Custom Practice Test - 12-Dec

Contact Number: 9667591930 / 8527521718

Chemistry-Section-A 7. Which pair of symbols, from the following,

represents nuclei with an identical number of
1. Of the following transitions in hydrogen neutrons?
atom, the one which gives an absorption line of 1. 56 Co and 58 Co
lowest frequency is: 2. 57 Mn and 57 Fe
1. n = 1 to n = 2 3. 57 Fe and 58 Ni
2. n = 3 to n = 8 4. 57 Co and 58 Ni
3. n = 2 to n = 1
4. n = 8 to n = 3 8. Which of the following series of transitions in
the spectrum of hydrogen atoms falls in the
2. Incorrect set of quantum numbers from the visible region?
following is : 1. Brackett series
1. n=4,l=3, m1 =-3, -2, -1, 0, +1, +2, +3, ms=-1/2 2. Lyman series
2. n=5, l=2, m1 =-2, -1, +1, +2, ms=+1/2 3. Balmer series
3. n=4, l=2, m1 = -2, -1, 0, +1, +2, ms=-1/2 4. Paschen series
4. n=5,l=3, m1 =-3, -2, -1, 0, +1, +2, +3, ms=+1/2
9. The possible correct set of quantum numbers
for the unpaired electron of Cl atom is:
3. The correct statement among the following 1
is: 1. 2, 0, 0, + 2
1. The number of orbitals in nth shell is n2 . 2. 2, 1, − 1, + 2
1
2. The number of orbitals in a subshell is 1
3. 3, 1, + 1, + 2
(2l − 1).
1
3. The number of subshells in nth shell is 4. 3, 0, + 2, 2
(n + l).
4. The number of electrons in a shell is 10. Which of the following pairs of d-orbitals
2(2l + 1). will have electron density along the axes?
1. dz2,dxz
4. Two sets of quantum numbers with the same 2. dxz,dyz
number of radial nodes are : 3. dz2,dx2-y2
1. n = 3, l = 0, ml = 0 and n = 2, l = 0, ml = 0 4. dxy,dx2-y2
2. n = 3, l = 2, ml = 0 and n = 2, l = 1, ml = 0
3. n = 3, l = 1, ml = –1 and n = 2, l = 1, ml = 0 11. The energy of the second Bohr orbit in the H
4. n = 3, l = 1, ml = 1 and n = 2, l = 1, ml = 0 atom is –3.41 eV. The energy of the second Bohr
orbit of He+ ion would be:
5. Which among the following are isoelectronic 1. –0.85 eV
species? 2. –13.6 eV
+ + 2+ 2+ 3. –1.70 eV
1. Na , K , Ca , Mg
2+ 2+ 2− + 4. –6.82 eV
2. Ca , Mg , S , K
2+
3. Ca , Ar, S2− , K+ 12. The orbital angular momentum value for 3s
4. None of the above orbital is:
1. 0
6. For a multi-electron atom, the highest energy 2. 1
level among the following is: 3. 2
1. n=5, l=0, m=0, s=+1/2 4. -1
2. n=4, l=2, m=0, s=+1/2
3. n=4, l=1, m=0, s=+1/2
4. n=5, l=1, m=0, s=+1/2

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 Custom Practice Test - 12-Dec
Contact Number: 9667591930 / 8527521718

13. If the value of m = +3 for an electron, then 19. From the given equation, certain
the electron must be present in: conclusions are drawn.
2
1. s subshell E = −2.178 × 10−18 (J) nz 2
2. p subshell
3. d subshell Choose the incorrect statement:
4. f subshell The negative sign in the equation implies
that the energy of an electron bound to the
14. A gas absorbs a photon of 355 nm and emits 1. nucleus is lower than it would be if the
at two wavelengths. If one of the emissions is at electron were at an infinite distance from
680 nm, the other is at: the nucleus.
1. 1035 nm The larger the value of n, the greater the
2.
2. 325 nm orbit radius.
3. 743 nm The equation can be utilized to calculate the
4. 518 nm 3. change in energy when the electron
transitions between orbits.
15. Ejection of the photoelectron from a metal For n=1, the electron has a more negative
in the photoelectric effect experiment can be energy than it does for n=6. This means that
stopped by applying 0.5 V when the radiation of 4. the electron is more loosely bound in the
250 nm is used. The work function of the metal smallest allowed orbit.
is:
1. 4.0 eV
2. 5.5 eV 20. Orbital having 3 angular nodes and 3 total
3. 4.5 eV nodes is:
4. 5.0 eV 1. 5 p
2. 3 d
16. Calculate the energy corresponding to light 3. 4 f
of wavelength 45 nm: 4. 6 d
(Planck's constant h = 6.63 × 10–34 Js:
speed of light c = 3 × 108 ms–1) 21. Given the following data:
15
1. 6.67 x 10 J (a) Mass of electron: 9.11 x 10-31 kg
11
2. 6.67 x 10 J (b) Planck's constant: 6.626 x 10-34 Js
-15
3. 4.42 x 10 J
4. 4.42 x 10-18 J In light of the data given above, the uncertainty
involved in the measurement of velocity within
17. The number of d -electrons in Fe2+ (atomic a distance of 0.1 A °
will be:
number Z = 26) is different from the number 1. 5.79 x 106 ms-1
of:
2. 5.79 x 107 ms-1
1. s-electrons in Mg (Z = 12)
2. p-electrons in Cl (Z = 17) 3. 5.79 x 108 ms-1
3. d-electrons in Fe (Z = 26) 4. 5.79 x 105 ms-1
4. p-electrons in Ne (Z = 10)

18. In which of the following transitions of

hydrogen atom, radiation of minimum
frequency is emitted ?
1. n2 = ∞ to n1 = 1
2. n2 = 2 to n1 = 1
3. n2 = 3 to n1 = 2
4. n2 = ∞ to n1 = 3

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 Custom Practice Test - 12-Dec
Contact Number: 9667591930 / 8527521718

22. The radius of the second Bohr orbit for 26. Which of the following orbits has a radius
hydrogen atom is: identical to that of the first Bohr orbit of a
(Planck's Const. h = 6.6262 × 10–34 Js; mass of hydrogen atom?
+
electron = 9.1091 × 10–31 kg; charge of electron 1. He (n = 2)
2+
e = 1.60210 ×10–19 C; permittivity of vaccum 2. Li (n = 2)
2+
∈0 = 8.854185 ×10–12 kg–1m–3A2) 3. Li (n = 3)
3+
1. 0.529 Å 4. Be (n = 2)
2. 2.12 Å
3. 1.65 Å 27. The number of angular nodes and radial
4. 7.76 Å nodes in 3s orbital are:
1. 0 and 2, respectively
23. An element with mass number 81 contains 2. 1 and 0, respectively
31.7 % more neutrons as compared to protons. 3. 3 and 0, respectively
The atomic symbol of the element is: 4. 0 and 1, respectively
1. 81
40 X
2. 81 28. The electrons identified by quantum
35 X
numbers n and l can be placed in order of
3. 31.7
81 X increasing energy as:
4. 81
41 X a. n = 4, l = 1
b. n = 4, l = 0
24. Two electrons occupying the same orbital c. n = 3, l = 2
are distinguished by: d. n = 3, l = 1
1. Magnetic quantum number 1. (d) < (b) < (c) < (a) 2. (b) < (d) < (a) < (c)
2. Azimuthal quantum number 3. (a) < (c) < (b) < (d) 4. (c) < (d) < (b) < (a)
3. Spin quantum number
4. Principal quantum number
29. The energy of an electron moving in nth
25.
Bohr's orbit of an element is given by
In the Balmer series of the −13.6 2
hydrogen spectrum, the En = n2
Z eV/atom (Z=atomic number). The
2
transitions occur from an initial graph of E vs. Z (keeping "n" constant) will
Assertion (A):
energy level ( n1 = 2 ) to be:
successive higher energy levels
n2 = 3, 4, 5,... .
In the Balmer series of the
hydrogen spectrum, the 1. 2.
transitions with the highest
Reason (R):
wavelength correspond to
energy level values of n equal to
4 and 6.

Both (A) and (R) are True and (R) is the

1.
correct explanation of (A).
Both (A) and (R) are True but (R) is not the 3. 4.
2.
correct explanation of (A).
3. (A) is True but (R) is False.
4. Both (A) and (R) are False.

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 Custom Practice Test - 12-Dec
Contact Number: 9667591930 / 8527521718

30. The variation of radial probability density 34. According to Einstein’s photoelectric
R2(r) as a function of distance (r ) of the equation, the graph between kinetic energy of
electron from the nucleus for 3p-orbital is photoelectrons ejected and the frequency of the
captured in which of the following graphs? incident radiation is:

1. 2.
1. 2.

3. 4.

3. 4.

31. ψ3,2,0 is the representation of the orbital:

1. 3px
2. 3dxy 35. The quantum numbers + 12 and − 12 for the
3. 3dz2 electron spin represent:
4. 3dx2-y2 Rotation of the electron in clockwise and
1.
anticlockwise directions, respectively.
32. If the value of m for an electron is +3, it may Rotation of the electron in anticlockwise and
be found in : 2.
clockwise directions, respectively.
1. 4s orbital
The magnetic moment of the electrons
2. 4p orbital 3.
pointing up and down, respectively.
3. In any f-orbital
4. In any d-orbital Two quantum mechanical spin states that
4.
have no classical analogues.
33. Which one of the following electrons in the
ground state will have least amount of energy?
1. An electron in hydrogen atom.
2. An electron in 2p orbital of carbon atom.
Chemistry-Section-B
36. A sample set of electrons have the following
The electron of copper atom present in 4s quantum numbers:
3.
orbital.
(i) n = 4, l = 1
4. The outermost electron in sodium atom.
(ii) n = 4, l = 0
(iii) n = 3, l = 2
(iv) n = 3, l = 1

Arrange them in the increasing order of energy

from lowest to highest:
1. (iv) < (ii) < (iii) < (i)
2. (ii) < (iv) < (i) < (iii)
3. (i) < (iii) < (ii) < (iv)
4. (iii) < (i) < (iv) < (ii)

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 Custom Practice Test - 12-Dec
Contact Number: 9667591930 / 8527521718

37. Which of the following ions has the 43.

maximum magnetic moment? The wave function is a
1. Mn3+ mathematical function whose value
Statement-
2. Cu2+ depends upon the coordinates of
I:
3. F e3+ the electron in the atom and does
4. V 3+ not carry any physical meaning.
Statement- The ionization potential of He atom
38. The number of electrons that can be present II: is greater than that of He+ ion.
1
in the subshells having ms value of − 2 for n =
4 are: 1. Both statements are correct.
1. 36 2. Both statements are incorrect.
2. 4 3. Statement -I is correct and statement -II is
3. 16 incorrect.
4. 2 4. Statement -II is correct and statement-I is
incorrect.
39. If the shortest wavelength in the Lyman
series of a hydrogen atom is A, then what is the 44. According to Bohr's theory, what is the
longest wavelength in the Paschen series of angular momentum of an electron located in
the fifth orbit?
He+? h
5A 1. 25 π
1. 9
h
9A 2. 1. 0 π
2. 5 h
36 A 3. 10 π
3. 5 h
36 A
4. 2. 5 π
4. 7
45. The azimuthal quantum number (l) is
40. The magnetic moment of Ni2+ (Z=28) is: defined, as:
1. 1.732 BM 1. Shape of orbitals 2. Orientation of orbitals
2. 2.82 BM 3. Energy of orbitals 4. Size of orbitals
3. 3.87 BM
4. 4.89 BM
46. The number of neutrons in Zn2+ ion (mass
41. How many of the given metals will show
photoelectric effect when a light of 400 nm falls number: 70) will be:
on them? 1. 34
2. 36
Metal Li Na K Mg Cu Ag
3. 38
W(eV) 2.42 2.3 2.25 3.7 4.8 4.3 4. 40
1. 4
2. 3 47. The azimuthal quantum number
3. 6 characterizes:
4. 2 1. e/m ratio of electron
2. Spin of electron
42. The orbital having two radial as well as two 3. Angular momentum of the electron
angular nodes is: 4. Magnetic momentum of the electron
1. 3p
2. 4f
3. 4d
4. 5d

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 Custom Practice Test - 12-Dec
Contact Number: 9667591930 / 8527521718

48.
According to Bohr’s model, angular
Statement
momentum is quantized for
I:
stationary orbits.
Statement Bohr’s Model doesn’t follow
II: Heisenberg's uncertainty principle.
1. Both statement I and statement II are true.
2. Statement I is true and Statement II is false.
3. Statement I is false and Statement II is true.
4. Both Statement I and Statement II are false

49. Millikan’s Oil drop Method was used to

determine:
1. Neutron
2. Alpha particle
3. Positron
4. Charge on the electrons

50. The most probable radius (in pm) for

finding the electron in He+ is :
1. 26.5
2. 105.8
3. 0.0
4. 52.9

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