NAME: …………………………………………………..CLASS:…....…..ADM. NO…….…….
Index No…………………. Chemistry Teacher……………………………………………
PANGANI GIRLS SCHOOL
CHEMISTRY PRACTICAL
MOCK 2024
233/3
Paper 3 Practical
2 hours
July 2024
Instructions to candidates
Write your name, class, admission number in the space provided above.
Answer ALL the questions in the spaces provided.
You are not allowed to start working with the apparatus for the first 15 minutes of the 2
hours allowed for this paper. This time is to enable you to read the question paper and
make sure you have all the chemicals and apparatus that you may need.
Mathematical tables and silent calculators may be used.
All working MUST be clearly shown where necessary.
For Examiner’s Use Only
Questions Maximum Candidate’s
Score Score
1 11
2 11
3 18
TOTAL 40
This paper consists of 7 printed pages.
Candidates should check the question paper to ascertain that all
the pages are printed as indicated and no questions are missing.
2
Q1. (11 Marks)
You are provided with:
Saturated solution W of H2C2O4.2H2O at 19oC, 0.15M sodium hydroxide solution P,
phenolphthalein indicator.
You are required to:
Determine the solubility of H2C2O4.2H2O at 19oC.
PROCEDURE
(i) Transfer exactly 25.0cm3 of the saturated solution W into a volumetric flask by means
of a pipette and pipette filler and add water from a wash bottle until the 250ml mark and
label this as solution W1.
(ii) Rinse the Pipette and transfer 25.0 cm 3 of solution P into a conical flask, add 2 drops
of phenolphthalein indicator and titrate using solution W1 from the burette. Record your
values in the table 1 below. Repeat the procedure to obtain concordant titres.
CT =
I II III DP =
3
Final Burette Reading (cm )
A =
3
Initial burette Reading (cm )
PA =
3
Volume of solution W1 (cm ) used
FA =
(4 marks)
(a) Average volume of solution W1 used. (1 mark)
(b) Determine the number of moles of solution P reacting. (1 mark)
3
(c) Calculate the moles of solution W1 reacting. (1 mark)
(d) calculate the number of moles of solution W1 in 250cm3 of solution. (1 mark)
(e) Calculate the mass of H2C2O4.2H2O in 250cm3 of solution W1. (1 mark)
(R.A.M: H = 1, C = 12, O = 16)
(f) Determine the mass of saturated solution W. (1 mark)
(Density of saturated solution W = 1.055g/cm3)
(g) Determine the solubility of H2C2O4.2H2O in g/100g H2O at 19oC. (1 mark)
4
Q2. (11 marks)
You are provided with solid A of Barium hydroxide weighing 4.0g, solution E
hydrochloric acid.
You are required to;
Determine the heat of reaction between barium hydroxide and carbon (IV) oxide gas.
PROCEDURE II (a)
(i) Using a 100ml measuring cylinder, measure 30 cm 3 of hydrochloric acid Solution
E and place it in a 250ml plastic beaker.
(ii) Measure the temperature of the hydrochloric acid and record in Table 2.
(iii) Add all of the solid A provided to solution E. Stir with the thermometer and
measure the final temperature reached. Record the reading in Table 2.
Table 2
Final temperature of solution, oC
Initial temperature of solution, oC
Temperature change, oC
(2 marks)
Calculate:
(i) heat change of the reaction. (assume specific heat capacity of solution = 4.2J/g/ oC,
density of solution = 1.0g/cm3) (1 mark)
(ii) number of moles of Barium hydroxide, solid A used.
(Relative formula mass of barium hydroxide = 315.0) (1 mark)
(iii) heat change ∆H1 in kJmol-1 of barium hydroxide reacting. (1 mark)
Ba(OH)2(s) + 2HCl(aq) BaCl2(aq) + 2H2O(l) ∆H1 = ?
5
PROCEDURE II (b)
(i) Clean the 250ml plastic beaker.
(ii) Repeat procedure II (a) using the barium carbonate solid B which weighs 5.6g
and 30 cm3 of solution E.
(iii) Record the results in Table 3.
Table 3
Final temperature of solution oC
Initial temperature of solution oC
Temperature change, oC
(2 marks)
Calculate the:
(i) heat change of the reaction. (assume specific heat capacity of solution = 4.2 /g/ oC,
density of solution = 1.0g/cm3) (1 mark)
(ii) number of moles of Barium carbonate, solid B used.
(Relative formula mass of barium carbonate = 197.0) (1 mark)
(iii) heat change, ∆H2 in kJmol-1 of barium carbonate. (1 mark)
BaCO3(s) + 2HCl(aq) BaCl2(aq) + 2H2O(l) + ∆H2 = ?
(iv) heat change, ∆H3 for the reaction of barium hydroxide and carbon (IV) oxide.
(1 mark)
Ba(OH)2(s) + CO2(g) BaCO3(s) + H2O(l) ∆H3 = ?
∆H3 = ∆H2 – ∆H1
6
Q3. (a) (10 marks) You are provided with solid C to carry out the tests below. Write
your observations and inferences in the spaces provided.
a) Place two thirds of solid C in a clean test tube. Add 10cm3 of distilled water and
shake. Divide the solution in into 4 portions.
OBSERVATIONS INFERENCES
(1 mk) (1
mks)
(ii) To the first portion add 5 drops of aqueous lead (II) nitrate solution.
OBSERVATIONS INFERENCES
(1 mk) (2
mks)
(iii) To the second portion add 5 drops of aqueous barium nitrate solution.
OBSERVATIONS INFERENCES
(1 mk) (1
mk)
(iv) To the third portion add 5 drops of aqueous sodium hydroxide solution until in
excess
OBSERVATIONS INFERENCES
(1 mk) (1 mk)
(iv) Place a small portion of the remaining solid C on a metallic spatula and heat
directly in a Bunsen burner flame.
OBSERVATIONS INFERENCES
(1 mk) (1 mk)
7
(b) (8 marks) You are provided with solid D. You are required to carry out the tests
below. Write your observations and inferences in the spaces provided.
a) Place a small portion of the solid D provided into a metallic spatula and heat directly
in a non luminous flame.
OBSERVATIONS INFERENCES
(½ mk) (½
mk)
b) Add all the remaining solid D to about 10cm3 of distilled water in a test tube and
shake. Divide the solution into 4 portions
(iv) to the 1st portion place a piece of universal indicator paper.
OBSERVATIONS INFERENCES
(½ mk) (½mk)
(iii) to the 2nd portion add the sodium hydrogen carbonate solid.
OBSERVATIONS INFERENCES
(1 mk) (1 mk)
(i) to the 3rd portion add 5 drops of acidified potassium manganate (VII).
OBSERVATIONS INFERENCES
(1 mk) (1mk)
(ii) to the 4th portion add 5 drops of acidified potassium dichromate (VI) and heat.
OBSERVATIONS INFERENCES
8
(1 mk) (1mk)
This is the last printed page
CHEMISTRY PRACTICAL (Saturday 06/07/24)
The following apparatus, chemicals and materials will be required
.
1. Burette 50ml
2. Pipette 25ml
3. Pipette Filler
4. Conical flask
5. White tile
6. Thermometer 0 – 100oC
7. Volumetric flask 250ml
6. Solution E (each candidate requires about 100ml) 1.5M hydrochloric acid
7. Solution W (Each candidate requires about 50ml) Oxalic acid
8. Solid A (Each candidate requires 4.0g accurately weighed)
9. Solid B (Each candidate requires 5.6g accurately weighed)
10. Solid C (Each candidate requires 0.5g)
11. Solid D (Each candidate requires 0.5g)
12. Sodium hydrogen carbonate (Each candidate requires 0.5g)
13. Plastic Beaker 100ml
14. Solution P (each candidate requires about 150ml) NaOH
15. Distilled water in a wash bottle
16. Test tubes (five)
17. Boiling tube (one)
18. Universal indicator paper & Full range chart
19. Spatula metallic
20. Test tube holder
21. Label (one)
Candidates should have access to the following;
22. Phenolphthalein indicator
23. Aqueous Barium nitrate solution
24. Aqueous Lead (II) nitrate solution
25. Aqueous sodium hydroxide solution
26. Acidified potassium dichromate (VI) solution
27. Acidified potassium manganate (VII) solution
28. Bunsen burner
29. Bromine water
9
PREPARATION OF SOLUTIONS
(1) Barium nitrate solution is prepared by dissolving 26.0g of solid barium nitrate in
about 800cm3 of distilled d water and diluting to one litre of solution. Label this as
aqueous barium nitrate.
(2) Lead (II) nitrate is prepared by dissolving 33.0g of solid lead (II) nitrate in about
800 cm3 of distilled water and diluting to eon litre of solution. Label this as aqueous lead
(II) nitrate in about 800cm3 of distilled water and diluting to one litre of solution. Label
this as aqueous lead (II) nitrate.
(3) Sodium hydroxide solution is prepared by dissolving 80.0g of solid sodium
hydroxide in about 800cm3 of distilled d water and diluting to one litre of solution.
Label this as aqueous sodium hydroxide.
(4) Acidified potassium dichromate (VI) solution is prepared by dissolving 30.0g of
solid potassium dichromate (VI) in about 200 cm3 of 2M sulphuric (VI) acid followed
by about 600 cm3 of distilled water in a one litre volumetric flask, then adding more
distilled water to the mark. Label this as acidified potassium dichromate (VI).
(5) Acidified potassium manganate (VII) solution. This is prepared by dissolving
3.0g of solid potassium manganate (VII) in about 200 cm3 of 2M sulphuric (VI) acid
followed by 600 cm3 of distilled in a one litre volumetric flask, then adding more distilled
water to make up to the mark. Label this as acidified potassium manganate (VII) solution.
10
PANGANI GIRLS SCHOOL
CHEMISTRY PRACTICAL (TUESDAY 09/07/24)
The following apparatus, chemicals and materials will be required
.
8. Burette 50ml
9. Pipette 25ml
10. Pipette Filler
11. Conical flask
12. White tile
13. Thermometer 0 – 100oC
14. Volumetric flask 250ml
30. Solution E 1.5M hydrochloric acid
31. Solution W
32. Solid A
33. Solid B
34. Solid C
35. Solid D
36. Sodium hydrogen carbonate
37. Plastic Beaker 100ml
38. Solution P
39. Distilled water in a wash bottle
40. Test tubes (five)
41. Boiling tube (one)
42. Universal indicator paper & chart
43. Spatula metallic
44. Test tube holder
45. Label (one)
Candidates should have access to the following;
46. Phenolphthalein indicator
47. Aqueous Barium nitrate solution
48. Aqueous Lead (II) nitrate solution
49. Aqueous sodium hydroxide solution
50. Acidified potassium dichromate (VI) solution
51. Acidified potassium manganate (VII) solution
52. Bunsen burner
11
