ethers?
equations for the following:
(26) Wite balancedchemical ethanol DMarch 2019) 2)
(a) Action of sodium metal on
phenol.
)Action of zine dust on
OH huly 2o19) (1)
(CHJ,C-CH-C,H.
(27) Give IUPAC name of Ethoxvethane into ethanol.
July 2019) (1)
2S) Wite the following conversion: uly 2019) (1)
(29) Give two uses of ethanoL. huly 2019) (1)
3O) Wite IUPAC name of pyrogallol. is
alcohol that results when acetaldehvde hyirolysed. March 2020) (1)
31) Wite structural formula of the dry ether and the product is
reacted with CH MgBr in the presence of ether. March 2020) 2)
etheriñcation process for the preparation of diethyl
(32) Explain the continuous
($3) How isethanol prepared from the following compounds: March 2020) (3)
b) Ethene (c) Bromoethane. Sept 2021) (2)
(a) Ethanal
(34) Write a note on Kolbe reaction.
(35) Convert the following: methane Sept 2021] (3)
to ethanol (iii) Iodomethane to methoxv
() Chlorobenzene to phenol (ii) Ethanal March 2022 (2)
from aniline.
(36) Write the preparation of phenol
reagents on methoxyethane:
(37) Write chemical reactions of following March 2022) (3)
() Hot HI () PCI, (iü) Dilute HSO_. Kuly 2022) (1)
conversion of phenol to salicycic acid
(38) Write the name of reaction during
following reagents on carbolic acid:
(39) Write balanced chemical reactions of the Khuly 2022) (2)
() Br, water (ii) Concentrated HNO, Jhly 2022 (2)
alcohols are passed over hot Cu metal?
(40) What happens when vapours of 1 and 2 March 2023) (1)
conversion: Acetic acid into ethyi alcohol
(41) Write chemical reactions for the following
(42) Convert the following:
() Ethyi alcohol into ethyl acetate
(i) Phenol into benzene pMarch 2023) (3)
(ii) Diethyi ether into ethyl chloride. phenl? March 2023) (3)
What is the action of bromine water on
) Write Dow process for preparation of Phenol.
(4) Prepare the following by using methyl magnesium iodide: huly 2o23) (3)
(a) Ethanol (b) Propan-2 -ol (cl) 2-Methylpropan-2-olfrom ethyl bromide. DMarch 2024) 2)
cyanide
) Wite preparation of (a) Diethyi ether b) Ethyl
and rewrite the chemical reactions:
O) ldentify 'A', B'and Cin following chain reaction
pMareh 2024) (3)
CH,CH,OH
red P
Br,
KCN
alc.
+B
LiAIH,C
Ether

(47) Convert the following:

(iii) Anisole to phenol. March 2024) (3)
(1) Acetaldehyde to isopropyl alcohol (ii) Cumene to phenol
 UTTAM s XIlChemistry Papers Solution
322
12 ALDEHYDES, KETONES AND CARBOXYLIC ACIDS
4-methyipent-3-en-2-one obtained from propan-2-one? (March 2013) (2)
(1) How is compounds prepared?
12) How are the following
from benzene.
(a) Benzaldehyde
from benzene.
(b) Acetophenone benzoyl chloride.
(c) Benzaldehyde frompropan-2-one. (March 2013) (3)
(3) Mention two' uses
of (March 2013) (1)
mechanisn of aldol condensation (Oct. 2013; March 2015) (3)
(4) Explain the benzonitrile ?
prepared from (0ct. 2013; July 201 6; March 2018) (2)
I5) How is benzophenonecondensation.
(6) Write a note on aldol (March 2014, 2017; uly 2022) (2)
Wite a note on self oxidation-reduction reaction of aldehyde with suitable exarmple. (March 2014) (2)
THentify A' and B'in the following reaction : CH,MgBr+CO, HHO
ether
Dry .. PCl,, B' (Oct. 2014) (2)
(O) Write the structure and IUPAC names of all the metamers represented by formula C,H,60. (Oct. 2014) (3)
10) Write balanced chemical equations for action of ammonia on -
(a) Formaldehyde (b) Acetaldehyde (c) Acetone. (Oct. 2014) (3)
(11) Write a note on Friedel Craft's acylation. (March 2015) (2)
(12) Explain, why are boiling points of carboxylic acids higher than corresponding alcohols. (March 2015) (2)
(13) Write the structures and IUPAC names of the following compounds:
(a) Adipic acid (b) a-methyl butyraldehyde (March 2015) (2)
(14) What is Stephen reaction? (Oct. 2015) (2)
(L5) Write the structure and IUPAC names of isomeric aldehydes having molecular formula C,H,o0.(March
(0ct. 2015) (4)
2016) (2)
(16) What are ketones? How are ketones classified?
(17) Explain the mechanism of esterification. (March 2016) (4)
(18) Write IUPACnames of the following compounds :

(July 2016) (2)

(a) CH, (b) CH, -C-c-CH,
(19) How is ethanoic acid prepared from dry ice? (March 201 7) (2)
(March 201 7) (1)
(20) Give IUPAC name of CH,-CH,-CH-CHo.
(21) What is the action of the following reagents on prepanone?
(July 2017) (3)
(a) Phenyl hydrazine (b) Zn-Hg/conc. HCI (c) Sodium bisulphite. (July 2017) (2)
with suitable example.
(22) Write a note on self oxidation-reduction reaction of aldehyde
(23) Complete and rewrite the balanced chemical equations:
NaCN + CuCN
(a) Chlorobenzene 473 K, pressure
50% KOH
(b) Isobutyraldehyde
H
+?o (March 2018) (3)
(c) Butanone +2, 4-dinitro-phenyl hydrazine
ethanoic acid?
(24) What is the action of the following reagents on
(March 2018) (3)
(a) LiAlH, /F,0* (b) PCI, heat (c) P,O5, heat. reactions:
(25) Complete and rewrite the balanced chemical equation for the following
50% KOH
(a) Benzaldehyde
H*
(b) Acetone + phenylhydrazine July 2018) (2)
(26) Write balanced equations for the following conversions:
(a) Cyclopropane carboxylic acid to cyclopropylmethanol.
(b) Acetyl chloride to benzyl methyl ketone using dialkyl cadmium. (uly 2018) (2)
(27) Write chemical equation for the following:
() Gatterman-Koch formylation (ii) Rosenmund reduction (lii) Fischer esterification. (March 2019) (3)
(28) How will you convert:
(4) Calcium acetate to acetaldehyde (i1) Acetone to acetone cyanohydrin
(il) Sodium acetate to methane (iv) Benzoic acid to m-bromobenzoic acid? (March 2019) (4)
(29) Convert the following:
(1) Ethanal into ethanal cyanohydrin
(i) 3,5-Dinitorbenzoic acid into 3,5- dinitrobenzoyl chloride. (July 2019) (2)
 323

Questions
Summary of Board out?
Muly 2019) (1)
conversion carried
How are the following
Muly 2019) (2)
(30) acid. (March 2020) (1)
Dry ice into ethanoic and propanal.
condensation reaction between ethanal anhydride using acetic acid.
131) Write aldol preparation of acetic
chemical reaction for
(32) Write balanced reaction: (March 2020) (1)
Identify 'A' and 'B' in the following
(33) Zn Hg H,0
AICI, Cone. HCI, Á B carboxylic acids.
(March 2020) (4)
HCI Mention two uses of
mechanism of aldol addition reaction, acetaldehyde to (Sept. 2021) (1)
(34) Explain the reagent used during conversion of (Sept. 2021) (2)
Write the name of
(35) acetaldehyde cyanohydrin. benzonitrile? (Sept. 2021) (4)
benzophenone prepared from reaction of ethanal, Write chemical potash.
(36) How is condensation caustic (March 2022) (1)
(37) Write a note on 'aldol' benzaldehyde is treated with concentrated -dinitrophenyl hydrazine.
with 2,4
reaction involved when formed, when acetone is treated
of product
(38) Write the name from the following reaction: (March 2022) (2)
A and B
(39) ldentify
CH, B(OH2A AB+ H,0 (March 2022) (2)
2CH, -C-0 from:
preparation of acetic acid
(40) Write What is the action of (March 2022) (2)
(i) Acetylchloride.
() Dry iceclassification aliphatic ketones with example. Juty 2022) (1)
of
(41) Write thehypoidite on acetone ?
acid.
sodium
a- methylpropionic
IUPAC name offollowing carboxylic acid :
(July 2022) (2)
(42) Write the on July 2022) (2)
action of the
(43) What is the (March 2023) (3)
(ii) P,0,?
() SOCl,carboxylic to: (i) Ester (i1)
Acid amide. (March 2023) (2)
acids
(44) Convert condensation of ethanal. July 2023) (1)
(45) Explain Aldol
Haloform reaction. July 2023) (2)
note on isobutyraldehyde.
(46) Write a
Write the IUPACname of reaction.
147) Kishner reduction acetic anhydride July 2023) (3)
(48) Write a note on: Wolf-
acetamide (b) Acetyl chloride to July 2023) (1)
Acetic acid to
(49) Convert: (a) Sodium acetate to methane.
(c)
Rosenmund reduction
March 2024) (3)
Define: Aromatic ketones.
(50) reactions involved in: (a) reaction of methanal.
(51) Write
chemical (c)Cannizaro by using (March 2024) (3)
Gattterman Koch formylation
Write preparation of propanone
(b) reaction. (March 2024) (2)
Kishner reductioncadmium.
(53) Explain Wolf- dimethyl Cyclohexane into adipic acid.
ethanoyl chloride and Ethanentrile into ethanal. (b)
following:(a)
(53) Convert the 13
AMINES
(March 2013) (2)
medium on:
in alkaline
action of bromine
(1) What is the NO,
(b) CH, - CH - (March 2013) (3)
(a) CH,CH,NO,
CH, bromamide degradation. (Oct. 2013) (3)
on Hoffmann
(2) Write a short note prepared from the following? a-Nitroalkene. 2018) (2)
nitromethane acid (c) March 2017,
(3) How is carboxylic (Oct. 2013;
(b)a-Halogendegradation reaction.
(a) Alkyl halide bromamide aniline?
(March 2014) (3)
(4) Explain Hoffmann reagents on sulphuric acid.
of the following Hot and conc.
(5) What is the action anhydride (c) (March 2014) (2)
water (b) Acetic following equation:
(a) Brominecompound 'A' and B'in theSn/conc. HCI
(6) Identify the 423-600 K + B' + H,0 hydrochloric acid on: (3)
nitrite and dilute (Oet. 201 4)
CH, - CH, + HNO, mixture of sodium (Oct. 2014) (2)
action of the
the
(7) What will be Triethyl amine? (March 2015) (2)
amine (b) Aniline (c)propan-2-amine prepared from oxime? (March 2015) (3)
(a) Ethyl
propan-1-amine and iodide?
(6) How are amine prepared from methyl
synthesis.
(9) How is ethyl on Gabriel phthalimide
(10) Write a note
 UTTAM's XIl Chemistry Papers Sohution
on:
aceticanhydride
324
the action of
I11) What is (b) Diethyi
amine.
(Oet 2015) (2)
(a) Ethyl amine nitrous acid on
action of
(12) What is the nitroalkane (b) Secondary nnittrroalkane (e) Tertiary nitroalkane. (Oet. 2015) (3)
(a) Primary 1-Nitropropane and
(13) How are: (a) suitable oxime?
(b) 2-Nitropropane prepared from March 2016) (2)
1-nitropropane, 2-nitropropane and 2-methyl-2-nitropropane are distinguished
(14) How are other using nitrous acid? March 2016) (3)
from each
action of benzene diazonium chloride on:
(15) What is the Aniline.
ia) Phenol in alkaline medium (b) huly 2016) (2)
A'and B and rewrite the reactions:
(16) ldentify As,0/ H,o H
CH,-NCH,), A + B+ (CH),N H,0 huly 2016 (1)
1) What is the action of mixture of NaNO, and dil.HCl on:
(a) Ethylamine (b) Aniline (e) Diethylamine March 2017) (3)
(18) How is nitroenthane converted into:
(a) Ethyl amine (b) N-ethylhydroxyl amine (c)Acetic acid? Auly 2017 (3)
I19) How is ethylamine prepared from (a) Nitro-alkane (b) Oxime?
Explain basic nature of amines. (March 2010; Oct. 2009; Jhuly 2017) (4)
(20) What is the action of p-toluenesulphonyl chloride on ethylamine and diethylamine? March 2018) (2)
(21) What is the action of lithium aluminium hydride in the presence of ether on the following compounds?
(a) Nitroethane (b) 2-Methyl-1 -nitropropane. Jhuly 2018) (2)
(22) Write resonance structures of aniline. What is the action of benzene diaozonium chloride
on ethanol? huly 2018) (2)
(23) Write the structure of Phenyimethanamine. March 2019) (1)
(24) Write a short note on Hoffmann elimination. (March 2019) (3)
(25) What are amines? (March 2019) (1)
Jhuly 2019) (1)
(26) Write the following conversion: Acetaldoxime into ethylamine.
Jhuly 2019) (2)
(27) Amines are basic in nature. Explain.
July 2019) (1)
(28) Convert benzene diazonium halide into aryl iodide.
July 2019) (1)
(29) What is the action of benzene sulphonyl chloride on ethanamine?
(30) Define : Quaternary ammonium salt. March 2020) (1)
(31) Write the chemical reaction involved in the formation of ethyl amine using acetaldoxime. (March 2020) (3)
(32) Write reactions to prepare ethanamine from :
(Sept. 2021) (3)
(i) Acetonitrile (ii) Nitroethane (ii) Propionamide.
(33) How will you convert -
(1) Methyl iodide to methyl isocyanide.
(Sept. 2021) (3)
(ii) Methyl cyanide to ethanoic acid ?
(34) Write chemical reactions to prepare ethanamine from:
(4) Acetonitrile (ii) Nitroethane. (March 2022) (2)
(35) Write the formula of Hinsberg's reagent. huly 2022) (1)
uly 2022) (1)
(36) Write chemical reaction for carbylamine test.
(37) Complete the following reaction and identify Aand B.
Isopropyl alcohol PBr, NH, +B uly 2022) (2)
excess

(38) Write the name of the product formed by the action of LiAlH,/ether on acetamide. March 2023) (1)
(39) Write chemical reactions for the following conversion:
Acetic acid into acetic anhydride. (March 2023) (1)
(40) Write IUPAC name and structure of mnethylphenylamine. (March 2023) (1)
(41) What is the action of the following reagents on ethylamine.
(4) Chloroform and caustic potash (ii) Nitrous acid. (March 2023) (3)
(42) Write a note on Hofmann bromamide degradation. Convert benzene diazonium chloride
into benzene. Jhuly 2023) (3)
(43) Write the name of reduction product formed when ethyl eyanide is treated with
sodium and alcohol. (March 2024) (1)
(44) Why amines are basic in nature? Among dimethylamine (pk, =3.27) and
diethylamine (pk, = 3.0), which one is more basic ? (March 2024) (2)
 325

Questions
Summary ofBoard BIOMOLECULES (March 2013) (2)
14
nucleoside. open chain
structures of nucleotide and explainedon the basis of
(Oct. 2013) (3)
(1) Write the glucose that cannot be
Enlist the properties of
(2) structure (March 2014) (3)
of it.,
is treated with
when glucose cyanide (HCN).
(3) What happens (b) Dilute nitric acid (c) Hydrogen Write the reactionthat indicates (Oct. 2014) (3)
(a) Bromine water preparation of glucose.
laboratory method for (Oct. 2014) (2)
(4) Describe group in glucose. D--- fructose. (March 2015) (2)
the presence of - CHO projection formulae of D-(+)-glucose and
Fischer (March 2015) (3)
(5) Draw the simple classified on the basis of molecular shapes? (Oct. 2015) (2)
proteins non-reducing sugars?
(6) How arecarbohydrates, What are reducing and glucopyranose ? (Oct. 2015) (3)
(7) Define monosaccharides? Draw ring structure ofa - D - (+) - (March 2016) (1)
(8) What are How is tripeptide formed?
linkage?
(9) What is peptide
carbohydrates? (3)
(10) What are reagents on glucose? (July 2016, 2018)
of following 2022) (2)
(11) What is the action (b) Dilute HNO, (c) Hydroxyl amine. July
(March 2009, 2017; (July 2017) (3)
(a) Brominewater sucrose ?
glucose prepared from
(12) How is the linkage formed?
Define enzymes. How is peptide (huly 2017) (2)
(13) glucose is treated with:
(14) What happens when Hydrogen cyanide. (March 2018) (2)
(a) Hydroxylamine
(b)
glucose is prepared from cane suger? peptide bond between
(15) How Write the correct reaction for formation of (March 2018) (2)
acids?
(16) What are amino (July 2018) (2)
amino acids.
prepared from starch? (July 2018) (1)
(17) How isglucose (March 2019) (1)
structure of Thymine.
(18) Draw the (+)- Glucopyranose (trans).
Write the number of hydroxyl groups present in a-D - peptide linkage formed? (March 2019) (3)
(19) How is
by commercial method? (July 2019) (1)
(20) How is glucose prepared
(21) Define enzyme.
conversion carried out? (July 2019) (2)
(22) How are the following Glucose into glucoxime?
(4)Glucose into n-hexane (ii) hormones. (March 2020) (2)
Haworth projection formula of a-D -(t)-glucopyranose. Define (March 2020) (3)
(23) Write proteins.
? Explain denaturation of (Sept. 202 1) (1)
(24) What are monosaccharides
present in RNA. (Sept. 2021) (2)
(25) Write the name of sugar examples.
the basis of molecular shapes with
(26) Write classification of proteins on example.
(March 2022) (2)
linkage in protein with an
(27) Explain formation of peptide of glucose. Write structure of adipic
acid. (March 2022) (3)
preparation
(28) Write commercial method of (July 2022) (1)
protein?
(29) What is denaturation of
preparation of glucose fromn sucrose.
(30) Write chemical reaction for the (March 2023) (2)
Write structure of D - ribose. (March 2023) (1)
(31) What is peptide bond. (July 2023) (1)
(32) Write the structure of glycine. (July 2023) (2)
(33) How is glucose prepared from sucrose? glucose.
(July 2023) (1)
(34) Draw the Fischer projection formula for a-D-(t) (March 2024) (2)
(35) Write classification of proteins with an example. (March 2024) (1)
(36) What are enzymes?
15 INTRODUCTION TO POLYMER CHEMISTRY

(1) Explain the following terms: (March 2013) (2)

() Homopolymers (ii) Elastomers. (March 2013) (2)
(2) Write the chemical reaction to prepare novolac polymer. process? (Oct. 2013) (2)
(3) How are polymers classified on the basis of polymerisation (Oct. 2013) (1)
(4) Write the structure of melamine. (March 2014) (2)
used in preparing Buna-S.
(5) Write names and chemical formulae of monomers (March 2014) (1)
(6) What are thermoplastic polymers? (Oct. 2014) (3)
(7) How is Nylon 6, 6 prepared? Write any two' uses of terylene. (March 2015) (2)
(8) Explain with examples, branched and linear polymers.
 326

(9) What are biodegradable polymers and non-biodegradable polymers? WriteUTTAM's XIl Chemistry Papers Solution
'one example' of each,
sO Wite the reactions involved in the preparation of -(a)
(11) Write the reaction for the preparation of Nylon 6.
Teflon (b) Orlon (c) PVC. (March 2015) (2)
(Oct. 2015) (3)
(12) How are polythene and neoprene prepared?
13) Write the formulae of the raw materials Used for (March 2016) (1)
(14) How are the following polymers prepared?
preparation of Buna -S, (March 2016) (2)
(a) Orlon (b) Teflon (Juty 2016) (1)
(15) Explain the term: Homopolymers
(16) How is nylon 6,6 prepared? (July 2016) (2)
(17) How is Terylene prepared ? (March 2017;(March
July
2017) (2)
2023) (2
(L8) Write the names and chemical
(19) Explain the
formulae of monomers used in preparing
Buna-N. (July 2017) (2)
preparation
and uses of nylon-2-nylon-6. (July 2017) (2)
(20) What are elastomers?
Distinguish between thermoplastic polymers and (March 2018) (3)
(21) Write chemical reactions to prepare the following thermosetting polymers. (July 2018) (3)
(1) Teflon (ii)
Nylon-6 polymers:
(22) Write the reactions for the (March 2019) (3)
() Vinyl chloride () preparation of polymers by using the following monomers:
(23) Define: (1) Tetrafluoroethane.
(24) Define
Condensation polymer (i) Homopolymer. July 2019) (2)
non-biodegradable polymer. Write the preparation of terelyne.
(25) Write names and structure of
(July 2019) (2)
(March 2020) (2)
(26) Write classification of monomers used in the preparation of Nylon 6, 6 polymer.
polymers on the basis of structure. (Sept. 2021) (2)
(27) Write the name of (March 2022) (3)
biodegradable
(28) Write the name of monomer usedpolyamide copolymer. (March 2022) (1)
for preparation of Nylon 6.
(29) Write chemical composition of Zieglar- Natta July 2022) (1)
(30) Define: Elastomer. catalyst. (July 2022) (1)
(31) Write the reactions for the formation of nylon 6, 6 (July 2022) (1)
(32) Define: Vulcanization.
polymer. (March 2023) (3)
(33) Write the reaction involved in the formation of Teflon. (March 2023) (1)
(34) Write the structure of and name of monomer of: (a) Nylon -6 (b) Natural rubber. (July 2023) (1)
(35) Write the chemical reaction for the preparation of polyacrylonitrile. (March 2024) (2)
(March 2024) (1)
16 GREEN CHEMISTRY AND NANOCHEMISTRY
(1) Write the name of nanostructural material used in tyres to increase their life.
(Sept. 2021) (1)
(2) Explain three principles of green chemistry. (Sept. 2021) (2)
(3) Define green chemistry. Write two disadvantages of nanotechnology. (March 2022) (2)
(4) Define: Nanochemistry. (July 2022) (1)
(5) Define: Nanotechnology.
(July 2022) (1)
(6) Define: Green chemistry.
July 2022) (1)
(7) Write the name of the technique used to know geometry of nanoparticles. (March 2023) (1)
(8) Define: Green chemistry. Write two advantages of nanoparticle and nanotechnology. (March 2023) (2)
(9) Write the name of nano structured material used in car tyres to increase the life of tyres. (March 2023) (1)
(10) Name they- isomer of BHC
July 2023) (1)
(11) Write any three advantages and disadvantages of nanoparticles and nanotechnology. July 2023) (2)
(12) Write the name of metal nanoparticle used to remove E.coli bacteria from water (March 2024) (1)
12 What is nano material ?Write the reaction involved in sol-gel process during hydrolvsis
(March 2024) (2)
(14) Define: Nanoscience. (March 2024) (1)