Chapter 10

Acids, Bases and Salts

LEARNING OUTCOMES
■Define acid and acid anhydride
■Investigate the reactions of non-oxidising acids with
metals, carbonates, hydrogen carbonates and bases
■Define base and alkali
■Investigate the reaction of bases with ammonium
salts
■Relate acidity and alkalinity to the pH scale
■Discuss the strength of acids and alkalis on the basis
of their completeness of ionisation
■Define acidic, basic, amphoteric and neutral oxides
Chapter 10
Acids, Bases and Salts
LEARNING OUTCOMES
■Define salt
■Identify an appropriate method of salt preparation
based on the solubility of the salt
■Distinguish between acidic and normal salts
■Investigate neutralisation reactions using indicators
and temperature changes
 Chapter 10
Acids, Bases and Salts
What are acids?
■ Fruits like apples, oranges and pineapples taste sour because they
contain acids.
■ Acids also turn blue litmus paper red.
■ Acids produce hydrogen ions H+ in water.
Chapter 10
Acids, Bases and Salts
Definition of An Acid
An acid is a substance which produces hydrogen ions, H+(aq) in water.

■ For example, hydrochloric acid dissolves in

water to form hydrogen ions and chloride ions:
HCl(aq) H+(aq) + Cl-(aq)
■ It is the hydrogen ions which turn blue litmus
to red and give acids their characteristic properties.
 Chapter 10
Acids, Bases and Salts
What are acids?
pop
Other chemical properties of acids

■ Acids react with metals to produce

hydrogen gas.
E.g. Mg + H2SO4 MgSO4 + H2
( test for hydrogen gas)

■ Acids react with carbonates to

produce carbon dioxide.
E.g.
CaCO3 +2HCl CaCl2 + H2O + CO2 Limewater HCl+CaCO3
turns chalky
(test for carbon dioxide)
Chapter 10
Acids, Bases and Salts
What are acids?
Other chemical properties of acids
■ Acids react with bases to form a salt and water only.
■ E.g. sulphuric acid reacts with copper(II) oxide to form a salt
called copper(II) sulphate and water:
H2SO4 + CuO CuSO4 + H2O

■ This reaction is called neutralisation.

Chapter 10
Acids, Bases and Salts
A Strong Acid
Strong acid
■ A strong acid is an acid that
is completely ionised in
water. This means that all
the acid molecules become
ions in the water.

■ Examples of strong acids are: sulphuric acid, hydrochloric

acid and nitric acid.
Chapter 10
Acids, Bases and Salts

A Weak Acid
Weak acid

■ A weak acid is an acid that is

only partially ionised in water.
This means that only a few
molecules of the acid become
ions in water.

■ E.g.s. of weak acids are: ethanoic acid, citric acid and

carbonic acid.
Chapter 10
Acids, Bases and Salts
Some Common Acids

Name of acid Formula

Sulphuric acid H2SO4
Hydrochloric acid HCl
Nitric acid HNO3
Citric acid C6H8O7
Ethanoic acid (vinegar) CH3COOH
Chapter 10
Acids, Bases and Salts
Uses of Acids
■ Hydrochloric acid is used in the industry to remove
rust from metals before they are painted.
■ Sulphuric acid is used to make fertilisers and
detergents.
■ Ethanoic acid is used in vinegar for cooking and
to preserve food such as vegetables.
■ Used in making fruit salts
❑ Acids are naturally present in a lot of fruits. Citric acid is found
in citrus fruits, tartaric acid is found in grapes, ascorbic acid the
scientific name for vitamin C. Vitamin C is found in a lot of fruits
and vegetable and is very important in maintaining good health.
 Uses of Acids
♦ Hydrochloric acid is naturally found in the human
stomach. It is used by our body to aid in the digestion
of our food.

♦ Humans also need a special group of acids called

amino acids to stay alive. Amino acids are the
building blocks of proteins.

11
 Chapter 10
Acids, Bases and Salts
Quick check 1
1. What ions do acids produce in water?
2. State three properties of acids.
3. Explain what is meant by a strong acid. Give one
example of a strong acid.
4. Explain what is meant by a weak acid. Give one example
of a weak acid.
5. Some dry citric acid crystals are placed on a dry piece of
litmus paper. Will there be a colour change? Explain your
answer.
Solution
 Chapter 10
Acids, Bases and Salts
Solution to Quick check 1
1. Hydrogen ions
2. (a) Acids have a sour taste.
(b) Acids turn blue litmus to red.
(c) Acids react with metals to produce hydrogen.
3. A strong acid is an acid that is completely ionised in water. E.g.
sulphuric acid.
4. A weak acid is an acid that is only partially ionised in water. E.g.
ethanoic acid.
5. There will be no colour change because there is no water, so
the citric acid cannot form hydrogen ions.
Return
Chapter 10
Acids, Bases and Salts
Bases
■ A base is an oxide or hydroxide of a metal.
■ Examples of bases are:
sodium oxide, sodium hydroxide, copper(II)
oxide, copper(II) hydroxide, etc.
■ A base reacts with an acid to form a salt and
water only.
E.g. CuO + H2SO4 CuSO4 + H2O
■ This process is called neutralisation.

14
 Chapter 10
Acids, Bases and Salts
Alkalis
■ If a base is soluble in water, it is called an alkali.

■ An alkali is a soluble base which

produces hydroxide ions, OH− (aq)
in water.

■ Sodium hydroxide is an alkali because it dissolves in

water to produce hydroxide ions:
NaOH(aq) Na+(aq) + OH−(aq)
15
Chapter 10
Acids, Bases and Salts
Difference between base and alkali

■ Copper(II) hydroxide is a base but not an alkali. This is

because it is insoluble in water and hence cannot produce
hydroxide ions in water.

■ Is this true? BASE

CuO ALKALI
All alkalis are bases,
Cu(OH)2 NaOH NH3(aq)
but not all bases are alkalis. KOH
Fe2O3
Ca(OH)2
MgO

16
Chapter 10
Acids, Bases and Salts
Chemical properties of alkalis

■ Alkalis have a bitter taste and soapy feel.

■ Alkalis turns red litmus to blue.
■ Alkalis react with acids to from salt and water
only.
E.g. 1. NaOH + HCl NaCl + H2O
E.g. 2 2KOH + H2SO4 K2SO4 + 2H2O

17
 Chapter 10
Acids, Bases and Salts
Chemical properties of alkalis
■ Alkalis react with ammonium salts to produce ammonia gas.
■ Ammonia gas is basic, thus it turns red litmus paper blue.
■ Ammonia gas is very soluble in water and gives out a pungent
smell.
E.g.1: NaOH + NH4Cl NaCl + NH3 + H2O
NH3 gas produced turns
red litmus blue

Sodium hydroxide +
ammonium chloride

E.g. 2: Ca(OH)2 + 2NH4Cl CaCl2 + 2NH3 + 2H2O

18
Chapter 10
Acids, Bases and Salts
Uses of Bases

■ Sodium hydroxide and potassium hydroxide are used

in making soaps.
■ Ammonia solution is used in window cleaners.
■ Magnesium hydroxide is used in toothpastes to neutralise
the acid produced by bacteria.
■ Calcium hydroxide (slaked lime) is used to neutralise
acids found in acidic soil.

19
 More Uses of Bases

♦ Baking soda is used in toothpastes, in cleaning agents and

is also used to absorb odours- especially in refrigerators.
♦ Baking powder is used in baked products as a raising
agent.
♦ Household bleach is mainly used to remove stains, whiten
materials and kill germs as a disinfectant.
♦ Ammonia and its compounds are commonly used in the
home. Ammonium hydroxide is used to remove ink stains
from clothes.
♦ Sodium hydroxide is used as the ‘base’ necessary to mix
most relaxers when straightening human hair. 20
Chapter 10
Acids, Bases and Salts
Some Common Alkalis
Name Chemical formula

Sodium hydroxide NaOH

Potassium hydroxide KOH

Calcium hydroxide Ca(OH)2

Ammonia solution NH3(aq)

(ammonium hydroxide)
21
 Chapter 10
Acids, Bases and Salts
Quick check 2

1. What is a base? Give 3 examples of bases.

2. Define what is an alkali. Give 3 examples of alkalis.
3. State 3 properties of alkalis.
4. Explain why iron(II) hydroxide is a base, but not an alkali.
5. Write balanced chemical equations for the following
reactions:
(a) potassium hydroxide + ammonium chloride
(b) calcium hydroxide + ammonium chloride

Solution
22
 Chapter 10
Acids, Bases and Salts
Solution to Quick check 2

1. A base is an oxide or hydroxide of a metal.

E.g. sodium oxide, copper(II) oxide, calcium hydroxide.
2. An alkali is a soluble base which produces hydroxide ions in water.
E.g. sodium hydroxide, potassium hydroxide, calcium hydroxide.
3. (i) Alkalis turn red litmus blue.
(ii) Alkalis react with acids to produce a salt and water.
(iii) Alkalis react with ammonium salts to produce ammonia.
4. Iron(II) hydroxide is a base, but not an alkali because it is insoluble
in water, so it cannot produce hydroxide ions in water.
5. (a) KOH + NH4Cl KCl + H2O + NH3
(b) Ca(OH)2 + 2NH4Cl CaCl2 + 2H2O + 2NH3
Return
23
Chapter 10
Acids, Bases and Salts
Indicators

■ Indicators are substances which show different

colours in acidic and alkaline solutions.

■ Litmus is a common indicator. It is red in acidic

solutions and blue in alkaline solutions.

■ Other important indicators are shown in the table

on the next slide.

24
Chapter 10
Acids, Bases and Salts
Indicators

Indicator Colour in pH at which Colour in

strong colour strong
Acids changes alkalis

Methyl orange red pH 4 yellow

Litmus red pH 7 blue

Phenolphthalein colourless pH 9 pink

25
26
Chapter 10
Acids, Bases and Salts
The pH Scale
■ The pH of a solution tells us how acidic or alkaline a
solution is.
■ The pH is a measurement of the hydrogen ion concentration
in a solution.
■ The pH scale ranges from 0 to 14.
■ The pH of a solution can be measured with a pH meter.

27
28
Chapter 10
Acids, Bases and Salts
The pH Scale

■ The lower the pH, the more acidic the solution is.
■ The higher the pH, the more alkaline the solution is.
■ pH 7 is neutral.
■ Distilled water, sugar solution and most salt solutions are
neutral (pH 7).

29
Chapter 10
Acids, Bases and Salts
The Universal Indicator
■ The Universal Indicator consists of a mixture of dyes which
changes its colour in different pH solutions.
■ We can use the Universal Indicator to tell us the
approximate pH of a solution.
■ The Universal Indicator or pH paper changes its colour
according to the pH shown in the chart below.

Box of pH paper with

colour chart 30
 Chapter 10
Acids, Bases and Salts
Types of Oxides
■ Elements burn or react with oxygen to form oxides.

■ There are 4 types of oxides: acidic oxides, basic oxides, amphoteric oxides and
neutral oxides.

■ An acidic oxide is an oxide of a non-metal. It dissolves in water to form an acid.

Acidic oxides react with alkalis to form salts .

■ A basic oxide is an oxide of a metal. If soluble, it will dissolve in water to form an

alkali. Basic oxides react with acids to form salts.

■ An amphoteric oxide is an oxide which can react with both acids and strong alkalis to
form salts.
■ A neutral oxide does not react with either acids or alkalis. 31
 Chapter 10
Acids, Bases and Salts
Types of Oxides
4 TYPES OF OXIDES

Acidic Oxides Basic Oxides Amphoteric Oxides Neutral Oxides

CO2 , SO2 Na2O, CaO, Al2O3 , PbO , H2O, CO ,

NO2 , NO K2O, MgO, CuO ZnO N2O

React with React with both Do not react with

alkalis to form React with acids to acids & alkalis to both acids &
salts form salts form salts alkalis
32
Acids, Bases and Salts: Reaction of Amphoteric Oxides

33
 Chapter 10
Acids, Bases and Salts
Quick check 3
1. Name 3 common indicators and their colour change in strong
acidic and strong alkaline solutions.
2. What is meant by the pH of a solution? What is the pH of :
(a) hydrochloric acid, (b) citric acid, (c) sodium chloride
solution, (d) sodium hydroxide solution?
3. What are the 4 types of oxides? Give one example of each
type of oxide.
4. What colours would you expect to see when the following
indicators are added to a solution of pH 5?
(a) litmus, (b) phenolphthalein, (c) methyl orange
Solution
34
 Chapter 10
Acids, Bases and Salts
Solution to Quick check 3

1. Litmus: red, blue;

Phenolphthalein: colourless, pink;
Universal Indicator: red, violet
2. The pH of a solution measures the acidity or alkalinity of a
solution. (a) 0 – 1, (b) 3 – 4, (c) 7, (d) 13 – 14.
3. Acidic oxides, basic oxides, amphoteric oxides and neutral
oxides. E.g. sulphur dioxide, sodium oxide, aluminium oxide,
water.
4. (a) litmus: red, (b) phenolphthalein: colourless,
(c) methyl orange: yellow
Return
35
Chapter 10
Acids, Bases and Salts
Salts

■ A salt is formed when an acid is

neutralised by a base. Acid + Base
■ A salt contains two parts:
■ Metal part : cation (comes from the
base)
■ Non-metal part : anion (comes from
the acid) Salt

36
 How are salts formed ?

Salts are made when an acid reacts with a base,

carbonate or metal.
The name of the salt formed depends on the metal in the
base and the acid used.
For example,
∙ salts made using hydrochloric acid are called chlorides.
∙ salts made using sulphuric acid are called sulphates
∙ salts made using nitric acid are called nitrates
∙ salts made using phosphoric acid are called phosphates
37
Naming salts
∙The name of a salt has two parts. The first part comes
from the metal in the base or carbonate, or the metal
itself if a reactive metal like magnesium or zinc is used.

∙The
second part of the name comes from the acid used to
make it.
∙ The names of salts made from hydrochloric acid end
in -chloride, while the names of salts made from
sulfuric acid end in -sulfate.

38
Chapter 10
Acids, Bases and Salts
Examples of Salts
Table 1
Base (alkali) Acid Salt formed
Sodium hydroxide Hydrochloric acid Sodium chloride
Potassium hydroxide Hydrochloric acid Potassium chloride
Sodium hydroxide Sulphuric acid Sodium sulphate
Potassium hydroxide Sulphuric acid Potassium sulphate
Calcium hydroxide Nitric acid Calcium nitrate
back
Ammonia solution Nitric acid Ammonium nitrate

39
Try
■ zinc + sulphuric acid →

■ calcium carbonate + nitric acid →

40
Chapter 10
Acids, Bases and Salts
Uses of Salts
■ Sodium chloride is used as table salt and to preserve
meat and vegetables.
■ Sodium chloride is electrolysed to obtain sodium and
chlorine in the industry.
■ Ammonium nitrate and ammonium sulphate are used
as plant fertilisers.
■ Magnesium sulphate, commonly called Epsom salt, is
used as a bath-salt.

41
Acids + Bases
•When acids react with bases, a salt and water are made
(neutralization reaction) – In general:
acid + metal oxide → salt + water
acid + metal hydroxide → salt + water
Remember that most bases do not dissolve in water. But if a
base can dissolve in water, it is also called an alkali.

42
Acids + Carbonates
•When acids react with carbonates, such as calcium
carbonate (found in chalk, limestone and marble), a salt,
water and carbon dioxide are made. In general:
acid + metal carbonate → salt + water + carbon dioxide
•Notice that an extra product - carbon dioxide - is made.
•It
causes bubbling during the reaction, and can be detected
using limewater.
• You usually see this reaction if you study the effects
of acid rain on rocks and building materials.
43
Acid + Reactive metals
•Acidswill react with reactive metals, such as magnesium
and zinc, to make a salt and hydrogen. In general:
acid + metal → salt + hydrogen

The hydrogen causes bubbling during the reaction, and can

be detected using a lighted splint

44
Salt can be classified into two groups:
•Normal salts – formed when all of the H+ ions in an acid are replaced by metal
or ammonium ions:
• E.g. 2KOH(aq) + H2SO4(aq) K2SO4(aq) + 2H2O(l)
•All acids can form normal salts

•Acid salts –formed when the H+ ions in an acid are only partially replaced by
metal or ammonium ions
• E.g. 2KOH(aq) + H2SO4(aq) KHSO4(aq) + 2H2O(l)
•Only dibasic and tribasic acids can form acid salts

45
 Water of Crystallization
■ Some salts may contain water of crystallization. This is
a fixed proportion of water molecules held within their
crystal lattice.
◻ Salts containing water of crystallization are hydrated and
can be shown in formula:
■ CuSO4.5H2O (hydrated copper sulphate)
◻ In some compounds, water of crystallization is responsible
for the shape and sometimes the colour of the crystals.
◻ If the water is removed by heating, the salt becomes
anhydrous; it loses the crystalline structure and its colour
may change.
◻ E.g. CuSO4.5H2O (s) CuSO4 (s) + 5H2O(g)
(blue crystals) (white powder) 46
Water of Crystallization

47
 Is the salt an anhydrous
chloride: if yes heat suitable
metal in stream of chlorine

Preparation of Salt gas in a fume cupboard, if

no: see below

Is the salt an
anhydrous
chloride: if yes No
use direct
combination
otherwise use
method 1 below

2
1

Finally
48
 Chapter 10
Acids, Bases and Salts
Methods of Preparing Salts
1. Action of acid on alkali (Titration)
ACID + ALKALI SALT + WATER

■ This process is called neutralisation.

■ To carry out the neutralisation of the acid

and alkali exactly, a method called titration
is used.
■ The salts listed in Table 1 can be prepared
by the titration method.
49
Chapter 10
Acids, Bases and Salts
To prepare sodium nitrate by neutralisation (titration method)

burette

Pipette
Sodium nitrate and water
(phenolphthalein as indicator) 50
Chapter 10
Acids, Bases and Salts
To prepare sodium nitrate by neutralisation (titration method)

back

51
 Chapter 10
Acids, Bases and Salts
Methods of Preparing Salts
2. Action of acid on insoluble base
ACID + BASE SALT + WATER
■ This method is used for bases which are insoluble in water.

■ Examples of salts prepared by this method:

* copper(II) sulphate from copper(II) oxide and sulphuric acid:
CuO + H2SO4 CuSO4 + H2O
* zinc chloride from zinc oxide and hydrochloric acid:
ZnO + 2HCl ZnCl2 + H2O
52
Chapter 10
Acids, Bases and Salts
Preparation of copper(II) sulphate (acid on insoluble base)
Step 1 Place about 50 cm³ of dilute
sulphuric acid in a beaker and gently
warm the acid. Copper(II) oxide is added,
a little at a time, to the acid, until no more
can dissolve.
Equation: CuO + H2SO4 CuSO4 + H2O
Step 2 Filter off the excess copper(II) oxide
using a filter paper and funnel. Collect the
filtrate which contains copper(II) sulphate in
an evaporating dish.
53
 Chapter 10
Acids, Bases and Salts
Preparation of copper(II) sulphate (acid on insoluble base)

Step 3 Evaporate the copper(II) sulphate solution until it is saturated.

Allow the hot solution to cool to form crystals.
Step 4 Filter off the copper(II) sulphate crystals formed and dry
them by pressing them between sheets of filter paper.
54
Chapter 10
Acids, Bases and Salts
Methods of Preparing Salts
3. Action of acid on a carbonate
ACID + CARBONATE SALT + WATER + CO2
Eg.1 Sulphuric acid on sodium carbonate
H2SO4 + Na2CO3 Na2SO4 + H2O + CO2
Eg.2 Hydrochloric acid on calcium carbonate
2HCl + CaCO3 CaCl2 + H2O + CO2

■ This method is similar to the previous method; instead of the

oxide, the carbonate is added in excess to the acid.

55
Chapter 10
Acids, Bases and Salts
Methods of Preparing Salts
4. Action of acid on a metal
ACID + METAL SALT + HYDROGEN
Eg.1 Sulphuric acid on zinc
H2SO4 + Zn ZnSO4 + H2
Eg.2 Hydrochloric acid on magnesium
2HCl + Mg MgCl2 + H2
■ NOTE:
Only metals like magnesium, zinc and iron are suitable. Metals
like sodium, potassium and calcium are explosive with acids;
while metals like lead and copper are unreactive with acids.
56
 Chapter 10
Acids, Bases and Salts
Making zinc sulphate (acid on metal)

back

Can you describe how zinc sulphate is prepared with the aid of the diagrams? 57
 Chapter 10
Acids, Bases and Salts
Methods of Preparing Salts
5. Double Displacement (Precipitation method)
■ This method is used to prepare insoluble salts.
■ Two solutions are mixed together to produce a precipitate of
the insoluble salt which can then be filtered off from the mixture.

+ CB (aq)
AD (s)
AB (aq) CD (aq)
E.g. Lead(II) nitrate + Sodium chloride Lead(II) chloride + Sodium nitrate
Pb(NO3)2(aq) + 2NaCl(aq) PbCl2(s) + 2NaNO3(aq)
58
Chapter 10
Acids, Bases and Salts
Other salts made by precipitation method

■ Silver chloride
AgNO3(aq) + HCl(aq) AgCl(s) + HNO3(aq)

■ Barium sulphate
Ba(NO3)2(aq) + H2SO4(aq) BaSO4(s) + 2HNO3(aq)

■ Copper(II) carbonate
CuSO4(aq) + Na2CO3(aq) CuCO3(s) + Na2SO4(aq)
back
59
Chapter 10
Acids, Bases and Salts
Table of soluble and insoluble salts
■ This table will be useful to you when preparing salts

Soluble salts Insoluble salts

All sodium, potassium and ammonium All carbonates except those of
salts sodium, potassium and ammonium
All nitrates None
All sulphates except those of calcium, Calcium sulphate, lead(II) sulphate
lead and barium and barium sulphate
All chlorides except those of silver Silver chloride and lead(II) chloride
and lead

60
Chapter 10
Acids, Bases and Salts
Quick check 4
1. Define what is salt. Give an example of a soluble and insoluble
salt.
2. State 4 methods of making salts.
3. State whether the following salts are soluble or insoluble:
(a) sodium carbonate, (b) calcium chloride, (c) barium sulphate,
(d) lead(II) nitrate, (e) lead(II) chloride.
4. State the method you would choose to prepare the following
salts:
(a) potassium nitrate, (b) zinc nitrate, (c) magnesium sulphate,
(d) copper(II) carbonate.
For each method, state the chemicals you will need and
write a balanced chemical equation for the reaction.

Solution 61
 Chapter 10
Acids, Bases and Salts
Solution to Quick check 4

1. A salt is formed when an acid is neutralised by a base.

E.g. soluble salt: sodium chloride
E.g. insoluble salt: calcium sulphate
2. (a) Acid on metal, (b) acid on base, (c) acid on carbonate,
(d) precipitation method
3. Soluble: sodium carbonate, calcium chloride, lead(II) nitrate; Insoluble: lead(II)
chloride, barium sulphate
4. (a) potassium nitrate: titration method; potassium hydroxide and
nitric acid; KOH + HNO3 KNO3 + H2O
(b) zinc nitrate: acid on carbonate; nitric acid and zinc carbonate;
2HNO3 + ZnCO3 Zn(NO3)2 + H2O + CO2
(c) magnesium sulphate: acid on metal; magnesium and sulphuric acid;
Mg + H2SO4 MgSO4 + H2
(d) copper(II) carbonate: precipitation method;
copper(II) sulphate and sodium carbonate;
CuSO4(aq) + Na2CO3(aq) CuCO3(s) + Na2SO4(aq) Return
62
Chapter 10
Acids, Bases and Salts
State symbols in equations
■ The state symbols in a chemical equation tell us about the state of each reactant
and product.
■ The following are the state symbols used:
■ Solid (s)
■ Liquid (l)
■ Gas (g)
■ Aqueous solution (aq)
■ Example: CaCO3(s) + 2HCl(aq) CaCl2(aq) + H2O(l) + CO2(g)
■ The above equation tells us that solid calcium carbonate reacts with a solution of
hydrochloric acid to produce liquid water and carbon dioxide gas.

63
Chapter 10
Acids, Bases and Salts
Writing ionic equations
■ Ionic equations are general equations which can apply to
any particular reaction.
■ They represent ions taking part in a reaction, leaving out
those ions which do not react (spectator ions).
■ They contain state symbols.
■ Only solutions (aq) can form ions; gases, solids and liquids
do not ionise.

64
 Chapter 10
Acids, Bases and Salts
Writing ionic equations
Steps in writing ionic equations
EXAMPLE 1
HCl (aq) + NaOH (aq) NaCl (aq) + H2O (l)
Step 1: Break substances with (aq) into its ions:
H+(aq) + Cl-(aq) + Na+ (aq) + OH-(aq) Na+ (aq) + Cl- (aq) + H2O (l)

Step 2: Remove similar ions from both sides of equation.

Step 3: Rewrite the equation with the final ions left:

H+ (aq) + OH- (aq) H2O(l)
65
 Chapter 10
Acids, Bases and Salts
Writing ionic equations
Steps in writing ionic equations

EXAMPLE 2
2HCl(aq) + CaCO3 (s) CaCl2 (aq) + H2O (l) + CO2 (g)

Step 1: Break those with (aq) into its ions:

2H+ (aq) + 2Cl-(aq) + CaCO3 (s) Ca2+ (aq) + 2Cl- (aq) + H2O (l) + CO2 (g)

Step 2: Remove similar ions on both sides.

Step 3: Rewrite the equation with the ions left:
2H+(aq) + CaCO3(s) Ca2+(aq) + H2O(l) + CO2(g)
66
 Chapter 10
Acids, Bases and Salts
Writing ionic equations
Steps in writing ionic equations

EXAMPLE 3
Pb(NO3)2(aq) + 2NaCl (aq) PbCl2 (s) + 2NaNO3 (aq)

Step 1: Break those with (aq) into its ions:

Pb2+(aq) + 2NO3-(aq) + 2Na+(aq) + 2Cl- (aq) PbCl2(s) + 2Na+(aq) + 2NO3- (aq)
Step 2: Remove similar ions on both sides.
Step 3: Rewrite the equation with the ions left:
Pb2+(aq) + 2Cl- (aq) PbCl2(s)
67
Chapter 10
Acids, Bases and Salts
Quick check 5
Construct (i) a balanced chemical equation and (ii) an ionic
equation for each of the following reactions:

(1) Sulphuric acid + potassium hydroxide

(2) Nitric acid + sodium hydroxide
(3) Silver nitrate solution + sodium chloride solution
(4) Calcium carbonate + hydrochloric acid
(5) Magnesium + hydrochloric acid

Solution
68
 Chapter 10
Acids, Bases and Salts
Solution to Quick check 5

1. H2SO4(aq) + 2KOH(aq) K2SO4(aq) + 2H2O(l)

H+(aq) + OH-(aq) H2O(l)

2. HNO3(aq) + NaOH(aq) NaNO3(aq) + H2O(l)

H+(aq) + OH-(aq) H2O(l)

3. AgNO3(aq) + NaCl(aq) AgCl(s) + NaNO3(aq)

Ag+(aq) + Cl-(aq) AgCl(s)

4. CaCO3(s) + 2HCl(aq) CaCl2(aq) + H2O(l) + CO2(g)

CaCO3(s) + 2H+(aq) Ca2+(aq) + H2O(l) + CO2(g)

5. Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g)

Mg(s) + 2H+(aq) Mg2+(aq) + H2(g) Return
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Chapter 10
Acids, Bases and Salts

To learn more about Acids, Bases and Salts,

click on the links below!
1. http://www.sciencebyjones.com/acids_bases_salts.htm

2. http://ull.chemistry.uakron.edu/genobc/Chapter_09/

3. http://www.chem.ubc.ca/courseware/pH/index.html

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