Approved by AICTE, Government of India & affiliated to Dr. A.P.J.
Abdul Kalam Technical University, Lucknow
DEPARTMENT OF APPLIED SCIENCE AND HUMANITIES
TUTORIAL SHEET
COURSE OUTCOME: BTL
Get an understanding of the theoretical principles of chemistry of molecular structure,
BAS201.1 bonding and properties, Chemistry of advanced materials (liquid crystals, Nano-materials, K3
Graphite & Fullerene) as well as the Principles of Green Chemistry.
Apply the fundamental concepts of determination of structure with various spectral
BAS201.2 K4
techniques and stereochemistry.
Utilize the theory of construction of electrodes, batteries and fuel cells in redesigning new
engineering products and categorize the reasons for corrosion and study methods to
BAS201.3 K3
control corrosion and develop understanding of Chemistry of Engineering materials
(Cement)
Develop understanding of the sources, impurities and hardness of water, apply the
BAS201.4 K3
concepts of determination of calorific values and analyze the coal.
Develop the understanding of Chemical structure of polymers and its effect on their
BAS201.5 various properties when used as engineering materials. Understanding the applications of K3
specific polymers and Chemistry applicable in industrial process.
TUTORIAL: 03
NAME OF SUBJECT WITH CODE:Engineering Chemistry (BAS 201) DATE OF ISSUE
Unit Covered: 3
Q. No. Question Description CO BTL
Why does Portland cement contain both tri-calcium aluminate and di-calcium
1 silicate, even though their hydration rates are vastly different? The hydration of K2
cement releases heat, yet adding excess water weakens concrete. Explain the
paradox.
For cell: Mg (s) | Mg +2 (1M) || Cu +2 (0.1M) | Cu (s)
[E 0 Mg+2 / Mg = -2.13 V; E 0 Cu+2/Cu =0.25V]
2 (i) Identify the cathode and the anodes as the current drawn from it. 3 K3
(ii) Write the electrode reactions.
(iii) Calculate the cell potential
Consider the following cell:
Ni (s) |Ni +2 (0.01M) || Cu +2 (0.5M) |Cu (s).
3 The standard reduction electrode potential of Ni and Cu are - 0.25 and 0.34V 3 K3
respectively. Write the electrode Reactions and calculate the EMF of the cell at 298
K.
Differentiate between Primary and Secondary batteries ? Discuss the various
4 3 K2
reactions involve during the charging and discharging of lead storage battery.
Brass exposed to seawater loses zinc over time, leaving behind a copper-rich
5 3 K2
structure. Explain the underlying electrochemical process.
Explain sacrificial anodic and impressed cathodic protection method for prevention
6 of corrosion. 3 K2
Calculate the emf of Daniell cell at 250C when the concentration of ZnSO4 and
CuSO4 are 0.001M and 0.01 M respectively . The standard potential of the cell is 3
7 1.1 volt. K2
The emf of a cell measured by means of a hydrogen electrode against a saturated
calomel electrode at 298K is 0.4188 V. If the pressure of the H2 (g) was 3 K2
8 maintained at 1atm, calculate the pH of the unknown solution, given potential of
reference calomel electrode is 0.2415 V
Calculate the cell potential of the given cell at 25ºC. (R = 8.31JL-1 mol -1 , F= 96500C
9 mol-1). Ni(s)∣Ni+2(0.01 M)∣∣ Cu+2 (0.1M)∣Cu(s) Given Eº Cu+2/Cu = +0.34 V; 3 K3
Eº Ni+2/Ni = - 0.25 V
Can corrosion occur in the vacuum of space? If so, under what conditions? K3
10 3
A dry cell battery loses charge even wheh not in use. What fundamental chemical
processes lead to its slow degradation?
Add short note on POP.
CO: Course Outcome BTL: Bloom's Taxonomy Level
