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DPP 8 Solution

The document is a chemistry worksheet for XIth grade students, focusing on basic concepts of chemistry and includes various problems and their solutions. It covers topics such as empirical formulas, stoichiometry, molarity, and reactions involving acids and bases. An answer key is provided at the end for quick reference to the correct answers.

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17 views4 pages

DPP 8 Solution

The document is a chemistry worksheet for XIth grade students, focusing on basic concepts of chemistry and includes various problems and their solutions. It covers topics such as empirical formulas, stoichiometry, molarity, and reactions involving acids and bases. An answer key is provided at the end for quick reference to the correct answers.

Uploaded by

rajapandianprasannadharshi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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CLASS : XIth SUBJECT : CHEMISTRY

DATE : Solutions DPP No. : 8

Topic :- SOME BASIC CONCEPTS OF CHEMISTRY

1 (b)
It remains unchanged.
2 (d)
Given, % of C=54.55%
% of H=9.09%
%of O=36.36%

Elem % At. Ratio of Simplest


ent no. atoms ration
C 54.5 12 54.55/12= 4.54/2.2
5 4.54 7=2
H 1
9.09 9.09/1=9.0 9.09/2.2
O 16 9 7=4
36.0
6 36.16/16= 2.27/2.2
2.27 7=1

∴ Empirical formula is C2H4O.


3 (a)
12
6C contains 6 𝑁 protons, 6 𝑁 electrons and 6 𝑁 neutrons.
4 (d)
Meq. of H3PO4 = Meq. of Ca(OH)2;
0.25 × 3 × 𝑉 = 25 × 0.03 × 2
∴ 𝑉 = 2 mL
5 (a)
2PH3(g) ⟶2P(𝑠) + 3H2(g)
100 0 0 Bef ore dissociation
0 - 150 Af ter dissociation
6 (c)
moles of CH3COOH 2.05 × 1000
𝑚= = = 2.285
wt.of solvent in kg 897
wt. of solvent = wt. of solution-wt. of solute
= [1000 × 1.02 ― 2.05 × 60] = 897 g
7 (c)
Meq. of NaOH = Meq. of HCl
100 × 0.1 = 10
𝑤𝑡.
 40
× 1000 = 10 ; 𝑤NaOH = 0.4g
8 (a)
Meq. of Na2CO3 = 250 × 0.25 × 2 = 125
𝑤
∴ 53 × 1000 = 125
∴ 𝑤 = 6.625
9 (a)
𝑛
𝑛+𝑁 = 0.2;
𝑁
∴ 𝑛+𝑁
= 0.8
𝑛 1
Thus, 𝑁
=4
𝑛 × 18 × 1000 1
or 𝑊 × 1000
=4
molality × 18 1
or 1000
=4
10 (a)
weight of solute
%by weight = × 100
weight of solution
𝑤
or 20 = (𝑤 + 60) × 100
or 𝑤 = 15g
11 (b)
C3H8 + 5 O2⟶3CO2 + 4H2O
1 mol or 22.4 L C3H8 at STP requires 5 mole or 5 × 22.4 O2 at STP.
12 (d)
22.4 litre refers for mol. wt.
mol. wt.
∴ 11.2 litre refers for 2
= vapour density.
13. (c)
10 × 1000
𝑁= 60 × 100
= 1.66
14 (c)
K2S2O8 (𝑎𝑞) + 2KI (𝑎𝑞)→2K2SO4(𝑎𝑞) + I2(𝑎𝑞)
In this reaction one mole of K2S2O8 reacts with 2 moles of KI,
Hence the stoichiometry of this reaction is 1:2.
15 (d)
moles of alcohol 2 2
Mole fraction = = =
total moles 2+6 8
= 0.25
16 (b)
Ba(HO)2 + 2HCl ⟶ BaCl2 +2H2O
meq. 30 × 0.1 × 2 20 × 0.05 0 0
=6 =1
5 0 1 1
5
 [OH―] = 50 = 0.1 M
17 (a)
NaHCO3 being an acid salt will react with NaOH as,
NaOH + NaHCO3⟶Na2CO3 + H2O
18 (b)
Eq. of metal oxide = Eq. of oxygen
100 20
𝐸
= 8
𝐸 = 40
19 (b)
According to the equation,
NaCl + AgNO3⟶NaNO3 + AgCl
4.77
No. of moles of NaCl = 58.5 = 0.08154
5.77
No. of moles of AgNO3 = 170 = 0.03394
Thus, AgNO3 is the limiting reagent in the reaction.
Now, applying POAC for Ag (as Ag atoms are conserved in the reaction)
Moles of Ag in AgNO3 = moles of Ag in AgCl
Or 1 × moles of AgNO3 = 1 × moles of AgCl
Or 0.03394 × 143.4(for AgCl) = 4.87g
20 (d)
0.1 1
100 ML 𝑂2,𝑁𝐻3 and 𝐶𝑂2 = 22.4 = 224 mol
1
For 𝑂2no. of molecules = 224 × 6.023 × 1023
1
For 𝑁𝐻3 no. of molecules = 224 × 6.023 × 1023
1
For 𝐶𝑂2 no. of molecules = 224 × 6.023 × 1023
ANSWER-KEY
Q. 1 2 3 4 5 6 7 8 9 10
A. B D A D A C C A A A

Q. 11 12 13 14 15 16 17 18 19 20
A. B D C C D B A B B D

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