FINAL REVISION TEST ‘25
CLASS : 12TH STD. MARKS : 70
SUBJECT : CHEMISTRY TIME : 2.30HRS
PART-I
Chosse the correct answers. 15 X 1 =15
1. Zinc is obtained from ZnO by
a) Carbon reduction b) Reduction using silver
c) Electrochemical process d) Acid leaching
2. Thermodynamically the most stable form of carbon is
a) Diamond b) graphite c) Fullerene d) none of these
3. Which is true regarding nitrogen?
a) least electronegative element b) has low ionisation enthalpy than oxygen
c) d- orbitals available d) ability to form pπ − pπ bonds with itself
4. Which transition element shows the highest oxidation State
a)Os b)Ti c)Sc d)Zn
5. The coordination number of Al in the complex K3[Al(C2O4)3] is
a) 3 b) 4 c) 6 d) 2
6. Solid NH3 is an example of
a)Non polar molecular solid b)polar molecular solid
c) hydrogen bonded molecular solid d) metallic solid
7. For a reaction the rate law is rate=K[A] 6/2 [B]-4/2the overall order of reaction is
a)1 b)2 c) 3 d) 0
8. Which of these is not likely to act as lewis base?
a) BF3 b) PF3 c) CO d) F–
9. Which of the following is used as sacrificial anode in protecting iron from corrosion
a) magnesium b) zinc c) copper d) Both a and b
10. Which one of the following is an example for homogeneous catalysis?
a) manufacture of ammonia by Haber’s process
b) manufacture of sulphuric acid by contact process
c) hydrogenation of oil
d) Hydrolysis of sucrose in presence of all HCl
11. Oxidation of glycerol with con HNO3 gives to
a) Glyceric acid b)oxalic acid c)mesooxalic acid d)tatronic acid
12. On reacting with neutral ferric chloride, phenol gives
a) red colour b) violet colour c) dark green colour d) no colouration.
13. Which one of the following reaction is an example of disproporationation reaction
a) Aldol condensation b) cannizaro reaction
c) Benzoin condensation d) none of these
14. Which of the following amines will answer Libermann’s nitroso test
a) CH3NH2 b) C6H5NH2 c) (CH3)3N d) C6H5-NH-CH3
15. Which of the following is used as a substitute for wool in the manufacture of blankets
a) Orlon b) Dacron c) Neoprene d) Terylene
PART-II
Answer the following any six questions. (Question number 24 is compulsory.) 6 X 2 = 12
16. Write short notes on Autoreduction.
17. What are interhalogen compounds ? give two examples
18. Write the IUPAC names for the following compounds
i) [Cu(NH3)4]SO4 ii) Na2[Ni(EDTA)]
19. Define packing efficiency.
20. What are conjugate acid base pair give an example ?
21. Write a note on tyndall effect?
22. Write the rosenmud reduction?
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23. What are sugar substituents? Give examples.
24. From the following reaction identify A and B .
Sn/HCl
A
6[H]
CH3-NO2
Zn/NH4Cl
B
4[H]
PART-III
Answer the following any six questions. (Question number 33 is compulsory) 6 X 3 = 18
25. what are the factors responsible for the anomalous behaviour of first element of the p-block ?
26. What is lanthanoid contraction explain its consequences
27. write a short note on postulates of werner's theory?
28. Derive the Relation between PH and POH
29. State faraday’s law of electrolysis ?
30 Write any three characters of catalysts ?
31.Differentiate primary secondary and tertiary alcohols using Lucas test
32. Write a short note on peptide bond ?
33. Write the mechanism of aldol condensation reaction ?
PART-IV
Answer the following all questions. 5 X 5 = 25
34.a) i) Describe mond process for refining nickel.(3)
ii) How will you identify borate radical ? (2)
(OR)
b) i) Write the balanced equation for the overall reaction of chlorine with cold. NaOH and hot NaOH (2)
ii) What are interstitial compounds? Give example (3)
35.a) [Ni(CN)4]2- is diamagnetic , while [NiCl4]2- is paramagnetic explain (5)
(OR)
b) i) Classify molecular crystal with an example for each type.(3)
ii)Explain hume -rothery rule for formation of alloys ? (2)
36.a) i) Derive an expression for ostwald dilution law(3)
ii) Ionic conductance at infinite dilution of Al3+ and SO42- 189 and 160 mho cm2 equiv-1 calculate the equivalent
and molar conductance of the electrolyte Al2(SO4)3 at infinite dilution. (2)
(OR)
b) i) Derive integrated rate law for a first order reaction A →product (3)
ii)Define Electroosmosis.(2)
37.a) i) How are the following conversion effected?
1) ethylene glycol → 1,4 dioxane(1 ½)
2) glycerol → acrolein(1 ½)
ii) How does ammonia react with formaldehyde ? Draw the structure of product. (2)
(OR)
b) I) write short note on Gabriel phthalimide synthesis (3)
ii) Write a test to identify primary amines.(2)
38. a) i) What is isoelectric point?(2)
ii) Draw the structures of Lactose and Maltose.(3)
(OR)
b) How the following polymers are prepared ?
i) Teflon ii) Nylon-6 iii) PHBV
******All The Best********
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