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Polymer Chemistry QA

The document discusses key concepts in polymer chemistry, including the functionality of monomers, differences between thermosetting and thermoplastic polymers, solution polymerization processes, and the characteristics and applications of biodegradable polymers. It details the functionality of specific compounds like acetylene and styrene, and outlines the advantages and disadvantages of solution polymerization. Additionally, it highlights the importance of biodegradable polymers in reducing environmental impact and promoting sustainability.

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25 views3 pages

Polymer Chemistry QA

The document discusses key concepts in polymer chemistry, including the functionality of monomers, differences between thermosetting and thermoplastic polymers, solution polymerization processes, and the characteristics and applications of biodegradable polymers. It details the functionality of specific compounds like acetylene and styrene, and outlines the advantages and disadvantages of solution polymerization. Additionally, it highlights the importance of biodegradable polymers in reducing environmental impact and promoting sustainability.

Uploaded by

anshuman.behera
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Polymer Chemistry Questions and Answers

Q1: Functionality of Monomers

Functionality of a monomer refers to the number of reactive sites (functional groups) available for

polymerization.

It determines the type of polymer structure formed.

Functionality of Given Compounds:

1. Acetylene (C2H2) - Functionality: 2 - Has two reactive triple-bonded carbon atoms, allowing it to

form polymer chains or cross-linked structures.

2. Styrene (C8H8) - Functionality: 1 - Contains a single reactive double bond (-C=C-), used in

polystyrene production.

3. Adipic Acid (C6H10O4) - Functionality: 2 - Has two carboxyl (-COOH) groups, allowing it to form

polyesters or polyamides (e.g., Nylon-6,6).

4. Propylene (C3H6) - Functionality: 1 - Has a single reactive double bond, used in polypropylene

production.

Q2: Differences Between Thermosetting and Thermoplastic Polymers

Thermosetting Polymers:

- Undergo permanent hardening upon heating and cannot be remolded.

- Cross-linked or heavily branched.

- Not recyclable.

- High heat resistance.

- Examples: Bakelite, Epoxy resin, Melamine.

Thermoplastic Polymers:

- Soften upon heating and harden upon cooling, allowing remolding.


- Linear or lightly branched structure.

- Recyclable.

- Can soften and melt at high temperatures.

- Examples: Polyethylene, Polypropylene, Polystyrene.

Q3: Solution Polymerization

Solution polymerization is a method where monomers are dissolved in a solvent, and polymerization

occurs in solution.

Process:

1. Monomers are dissolved in a solvent.

2. A chemical initiator (e.g., peroxide) is added to start polymerization.

3. The reaction proceeds to form a polymer.

4. The polymer is separated from the solvent by precipitation or evaporation.

Advantages:

- Better heat dissipation.

- Easier viscosity control.

- Suitable for high-purity polymers.

Disadvantages:

- Requires solvent recovery and recycling.

- Increases process cost and complexity.

Example: Polymerization of acrylates in organic solvents for coatings and adhesives.

Q4: Biodegradable Polymers


Biodegradable polymers decompose into natural substances like water, carbon dioxide, and

biomass by microorganisms.

Characteristics:

- Decomposed by microbial action.

- Reduce plastic waste.

- Often derived from renewable resources.

Examples:

1. Polylactic Acid (PLA) - Derived from corn starch, used in packaging and medical implants.

2. Polyhydroxyalkanoates (PHA) - Produced by bacteria, used in bioplastics.

3. Polycaprolactone (PCL) - Used in drug delivery and biomedical applications.

4. Polybutylene Succinate (PBS) - Used in compostable packaging.

Applications:

- Biodegradable packaging.

- Medical sutures and implants.

- Agricultural films and disposable cutlery.

Biodegradable polymers help reduce environmental impact and promote sustainability.

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