AnswerKey RTS-17 - RF26G
AnswerKey RTS-17 - RF26G
(Answer Key)
21 - 60 22 - 31 23 - 1200 24 - 0 25 - 39
26 - C 27 - A 28 - D 29 - A 30 - C 31 - C 32 - B 33 - B 34 - B 35 - C
36 - D 37 - C 38 - C 39 - C 40 - C 41 - D 42 - C 43 - C 44 - A 45 - A
46 - 84 47 - 4 48 - 30 49 - 5 50 - 2
51 - C 52 - C 53 - B 54 - C 55 - D 56 - B 57 - C 58 - C 59 - B 60 - D
61 - D 62 - C 63 - B 64 - B 65 - D 66 - B 67 - A 68 - C 69 - B 70 - B
71 - 75 72 - 2 73 - 9 74 - 8 75 - 31
7
RTS-17 RF26G
(Solutions)
(2) A frictionless heat engine can be 100% efficient (5) Four rods of identical cross-sectional area and
only if its exhaust temperature is ............ made from the same metal form the sides of
(A) Equal to its input temperature square. The temperature of√ two diagonally
opposite points and T and 2 T respective in the
(B) Less than its input temperature
steady state. Assuming that only heat conduction
(C) 0 K takes place, what will be the temperature
(D) 0◦ C difference
√
between other two points
(A) 2 T
2+1 (B) √2+1
2
T
Solution:(Correct Answer:C) (C) 0 (D) None of these
8
Solution:(Correct Answer:C) Solution:(Correct Answer:C)
(c) Temperature difference between C and D is Vrms = 3kT = 3×1.38×10−23 ×293
5×10−17
zero. m
≈ 15 mm/s
9
(14) Two liquids A and B are at 32 o C and 24 o C. When (A) (B)
mixed in equal masses the temperature of the
mixture is found to be 28 o C. Their specific heats
are in the ratio of
(A) 3 : 2 (B) 2 : 3
(C) 1 : 1 (D) 4 : 3
Solution:(Correct Answer:C)
(C) (D)
Heat lost by A = heat gained by B
⇒ mA × cA × (TA − T ) = mB × cB × (T − TB )
since mA = mB and temperature of the mixture
(T ) = 28◦ C
∴ CA × (32 − 28) = cB × (28 − 24)
⇒ ccBA = 1 : 1
Solution:(Correct Answer:B)
(b) Input energy = sec 1g
× 2kcal
g
= 2kcal/ sec .
Output energy
= 10 KW = 10 K J/S= 4.2 10
kcal/ sec .
output energy
== > η = input energy = 4.2×2 > 1, it is impossible.
10
10
(19) At 27°C temperature, the kinetic energy of an ∴ 5 = T1253K
−253 K
ideal gas is E1 . If the temperature is increased to 5T1 − 5 (253 K) = 253 K
327°C, then kinetic energy would be 5T1 = 253 K + 5 (253 K) = 6 (253 K)
(A) 2E1 (B) 12 E1 T1 = 65 (253K) = 303.6 K = 303.6 − 273
√ = 30.6◦ C ≈ 31◦ C
(C) 2E1 (D) √12 E1
Solution:(Correct Answer:A) (23) The temperature of the mixture of one mole of
helium and one mole of hydrogen is increased
KE ∝ T
from 0o C to 100o C at constant pressure. The
So, KE 1 (27+273)K
= TT12 ⇒ (327+273)K =E 1
KE2 E2 amount of heat delivered will be ...... cal
E1
E2
= 300
600
= 12 ⇒ E2 = 2E1
Solution:
(20) A thermo-dynamical system is changed from µ C +µ C
(CP )mix = 1 Pµ11 +µ22 P2 (CP1 (He) = 52 R and
state (P1 , V1 ) to (P2 , V2 ) by two different process.
CP2 (H2 ) = 72 R)
The quantity which will remain same will be 1× 5 R+1× 7 R
(A) ∆ Q (B) ∆ W = 2 1+1 2 = 3R= 3 × 2 = 6 cal/mol.◦ C
Heat required to raise the temperature from 0o C
(C) ∆Q + ∆W (D) ∆Q − ∆W to 100o C
Solution:(Correct Answer:D) (∆Q)P = µCP ∆T = 2 × 6 × 100 = 1200 cal
Change in internal energy does not depend upon (24) Four identical rods of same material are joined
path so ∆U = ∆Q − ∆W remain constant. end to end to form a square. If the temperature
difference between the ends of a diagonal is
............ Physics - Section B (NUMERIC) ............ 100o C, then the temperature difference between
the ends of other diagonal will be ........ o C
(21) A thin rod having a length of 1 m and area of
cross-section 3 × 10−6 m2 is suspended vertically Solution:
from one end. The rod is cooled from 210◦ C to (a) Suppose temperature difference between A
160◦ C. After cooling, a mass M is attached at the and B is 100°C and θA > θB
lower end of the rod such that the length of rod Heat current will flow from A to B via path ACB
again becomes 1 m. Young’s modulus and and ADB . Since all the rod are identical so
coefficient of linear expansion of the rod are (∆θAC > ∆θAD
2 × 1011 N m−2 and 2 × 10−5 K −1 , respectively. The (Because heat current H = ∆θ ;here R = same for
R
value of M is .......kg. ( Take g = 10 ms−2 ) all.)
== > θA − θC = θA − θD == > θC = θD
Solution: i.e. temperature difference between C and D will
If ∆l is decease in length of rod due to decease in be zero.
temperature
∆l = lα∆T
α = 2 × 10−5 K −1 , ∆T = (210 − 160) = 50 K
∆l = 1 × 2 × 10−5 × 50 = 10−3 m
Young Modulus = Y = F∆l/l /A
A = 3 × 10−6 m2
−6
2 × 1011 = Mg/3×10
10−3 /1
M g = 2 × 10 × 3 × 10−9 = 6 × 10−2
11
M = 60 kg
(22) The coefficient of performance of a refrigerator is (25) At which temperature the velocity of O2
5. If the temperature inside freezer is −20o C, the molecules will be equal to the velocity of N2
temperature of the surroundings to which it molecules at 0 o C ....... o C
rejects heat is ........ o C
Solution:
Solution: vrms = 3RTM
⇒ T ∝ M [ ∵ vrms , R → constant]
The coefficient of performance of a refrigerator is T
⇒ THO2 = MHO2
M
T2
α = T1 −T2 2
TO2
2
32
where T1 and T2 are the temperatures of hot and ⇒ (273+0)
= 28
cold reservoirs (in kelvin) respectively. ⇒ T O2 = 312 K → 39o C
Here, α = 5, T2 = −20◦ C = −20 + 273 K = 253 K
T1 =? . . . . . . . . . . . . Chemistry - Section A (MCQ) . . . . . . . . . . . .
11
(26) Which of the following is not the correct order of (A) (B)
inductive effect
CH3
| CH2 − CH − CH3
(A) CH3 − C > | >
| CH2
CH3 (C) (D) All has same µ
(+I eff ect)
−CH2 − CH2 − CH2 − CH3
(B) −N O2 > −CN > −F (−I ef f ect)
(C) −N H2 > −C ≡ CH > −CH =
CH2 (−I ef f ect)
Θ
−CH2Θ > − O > −C − OΘ
(D) || (+I ef f ect)
O
Solution:(Correct Answer:A)
(a) Due to delocalisation of π electrons benzene
has resonance.
(C) (D)
Solution:(Correct Answer:C)
Solution:(Correct Answer:D)
is not the resonating structure of others .
(29) Which molecule has maximum dipole moment (µ) (31) Which of the following two are not resonating
? { where X = −N O2 } structure ?
12
(A) Solution:(Correct Answer:C)
(c) We know that there is more difference in the
electronegativities of hydrogen and chlorine.
Therefore HCl is a polar compound.
(35) Which of the following is a polar compound (40) The +I effect of alkyl groups is in the order
(A) C2 H6 (B) CCl4 (A) 2° > 3° > 1° (B) 1° > 2° > 3°
(C) HCl (D) CH4 (C) 3° > 2° > 1° (D) None of these
13
Solution:(Correct Answer:C) Solution:(Correct Answer:C)
(c)3◦ > 2◦ > 1◦
(44) Arrange following anions in decresing order of
their stability
Θ Θ Θ Θ
C H3 , N H2 , O H, C l
Θ Θ Θ Θ
(A) C l > O H > N H2 > C H3
Θ Θ Θ Θ
(B) O H > N H2 > C H3 > C l
(41) Which of the following is not a resonating
structure of others? Θ Θ
(C) N H2 > O H > C l > C H3
Θ Θ
(A) (B)
Θ Θ Θ Θ
(D) C l > N H2 > O H > C H3
Solution:(Correct Answer:A)
Solution:(Correct Answer:D)
See resonating structures
(42) Which of the following has zero inductive effect Solution:(Correct Answer:A)
(A) −CH3 (B) −D
(C) −H (D) −N H2
Solution:(Correct Answer:C)
since hydrogen does not exert I− effect, electron
releasing or electron withdrawing capability of
other atoms are compared by hydrogen. Thus, its
inductive effect is taken as Zero.
.......... Chemistry - Section B (NUMERIC) ..........
(C)
(D) Solution:
Resonance energy = Theoretical heat of
hydrogenation - Experimental heat of
hydrogenation
14
⇒ (a (t2 + 1)) = 8
⇒ t2 +√ 1 = 4 ⇒ t2 = 3
⇒t= 3
∴ c√ = 2at (2 + t2 )
= 2 3 (5)
√
|c| = 10 3
Solution:
e = (2 + 8 + 14) = 24
Here, mass number : A = 56
Z = No. of protons = No. of electrons in the
neutral atom = 24 + 2 = 26 (53) If the point on the curve y 2 = 6x, nearest to the
Mass Number = 56 point 3, 32 is (α, β), then 2(α + β) is equal to .....
No. Of Neutrons = Mass No. − Atomic No.
(A) 3 (B) 9
= 56 − 26 = 30
(C) 12 (D) 27
(49) The total number of isoelectronic species from
the given set is ....... Solution:(Correct Answer:B)
O 2− , F − , Al, M g2+ , N a+ , O+ , M g, Al 3+ , F Minimum distance is along the normal
P ≡ 32 t2 , 3t
Solution: Normal at point P
Isoelectronic species O 2Θ , F Θ , M g 2+ , N a⊕ , Al3+ tx + y = 3t + 32 t3
Passes through 3, 32
(50) According to the molecular orbital theory, the ⇒ 3t + 32 = 3t + 32 t3
bond order in C2 molecule is P ≡ 32 , 3 = 3t + 32 t3
P ≡ 32 , 3 = (α, β)
Solution:
⇒ t3 = 1 ⇒ t = 1
(c) B.O. of carbon = Nb −Na
2
= 8−4
2
= 2. 2(α + β) = 2 32 + 3 = 9
15
Solution:(Correct Answer:C) Solution:(Correct Answer:C)
Given parabola is y = a 3x + a2x − 2a (c) Let focus is S(0, 0) and A is the vertex of
3 2 2
3
⇒ y = a3 x3 + 2a 3
+ x + 16a 9
2 − 3a − 2a parabola.
16
35a a3
⇒ y + 16 = 3 x + 4a 3 2 Take any point Z such that AS = AZ.
Given tangent at vertex is x − y + 1 = 0.
Vertex of parabola is 4a 3 −35a
, 16
Since directrix is parallel to the tangent at the
To find locus of this vertex.
vertex.
x = −3 and y = −35a
4a 16 ∴ Equation of directrix is x − y + λ = 0,
⇒ a = 4x 3
and a = − 16y 35 where λ is constant.
−16y
⇒ −34x
= 35
⇒ 64xy = 105 A is midpoint of SZ,
⇒ xy = 105 64
which is the required locus. ∴ SZ = 2.SA
== > √|0−0+λ| 2 = 2 × √|0−0+1| 2
(55) Equation of the ellipse whose axes are the axes of 12 +(−1) 12 +(−1)
coordinates and which passes through the point == > |λ| = 2 i.e. λ = 2
Directrix in this case always lies in IInd quadrant
(−3, 1) and has eccentricity 25 is λ=2
(A) 5x2 + 3y 2 − 48 = 0 (B) 3x2 + 5y 2 − 15 = 0 Hence equation of directrix is x − y + 2 = 0
Now, P be any point on parabola
(C) 5x2 + 3y 2 − 32 = 0 (D) 3x2 + 5y 2 − 32 = 0
SP = P M
Solution:(Correct Answer:D) == > SP 2 = P M 2
2
Let the equation of the required ellipse be == > (x − 0)2 + (y − 0)2 = |x−y+2|
√
2
2
x2
a2
+ yb2 = 1 == > x2 + y 2 + 2xy − 4x + 4y − 4 = 0.
As it passses through (−3, 1) we get,
9
a2
+ b12 = 2
⇒ 9b2 + a2 = a2 b2
= 9a2 (1 − e2 ) + a2 = a2 · a2 (1 − e2 )
= 9a2 1 − 25 + a2 = a4 1 − 25
⇒ a2 = 32 5
Now b2 = a2 (1 − e2 )
⇒ b2 = 32 3
1 − 25
32
= 5
Hence the equation of required ellipse is
x2 y2
32 + 32 = 1
3 5
(or) 3x2 + 5y2 = 32
16
Solution:(Correct Answer:B)
(b) y = 2x + λ does not meet,
if λ > ma = 2.2
1
= 14
== > λ > 4 .
1
(A) y = −x − 1 (B) y = −x + 1
Hence e = 1− b2
a2
(C) y = x + 1 (D) y = x − 1 √
= 2
3
.
Solution:(Correct Answer:D)
(67) P Q is a double ordinate of the parabola y 2 = 4ax.
(d) Point (1, 0)
The locus of the points of trisection of P Q is
== > dxdy
=2−1 =1
(1, 0) (A) 9y 2 = 4ax (B) 9x2 = 4ay
Hence the tangent is y − 0 = x − 1.
(C) 9y 2 + 4ax = 0 (D) 9x2 + 4ay = 0
(62) The line lx + my + n = 0 will touch the parabola Solution:(Correct Answer:A)
y 2 = 4ax, if
(a) Required locus is (3y)2 = 4ax
(A) mn = al2 (B) lm = an2
== > 9y 2 = 4ax.
(C) ln = am2 (D) mn = al
Solution:(Correct Answer:C)
(c) y = − ml x − mn
(63) The straight line y = 2x + λ does not meet the (68) If the vertex of a parabola be at origin and
parabola y 2 = 2x, if directrix be x + 5 = 0, then its latus rectum is
(A) λ < 14 (B) λ > 14 (A) 5 (B) 10
(C) λ = 4 (D) λ = 1 (C) 20 (D) 40
17
Solution:(Correct Answer:C) (73) Let an ellipse with centre (1, 0) and latus rectum
(c) S ≡ (5, 0). of length 12 have its major axis along x-axis. If its
Therefore, latus rectum = 4a = 20. minor axis subtends an angle 60◦ at the foci, then
the square of the sum of the lengths of its minor
(69) The latus rectum of a parabola whose directrix is and major axes is equal to ............
x + y − 2 = 0 and focus is (3, −4), is
√ √
(A) −3 2 (B) 3 2
√ √
(C) −3/ 2 (D) 3/ 2
Solution:(Correct Answer:B)
(b) Distance between focus and directrix is
±3
= 3−4−2
√
2
=√ 2
√
Hence latus rectum = 3 2
(Since latus rectum is two times the distance
between focus and directrix).
Solution:
L.R. = 2ba = 12
2
(70) The focus of the parabola 4y2 − 6x − 4y = 5 is
(A) (−8/5, 2) (B) (−5/8, 1/2) 4b2 = a.......(i)
2 2
Ellipse (x−1) + yb2 = 1
(C) (1/2, 5/8) (D) (5/8, −1/2) a2
mB2 F1 = √13
Solution:(Correct Answer:B) b
a
= √13
(b) Given equation of parabola written in 3b2 = a2 e2 = a2 − b2
standard form, we get 4b2 = a2 ........(ii)
From (i) and (ii)
2
4 y − 12 = 6(x + 1)
2
⇒ y − 12 = 32 (x + 1) a = a2
⇒ Y 2 = 32 X ∴a=1
b2 = 14
where, Y = y − 12 , X = x + 1
((2a) + (2b))2 = 9
∴ y = Y + 12 , x = X − 1. . . ..(i)
For focus X = a, Y = 0 (74) A parabola passing through the point (−4, −2)
∵ 4a = 32 ⇒ a = 38 ⇒ x = 38 − 1 = − 58 has its vertex at the origin and y - axis as its axis.
y = 0 + 12 = 12 , Focus= − 58 , 12 . The latus rectum of the parabola is
λ+5
+ (y+1)
λ+5
=1 equal to
∵ a =4
2b2
2(λ+5)
√ Solution:
= 4( λ + 5) x2 2
4
a2
+ yb2 = 1a > b
λ = 59 2
λ = −5 √ e2 = 1 − ab 2
√ 1 2
l = 2a = 2 λ + 5 = 2 65 = 16 16
= 1 − ab2
b2 1
λ + = 59 + 16 = 75 a2
= 1 − 16 = 15
16
⇒ b2 = 15 2
16
a
2 2
x
a2
+ yb2 = 1
(72) The line y = 2x + c is a tangent to the parabola 16× 25
y 2 = 16x, if c equals a2
+ b92 = 1
32
5a2
+ b92 = 1
32
Solution: 5a2
+ 159a2 = 1
16
(d) According to the condition, c = 4
2
= 2. 80
b2
=1
18