Safety Data Sheet

Hempel's ZP Alkyd Primer

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2020/878 - Europe

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : Hempel's ZP Alkyd Primer
Product identity : 1209050410, 00008894
Product type : urethane alkyd primer

1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : -
Identified uses : Industrial applications.

1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : HEMPEL A/S Emergency telephone number (with hours of operation)
Lundtoftegårdsvej 91
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 - 17.00)
Denmark See section 4 First aid measures.
Tel.: + 45 45 93 38 00
[email protected]
Date of issue : 13 November 2023
Date of previous issue : 18 November 2022.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS
Skin Sens. 1, H317 SKIN SENSITIZATION
Carc. 1B, H350 CARCINOGENICITY
STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects)
STOT RE 1, H372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)
Aquatic Chronic 2, H411 AQUATIC HAZARD (LONG-TERM)
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H226 - Flammable liquid and vapor.
H317 - May cause an allergic skin reaction.
H336 - May cause drowsiness or dizziness.
H350 - May cause cancer.
H372 - Causes damage to organs through prolonged or repeated exposure.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements :
Prevention : Obtain special instructions before use. Wear protective gloves, protective clothing, eye protection, face
protection, or hearing protection. Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking. Avoid release to the environment. Do not breathe vapor, mist or spray.
Response : Collect spillage. IF exposed or concerned: Get medical advice or attention.
Hazardous ingredients : hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics (2-25%)
2-butanone oxime
cobalt bis(2-ethylhexanoate)
phthalic anhydride
cobalt(2+) propionate
Supplemental label elements : Repeated exposure may cause skin dryness or cracking. Restricted to professional users.
Special packaging requirements

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SECTION 2: Hazards identification

Containers to be fitted with child- Not applicable.
resistant fastenings :
Tactile warning of danger : Not applicable.

2.3 Other hazards

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
Other hazards which do not result None known.
in classification :

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type

hydrocarbons, C9-C12, n- REACH #: 01-2119458049-33 ≥10 - ≤25 Flam. Liq. 3, H226 - [1] [2]
alkanes, isoalkanes, cyclics, EC: 265-185-4 STOT SE 3, H336
aromatics (2-25%) CAS: 64742-82-1 STOT RE 1, H372
Index: 649-405-00-X (central nervous system
(CNS)) (inhalation)
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
EUH066
white spirit REACH #: 01-2119458049-33 ≥3 - ≤5 Flam. Liq. 3, H226 - [1] [2]
EC: 265-191-7 STOT SE 3, H336
CAS: 64742-88-7 STOT RE 1, H372
Index: 649-405-00-X (central nervous system
(CNS)) (inhalation)
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
trizinc bis(orthophosphate) REACH #: 01-2119485044-40 ≥1 - ≤3 Aquatic Acute 1, H400 M [Acute] = 1 [1]
EC: 231-944-3 Aquatic Chronic 1, H410 M [Chronic] = 1
CAS: 7779-90-0
Index: 030-011-00-6
xylene REACH #: 01-2119488216-32 ≥1 - ≤3 Flam. Liq. 3, H226 ATE [Dermal] = 1100 mg/kg [1] [2]
EC: 215-535-7 Acute Tox. 4, H312 ATE [Inhalation (gases)] =
5000 ppm
CAS: 1330-20-7 Acute Tox. 4, H332
Index: 601-022-00-9 Skin Irrit. 2, H315
2-butanone oxime REACH #: 01-2119539477-28 <1 Acute Tox. 3, H301 ATE [Oral] = 100 mg/kg [1]
EC: 202-496-6 Acute Tox. 4, H312 ATE [Dermal] = 1100 mg/kg
CAS: 96-29-7 Skin Irrit. 2, H315
Index: 616-014-00-0 Eye Dam. 1, H318
Skin Sens. 1, H317
Carc. 1B, H350
STOT SE 1, H370
(upper respiratory tract)
STOT SE 3, H336
STOT RE 2, H373
(blood system)
cobalt bis(2-ethylhexanoate) REACH #: 01-2119524678-29 <0.3 Eye Irrit. 2, H319 M [Acute] = 1 [1]
EC: 205-250-6 Skin Sens. 1A, H317
CAS: 136-52-7 Repr. 1B, H360F
Aquatic Acute 1, H400
Aquatic Chronic 3, H412
calcium bis(2-ethylhexanoate) EC: 205-249-0 <0.3 Repr. 1B, H360D - [1]
CAS: 136-51-6
Index: 607-230-00-6
phthalic anhydride REACH #: 01-2119457017-41 ≤0.3 Acute Tox. 4, H302 ATE [Oral] = 1530 mg/kg [1]
EC: 201-607-5 Skin Irrit. 2, H315
CAS: 85-44-9 Eye Dam. 1, H318
Index: 607-009-00-4 Resp. Sens. 1, H334
Skin Sens. 1, H317
STOT SE 3, H335
cobalt(2+) propionate REACH #: 01-2119532653-41 <0.1 Acute Tox. 4, H302 ATE [Oral] = 500 mg/kg [1]
EC: 216-333-1 Acute Tox. 4, H332 ATE [Inhalation (dusts and
mists)] = 1.5 mg/l
CAS: 1560-69-6 Eye Irrit. 2, H319 M [Acute] = 1
Skin Sens. 1A, H317
Repr. 1B, H360F
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
See Section 16 for the full text of the H statements declared
above.

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SECTION 3: Composition/information on ingredients

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention/advice.
Inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. Give nothing by mouth. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. If unconscious, place in recovery position and get medical attention
immediately.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Skin contact : Defatting to the skin. May cause skin dryness and irritation. May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
dryness
cracking
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments : No specific treatment.

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SECTION 5: Firefighting measures

5.1 Extinguishing media

Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.

5.2 Special hazards arising from the substance or mixture

Hazards from the substance or Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated,
mixture : a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides phosphorus oxides metal
oxide/oxides

5.3 Advice for firefighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid
breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or
without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.

6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if
released in large quantities.

6.3 Methods and materials for containment and cleaning up

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.

6.4 Reference to other sections

See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized
access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)

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SECTION 7: Handling and storage

See separate Product Data Sheet for recommendations or industrial sector specific solutions.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Product/ingredient name Exposure limit values

hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, EU OEL (Europe, 2000).

aromatics (2-25%) TWA: 25 ppm 8 hours.
TWA: 145 mg/m³ 8 hours.
white spirit EU OEL (Europe).
(ACGIH) TWA: 25 ppm 8 hours.
(ACGIH) TWA: 145 mg/m³ 8 hours.
xylene EU OEL (Europe, 1/2022). [xylene, mixed isomers pure] Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 221 mg/m³ 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 442 mg/m³ 15 minutes.

Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Derived effect levels
Product/ingredient name Type Exposure Value Population Effects
hydrocarbons, C9-C12, n-alkanes, isoalkanes, DNEL Long term Dermal 21 mg/kg bw/day Workers Systemic
cyclics, aromatics (2-25%)
DNEL Long term Inhalation 330 mg/m³ Workers Systemic
white spirit DNEL Long term Dermal 21 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 330 mg/m³ Workers Systemic
trizinc bis(orthophosphate) DNEL Long term Inhalation 5 mg/m³ Workers Systemic
DNEL Long term Dermal 83 mg/kg bw/day Workers Systemic
xylene DNEL Long term Inhalation 77 mg/m³ Workers Systemic
DNEL Long term Dermal 212 mg/kg bw/day Workers Systemic
2-butanone oxime DNEL Long term Inhalation 9 mg/m³ Workers Systemic
DNEL Long term Dermal 1.3 mg/kg bw/day Workers Systemic
phthalic anhydride DNEL Long term Dermal 14 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 49.4 mg/m³ Workers Systemic
cobalt(2+) propionate DNEL Long term Inhalation 21.9 µg/m³ General Local
population
DNEL Long term Oral 33.1 µg/kg bw/day General Systemic
population
DNEL Long term Inhalation 139.2 µg/m³ Workers Local

Predicted effect concentrations

Product/ingredient name Compartment Detail Value Method Detail
trizinc bis(orthophosphate) Fresh water 20.6 µg/l -
Marine water 6.1 µg/l -
Fresh water sediment 117.8 mg/kg dwt -
Marine water sediment 56.5 mg/kg dwt -
Soil 35.6 mg/kg dwt -
Sewage Treatment Plant 52 µg/l -
xylene Fresh water 0.327 mg/l -
Marine water 0.327 mg/l -
Fresh water sediment 12.46 mg/kg -
Marine water sediment 12.46 mg/kg -
Soil 2.31 mg/kg -
Sewage Treatment Plant 6.68 mg/l -
cobalt bis(2-ethylhexanoate) Sewage Treatment Plant 0.37 mg/l -
Fresh water 0.62 µg/l -
Marine water 2.36 µg/l -
Fresh water sediment 53.8 mg/kg dwt -
Marine water sediment 69.8 mg/kg dwt -
Soil 10.9 mg/kg dwt -

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SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.

Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: safety glasses with side-shields.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:

Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton®, nitrile rubber
Short term exposure: neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl chloride (PVC)

Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the hazards of the
product and the safe working limits of the selected respirator. If working areas have insufficient
ventilation: When the product is applied by means that will not generate an aerosol such as, brush or
roller wear half or totally covering mask equipped with gas filter of type A, when grinding use particle
filter of type P. Be sure to use an approved/certified respirator or equivalent.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state : Liquid.
Color : Brown.
Odor : Solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : Testing not relevant or not possible due to nature of the product.
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 38°C (100.4°F)
Evaporation rate : Testing not relevant or not possible due to nature of the product.
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Lower and upper explosive 0.6 - 7.6 vol %
(flammable) limits :
Vapor pressure : Testing not relevant or not possible due to nature of the product.
Vapor density : Testing not relevant or not possible due to nature of the product.
Specific gravity : 1.28 g/cm³
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Lowest known value: >220°C (>428°F) (white spirit).
Decomposition temperature : Testing not relevant or not possible due to nature of the product.

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SECTION 9: Physical and chemical properties

Viscosity : Aspiration hazard (H304) Not classified. Testing not relevant due to nature of the product.
Explosive properties : Explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.

9.2 Other information

Solvent(s) % by weight : Weighted average: 32 %
Water % by weight : Weighted average: 0 %
VOC content : 407.4 g/l
TOC Content : Weighted average: 362 g/l
Solvent Gas : Weighted average: 0.081 m³/l

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability

The product is stable.

10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.

10.5 Incompatible materials

Highly reactive or incompatible with the following materials: oxidizing materials.
Reactive or incompatible with the following materials: reducing materials, organic materials, acids, alkalis and moisture.

10.6 Hazardous decomposition products

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides phosphorus oxides metal oxide/oxides

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
trizinc bis(orthophosphate) LD50 Oral Rat >5000 mg/kg -
xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LC50 Inhalation Vapor Rat 6350 ppm 4 hours
LD50 Dermal Rabbit >4200 mg/kg -
LD50 Oral Rat 3523 mg/kg -
2-butanone oxime LD50 Dermal Rabbit 1001 mg/kg -
LD50 Oral Rat 930 mg/kg -
cobalt bis(2-ethylhexanoate) LD50 Dermal Rabbit >2000 mg/kg -
LD50 Oral Rat 3129 mg/kg -
phthalic anhydride LD50 Dermal Rabbit >3160 mg/kg -
LD50 Oral Rat 1530 mg/kg -
Acute toxicity estimates

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SECTION 11: Toxicological information

Product/ingredient name Oral Dermal Inhalation Inhalation Inhalation

mg/kg mg/kg (gases) (vapors) (dusts and
ppm mg/l mists)
mg/l
Hempel's ZP Alkyd Primer 34345 48003.6 218198.1
xylene 3523 1100 5000
2-butanone oxime 100 1100
cobalt bis(2-ethylhexanoate) 3129
phthalic anhydride 1530
cobalt(2+) propionate 500 1.5
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
xylene Eyes - Severe irritant Rabbit - 24 hours 5 milligrams
Skin - Irritant Rabbit - -
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
2-butanone oxime Eyes - Severe irritant Rabbit - 100 microliters
phthalic anhydride Eyes - Moderate irritant Rabbit - 24 hours 50 milligrams
Sensitizer
Product/ingredient name Route of exposure Species Result
cobalt bis(2-ethylhexanoate) skin Mouse Sensitizing
phthalic anhydride skin Guinea pig Sensitizing
skin Mouse Sensitizing
Mutagenic effects
No known significant effects or critical hazards.

Carcinogenicity
May cause cancer. Risk of cancer depends on duration and level of exposure.

Reproductive toxicity
No known significant effects or critical hazards.

Teratogenic effects
No known significant effects or critical hazards.

Specific target organ toxicity (single exposure)

Product/ingredient name Category Route of exposure Target organs
hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, Category 3 Narcotic effects
aromatics (2-25%)
white spirit Category 3 Narcotic effects
2-butanone oxime Category 1 upper respiratory tract
Category 3 Narcotic effects
phthalic anhydride Category 3 Respiratory tract irritation
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of exposure Target organs
hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, Category 1 inhalation central nervous system (CNS)
aromatics (2-25%)
white spirit Category 1 inhalation central nervous system (CNS)
2-butanone oxime Category 2 - blood system
Aspiration hazard
Product/ingredient name Result
hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, ASPIRATION HAZARD - Category 1
aromatics (2-25%)
white spirit ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
No known significant effects or critical hazards.

Sensitization : Contains 2-butanone oxime, cobalt bis(2-ethylhexanoate), phthalic anhydride. May produce an allergic
reaction.

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SECTION 11: Toxicological information

11.2 Information on other hazards
Endocrine disrupting properties : See Section 15 for details.
Other information : No additional known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Do not allow to enter drains or watercourses. Toxic to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
hydrocarbons, C9-C12, n-alkanes, Chronic EC50 4.6 - 10 mg/l Algae 72 hours
isoalkanes, cyclics, aromatics
(2-25%)
Chronic EC50 10 - 20 mg/l Daphnia 48 hours
Chronic EC50 10 - 30 mg/l Fish 96 hours
white spirit Acute EC50 4.6 - 10 mg/l Algae 72 hours
Acute EC50 10 - 20 mg/l Daphnia 48 hours
Acute EC50 10 - 30 mg/l Fish 96 hours
trizinc bis(orthophosphate) Acute EC50 0.8 mg/l Algae 72 hours
Acute EC50 2.44 mg/l Daphnia 48 hours
cobalt bis(2-ethylhexanoate) Acute LC50 0.1 - 1 mg/l Fish 96 hours
phthalic anhydride Acute EC50 >640 mg/l Fresh water Daphnia 48 hours

12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
hydrocarbons, C9-C12, n-alkanes, OECD 301F Ready 74.7 % - Readily - 28 days - -
isoalkanes, cyclics, aromatics Biodegradability - Manometric
(2-25%) Respirometry Test
white spirit 301F Ready Biodegradability - 7 - 74 % - Readily - 28 days - -
Manometric Respirometry Test
xylene OECD 301F Ready 90 - 98 % - Readily - 28 days - -
Biodegradability - Manometric
Respirometry Test
- >60 % - Readily - 28 days - -
phthalic anhydride - 85.2 % - Readily - 28 days - -

Product/ingredient name Aquatic half-life Photolysis Biodegradability

hydrocarbons, C9-C12, n-alkanes, - - Readily
isoalkanes, cyclics, aromatics
(2-25%)
white spirit - - Readily
xylene - - Readily
phthalic anhydride - - Readily

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
hydrocarbons, C9-C12, n-alkanes, isoalkanes, cyclics, aromatics - 10 - 2500 high
(2-25%)
white spirit 3 - 7.3 - high
trizinc bis(orthophosphate) - 60960 high
xylene 3.12 8.1 - 25.9 low
2-butanone oxime 0.63 2.5 - 5.8 low
cobalt bis(2-ethylhexanoate) - 15600 high
calcium bis(2-ethylhexanoate) - 2.96 low
phthalic anhydride 1.6 3.4 low
cobalt(2+) propionate - 15600 high

12.4 Mobility in soil

Soil/water partition coefficient No known data avaliable in our database.
(KOC) :
Mobility : No known data avaliable in our database.

12.5 Results of PBT and vPvB assessment

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Safety Data Sheet
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SECTION 12: Ecological information

Product/ingredient name PBT P B T vPvB vP vB

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Endocrine disrupting properties

See Section 15 for details.
12.7 Other adverse effects
No known significant effects or critical hazards.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose
of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof
container.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11*
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.

SECTION 14: Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN / ID no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

ADR/RID UN1263 PAINT 3 III Yes. The environmentally

Class hazardous substance mark
is not required when
transported in sizes of ≤5 L
or ≤5 kg.
Tunnel code (D/E)

IMDG UN1263 PAINT. (hydrocarbons, C9-C12, n- 3 III Yes. The marine pollutant
Class alkanes, isoalkanes, cyclics, mark is not required
aromatics (2-25%)) when transported in
sizes of ≤5 L or ≤5 kg.
Emergency schedules
F-E, S-E

IATA UN1263 PAINT 3 III Yes. The environmentally

Class hazardous substance mark
may appear if required by
other transportation
regulations.
PG* : Packing group
Env.* : Environmental hazards

14.6 Special precautions for user

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Maritime transport in bulk according to IMO instruments
Not applicable.

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Safety Data Sheet
Hempel's ZP Alkyd Primer

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Restricted to professional users.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
E2: Hazardous to the aquatic environment - Chronic 2

15.2 Chemical Safety Assessment

-

SECTION 16: Other information

Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
EUH statement = CLP-specific Hazard statement
RRN = REACH Registration Number
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
Full text of abbreviated H statements : H226 Flammable liquid and vapor.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H350 May cause cancer.
H360D May damage the unborn child.
H360F May damage fertility.
H370 Causes damage to organs.
H372 Causes damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH066 Repeated exposure may cause skin dryness or cracking.
Full text of classifications [CLP/GHS] : Acute Tox. 3 ACUTE TOXICITY - Category 3
Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Acute 1 AQUATIC HAZARD (ACUTE) - Category 1
Aquatic Chronic 1 AQUATIC HAZARD (LONG-TERM) - Category 1
Aquatic Chronic 2 AQUATIC HAZARD (LONG-TERM) - Category 2
Aquatic Chronic 3 AQUATIC HAZARD (LONG-TERM) - Category 3
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Carc. 1B CARCINOGENICITY - Category 1B
Eye Dam. 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Eye Irrit. 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Repr. 1B TOXIC TO REPRODUCTION - Category 1B
Resp. Sens. 1 RESPIRATORY SENSITIZATION - Category 1
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1 SKIN SENSITIZATION - Category 1
Skin Sens. 1A SKIN SENSITIZATION - Category 1A
STOT RE 1 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

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SECTION 16: Other information

STOT SE 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 1
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 3
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification
FLAMMABLE LIQUIDS On basis of test data
SKIN SENSITIZATION Calculation method
CARCINOGENICITY Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) Calculation method
AQUATIC HAZARD (LONG-TERM) Calculation method

Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

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Safe Use of Mixture Information
Hempel's ZP Alkyd Primer

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor or outdoor painting by professionals with brush, roller, putty knife, dipping etc. with good general room ventilation plus respiratory
protection.
This safe use information is : Professional low-energy painting, near-industrial setting
linked to Priority
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor or outdoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions
Others : Depending on actual conditions of application. Please consult your local HEMPEL representative
for further advise.

Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
application hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Loading of application PROC08b More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
equipment and handling hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
of coated parts before an assigned protection in combination with 'basic'
curing factor of at least 10. employee training.

Industrial application of PROC10 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
coatings by other than hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
spraying an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Film formation - force PROC04 More than 4 Good general room 3-5 None Use eye protection Wear chemical-resistant
drying, stoving and other hours ventilation - Outdoors according to EN 166. gloves (tested to EN374)
technologies in combination with 'basic'
employee training.

Cleaning PROC05 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Waste management PROC08b More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
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