<br>

Thiosulphate reacts differently with iodine and

bromine in the reactions given below:
2
S,0 +I2 S40+2I
+4Br + 10H

0
+
S,0? +5Br2 5H20 2S07

13
42
0
Which of the following statement justifies the above

9
6
3
dual behaviour of thiosulphate?

/7
5
9
9
8
8
8
Thiosulphate undergoes oxidation by
9
40

(A bromine and reduction by iodine in these

8
m
ha

reactions
ub
Sh
n
ia

Bromine is a weaker oxidant than iodine

IT

B
N
r
to
en
M

(C) Bromine is a stronger oxidant than iodine

E
JE

Bromine undergoes oxidation and iodine

(D
undergoes reduction in these reactions
<br>

Total number of species from the following which

can undergo disproportionation reaction is

0
13
42
K+
H,0,,CIO,,P4,Clz, Ag, Cu, F2, NO2,

0
9
6
3
/7
5
Input

9
9
8
You entered nothing 8
8
9
40
8
m

Answer
ha
ub

Correct answer is 6
Sh
n
ia
IT
N

Explanation
r
to
en

Intermediate oxidation state of element can undergo

M
E

disproportionation.
JE

H,02, Cl0; ,P4, Cl2, Cu,NO;

<br>

Chlorine undergoes disproportionation in alkaline

mediunm as shown below:

0
13
42
aCl2(g) +
bOHa) cClofa6) t dolat eH,O

0
9
6
The values of a, b, c and d in a balanced redox

3
/7
5
reaction are respectively :

9
9
8
8
8
9
40

(A) 3, 4,4 and 2

8
m
ha
ub
Sh

1, 2, 1 1
(B) and
n
ia
IT
N
r
to

(C) 2, 4, 11 and 3
en
M
E
JE

(D) 2, 2, 1 and 3
<br>

0
Which of the following cannot function as an

13
42
oxidising agent?

0
9
6
3
/7
5
9
sO

9
(A

8
8
8
9
40
8

MnO
m

B
ha
ub
Sh
n
ia
IT
N
r
to
en
M

D) BrO3
E
JE
 <br>

Which of the following options are correct for the

reaction

2[Au(CN)2) (aq) + Zn(s) 2Au(s) + (Zn(CN)

0
13
A. Redox reaction

42
0
B.

9
Displacement reaction

6
3
/7
C. Decomposition reaction

5
9
9
8
D. Combination reaction
8
8
9
40

Choose the correct answer from the options given

8
m

below:
ha
ub
Sh

A and B only
n
ia
IT
N
r
to

(B C and D only
en
M
E
JE

()C A
only

(D) A and D only

 0
13
42
0
9
<br>

In ammonium - phosphomolybdate, the oxidation

6
3
/7
5
state of Mo is +

9
9
8
8
8
9

Input
40
8
m

You entered nothing

ha
ub
Sh

Answer
n
ia
IT

Correct answer is
N

6
r
to
en
M
E
JE
 0
13
42
0
<br>

9
6
The oxidation state of phosphorus in

3
/7
5
hypophosphoric acid is +

9
9
8
8
8
9

Input
40
8
m

You entered nothing

ha
ub
Sh
n

Answer
ia
IT
N

Correct answer is 4
r
to
en
M
E
JE
 0
<br>

13
The density of a monobasic strong acid (Molar mass

42
0
24.2 g/mol) is 1.21 kg/L. The volume of its solution

9
6
3
required for the complete neutralization of 25 mL of

/7
5
0.24 M NaOH is X 10-2 mL (Nearest

9
9
8
integer) 8
8
9
40
8

Input
m
ha
ub

You entered nothing

Sh
n
ia
IT

Answer
N
r
to
en

Correct answer is 12
M
E
JE
 0
13
42
0
<br>

9
6
3
Sum of oxidation states of bromine in bromic acid

/7
5
9
and perbromic acid is

9
8
8
8
9

Input
40
8
m

You entered nothing

ha
ub
Sh

Answer
n
ia
IT
N

Correct answer is 12
r
to
en
M
E
JE
<br>

20mL of 0.02 M hypo solution is used for the

0
titration of 10mL of copper sulphate solution, in the

13
42
presence of excess of KI using starch as an indicator.

0
9
6
The molarity of Cu is found to be

3
/7
5
x10- M. (nearest integer]

9
9
8
: 2 Cu + 4I 8 + Iz
Given Cuzl
8
9
40
8

+
I, 2
S,021 +S07
m
ha
ub
Sh

Input
n
ia
IT

You entered nothing

N
r
to
en

Answer
M
E
JE

Correct answer is 4
<br>

0
13
Identify the process in which change in the

42
0
Oxidation state is five:

9
6
3
/7
5
9
Cr2O 2Cr3+

9
(A

8
8
8
9
40
8

Mn2+t
© MnO,
(B
m
ha
ub
Sh
n

CrO Crt
ia
IT
N
r
to
en

O C;0 2002
M
E
JE
<br>

The oxidation states of nitrogen in NO, NO2, N20 and

0
13
NO, are in the order of:

42
0
9
6
3
/7
5
(A) Nz0 > N0, > NO> NO,

9
9
8
8
8
9
40

> NO0, >

8

(B NO N20 >
NO,
m
ha
ub
Sh
n

C) NO2 > NO, > NO >

N0
ia
IT
N
r
to
en

> > >

M

D) NO, NO, NO Ng0

E
JE
<br>

0
13
Oxidation number of potassium in Kg0. K02 and

42
0
:

KO, respectively is

9
6
3
/7
5
9
9
(A +1, +2 and + 4
8
8
8
9
40
8
m

(B +1, +1 and + 1
ha
ub
Sh
n
ia

1
+2, +1 and +
IT
N
r
to
en
M

+1, +4, and +2

E
JE
 0
13
42
0
<br>

9
6
Dichronmate ion is treated with base, the oxidation

3
/7
5
number of Cr in the product formed is

9
9
8
8
8
9

Input
40
8
m

You entered nothing

ha
ub
Sh

Answer
n
ia
IT
N

Correct answer is 6
r
to
en
M
E
JE
<br>

In order to oxidise a mixture of one mole of each of

0
13
FeCz04, Fez(Cz04)3, FesO4 and Fez(S04)3 in acidic

42
0
medium,the number of moles of KMnO4 required is

9
6
3
/7
5
9
9
8
8
8
9

1.5
40
8
m
ha
ub

(B) 3
Sh
n
ia
IT
N

) 2
r
to
en
M
E
JE

D 1
 0
<br>

13
An example of a disproportionation reaction is :

42
0
9
6
3
/7
2NaBr + Clh 2NaCl + Br2

5
(A)

9
9
8
8
8
9
40

2KMnO4 2KMn04 + MnO2 + O2 (3) (4)

8
m
ha
ub
Sh

(C) 2CuBr CuBr, + Cu

n
ia
IT
N
r
to
en

+ +
(D) 2Mn04 10[+ 16H* 2Mn2* 5l, + 8H0
M
E
JE
<br>

0
The compound that cannot act both as oxidising and

13
42
reducing agent is
:

0
9
6
3
/7
5
9
(A) HgPO4

9
8
8
8
9
40
8

(B) HzS03
m
ha
ub
Sh
n
ia

Hz02
IT
N
r
to
en
M

(D) HNO2
E
JE
 0
13
42
<br>

0
9
The oxidation states of transition metal atoms in

6
3
/7
KzCr207, KMnO4 and KFe04, respectively, are x, y

5
9
9
and z. The sum of x, y and z is
8
8
8
9
40

Input
8
m
ha

You entered nothing

ub
Sh
n
ia

Answer
IT
N
r

Correct answer is 19
to
en
M
E
JE
 0
<br>

13
A 100mL solution was made by adding 1.43 g of

42
0
NazCO3.xH,0. The normality of the solution is 0.1 N.

9
6
3
/7
The value of x is

5
9
9
8
8
(The atomic mass of Na is 23 g/mol)
8
9
40
8
m

Input
ha
ub
Sh

You entered nothing

n
ia
IT
N

Answer
r
to
en

Correct answer is 10
M
E
JE
 0
<br>

13
42
0.01 M KMnO4 solution wasadded to 20.0 mL. of 0.05

0
9
M Mohr'ssalt solution through a burette. The initial

6
3
/7
reading of 50 mL burette is zero. The volume of

5
9
9
KMnO4 solution left in the burette after the end
8
8
8
9

point is mL. (nearest integer)

40
8
m
ha

Input
ub
Sh

You entered nothing

n
ia
IT
N
r

Answer
to
en
M

Correct answer is 30
E
JE
<br>

Statement I: Sodium hydride can be used as an

oxidising agent.

0
13
Statement II:The lone pair of electrons on nitrogen

42
0
in pyridine makes it basic.

9
6
3
/7
5
Choose the CORRECT answer from the options given

9
9
8
below: 8
8
9
40
8
m

Statement I is false but statement II is true

ha
ub
Sh
n
ia

Both statement I and statement II are true

IT

(B
N
r
to
en
M

Statement I is true but statement IIis false

E
JE

Both statement I and statement II are false

<br>

0
Which of the given reactions is not an example of

13
42
disproportionation reaction?

0
9
6
3
/7
5
9
(A) 2H,O, 2H,0 + O2
9
8
8
8
9
40
8

(B) 2NO2 + H,0 HNO3 + HNO

m
ha
ub
Sh

+
+3e MnO2 + 2H,0
n

MnO, 4H
ia
IT
N
r
to
en

(D) 3Mn0 + 4H+ 2MnO, + MnO2 + 2H2'

M
E
JE
 <br>

Given below are two statements: one is labelled as

Assertion A and the other is labelled as Reason R.

Assertion A: Phenolphthalein is a pH dependent

indicator, remains colourless in acidic solution and

0
13
gives pink colour in basic medium.

42
0
9
is a weak acid. It doesn't

6
Reason R:Phenolphthalein

3
/7
dissociate in basic medium.

5
9
9
8
In the light of the above statements, choose the most
8
8
9

appropriate answer from the options given below.

40
8
m
ha

Both A and Rare true and Ris the correct

ub

(A
Sh

explanation of A.
n
ia
IT
N
r
to

Both A and Rare true but Ris NOT the

en

(B
correct explanation of A.
M
E
JE

You are wrong

A istrue but R1S Ialse.

D A is false but R is true.

<br>

A compound 'X is a weak acid and it exhibits colour

change at pH close to the equivalence point during

0
13
42
neutralization of NaOH with CH;COOH.

0
9
Compound 'X exists in ionized form in basic

6
3
/7
medium. The compound'X is

5
9
9
8
8
8
9

A)
A methyl orange
40
8
m
ha
ub

(B methyl red
Sh
n
ia
IT
N
r

© phenolphthalein
to
en
M
E
JE

(D erichrome BlackT
 0
13
<br>

42
The normality of H,S04 in the solution obtained on

0
9
6
3
mixing 100 mL of 0.1 MH,S04 with 50 mL of

/7
5
x10-1 N.(Nearest

9
0.1 MNaOH is

9
8
Integer) 8
8
9
40
8

Input
m
ha
ub

You entered nothing

Sh
n
ia
IT

Answer
N
r
to

Correct answer is
en

1
M
E
JE
 <br>

Given below are two statements:

Statement I:In redox titration, the indicators used

are sensitive to change in pH of the solution.

0
13
Statement II: In acid-base titration, the indicators

42
used are sensitive to change in oxidation potential.

0
9
6
3
In the light of the above statements, choose the most

/7
5
9
appropriate answer from the options given below

9
8
8
8
9
40

Both Statement I and Statement II are

8

A
m

incorrect
ha
ub
Sh
n

Statement I is correct but Statement II is

ia
IT

B
N

incorrect
r
to
en
M
E

Statement I is incorrect but Statement II is

JE

Correct

Both Statement Iand Statement II are correct

D
 0
13
42
0
9
<br>

6
The sum of oxidation state of the metals in

3
/7
5
Fe(CO)5, VO and WO3 is

9
9
8
8
8
9

Input
40
8
m

You entered nothing

ha
ub
Sh

Answer
n
ia
IT

Correct answer is 10
N
r
to
en
M
E
JE
 0
13
42
<br>

See the following chemical reaction:

0
9
6
3
+ XH +6F YCt +6 F+ +

/7
Cr20 e
ZH

5
9
9
8
The sum of X, Y and Z is 8
8
9
40
8

Input
m
ha
ub

You entered nothing

Sh
n
ia
IT

Answer
N
r
to

Correct answer is 23
en
M
E
JE
<br>

0
2I0, +al +

13
12H 6L,+ 6H,0

42
0
9
What is the value of æ ?

6
3
/7
5
9
9
8
(A 10 8
8
9
40
8
m

(B) 2
ha

2
ub
Sh
n
ia
IT

12
N
r
to
en
M
E

6
JE
 <br>

Which of the following reactions are

disproportionation reactions?

(A) Cut Cu++Cu

0
13
(B)

42
+
3Mn0+ 4Ht 2MnO,+ MnO2 2H,0

0
9
6
3
/7
(C) 2KMnO4 KMnO4+ MnO, +O2

5
9
9
8
(D) 8
8
9

2MnO, +3Mn++2H,0 5MnO, + 4H+

40
8
m

Choose the correct answer from the options given

ha
ub

below:
Sh
n
ia
IT

(A) (A), (B)

N
r
to
en
M

B (A), (D)
E
JE

(B), (C), (D)

(D) (A), (B), (C)

<br>

In acidic medium,K2Cr2O; shows oxidising action

represented in the half reaction:

0
13
42
CrO2-+ XH+Ye 2A ZH,0 +

0
9
6
3
/7
5
X, Y,Zand A
are respectively are:

9
9
8
8
8
9
40

14, 7,6 and Cr+

8
m
ha
ub
Sh

B) 14, 6, 7 and OC3+

n
ia
IT
N
r
to

(C) 8,4, 6 and CrO3

en
M
E
JE

8,6,4 and Cr203

 0
13
42
<br>

0
9
In the reaction of potassium dichromate, potassium

6
3
/7
chloride and sulfuric acid (conc.), the oxidation state

5
9
of the chromium in the product is (+)

9
8
8
8
9
40

Input
8
m
ha

You entered nothing

ub
Sh
n

Answer
ia
IT
N

Correct answer is 6
r
to
en
M
E
JE
 0
<br>

13
42
In alkaline medium, MnO, Oxidises I to

0
9
6
3
/7
5
9
9
8
8
8
9
40

B
8
m
ha
ub
Sh

IO
n
ia
IT
N
r
to
en
M
E
JE
 0
13
42
0
<br>

9
6
Number of moles of H+ ions required by l mole of

3
/7
5
Mn0, to oxidise oxalate ion to CO, is

9
9
8
8
8
9

Input
40
8
m

You entered nothing

ha
ub
Sh

Answer
n
ia
IT
N

Correct answer is 8
r
to
en
M
E
JE
 0
13
42
<br>

0
The oxidation number of iron in

9
the compound

6
3
formed during brown ring test for NO, iron is

/7
5
9
9
8
8
8
9
40

Input
8
m
ha

You entered nothing

ub
Sh
n

Answer
ia
IT
N
r

Correct answer is
to

1
en
M
E
JE
 0
13
<br>

42
Only 2 mi of KMnO4 solution of unknown

0
molarity is required to reach the end point of a

9
6
3
/7
titration of 20 mL of oxalic acid (2M) in acidic

5
9
medium. The molarity of KMnO4 solution should

9
8
8
be M.
8
9
40
8
m

Input
ha
ub

You
Sh

entered nothing
n
ia
IT
N

Answer
r
to
en

Correct answer is 8
M
E
JE
 0
<br>

13
When MnO, and H,SO, is added to a salt (A), the

42
0
greenish yellow gas liberated as salt (A) is:

9
6
3
/7
5
9
9
A)
NH,CI
8
8
8
9
40
8

Cal,
m

©)
(B
ha
ub
Sh
n
ia

KNO3
IT
N
r
to
en
M

NaBr
E
JE
<br>

The number of ions from the following that are

0
13
expected to behave as oxidising agent is :

42
0
9
Sn,Sn, Pb²+,TI, Pbt, TIt

6
3
/7
5
9
9
8
A) 3 8
8
9
40
8
m
ha

B 4
ub
Sh
n
ia
IT

C 2
N
r
to
en
M
E
JE