Anderson Terry M
Anderson Terry M
Presented to
by
Terry M. Anderson
for the degree of
Master of Arts
August 1974
Duluth, l:linnesota
" TOPOG Rl\PHIC_ II II
Earth , air, and fir e ge nerat e the creation of the bronze through
the t echnic ; just as the earth, and its own evolution through a
glimpse of the magnet ude, sound nes s , and s ensuous r eality of the
earth.
- CONTENTS -
Development of Casting . . 1
The Materials 10
Bronze . . 10
Wax . . 11
Plaster . . 12
Investment 31
Types of Investment 31
Investing the Wax . 33
Burnout 42
Patination . . . . . . . . . . . . . . . . . . . . . . . 57
Patina Application 58
21 Patina Formula. 6()
Summary 63
Foot notes . 64
Bibliography . . . . . . . . . . . . . . . . . • . . . . . . . . . . 65
THE DEVELOPMENT OF BRONZE CASTING
The technic employe d in casting bronze has little changed since Biblical
t imes, wh en Aaron cast his golden calf. Albeit the story of Aaron could be
my th, sufficient evidence remains to prove that bronze was cast in very
early historical times. Bronze bells and other castings have been f o und
·1
in China , their marks indicating t ha t they were cast circa 2000 B.C. Earlier
2
castings have been found in India, these dating from 5000 B.C. Seemingly
Before the casting technic was developed, bronze was hammered into
thin sheets, then beaten to conform to wooden or bituminous molds. The metal
fine results, had its drawbacks. The form had to be annealed and hanunered
many times, and total freedom of form was limited. The casting of metal
made possible larger, more substantial forms which could now be as fluid
in concept and design as the wax model would permit. The ori ginator of
the lost wax process remains anonymous. Most likely, early bronze forms
Most of the fine bronze articles of the past are lost. Invaders could
destroy the forms by bui lding a fire inside or out. Many other valuable
pieces we re lo a ded on camel or ship, destined for one of the great Med-
iterranean cit ies . Eventually, the prized bronzes reached the sovereign
city- Rome . This historical anal ysis well accounts for the prominent role. of
the Bronze Age, man through all of his civilizations has produced bronze
articles. Because so many bronzes have been preserved, today 's museums
various craft guilds. Until recent times, sculptors knew nothing of the
technic. Before the knowledge of bronze casting was disseminated, the artist
would take his model to a foundry where it would be cast for him. The
feelings for technic himself. The once guarded secrets of casting are now
is made of wax or a similar material that will burn out and leave little
residue. (Fig. 1) Here a head study has been made in wax; the thickness of
(Fig. 2) The sprue system is attached to the wax pattern. Sprues and vents
in the shape of wax rods are attached to designated points on the wax form
and arranged in a manner to distribute the molten bronze rapidly and uniformly
to all parts of the mold with a minimum of turbulence. These wax rods range
-4-
in size and form from 1/4" to l" in diameter, varying according to the
the weight and shrinkage of bronze, most castings are made hollow - the
wax form or pattern is also hollow. The thickness of the wax and con-
(Fig. 3) The wax pattern with the sprue system attached is now enclosed in
the investment must also be on the inside of the wax pattern. This core must
to the outside of the mold at two critical periods - after the wax support
-5-
has been melted away and while the molten bronze is exerting heavy pressure
in filling the space between the inner core and the exterior mold. The
wax and linking the mold and core once the wax is melted away.
(See Fig. 2)
surround the mold with a minimum of wasted space. The mold is then fired to
a temperature of around 1000 degrees F., or until the wa x and moisture are
completely driven out. Firing time may . range from one to two days, depending
(Fig. 5) After being allowed to cool in the kiln, the mold is care-
and cohesive, the sand is tightly rammed into the space between the molds
and the container walls. The packed sand assists the mold when it is being
filled with molten bronze by helping resist the pressure and weight exerted
from the inflow of the metal being poured. After proper cooling the
casting is removed from the sand and investment mold and cleaned. Sprues,
core pins and core are removed; any holes are repaired and the surface is
Patinas can give a variety of color effects. The bronze surface is treated
to produce the various copper and iron compounds. Patinas are not applied
Keeping in mind the overview of the bronze casting process, one can
Many arguments against the lost-wax casting process have been raised -
tedious, etc. In most peoples minds, these are the drawbacks to the lost-
wax process. But, perhaps they are "overlooking" the method and missing
Perhaps in the idea of "transition" lies the worth of the lost-wax process
the transition of ideas through material changes. For example, one can
take form very easily. From the clay image a plaster mold is made. This
process need not be tedious, but rather a whole dimension of positive and
negative imagery may arise. The original clay image of the modeled form can
original form can be contrasted or joined (as male and female) by using only
disjoined parts of the mold. A rhy~hm of vibrant forms and. images can
process of the mold is the essence of birth, of fetus and of womb and
mold. This wax will become the e xact form of the ori ginal clay . In other
instances, the wax can be treated directly. It can be flashed with a flame,
process) leaving an empty cavity. The original image gone, only the fragile
shell remains after firing. The cavity is only made whole again when the
There is a certain character to the process of lost wax. One can exper-
ience a richness in the qualities of plastic clay and moldable wax, the
negative mold, the fire of casting and the array of colors and textures
Hopefully, those who proceed to cast will enjoy the process equally with
the outcome, for in the process lie inherent ideas, new directions, and
Bronz e
There are numerous metals that can be c a st. Traditiona lly and
copper and tin. Small proportions of other metals are sometimes added for
of the ancient bronze alloys consisted of 88 parts co pper, 10 parts tin and
4
2 parts zinc. The addition of tin and zinc give the copper a greater
similar in make-up.
Aluminum can be alloyed with copper. Lead can be added to lower the
melting temperature. Silv er can be added to change the colo r~ Each of the
many a lloy s of bronze is distinct. The melting temperature may vary greatly.
Some need fluxes when melted and most c annot be mixed one with the other.
It is very important that the composition of the alloy and its properties
b e understood before casting. Bronze should not be contaminated with any ether
metal, nor any other alloy of bronze, unless compatibility has been established.
be clean. In most cases, it is best to purchase new ingots, which cost little
arise in the casting one can eliminate the meta l a s the source of the problem.
One alloy th a t should be stress ed for found a ry use is silicon bron ze.
It is very fluid when melt e d and will readily cast into thin, comp lex s e ctions.
This me tal do e s not form a heavy slag , nor does it n eed a flu x when melte d.
One thing that af f ects t h e castability of bronzes is the pre s ence of ox ide s.
-11-
Tin (found in most alloys) readily forms tin oxide when melted. This oxide
forms quickly and will impede the fluidity of the metal. Silicon forms no
stable oxide when melted and silicon bronze is a relatively clean metal
when poured.
5 The composition of silicon bronze is essentially copper and
4% silicon. There may be small amounts of zinc ormaganese and other trace
elements.
Wax
suitably finished wax pattern. There are two means of getting a wax pattern.
refractory material to within what will be the end thickness of the bronze.
Wax is spread over the core to achieve this final thickness. Final
modeling is done on the wax. My emphasis will be given to the indirect method,
since many sculptures are not first conceived in wax, but rather in clay,
Two t ypes of wax are derived from petroleum ·- Paraffin and microcrystalline.
Microcry stalline is best suited for studio use. Paraffin is brittle and cracks
when bent. Microcrystalline waxes bend easily and are not brittle.
Much care should be exercised when working with any kind of wax. If wax
-12-
a much lower temperature, it g ives allowance for a good saf ety margin.
Plaster
years. Casts from faces and other parts .of the body have been found in
6
Egypt and date from 2400 B.C. From the Egyp tians through .the Greeks and to
the present day, pl as ter ranks as one of the most versatile materials of
the sculptor. One should try to understand some of its physical and chemical
two equations, one c an see that plas ter is dehydrated gypsum. The sculptor
over the surface of the water. Never drop in whole handfuls, as the result
will be a lumpy, hard to blend mixture. Keep adding until the water is completel~
saturated with plaster . Let stand untiL bubbling and saturation are complete.
Prope rly mixed, plaster will set u p in 20 minutes. Mixing should be done
from the bottom as this will ke ep air bubbles from being trapped in the mix.
quickly. If the plaster i s mix ed dur ing its setting phase, it will not
plaster to water caus es the pl as ter to set quickly. Minimal, gen tle mixin&
cold wa ter and the use o f less plaster wi ll ret ard the setting time.
-13-
Molds are made for several reasons - to transfer the form into wax,
process. This development only hinders the sculptor, limiting his freedom
simplest and most apparent divisions. This will indicate how to make
the mold easy to remove and re-assemble to pour the wax pattern.
/ '
Plate 1
-1 4-
The figure (1) is made of solid wax, about 7 inches high. A mold is
clay wall surrounds the fi gure where th e re are no undercuts. This assures
that f irs t piece of the plaster mo ld will release easily. The clay sh im is
Plat e 2
se t.
-15-
Plate 3
Plate 4
I
-16-
(4) The same tool smooths the surface as the plaster reaches a "frosting-
like" consistency.
(5) The first piece has hardened in about 20 minutes. The cl ay h as been
removed and the next piece will be made. Notice the undercut in b etween
the two arms . It prevents the whole back from being made in one piece.
Plate 5
(6) A piece has been made in this portion of the back. Two keys have been
carved to prevent _ the piece from shifting when it is connected to the back
A non detergent soap solution works well - Fels Naptha or Ivory Snow.
Green soap or clay slip works well also. The separator is brushed over the
plaster. After it soaks in for a few seconds, any excess is brushed away to
prevent its goin g into solution with the plaster where it is applied .
-17-
Plate 6
(7 & 8) After the b vo pieces have been soaped, the third piece is applied
over the back. The whole process continues until the mold is complete.
- 18-
Plate 7
Plate 8
-19-
T
Plate 9
(9) \fnen the plaster is set, the pieces can be removed. There will be some
resistance. Pouring hot water into the seams softens and relieves the resis-
tance of the wax. Clean the pieces out with a soft brush. Any concave errors
in the mold can be filled with soft clay. For wax pouring, a ~" hole is
carved in one of the top mold pieces. The hole can later be repaired with
the pan before putting it directly over the burner. This will relieve
the tension of the expanding, melting wax at the bottom of the pan and allow
its coming to the surface instead of exploding. Rapid melting and high
heat are not necessary. Wax does not conduct heat well. If the melted
wax starts to make a boiling sound, water is pr esent in the wax. This can
be very dangerous since it causes the wax to bubble and spatter. The noise
also indicates a temperature which is, in most c ases, too hot. Another indicato
There are 3 methods for making a wax pattern, pouring, painting and
a combination of both. In all cases the plaster mold must be wet or the
hot wax will stick to the plaster surface. After the mold has soaked in
water, remove it and sponge off any excess surface water. Bind the mold
pieces together with clamps, rubber bands or rope. If the seams between the
mold pieces are not snug , clay can be pushed into the seam. Pour the mold
full of hot wax, then immediately pour the wax back out. A wax layer of
1/16" will have built up on the surface. If the wax from this first
pour had been left in the mold too long it would have hea ted up cert a in thin
or delicate areas of th e plas ter mold. The deposition of wax in these areas
would then become t hinner and thinner. The wax temperature in this fi r s t
pour is fairly hot, so as not to make chill or ripple marks on the mold
surface from rapid cooling. Now l et the pan of hot wax cool of f, so
-21-
that when it is poured in the mold,it does not remelt the first wax coat.
Pour this cooler wax back into the mold. Slowly rotate the mold as the
wax is poured back out to ge t a uniform wax coating on the mold. When
pouring the wax back out make sure it does not gurgle, as this slight
vac uum may cause the warm wax inside the mold to collapse on distort.
facilitate filling and emptying the mold of wax. The process is repeated
the wax will be the thickness of the bronze. The mold is then placed
in cold water to cool, the pieces are carefully pulled off the wax pattern.
Good results can also be achieved by brushing the wax into the mold.
The best brush to use is a natural bristle brush. A nylon brush would melt.
b efore it fre eze s. Never keep brushing after the wax starts to t hic::en.
Start slapping the brus hfuls of hot wax on the mold from the bottom up.
This helps avoid lapping lines. If the brush can not be gotten into the
mold, the individual pieces of the mold can be separately painted with a
thin l aye r of wax. The edges are then trimmed of the pieces put together, and
When. the mold is taken off the wax can be given its final repairs
or retouchings. Johnson's paste wax works well for filling bubbles, pits
or undesirable cavities on the surf a ce of the wax. The wax pattern is now
re a dy fo r sprueing.
-22-
The sprue system is to the wax pattern as the veins and arteries are to
the human body. This system provides the channels for the wax to run out of
the mold and for the introduction of the molten metal during casting.
bronze. To better underst and the casting process, one should become, dcquainted
- t'\~'/\ Si>Y'u..e
- .Oh V'\ V\ \<e..'r ba..ll
~- .rhl-'e5lMe)r\\
V°' u...V\\f\ er
c...o y..e, pl V)
Fig . 6
-24-
The pouring cup should be of adequate width and depth to minimize the
danger of hot metal spilling, as well as to reduce the loss of needed metal
to fill the mold. Its size should be a minimum of 3 inches wide and 2
inches deep. The cup can be carved from or molded into the soft investment
material.
As the metal is poured into the mold, the .air-vents allow the gases and
air to escape from within the mold cavity. The vents must always be attached
to all of the highest isolated portions of the wax system, so that no air
is trapped in the cavities as the metal is poured. Air vents should come
out of the mold at least two or more inches away from the pouring cup, lest
any spills from the pouring cup plug the air vents.
Because the air vent directly connects to the head, the dirt trap
The metal flows down through the sprue, reaches the bottom of the system
and starts to flow upward throught the runners and into the head. The sprue
should have at least twice the volume of the runners it feeds. For attach-
ment, the sprue should be positioned at least an inch away from the sculptural
from but not so far away as to make the mold excessively large - this would
The shrinker ball is sometimes used at the top of a wax form to act
hot metal back into the head as shrinkage occurs. Notice that a runner coming
from the sprue· connects to the ball. This positioning ensures that -t:ha-t the
The gate is the point of attachment between the runner and the head.
runner itself, thereby forcing or spraying the metal into the cavity or
form. This minimizes any chance of shrinkage from the head back into the
runner. The small diameter of the gate makes the runner easier to remove after
casting. The gate's small diameter also ensures that the sprue system is
kept full of molten metal, which reduces the chances of air getting into
the head.
The runners or risers connect from the sprue to the head and feed the
metal into the form as the sprue fills from the bottom. Each runner is always
slanted upwards from the sprue. This ensures that the metal does not spill
from the sprue into the form as it flows down to the bottom of the wax
runners as it rises up the mold, pushing all of the air out in front of it.
The core pins secure the outer investment to the inner investment, or core.
The heavy core inside the head may need 8 to 10 eight penny nails to keep
it in place when the wax is burned out. Pins are sometimes used in very
small light cores. One sh ou ld make sure that when a core pin is positioned,
After it is melted in the firing, the wax runs out through the drain in
the mold. Once the wax is gone, it furnishes a cavity, so the hot kiln air
sprue system:
*If possible, the wax used to make the sprue system should melt at
lessens the danger of cracking the mold from the expanding wax during the
burnout cycle. This procedure also facilitates rapid drainage of the wax
from the mold with less absorption of the wax into the investment mold.
*The diameter of the wax sprues should be greater than the thickness of
*The length of the sprues and runners should be kept as short as possible,
length being relative to diameter. The longer they are, the larger their
*There is no set formula for spruing. The number of sprues and their
points of attachment to the form depend entirely on the shape and size of the
form. Each separate heavy section of the form requires its own sprue,
best set-up for drainage, escape of gas and air through the vents, the place-
ment of core pins and the even flow and solidification of the metal.
otherwise pieces of investment material may fall into the molten metal as it
passes.
round. This prevents metal, when it is poured, from swirling and sucking in
air.
-27-
of th e runners and core pins to facilitate metal flow and make the runners
(10) The triangular sprue can be cast in a one piece plaster mold. When
pouring the wax into the plaster mold mak~ sure .that the wax is not too hot -
wax will often burn and stick to the mold if poured under improper conditions
The smaller round runners and vents can be extruded from a caulking gun
Plate 10
-28-
the head. The metal is f e d indirectly into the mold cavity from the bottom
o f th e sprue and up throu gh the runners. The core pins or nails, have
already been pushed throug h th e 1/8 inch thickness of wax. A ~ inch hole
was made through the wax form so that the investment could be poured into
th e core. The hole was then covered · over with wax to restore the original
forra.
Plate 11
This method of pref illing the core works well if the core is small and
it is necessary to fill th e interior core and out side inve s tme nt at the s ame
cutting holes, one at th e bott om and one at the top of th e wax form to
-29-
release the air. The core can then be filled at the same time as th e outside
when the investment is poured over the wax system. The holes in the cast form
Plate 12
(12) This represents a simplified, indirect spruing method. One sees only
two runners and they are at the bottom. The metal must run completely
through the sprue and up the entire form before it solidifies. As long as the
form is small and the metal is poured at a high temperature, this method
works very well. Additional runners, although they are not always needed,
ensure that the form will fill completely before solidific~tionof the metal.
It has been said, that if in doubt about the distance the metal will flow,
sprue it.
-30-
Plate 13
(13) Shown here is the direct method of casting. The metal is poured
directly into the form and only one vent and drain have been added. This system
when cast, filled perfectly· After cleaning the metal, however, it could
be seen that small particles of investment had broken off into the molten
flow causing pits and .blemishes on the bronze surface. This occurred because
of the extreme agitation of the metal when it entered the mold and the air
tried to flow out. It is likely when using this method that areas of
investment wash out or break away b ecause the metal must always flow over the
INVESTMENT
Types of Investment
silica flour are added to the plaster to withstand the thermal shock. There
are many mixtures that work well. The most widely used is 1 part plaster, 1
1 plaster - 1 silica flour - 1 silica sand: This mixture works very well and
1 plaster - 2 silica flour: This mixture proved to be too chalky and soft.
1 plaster - 1 silica flour - 1 grog (ground up fire brick): The grog proved
to be superior to silica sand because its particles were angular and sharp
and gave the mixture a better cohesive strength. Silica sand particles are
is a very strong gypsum cement. I had hoped that it would furnish more
strength than just plaster but after firing it proved to be much weaker than
plaster alone.
1 plaster - 2 silica sand: This mixture was somewhat brittle and cracked, if
handled carefully it could work well. Clean washed sand from the gravel
\
-32-
Fibrous mat e rials can also be added to the mixture to add strength.
basic mixture.
fired investment material that has been crushed up and sifted. As Luto
already contains the basic mixture minus the binding power of plaster, it
can be substituted in part for sand and flour. The normal setting time of
When working with any investment material, always wear a dust mask.
first. The plaster is slowly added, followed by the silica flour and then
the sand. Let the mixture stand to soak for a minute and then mix slowly
the sand will settle to the bottom. If it is too thick, it will not pour
Plate 14
thin mixture of 1 part liquid soap and 3 parts alcohol . .The alcohol will
cause the mixture to dry quickly and the soap will lessen the chances of
air bubbles adhering to the wax surface when the investment is poured.
(15) The wax system is mounted on a clean surface. The two wax systems on
the left are supported by a small mound of investment which has been
thickened with luto. The two on the right were able to support themselves
by their sprue systems, which were stuck to the table top with hot wax.
-34-
Plate 15
(16) A wire mesh or chicken wire is placed around the supported wax form. This
Plate 16
- 35-
Plate 17
(17) A strip of linoleum or tin is placed around the wire to contain the
liquid investment.
(18) Wire is wrapped around t he linole um and clay is pressed around the bottom
to keep the investment securely contained. The investment can now be mixed
and poured. Try to pour the investment down the edge of the container
in such a manner so as not to mix air bubbles into it, or break down the
wax system.
- 36-
Plate 18
Plate 19
-37-
(19) Another method of investing was used on this irregularly shaped relief.
(20) A luto wall was built up around the entire piece, almost to the top. It
By being able to use luto and produce an investment mold that exactly
follows the contour of the wax system, this method wastes very little material.
To make the wall, a basic batch of investment is made. Luto is added until
the mixture is thick enough to be manipulated into a wall. The small sticky
luto locks are laid one upon the other until the wall is made. As this mixture
round it.
Plate 20
-----------::~)
·-3 8-
_ _ _ _ _J
Plate 21
(21) The whole surface is covered with more of the same_ investment until
all of the holes are filled and the chicken wire is securely covered.
(22) Enough basic investment is mixed to fill the mold cavity and "cap
off ·" the top of the mold. This mixture does not contain the luto, which
(23) A pouring cup is carved into the investment. the drain and vents are
scraped clean.
-39-
Pla te 22
Plate 23
-40-
(24) The molds are loaded into the kiln for wax burn out and curing. If
th e mold has been allowed to dry for several days, it should be wet down
with water. This assures that as the -.kiln temperature rises, th e wax will
run out of the drain r ather than be abso rbed into the investment. In most
cases th e molds are supported on bricks. Angle irons are run under the
Plate 24
This is done so that all of the wax does not burn up inside the kiln,
Plate 25
(25) The fire bricks are placed tightly together around the mold to form
a kiln, the lid of the kiln secured. Any loose investment or dirt around the
pouring coup is vacuumed away. This same cleaning should also be done after
THE BURNOUT
can be held until total wax burnout occurs. The investment itself is dry at
500 degrees. The higher temperature is needed to burn off all of the wax
residue.
The length of the firi~g cycle depends greatly upon the thickness of
the molds. Generally, burnout takes between 24 and 48 hours. Burnout need
visible burning or dark soot around the pouring cup, the temperature should
be held until the burning stops and the dark soot changes to a white ash .
The kiln is turned off and allowed to cool slowly to about 300 degrees t F.
Later it is di.smantled. The molds are ready to be buried in the sand pit
for casting.
-43-
The sand in the casting pit aids in supporting the fragile investment
molds during pouring. Plain sand will not be firm enougt to furnish the support.
The sand is mixed with small amounts of fine clay and ball clay. Some
always ready for casting, the sand should be covered and kept moist. Too
much moisture in the sand could cause the water to soak into the mold and
come in contact with the molten metal. Too little moisture will keep the
sand from packing properly. The right amount of moisture should just hold
the sand together when squeezed in one's fist. A hole dug in the sand pit
a~comodates the largest mold. The smaller molds are added, the sand being
built up until the tops of all of the molds are at the same level. The
sand is not packed all at once, but in layers of one or two inches at a time.
When packing, areas around the bottom of the mold deserve special
attention. They are likely places for the metal to exert pressure and burst
through the mold. The sand can be packed by foot, or with small lengths; of
wood or pipes to make it firm. When packing, one should not hit or pat
(26) The sand has been packed to the top of the molds. During the entire
process the pouring cup and air vents should be covered with a paper and a
brick to prevent spillage of sand into the mold's cavities. · Before casting,
·.,
Plate 26
-45-
ceramic bounded and the silicon carbide bonded type. Both use the refractory
materials graphite and silicon for heat conduction and for structural strength.
Due to its greater heat conductivity and its greater strength, the silicon
used for melting bronze. However, different metals should not be melted in
the same crucible. This practice will cause contamination in the melt and
use, inspect each crucible for cracks and damage. New crucibles should be
properly annealed before use. Annealing relieves all strains set up during
shock are also developed. To anneal the crucible, make sure it is dry and
then place it in the furnace. Adjust the burners to idle, or the lowest
heat for the first 10 minutes. Increase the burner setting gradually
to raise the furnace to a red heat. The total heating period should be
about 45 minutes. After this the crucible can be put into use.
The crucible is cha r ge d with metal before the furnace is started. Sprues
or clean scrap are charged first, while ingots or bars are charged last. Never
wedge metal tightly into the crucible, as the crucible may crack as the
bronze expands in heating. Any metal added to a molten mass should be dry,
thoroughly dry, and added gently to the molten charge with tongs.
- 46-
the exhaust port in the lid of the furnace, or on the lid. The metal may
melt or pieces may fall in, a l lowing molten metal to run down inside the
furnace lid and walls. The metal is oxidized very rapidly and attacks
and deteriorates the refractory furnace lining. Ingots and scrap can be
placed around the lid ;for preheating well away from the exhaust port.
The crucible rest supports the crucible on the floor of the furnace. It
is usually of the same material as the crucible. The rest positions the
from contacting the cooler furnace floor. The diameter of the rest should
to separate the crucible from the rest. A separating material. such as z. sheet
of corrugated card board can be placed between the two before the furnace is
started . After it burns, the remaining carbon will make separation easier.
The crucible of bronze is lifted out of the furnace and held for pouring .
Crucible tongs and shanks are tools necessary for handling the crucible
during melting and pouring. The tongs are used to place the crucible in
the furnace and to withdraw the crucible of molten metal at the close
of the melting period. After the crucible has been with drawn from the
the metal into the molds. Both tools should fit the specific size of the
crucible being used. This prevents damage to the crucible. Hazards related
to melting and pouring bronze are minimized by proper use and understanding
of th e crucible tools.
-47-
Preheat the melt on low for about 10 minut e s. After this warm up
stage, the burner can be adjusted to maximum until the atmosphere is slightly
reducing, with stringers of flame in the exhaust. Then the fuel should be
closed to a setting where traces of flame just disapp e ar. The burner should
best furnace performace, the air valve should be adjusted to the full open
oil and other organic substances prior to charging. These contaminating mat-
erials, at high temperatures, give off water vapor, carbon monoxide, hydrogen,
and carbon which are absorbed directly into the molten metal. Over heating
the melt should be avoided. The possibility of gas absorption increases with
The residual heat of the metal mass and crucible will be enough to sustain
time spent in the furnace. Once the melt has reached temperature for
furnace exposes the metal to the oxidizing effects of the atmosphere. When
pouring the metal into the mold, it should be done smoothly and without any
interval.
-48 -
Plate 27
(27) The clean scrap is added prior to starting the furnace . One should
not wedge the material in tightly nor let it rest above the top of the crucible
,/
Plate 28
-49-
(2 8) The furn a ce is start ed. The rema inder of the metal is added through
t he port of the lid with tongs. Some scraps and ingots are preheating on the
e dge of th e kiln.
Plate 29
(29) As the melt progresses, the last ingots are carefully added; they should
Plate 30
(30) The melt takes about one hour. During this time the molds have been
Pla t e 31
-51-
(31) After an hour has gone by , the temperature is checked with a pyrome t er .
Insert the bottom p a rt (below the weld mark) of th e pyrometer into the metal.
Befo re it is put directly into the molt e n mass, allow the temperature to
- - - - - - -1 Plate 32
(32) The lid of the kiln is opened and the crucible tongs used to lift
out th e crucible, which is then placed in the pouring shank. Each member of
the pouring crew wears safety gear - a long sleeved shirt, an apron, asbestos
'
gloves, leggings and a face viser. Because of the extreme weight, the hoist
is used in this pouring. The slag is b e ing skimmed off of the rnetal.(33)
- 52-
Pla te 33 ·
Pl a te 34
-53-
(3 4) The crucible is guided to the mold and the metal poured at a moderate speed.
One should try not to spill and keep th e pouring cup full until the metal
can be see n to rise out of the air vents. If any metal is left in the
Plate 35
(35) Before placing the crucible back into the furnace, the slag is scraped
Plate 36
(36) The crucible is placed back into the furnace and allowed to slowly cool
-55-
Plate 37
-56-
Plate 38
(38) The wire on the mold is cut and pulled off. The invPstment usually breaks
away.
Plate 39
-57-
(39) The bronze can be tapped with a hammer to knock off any remaining
PATINATION
Bronze has been gilded ·with gold, notably by the Greeks, silvered,
embellished by the use of enamels, and inlaid with other metals by the
from antiquity. Many bronzes from the past have obtained a rich patina through
their aging. The natural aging process of bronze has resulted in the
practice . of making sculptures look old, of antiquing them. One should not
but recalling the long and rich h eritage of bronze work. Emulating or
can explore three different surfaces. First, a surface could remain just as
it came from the casting , usually being covered by a brownmottled fire scale.
After the sprues are cut off bright spots are on the surface. The surface
would remain this. way. A second approach would be to tone down thebright
spots to match the fire scale. A third method would be to brighten up the
whole surface until none of the "clean up" blemishes showed. The technical
approach is simple, direct and expresses the "cast" character of the metal.
The last approach involves a patina, or any surface that best integrates
the form and cont ex t of the sculpture. Se emingly , this is the most
pragmatic approach.
-58-
sculptor. A purist would have no ground to stand on, because the color and
To seek integrity for the surface of the sculpture then, is not to decide
if there should be a patina or not, but rather what the sculptor feels to be
the adequate, integrating patina that will harmonize with his sculptural
form.
Patina Application
which can break down into chlorine gas . One should make sure that the area is
well vented.
There are three methods of patina application - cold and hot application
with a brush, or dipping and by fuming the surface with chemical vapors. The
same chemicals can react quite differently in each case. Fuming can be very
time consuming and at the mercy of many variables, so discussion here will
mild solution of nitric acid. It should then be wire brushed under running water
to further clean the surface and remove any acid residue. Sand blasting the
surface works well also, but may tend to mute some of the surface detail.
The patina solution is brushed over the entire surface and allowed to dry.
Faster drying and more stable colors can be facilitated by use of a torch .
As the bronze gets hotter and more applications of the solution are made,. the
patina becomes more substantial and opaque. The application process can be
-59-
application is complete and the bronz e ha s cooled, the surface can be rubbed
with paste wax, or .a beeswax- kerosene solution. This application will bring
out the color and protect the surface from undergoing any further change through
oxidation.
Ferric nitrate and ammonium sulphide are common compounds that are readily
available and easy to work with. Once applied they are fairly stable and
Ferric, or iron nitrate can easily be made with ~itric acid and nails.
Place about a pound of nails in a two quart glass jar. Add to this
about a one inch depth of full strength nitric acid. No severe reactions
will occur in the absence of water. Then · add two cups of water. Be sure
to do this outside in an open area, as noxious ,gases are given off in the chemical
reaction. After the bubbling and fuming have stopped, fill the jar with water and
let stand for 24 hours. The nails can then be removed and the remaining brown
sludge used as ferric nitrate. For use, the sludge is again diluted with 5
to 10 parts more water, or unitl one finds the solution working to satisfaction.
Slowly brush the ferric nitrate on the cool bronze surface. It will
be gin to yellow the metal. As heat and more applications of the solution are
made, the patina will build up and intensity, going through color stages of
t an to brown. When more heat is applied, the brown will turn to a cordovan
red. Even shop dust can b e collected and applied with the solution to change
Ammon ium sulphide can be used in conjunction with ferric nitrate to achieve
blacks or shaded areas on the bronze. The ammonium sulphide should be diluted
The previous technic represents only a minute portion of the vast multitude
-60-
addition of heat.
21 Patina Formula
y 1. Blue
2. Yellow Green
Parts By Wt.
Sodium Thiosulphate 1
Iron Nitrate 8
Water 128
The solution is brushed on clean surface until a crusty green appears. (An
inexpensive paintbrush is recommended since it wil1. have :o-15 e aiscarded after use.
Afterwards dip the bronze for six minutes in diluted nitric acid. Remove the
bronze, wash and dry.
3. Brown
The recipe is the same as the former, the only difference b eing the lengt h
of time brushing the solution on. In this case, brush until brown appears.
4. Antique Green
5. Matte Brown
, 6. Yellow Green
Parts by Weight.
Ammonium Ch l o ride 7
Copper Ac eta te 4
Water 8
7. Li gh t to Dark Brown
( 7 Continued)
Heat the Bronze and apply the liquid.
8. Brown to Bla ck
Parts by Weight
Antimony Sulphide 2
Sodium Hydroxide 4
Hater 255
9. Brm·m to Black
11. Additional application and chemical action turns the bronze light green.
Parts by Weight
Sodium Chloride 5
Ammonia 4
Ammo nium Chloride 5
Glacial Acid 4
Hater 32
Brush to surface
Parts by Weight
c Copper Sulphate 12
Ammonium Chloride 2
Water 125
13 . Black.
Parts by Weight
Copper Carbonate 2
Ammonium Carbona te 4
Sodium Carbonate 1
Water 32
Hea t t he solution to a boil . The bronze should be immersed. The solution should
be stirred .
14. Green
15 . Brown to Black
17. Verde
Parts by Weight
Copper Nitrate
,
..L
Ammonium Chloride 1
Calcium Chloride 1
Water 32
v 19. Blue
Brush to surface.
Co pp er Nitrate 48 Grams .
Sal Ammoniac 48 Grams
Calcium Chloride 20 Grams
Copper Sulfate 10 Grams
Oxalic Acid 10 Grams
Water 4 Fluid Ounces
Brush to surface for the color. Then dip into diluted nitric acid solutions
(one pa rt acid to 8 pa rts water) for one half hour, remove wash and dry . In
the above, the wron g combinations will give a deep d a rk green.
SUMMARY
I hope this paper will aid the beginning student and introduce him to the
There are numerous books and publications on the methods of bronze casting.
Many of them are conflicting and out of date. This paper draws upon their
dealing with the sprue system and types of investment should be regarded as
experimental on my part. There are many ways to approach these technics; they
Host of my experience has not come through reading, but from working in
a foundry. For that experience I wish to thank Paul Granlund, sculptor, with
whom I worked for a year; and Boyd Christensen, sculptor and instructor at
- FOOTNOTES -
1 John }lill, Studio Bronze Cas ting: Lost Wax Me thod
(New York: Praeger , 1970), p.l.
2 rbid.
7rbid., p.57.
B I BL I 0 GRAP HY
Casson, Stanley. The Technique of Early Greek Sculpture. New York: Hacker
Art Books, 1970.
Vntrac ht, Opp:. Metal Techniques for the Craftsme n. Garden City, New York:
Doubleday & Co., 1948.
(Continue d)
(Continued) This book is an excellent guide for all metal technics.