PHYSICS MAX.

MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

01. In the following circuit the output y becomes zero for the inputs

A) A  1; B  0; C  0 B) A  1; B  1; C  0
C) A  0; B  1; C  1 D) A  0; B  0; C  0
02. Position of particle is given by x = t3 - 4t2 + 5t + 9. What would be the distance
travelled by particle from instant t = 0 to instant when particle changes its direction of
velocity for last time.
A) 1.85 m B) 2.15 m C) 2m D) 2.85 m
03. A silver ball is suspended by a string in a vacuum chamber and ultraviolet light of
wavelength 200 nm is directed at it. What electrical potential will the ball acquire as a
result of it, if work function of silver is 4.7 eV  h  6.6  10 34 J-s and c  3  108 m/s 

A) 1.5V B) 3.5V C) 4V D) 0.5V

04. Fluid of density 103 kg/m3 is kept in container. Container is moving with acceleration
of 10 ms 2 . Find the magnitude of pressure (in Pa) difference between A and B as
shown in figure. Distances are in meters. (Take g  10 m / s 2 )

A) 104 B) 0 C) 2  104 D) 2  10 4
05. The wavelength of radiation emitted is 0 when an electron jumps from the third to
the second orbit of hydrogen atom. If the electron jumps from the fourth to the second
orbit of the hydrogen atom, the wavelength of radiation emitted will be
16 20 27 25
A) 0 B) 0 C) 0 D) 0
25 27 20 16
06. A time varying force is applied on a block placed over a rough surface as shown in
figure. Let  be the angle between net contact force on the block and the normal
reaction. Then with time,  will
F=2t

Rough
 A) remain constant
B) first increase to a maximum value (say max ) and then becomes constant in a value
slightly less then max
C) first decrease to a minimum value (say  min ) and then becomes constant in value
slightly more then  min
D) None of the above
07. A body is projected vertically upwards from the surface of the earth with a velocity
equal to half of escape velocity of the earth if R is radius of the earth, maximum
height attained by the body from the surface of the earth is
R R R
A) h  B) h  C) h  D) h  R
4 2 3
08. Find the magnetic moment of a thin round loop with current if the radius of the loop is
equal to R  100 mm and the magnetic induction at its centre is equal to B  6 T .

A) 3  102 Am 2 B) 4  103 Am 2 C) 5  102 Am2 D) 2  102 Am 2

09. The displacement of two identical particles executing SHM are represented by

equations x1  4sin  10t   and x2  5cos t
 6
For what value of  , the energy of both the particles become equal?
A) 16 unit B) 6 unit C) 4 unit D) 8 unit
10. An ideal gas mixture filled inside a balloon expands according to the relation
2
PV 3  Constant. The temperature inside the balloon is
A) Increasing B) Decreasing C) Constant D) Can’t be said
11. A plane electromagnetic wave of frequency 200 MHz is travelling in vacuum along
the positive x-direction. At a particular point in space and time magnetic field is

B  20  108 k T . What is the electric field at that point (speed of light c  3  108 ms 1 )
 
A) 60.0 k V / m B) 6 k V / m C) 60jV / m D) 6jV / m
 EB
12. The dimensional formula for the physical quantity is (here, E-Intensity of electric

field, B-magnetic induction and  -absolute permeability).
A) ML0T 3 B) ML2T 2 C) M 2 L3T 3 D) ML2T 3
13. In series LCR circuit voltmeter and ammeter reading are

A) V = 250 V, I = 4A B) V = 150 V, I = 2A
C) V = 1000V, I = 5A D) V = 100 V, I = 2A
1
 1 2
14. The rms speed of oxygen molecule in a vessel at particular temperature is  1   V ,
 x
where ‘V’ is the average speed of the molecule at the same temperature. The value of
 22 
‘x’ will be     .
 7 
A) 2.8 B) 3.8 C) 5.6 D) 6.6
15. Angle of minimum deviation is equal to the angle of prism A of an equilateral glass
prism. The angle of incidence at which minimum deviation will be obtained is
A) 60 B) 30 C) 45 D) sin 1  2 / 3
16. 1 cm on the main scale of a vernier calipers is divided into 10 equal parts. If 10
divisions of vernier coincide with 8 small divisions of main scale, then the least count
of the vernier calipers will be:
A) 0.01 cm B) 0.02 cm C) 0.05 cm D) 0.005 cm
17. The period of oscillation of a simple pendulum of length L suspended from the roof of
a vehicle, which moves without friction down an inclined plane of inclination  , is
given by.
L L L L
A) 2 B) 2 C) 2 D) 2
g cos  g sin  g g tan 

18. Positive and negative point charges of equal magnitude are kept at
 a  a 
 0,0,  and  0,0,  respectively. The work done by the electric field when another
 2  2 
positive point charge is moved from  a,0,0  to  0, a,0  is.
A) Positive
B) Negative
C) Zero
D) Depends on the path connecting the initial and final positions
19. A disc of mass M and radius R is rolling with angular speed  on a horizontal x-z
plane as shown in figure. The magnitude of angular momentum of the disc about the
origin O is.

A) 1 / 2  MR 2 B)  3 / 2  MR 2 C) MR 2 D) 2MR 2
20. In the given circuit with steady current the potential drop across the capacitor must be:

A) V B) V / 2 C) V / 3 D) 2V / 3
 SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 5 questions. The answer to each question is a Numerical value. If the
Answer in the decimals , Round off to the nearest Integer only. Have to Answer all 5
questions and question will be evaluated according to the following marking scheme:
Marking Scheme: +4 for correct answer, 0 if not attempted and –1 if not correct.

21. Figure shows the graph of angle of deviations  versus angle of incidence i for a
light ray striking a prism. The prism angle is ______ (in degree).

30

i
15 60
22. The value of resistance  in   should be connected in parallel with 20  resistor (in
ADC branch) so that potential difference between B & D may be zero.

23. Consider a body of mass 1.0 kg at rest at the origin at time t  0 . A force
   
F  t i  j  is applied on the body, where   1.0N s -1 and   1.0N . The torque
 
  1
acting on the body about the origin at time t  1.0 s is  .   Nm then find x
x
24. A wire of length L metre carrying a current I ampere is bent in the form of a circle.
Lx i
The magnitude of its magnetic moment is M  then find x ______
4
25. Two soap bubbles A and B are kept in a closed chamber where the air is maintained at
pressure 8 N / m2 . The radii of bubbles A and B are 2 cm and 4 cm respectively.
Surface tension of the soap-water used to make bubbles is 0.04 N / m . The value of
nB / nA is _______ (where nA and nB are the number of moles of air in bubbles A and
B, respectively). [Neglect the effect of gravity.]

CHEMISTRY MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
26. Dry air was passed successively through a solution containing 5 g of solute (non-
volatile and non-electrolytic) in 90 ml H 2O and then through pure H 2O . The loss in
weight of solution was 2 g and that of pure solvent 0.05 g . The mol. wt. of solute (in
gm ) is: (Given: density of water  1g / cc )
A) 60 B) 40 C) 80 D) 20
0
27. For the fuel cell reaction 2 H 2 g   O2 g   2 H 2Ol  ;  f H 298 (H 2O, l ) = - 285.5 kJ/mol
0 0
The values of S298 and G298 for the given fuel cell reaction respectively are

Given : O2 g   4 H aq   4e  2 H 2Ol  , E 0  1.23 V

A) -0.323 kJ/K, -474.78 kJ B) -0.635 kJ/K, -463.78 kJ

C) 3.51 kJ/K, -463.78 kJ D) -0.323 J/K, -474.78 kJ
28. At 25C , Solubility of AgCl is S1, S2, S3 and S4 respectively in pure H2O, 0.3M
BaCl2, 0.2M AgNO3 and 0.5M HCl, then decreasing order of solubility is
(Given: ksp AgCl  1  1010 at 25C )

A) S2  S1  S4  S3 B) S1  S4  S3  S2
C) S1  S3  S4  S2 D) S3  S1  S4  S2
29. N 2O5 g  decomposes to NO 2(g) and O 2(g) follows 1st order kinetics. After 50 minutes the

pressure inside the vessel increases from 50mm Hg to 87.5 mm Hg. The pressure of
the gaseous mixture after 100 minutes at constant temperature will be
A) 175.0 mm Hg B) 116.25mm Hg
C) 136.25 mm Hg D) 106.25 mm Hg
30. 1.0 molal aqueous solution of an electrolyte A2B3 is 70% ionized. The boiling point of

 
the solution at 1 atm is Kb H 2O   0.5 k kg mol 1 ( BP of water is 373K at 1 atm)

A) 371.1 K B) 374.9 K C) 376.4 K D) 373.76 K

31. Find  r H 0 for the reaction 4 HCl g   O2 g   2Cl2 g   2 H 2O g  at 300 K. Assume all

gases are ideal.

0
Given : H 2 g   Cl2 g   2 HCl g  ;  r H 300  184.5 kJ
0
2 H 2 g   O2 g   2 H 2O g  ;  r H 300  483 kJ

A) 111.5 kJ B) -109.01 kJ
C) -111.5 kJ D) -114 kJ

32.
 Product of the reaction is

A) B)

C) D)

33. At constant temperature and pressure, the percentage of butane by volume in a

mixture of butane, propane and propyne is 40%. What will be the volume of CO2 g 

(in ml) under same pressure and temperature produced, when 150 ml of gaseous
mixture is burnt in excess of O2 ?
A) 270 ml B) 150 ml C) 510 ml D) 240 ml
34. The major final product in the following reactions sequence is:

A) B) C) D)
35. Slowest rate of electrophilic addition will take place in

A) B)

C) D)
36. Among the following, the species that is both paramagnetic and coloured is
2 2 3
A)  MnO4  B) TiCl6  C) VO4  D) CrO2Cl2

Page | 9
 2
37. Total number of possible isomers (including stereo) for  Fe  gly 2 Cl2 

 gly  NH 2  CH 2  COO  

A) 4 B) 6 C) 8 D) 2
38.

Zn dust
(X) or (Y) 

  Z   ZnO . ‘Z’ cannot be prepared by
H2 ( i ) SnCl  HCl
A) C6 H 5COCl 
Pd  BaSO4
 B) C6 H 5CN  4
( ii ) H O 

3

 2 2 2
i CrO Cl / CS  i  NBS  2 eq , h
C) C6 H 5CH 3 
( ii ) H O
 D) C6 H 5CH 3 
( ii ) Aq . KOH
3

39. Consider the following compounds and select the correct statement from the following:

NH 3 , PH 3 , SO2 , BF3 , NO2 , ClO3 , CO

2
A) Three molecules out of given compounds involves sp hybridization for central atom
3
B) Two molecules out of given compounds involves sp d hybridization for central atom

C) Four molecules out of given compounds involves both  p  d   and  p  p  bonding

D) Four molecules out of given compounds are hypervalent compounds
40. Salicin (structure given below) is a glycoside, found in the bark of willow tree, used in
relieving pain. Observe the following reaction of salicin

The correct statement(s) is (are) :

I. P is D- glucose
II. Q is 2-hydroxybenzylalcohol
 III. P is L-glucose
IV. The above reaction occurs through a carbocation
A) I, II, III only B) I, II, IV only C) I, IV only D) I, II only
41. Identify correct order of increasing ionic radii.

A) Mg 2 , Na  , F  , O 2 , N 3 B) N 3 , O 2 , F  , Na  , Mg 2

C) F  , Na  , O 2 , Mg 2 , N 3 D) Na  , F  , Mg 2 , O 2 , N 3

42.

CN

CN H3O +
CN A; Product (A) of the reaction is

CN

A) C) D)

43. The incorrect order of the following

A) B  Tl  Ga  Al  In , ( IP1 order)

B) C  Si  Ge  Sn  Pb (EN order)

C) S  Se  Te  O (Negative electron gain enthalpy order)

D) Cl2  Br2  F2  I 2 (Bond energy order)

44. Identify the f-subshells are half and completely filled, respectively in lanthanide ions.
[Given : Atomic no. Eu, 63 ; Sm, 62; Tm, 69 ; Tb, 65 ; Yb, 70 ; Dy, 66 ]
A) Eu 2 and Tm 2 B) Sm 2 and Tm3 C) Tb4 and Yb 2 D) Dy 3 and Yb3
45. Match the complex ions listed in column –I with the characteristics listed in column –
II using the codes gives below.

Column I Column II
(a)  Ni  NH 3 6 
2
(p) d2sp3 and diamagnetic

(b) CoF6 
3
(q) sp3d2 and diamagnetic

(c) Co  NH 3 6 
3
(r) sp3d2 and two unpaired electrons

(d)  Zn  NH 3 6 
2
(s) sp3d2 and four unpaired
electrons.
A) a  s; b  r ; c  q; d  p B) a  r ; b  s; c  p ; d  q
C) a  r ; b  s; c  q; d  p D) a  p; b  q ; c  r ; d  s
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 5 questions. The answer to each question is a Numerical value. If the
Answer in the decimals , Round off to the nearest Integer only. Have to Answer all 5
questions and question will be evaluated according to the following marking scheme:
Marking Scheme: +4 for correct answer, 0 if not attempted and –1 if not correct.

46. How many condensation products including stereoisomers are possible when ethanal
and phenyl ethanal (mixture) is treated with dil. NaOH/  ?
47. X = Sum of antibonding  electrons (  * electrons) in species O2, O 2¯ and O22
Y = The number of species, among the following species, where central atoms have
two lone pairs of electrons

XeF4 XeF5¯ F2SeO2

XeF3+ XeOF4 ClOF3
ICl4¯ SCl2 OSF4
Find the value of X + Y.
48. Given cell is H 2 g   P = 1.0atm  H +aq   pH = X  Calomel 1N  . At 250C, the standard

electrode potential is 0.28V and the cell potential is 0.516 V. What is the value of X?
2.303RT
(Given:  0.059 )
F
49. If Phosphorus acid, Tetrathionic acid and Pyrophosphoric acid have maximum
number of acidic hydrogens per molecule respectively are x, y and z, then find the
value of x + y + z?
50. In a linear tetrapeptide (Constituted with different amino acids), then, number of
amino acids  x , number of peptide bonds  y then x  y  ?

MATHS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
9 20
x  1  10 x  x
51.   1  x10  1  x 20  dx is equal to: (where c is an integral constant)
e
 

 1  x10  10
x 1 x 
 1  x10   1  x10 
A) e x  10 
 c B) e  10 
 c C) e x
   c D) e x
 c
1 x  1 x   1  x10   1  x10 
   
n
n n   1  1  1 
  n  1  n  3  n  32  .... n  3n 1   is e then k is
k
52. The value of lim n
n 
     
A) 1.5 B) 2.5 C) 1 D) 0
53. If cos  ,sin  ,sin  are in increasing G.P., then roots of x 2  2cot  .x  1  0 are:
(where  ,   R )
A) Real and distinct B) both positive C) Real and equal D) Imaginary
 bc b 2  bc c 2  bc
54. Let   a 2  ac  ac c 2  ac and the equation px3  qx 2  rx  s  0 has roots a,
a 2  ab b 2  ab  ab

2p
b, c where a, b, c  R . If   27 and a2 + b2 + c2 = 2, then  1 is
q
A) 1 B) 0 C) 1/2 D) – 1/2
55. In a test an examinee either guesses, copies or knows the answer to multiple choice
1
question with five choices. The probability that he makes a guess is and probability
4
1
that he copies the answer is . The probability that his answer is correct given that he
8
1
copies is . Find the probability that he knows the answer to the question given that
10
he correctly answered it:
10 1 12
A) 1 B) C) D)
11 2 19
20
56. The value of  sin x  cos x  dx
20 

A) 10 B) 20 C) 20 D) 10

57. The area of the parallelogram formed by the lines
4 y – 3 x  1, 4 y – 3 x – 3  0, 3 y – 4 x  1  0, 3 y – 4 x  2  0 is
A)3/8 B) 2/7 C) 1/6 D) 5/6
x  a2 ab ac
58. If a, b, c are real, then f  x   ab x  b2 bc is decreasing in
2
ac bc xc

 2   2 
A)    a 2  b2  c 2  ,0  B)  0,  a 2  b 2  c 2  
 3   3 
 a2  b2  c2 
C)  0,  D) No where
 3 
 x
59. The function f : R   x  R : 1  x  1 defined by f  x   is
1 x
A) One – one and into B) One – one and onto
C) many one and into D) many – one and onto
60. If a conic passes through (1, 0) and satisfies differential equation

1  y  dx  xydy  0 . Then the equation of circle which is touching this conic at

2

 
2,1 and passing through one of its foci is:

A) x 2  y 2  3 2 x  y  4  0 B) x 2  y 2  2 x  y  1  0

C) x 2  y 2  2 x  3 y  1  0 D) x 2  y 2  3 2 x  3 y  4  0

61. Area bounded by the graphs of y  x2  1, y  0, x  0 and x  2

A) 14/3 B) 3 C) 2 D) 2/3

62.  
An ellipse passing through the point 2 13,4 has its foci at (-4, 1) and (4, 1). Then

its eccentricity is
1 1 1 1
A) B) C) D)
2 2 4 2 2
63. A (1, 0) and B (0, 1) are two fixed points on the circle x 2  y 2  1 . C is a variable point
on this circle. As C moves, the locus of the ortho centre of the triangle ABC is
A) x 2  y 2  2 x  2 y  1  0 B) x 2  y 2  x  y  0

C) x 2  y 2  4 D) x 2  y 2  2 x  2 y  1  0
3
64. In binomial probability distribution B(n, p), mean is 3 and standard deviation is .
2
Then the value of p is
1 3 1 1
A) B) C) D)
4 4 2 3
 n n
 131 a  C
65. If the Second term of the expansion  a   is 14a then the value of n 3 is
5/ 2

 a 1  C2
A) 4 B) 3 C) 12 D) 6
66. If pth, qth, rth, terms of G.P. are the positive number a, b, c respectively, then angle

between the vectors log a 3i  log b3j  log c3 

k and  q  r i   r  p  j   p  q  
k is

   1 
A) B) C) 0 D) sin 1  
2 3  2 2 2 
p q r 

      x
67. Let a  i  j  
k and b  i  j  
k . If a  b  a  b and f  x    sin  t  dt , then
2

the value of f '    

1 1 1 1 1
A) sin  4  B) sin  2  C) sin   D) sin 1
4 2 2 2 2 2
68. Let f  x   x  sin x . Suppose g denotes the inverse function of f . The value of

  
g '   is equal to:
4 2

2 1
A) 2 1 B) C) 2  2 D) 2 1
2
P   x : x  R, x  2
69. Let
Q   x: x R, x  1  2

P  Q = R- S then set S is: (where R is the set of real numbers)

A) [-2, 2] B) [2, 3] C) [2, 3) D) (-1, 2]
x 1 y  2 z  3
70. Equation of the line of shortest distance between the lines   and
2 3 4
x2 y 4 z 5
  is
3 4 5

Page | 16
 5 13 5 13
x z x z
3 y  3 3 3 y  3 3
A)  B) 
2 1 1 1 2 1
5 13 5 13
x z x z
3 y  3 3 3 y  3 3
C)  D) 
2 1 1 1 2 1

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 5 questions. The answer to each question is a Numerical value. If the
Answer in the decimals , Round off to the nearest Integer only. Have to Answer all 5
questions and question will be evaluated according to the following marking scheme:
Marking Scheme: +4 for correct answer, 0 if not attempted and –1 if not correct.
71. The number of values of x satisfying 2
log5 16.log 4 x log x 5
2
 5x  x
 log 5  x5  0
5
4

72. The equation z 2   3  i  z   m  2i   0  m  R  has exactly one real and one non

real complex root, then product of real root and imaginary part of non-real complex

root is:

d2y
73. If e x  y  y 2 then at  1,1 is equal to
dx 2

74. Let a and b respectively be the points of local maximum and local minimum of the

function f  x   2 x 3  3 x 2  12 x . If A is the total area of the region bounded by

y  f  x  , the x – axis and the lines x = a and x = b, then 4A is equal to

75. If ‘a’ denotes the number of permutation of ‘n’ different things taken all at a time, ‘b’

the number of permutation of  n  2  different things taken 10 at a time and ‘c’ be the
number of permutations of  n  12  different things taken all at a time such that

a  182bc , then value of ‘n’ is: