CHEMISTRY COORDINATION COMPOUNDS

R-DPP
Day

46
REVISION-DAILY PRACTICE Date:27/12/24
PROBLEMS
EXCEL & ACCELARATOR
Sub.: CHEMISTRY
JEE 2025 Revision
Course: JP Revision Topic: COORDINATION COMPOUNDS

1. The IUPAC name for Pt  NH3 3  Br   NO2   Cl  Cl is

A) Triammine chloro bromo nitro platinum (IV) chloride
B) Triammine bromo chloro nitro platnium (IV) chloride
C) Triammine nitro chloro bromo platinum(IV) chloride
D) Triammine chloro nitro bromo platinum (IV) chloride
2. The correct formula of a compound whose IUPAC name is Tetramethyl ammonium trioxalato
chromate (III) is
A)  CH3 4 NH4 Cr  C2O4 3  B)  CH3 4 N Cr  C2O4 3 

 
C) CH3 4 N Cr C2O4 3 
3
D) CH3 4 N Cr C2O4 3 
4
 
3. Which of the following complex ions obeys Sidgwick’s effective atomic number (EAN) rule?
3 4 3 2
A) Fe  CN6  B) Fe  CN6  C) Cr  NH3 6  D) Ni  en3 
4. Which one of the following coordination compounds exhibits ionization isomerism?
A) Cr  NH3 6  Cl3 B) Cr  en3 Cl3  C) Cr  en3  Cl3 D) Co  NH3 5 Br  SO4
5. A coordination compound of cobalt has the molecular formula containing five ammonia
molecules, one nitro group and two chlorine atoms for one cobalt atom. One mole of this
compound produces three moles of ions in an aqueous solution. The aqueous solution on
treatment with an excess of AgNO3 gives two moles of AgCl as a precipitate. The formula of this
complex would be
A) Co  NH3 4 NO2Cl  NH3Cl B) Co  NH3  Cl  ClNO2 
C) Co  NH3 5 NO2  Cl2 D) Co  NH3 5   NO2 2 Cl2 
6. Arrange the complexes in order of increasing electrical conductivity.
I) Co  NH3 6  Cl3 II) Co  NH3 4 Cl2  Cl III) Co  NH3 5 Cl  Cl2 IV) Co  NH3 3 Cl3 
A) IV < II < I < III B) IV < I < II < III C) I < III < II < IV D) IV < II < III < I
3
The hybridization states of the central atom in the complex ions FeF6  , Fe  H2O6 
3
7. and
2
Ni  NH3 6  are
 
3 2
A) sp d ,dsp2 and d2sp3 respectively B) all d2sp3
C) all sp3d2 D) sp3d2 ,sp3d2 andd2sp3 respectively
8. Among TiF62 ,CoF63 ,Cu2Cl2 and NiCl24 (atomic numbers of Ti = 22, Co= 27, Cu = 29, Ni = 28),
the colourless species are
A) CoF63 and NiCl24 B) TiF62 and CoF63
C) Cu2Cl2 and NiCl24 D) TiF62 and Cu2Cl2
and NiCl4 
2 2
9. Among Ni  CO4  , Ni CN4 

are diamagnetic and NiCl4 

2 2
A) Ni  CO4  and Ni  CN4  is paramagnetic

B) NiCl4  are diamagnetic and Ni(CO)4  is paramagnetic

2 2
and Ni  CN4 

are diamagnetic and NiCl4 

2 2
C) Ni  CO4  and Ni  CN4  is paramagnetic

D) Ni  CO4  is diamagnetic and NiCl4 

2 2
and Ni  CN4  are paramagnetic

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CHEMISTRY COORDINATION COMPOUNDS

10. What is the expected order for increasing octahedral  0  crystal field splitting for the ligands
I ,F ,H2O,NH3, en and CO?
A) I  F  H2O  NH3  en  CO B) F  I  NH3  en  CO  H2O
C) I  F  H2O  CO  NH3  en D) CO  en  NH3  H2O  F  I
11. Tetrahedral complexes of the types of Ma 4  and Ma3b (where M = metal; a, b = achiral
ligands) are not able to show optical isomerism because
A) These molecules/ions possesses Cn axis of symmetry
B) These molecules/ions possesses a plane of symmetry and hence are achiral
C) These molecules possesses a central of symmetry
D) These molecules/ions have non superimposable mirror images
12. FeSO4 is a very good absorber for NO, the new compound formed by this process is found to
contain number of unpaired electrons:
A) 4 B) 5 C) 3 D) 6

13. CoCl2  NH3 4   Cl  CoCl3  NH3 3   NH3
If in this reaction two isomers of the product are obtained, which is true for the initial
(reactant) complex:
A) Compound is in cis-forms
B) Compound is in trans-form
C) Compound is in both (cis and trans) forms
D) cann’t be predicted
14. Which of the following is not an organometallic compound?
A) Ferrocene B) Ruthenocene
C) Beryllium acetylacetonate D) Bis(benzene)chromium
15. Which is not a   bonded complex?
A) Zeise salt B) Ferrocene C) Bis(benzene)chromium D) Tetra ethyl lead
16. Mn2+ forms a complex with Br– ion. The magnetic moment of the complex is 5.92 B.M. What
could not be the probable formula and geometry of the complex?
4- 2-
(A) [MnBr6] , octahedral (B) [MnBr4] , square planar
2- 3-
(C) [MnBr4] , tetrahedral (D) [MnBr5] , trigonal bipyramidal
17. Which of the following statements is correct regarding the chirality (optical isomerism) of the
cis and trans isomers of the type M(aa)2b2 (M stands for a metal, a and b are achiral ligands
and aa means bidentate ligands
a b
a b a a

a b a a
a
b
cis trans
A) The trans form is achiral and optically inactive while the cis form is chiral and exists in
two enantiomeric forms
B) The cis as well as the trans form are achiral and optically inactive
C) The trans form is chiral and exists in two enantiomeric forms while the cis form is achiral
and optically inactive
D) The cis as well as the trans form are chiral and each of them exists in two enantiomeric
forms
2
18. How many isomers are possible for the complex ion Cr  NH3   OH2 Cl3  ?
A) 2 B) 3 C) 4 D) 5
19. A complex of certain metal has the magnetic moment of 4.91 BM whereas another complex of
the same metal with same oxidation state has zero magnetic moment. The metal ion could be :
A) Co2+ B)Mn2+ C)Fe2+ D)Fe3+
20. The correct order for the CFSE (numerical value) for the following complexes is:
Complex P Q R S
Formula [CoF6]3– [Co(CN)6]3– [Co(NH3)6]3+ [Co(H2O)6]3+
A) P > Q > R > S B) Q > R > S > P C) S > R > P > Q D) R > Q > P > S
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CHEMISTRY COORDINATION COMPOUNDS

21. 0.001 molal solution of a complex [M(NH3)4Cl4] in water has a freezing point depression of
0.0054oC. If Kf for water is 1.8 K Kg mol-1, the correct formula of the complex is:
A) [M(NH3)4Cl3]Cl B) [M(NH3)4Cl2]Cl2 C) [M(NH3)4Cl]Cl3 D) [M(NH3)4Cl4]
22. Of the following statements, which one is correct?
3
A) CoF6  is a high spin complex and Co  NH3 6 
3
is a low spin complex
3
B) CoF6  is a low spin complex and Co  NH3 6 
3
is a high spin complex
3
C) Both CoF6  and Co  NH3 6 
3
are low spin complexes
3
D) Both CoF6  and Co  NH3 6 
3
are high spin complexes

23. The two compounds Cr  NH3 5 Br  Cl and Cr  NH3 5 Cl  Br can be distinguished by reagent
(A) and the two compounds exhibit isomerism (B). Then (A) and (B) are:
A) AgNO3, ionization B) AgNO3, coordination
C) BaCl2, ionization D) BaCl2, coordination
2
24. On treatment of Ni  NH3 4  with concentrated HCl, two compounds I and II having the same

formula, Ni  NH3 2 Cl2  are obtained, I can be converted into II by boiling with dilute HCl. A

solution of I reacts with oxalic acid to form Ni  NH3 2  C2O4  whereas II does not react. Point
out the correct statement of the following:
A) I cis, II trans ; both tetrahedral B) I cis, II trans ; both square planar
C) I trans, II cis ; both tetrahedral D) I trans, II cis ; both square planar
25. Which one of the following high-spin complexes has the largest CFSE (Crystal field
stabilization energy)?
A) [Mn(H2O)6]2+ B) [Cr(H2O)6]2+ C) [Mn(H2O)6]3+ D) [Cr(H2O)6]3+
26. Find out the numbers of isomers (structural and stereo) produced by the complex
Pt  NH3   NO2  Cl3 
 2 
A) 6 B) 76 C) 8 D) 5
27. During of ‘Fixing of image’ in the photography process the following reaction takes place
AgBr + xNa2S2O3  Nay[Ag(S2O3)x] (water soluble). The value of (x + y) is
A) 9 B) 7 C) 5 D) 2
28. Effective atomic number of complex of 42Mo is 54. The formula of its carbonyl complex is
Mo(CO)x. The value of ‘x’ is …………….
A) 12 B) 6 C) 18 D) 24
29. How many of the following complexes can exist as ‘d’ and ‘l’ isomers
 
Co  NH3 4 Cl2  , Co  NH3 3 Cl3  , trans Co en2 Cl2  ,
   
 3 3
Cis Co  en2 Cl2  , Cr  Ox 3  , Cr  en3  , Pt en2 Cl2 
A) 1 B) 2 C) 3 D) 4
30. Ruthenocene like ferrocene, is a sandwich complex known to be a cyclopentadienyl complex,

 
which is represented as Ru x  C5H5  ; x  y is
y

A) 10 B) 9 C) 8 D) 7

1 6 11 16 21 26
2 7 12 17 22 27
OMR

3 8 13 18 23 28
4 9 14 19 24 29
5 10 15 20 25 30

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CHEMISTRY COORDINATION COMPOUNDS

1) B 2) C 3) B 4) D 5) C 6) D 7) D 8) D 9) A 10) A

11) B 12) C 13) A 14) C 15) D 16) C 17) A 18) B 19) C 20) B

21) B 22) A 23) A 24) B 25) D 26) A 27) C 28) B 29) C 30) D

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