PMMA
MMA
MMA (Methyl Meth Acrylate)
H
H H C H
C C
H C O
O
H C H
H
MMA
Naphtha
Naphtha Cracking
Cracking Isobutylene
Isobutylene
Mixed
Mixed C
C44 Isobutylene
Isobutylene Oxidation
Oxidation
Butadiene
Butadiene Extraction
Extraction Methyacrylic
Methyacrylic Acid
Acid
MAA
MAA
Raffinate
Raffinate -- 11
MeOH MeOH
MeOH
MeOH
MTBE
MTBE Sythesis
Sythesis Esterification
Esterification
MTBE
MTBE H
H H C H
MTBE
MTBE Cracking
Cracking C C
MMA
MMA
H C O
O
H C H
H
PMMA
PMMA(Poly Methyl MethAcrylate) MMA(Methyl MethAcrylate) Monomer
LG PMMA MMA MA MMA EA
. PMMA (93%)
.
l (Thermoplastics)
l (Liner Polymer) H
l (Amorphous)
H H C H
l (Light transmission)
l (Resistance to weathering) C C
l (High surface hardness)
H C O
l (Scratch resistance)
l O
l (Heat resistance) H C H
l (Rigidity)
H n
l (Chemical resistance)
l (100% Recyclable)
PMMA
MMA
MMA MA
MA EA
EA
Solution
Solution Make-up
Make-up Monomer
Monomer Make-up
Make-up
Polymerization
Polymerization H
H H C H
C C
Slurry
Slurry H C O
O
Drying
Drying H C H
H
n
Bead
Bead PMMA
PMMA
Extrusion
Extrusion
Pellet
Pellet
PMMA GRADE
PMMA
GRADE
GRADE
PMMA
PMMA IH830
IH830
IG840
IG840 ,, ,,
GRADE
GRADE
IF850
IF850
GRADE
GRADE IF870
IF870
EH910
EH910 ,,
GRADE
GRADE
EG920
EG920
HI835
HI835
GRADE
GRADE
HI855
HI855 ,,
GRADE
GRADE
BEAD
BEAD
BEAD
BEAD GRADE
GRADE
BEAD
BEAD
PMMA
CO-MONOMER CO-MONOMER CO-MONOMER
MOLECULAR WEIGHT MOLECULAR WEIGHT MOLECULAR WEIGHT
PMMA GRADE
GRADE
Grade
IH830
MFI
IG840
HDT
IF850
IF870
Grade
EH910 MFI
HDT
EG920
GRADE
VICAT
830 840 850 870 830 840 850 870 830 840 850 870
VICAT
910 920 910 920 910 920
GRADE
ROCKWELL
830 840 850 870 830 840 850 870 830 840 850 870
ROCKWELL
910 920 930 910 920 930 910 920 930
PMMA GRADE
GRADE
PMMA
CRACK PMMA
HI835H, HI835M, HI835S
HI855H, HI855M, HI855S, HI855HX
GRADE
ROCKWELL
HI835 M S H HI835 M S H HI835 M S H
ROCKWELL
HI855 M S H HX HI855 M S H HX HI855 M S H HX
GRADE
VICAT
HI835 M S H HI835 M S H M S H HX M S H
HI855 HI835
VICAT
HI855 M S H HX HI855 M S H HX M M S S H H HX
HI835 HI855
BEAD GRADE
, , ,
(ACRYL POWDER) .
BEAD GRADE
BEAD Grade
V.N
V.N
V.N
830B 840B 850B 870B 910B 920B 630B 490B 890B
Tg
Tg
Tg
830B 840B 850B 870B 910B 920B 490B 630B 890B
Bead
. MMA IH830B
EH910B .
( PVC Coating)
. PVC PMMA PMMA
. UPR ( FRP)
PMMA .
. , , SHEET COATING
Bead
VN (Viscosity Number)
- PMMA Chloroform .
- VN( ) .
VN 52 74 8 12 .
(Moisture Contents)
- : karl-Fischer
Tg (Glass Transition Temperature) :
- : DSC
- (Softening)
.
(Acidity value)
- PMMA KOH ( : mgKOH/g )
MFI (Melt Flow Index)
- Polymer PMMA 230 Melt
3.8Kg 10
- MI .
PMMA
PMMA : 93%
( 93% , 7% )
100
80
Transmission %
60
40
20
0
200 240 300 400 500 1000 1500 2000 2800
Wave length (nm)
(Ultra-Violet : UV) : 380 nm
(Visible) : 380 ~ 780nm,
(Infrared : IR) : 780 nm .
LG PMMA UV .
LG PMMA UV
100% at 280nm (UVA-280) IF850, IF870
100% at 360nm (UVA-360) IH830, IG840
100% at 390nm (UVA-390) Sunglass (IH830U)
PMMA Plastic
, .
( : Tail Lamp)
AMECA
•Test (3 ) : `89.4 ~ ‘92.4
•Test : Florida ( ), Arizona ( )
•Grade/ Color
- Grade : 4 (IH830 )
- Color : 19 (Clear 2, Amber 7, Red 10)
Haze(%) 30
25
PC
20
15
10
Acrylic Rubber
5 PMMA
0 500 1000 1500 2000
Time of Exposure(hr)
PMMA Plastic
Haze test 2000 PC 1500 Haze
PMMA Haze .
Y.I 6.0
PC
5.0
4.0
Acrylic Rubber
3.0
2.0
1.0 PMMA
0 500 1000 1500 2000
Time of Exposure(hr)
PMMA Yellow Index 2000
PC 450
.
/ /
/
, , , ,
, ,
1.19 ( 1/2)
, , , ,
- :
“ (Endocrine Disrupter) .
* : , ,
PMMA
: ASTM D570 (23 24 )
5% Polyvinylalcohol,
1~5% Celluros , Poly Vinyl ,
Poly Vinyl , Nylon
0.1~1% PVC, Styrene Copolymer, PMMA, PC, PET,
, Urea , , PA
0.1% PE, PP, , PS...
* 0.1 ~ 1%
PC,PET,PMMA ester
Polyacetal, Urea , ether
* PMMA ester ,
PMMA
(%) 0.8
30 ,80%RH
0.6
0.4
0.2 23 ,80%RH
0
40 80 120 160 200 240
( )
PMMA ( ):
(80% RH )
(%) 1.4
1.2
1.0
60
0.8
40
0.6
20
0.4
0.2
0
1 2 3 4 5 6 7
( )
PMMA ( ):
(20 )
(%) 1.4
1.2 92% RH
1.0
0.8
0.6 60% RH
0.4
40% RH
0.2
0
5 10 15 20 25 30 35
( )
/
• SILVER STREAK,
•
- , ,
-
• /
• /
•
• /
•
PMMA /SILVER
. 80%
. ,
0.08~0.05% , MODEL
/ 0.03~0.01% .
) GARNISH PANEL
.
/ AIR
PELLET
/ DEW POINT -40
AIR .
) PC
4 0.18 0.018%
0.18 0.006%
PMMA
.
PMMA
Grade ( ) (Hrs)
IH830, IH830S, IH830C 80 ~ 90
IH830HR, IH830G, EH910
IH830A , IH830P, IG840 70 ~ 80
EG920, EG930, 4~6
IF850 60 ~ 70
IF870 50 ~ 60
(ASTM D1003)
93%
89% 89% 90%
87% 87%
84%
PMMA PS SAN PC PVC ABS GLASS
• PMMA Plastic Glass
• PMMA 380 nm ~ 780 nm 93%
PC 480 nm ~ 680 nm 87% .
Coefficient of Linear
Expansion Rockwell Hardness
(ASTM D1003) (ASTM D785)
PMMA 7~8 PMMA 85 ~ 105
PS 6~8
PS 65~80
PC 7
PE 11 ~13 AS 80~90
Nylon6 8~13
PC 75~85
Glass 0.84
10 / M Scale
Heat Distortion Temp. Flexural Strength
(ASTM D648) (ASTM D790)
PMMA 74~105 PMMA 910~1330
PS 65~104
PS 560~980
AS 88~104
AS 980~1330
PC 130~141
PVC 60~77 PC 950
/
5
3 PMMA
PMMA
2 PC
PC
1 PVC
PVC
PS
PS
0 Rigidity SAN
SAN
Scatch
PMMA
LG PMMA
GRADE
UL (94HB) ALL GRADE
CSA (0.6HB) ALL GRADE
JHPC ALL GRADE (FDA )
AMECA IH830, IG840, EH910, EG930
UL : Underwriters Laboratories
CSA : Canada Standard Association
JHPC : Japan High Polymer Center
