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Salt Analysis Paragraph-59

The document presents advanced level chemistry problems involving the reactions and properties of various compounds, particularly focusing on chromium and manganese species. It includes specific reactions, color changes, and the formation of different complexes. Additionally, it discusses the stabilization of certain compounds in the presence of solvents.

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38 views1 page

Salt Analysis Paragraph-59

The document presents advanced level chemistry problems involving the reactions and properties of various compounds, particularly focusing on chromium and manganese species. It includes specific reactions, color changes, and the formation of different complexes. Additionally, it discusses the stabilization of certain compounds in the presence of solvents.

Uploaded by

ritusinghthakur19
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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ADVANCED LEVEL PROBLEMS

Question No. 108 to 110 (3 Question)

[Sol. (NH4)2Cr2O7 D
Cr2O3(s) + N2 ­ + H2O (g)
(A) (B) (C) (D)
Orange solid Green CoCl2
D Mg
D Conc. HCl
Mg3N2
CrCl3 (I) CoCl2.6H2O
(F) Pink
H2 O (E)
Green sol.

H2O2/OH¯ NH3­
2–
(J)
CrO4 NiCl2
(G) sol.
Yellow sol. 2+
+
[Ni(NH3)6]
Et2O H2O2/H
Deep blue
CrO5.OEt2 (K)
(H)
Blue
Ans.(i) (C) Mn2+ + NH3 + 2H2O ¾® Mn(OH)2 ¯ + 2NH4+

H2O2

MnO.(OH)2¯
or
MnO2
Brownish-block

3d 4s 4p 4d
Ans.(ii) (B) Ni2+ in [Ni (NH3)6 ]2 +
3 2
Hyb.:sp d
O µeff=2.8 B.M.
O O
Ans.(iii) (D) + 2H2O2 + 2H+ ¾® Cr + 3H2O
O O
deep blue
(unstable in the absence
of organic solvent)
O
O O 4Cr 3+
+ 12 H+ ¾® Green + 7O2 ­ + 6H2O
Cr
O O
® CrO5 is stabilized in presence of ether, Amyl alcohol, amylacetate ]

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