STRUCTURE OF ATOM 1. Choose the incorrect relation on the basis of Bohr's theary a) Velocity of electron x + b) Frequency of revolution x 3 ) Radius of orbit « n2Z 4) Force on electron « 2. X-rays were discovered by: a) Becquerel b) Roentgen ©) Mme. Curie 4) Van Laue 3. Two electrons in the same orbital may be identified with: a)n vt gm as 4. An electron has principal quantum number 3. The number of its (i) subshells and (ii) orbitals would be respectively: a) Band 5 b) 3and7 9) 3and9 a) 2and5 5. Maximum number of electrons in a subshell of an atom is determined by the following: a) 2n? byal+2 ga+t aa-2 6. Particle having mass 200 times that of an electron is: a) Proton ») Positron ©) Meson 4) Neutron 7. Which of the following has the maximum number of unpaired electrons? a) Mg’* by T* o) Fet* avs An electron from one Bohr stationary orbit can go to next higher orbit a) By emission of electromagnetic radiation ) By absorption of any electromagnetic radiation ©) By absorption of electromagnetic radiation of particular frequency 4d) Without emission or absorption of electromagnetic radiation 9. How many neutrons are present in tritium nucleus? a)2 b)3 ot ao 10. The number of wave made by an electron moving in an orbit having maximum magnetic quantum number 4+3is: a)4 »)3 os 11. The wavelength of a spectral line emitted by hydrogen atom in the Lyman series is= value of n:?(R=Rydberg constant) a)2 »)3 a4 ai 12. The statements, which is/are correct: a) Number of total nodes in an orbital b) Number of radial nodes in an orbital 6) Number of angular nodes in an orbital «) Allofthe above 13, If the wavelength of an electromagnetic radiation is 200A, what is its energy in ergs? a) 9.94 x 10° 9.94 x 10°? 4.97 x 107? 497 x10" 14, Number of unpaired electrons in the electronic configuration 1s?,2s*2p* ay2 »)3 4 ao 15. Asstrong argument for the particle nature of cathode rays is that they: a) Produce fluorescenceb) Travel through vacuum ©) Get deflected by electric and magnetic fields ) Cast shadow 16. ‘The electronic configuration 1s?,2s*2p°,3s*3p! correctly describes: a) Ground tate of Nab) Ground state of Si*__c) Excited stateofMg _) Excited state of A+ 17. What accelerating potential is needed to produce an electron beam with an effective wavelength of 0.090A7 a) 1.86 x 10¢eV b) 1.86 x 107eV ©) 2.86 x 10¢eV d) 2.86 x 107eV 18. Which of the following pairs have identical values of e/m? a) A proton and a neutron b) A proton and deuterium ©) Deuterium and an a-particles 4) An electron and y-rays 19. Positive charge in an atom is: a) Scattered all over the atom ) Concentrated in the nucleus ©) Revolving around the nucleus 4) None is true 20. [Cr(H20)g]Cls (at. No. of r= 24) has a magnetic moment of 3.83 B.M. The correct distribution of 34 electrons in the chromium of the complex: a) 3d}y,3d}_,3d2, b) Bshy, 3d, Bate 0) (Bdts_,2), 3d’, 3h, 4) 3dhy, (3d!2_,2) 3d, 21. ‘Themass of an electron is m, its charge is e and it is accelerated from rest through a potential difference, V. The velocity of electron will be calculated by formula 4) None of these v lev eV of off fe 22, The present atomic weight scale is: a)? pyor ou acs 23. Which one of the following set of quantum numbers is not possible for electron in the ground state of an. atom with atomic number 19? a)n=21=0.m=0 b)n=21 =0) Qn=3l=1m=-1 d)n=3,l=2,m=+2 24, Oxygen consists of O'%, 0°” and 0!* isotopes and carbon consists of isotopes of C'? and C'S. Total number of CO, molecules possible are: a)6 by 12 9) 18 ot 25. In order to designate an orbital n in an atom, the number of quantum number req) a) v2 93 aa 26, For a given value of azimuthal quantum number [, the total number of values for the magnetic quantum number m are given by: sd are: a)l+1 by2l+1 9) 2t- dl+2 27. Magnetic quantum number for the last electron in sodium is: a)3 byt Q2 d) Zero 28, The Heisenberg’s uncertainty principle can be applied to: a) Acricket ball b) A football ©) Ajet aeroplane 4d) An electron 29. Isotopes are a) Atoms of different elements having same mass number }b) Atoms of same elements having same mass number ¢) Atoms of same elements having different mass number d) Atoms of different elements having same number of neutrons30. Which element possess non-spherical shells? a) He b)B ©) Be Li 31. Splitting of spherical lines when atoms are subjected to strong electric field is called: a) Zeeman effect b) Stark effect ©) Decay 32, An orbital in which n = 4 and { = 2 is expressed by a) As b) 4p oad 33. Which wave property is directly proportional to energy of electromagnetic radi a) Velocity 1b) Frequency ©) Wave number d) All ofthese 34, Mass of an electron is, a) 9.1 x 10-%g b) 91x 10°%g 9) 91x 107g 4) 91x10" %g 35, Which is the correct outermost shell configuration of chromium? atti tii lt { »Lt{ {1 oL4{ 414 4 "OTT { 36. Which of the following ion will show colour in aqueous solution? a) la*(Z = 57) by Ti*(Z = 22) ) lu*(Z = 71) a sc¥(z = 21) 37. The electric configuration of element with atomic number 24 is a) 152, 2s?2p5,3s*3p%3ats, 4s? b) 152, 2s%2p6,3s*3p%aat? €) 1s?, 2572p, 3573p °3a® d) 1?, 25?2p6,35?3p°3a, 4s 38, What is the maximum number of electrons in an atom that can have the following quantum numbers mt = 4m, = 417 a4 by 15 93 6 39, The principal quantum number of an atom represents: a) Size and energy of the orbit ) Spin angular momentum 6) Orbital angular momentuin 4) Space orientation of the orbitals 40. The specific charge for positive rays is much less than the specific charge for cathode rays. This is because: a) Positive rays are positively charged bb) Charge on positive rays is less ©) Positive rays comprise ionised atoms, whose mass is much higher 4) Experimental method for determination is wrong 41, The magnetic moment of electron in an atom (excluding orbital magnetic moment) is given by: Vie #2) Bohr » AEF OM, a PER a 4) None ofthe above Magneton (or BM) 42, de Broglie equation isa relationship between: a) Position of an electron and its momentum b) Wavelength of an electron and its momentum ©) Mass of an electron and its energy ) Wavelength of an electron and its frequency 43, Which electromagnetic radiation has extremely small wavelength? a) Radiowave ) Cosmic rays 6) Infrared rays 4) Microwaves 44, Dimensions of Planck's constant are: a) force x time b) energy x ©) energy /time ) energy x ti45. Given: The mass of electron is 9.11 x 10-?*kg and Planck constant is 6.626 x 10-4 Js, the uncertainty involved in the measurement of velocity within a distance of 0.1 A is: a) 5.79x10%ms"* —b) 5.79 10° ms“? 5.79 10s?) 5.79 10? ms“ 46. If helium atom and hydrogen molecules are moving with the same velocity, their wavelength ratio will be ayaa bya2 21 ait 47, ‘The energy required to break one mode of Cl ~ Cl bonds in Cl; is 242k}mol™!, The longest wavelength of light capable of breaking a single Cl — Cl bond is a) 5941nm ») 640 nm ©) 700 nm 4) 494mm 48. The uncertainty in momentum of an electron is 1 x 10~® kg m/s. the uncertainty in its position will be (it = 6.62 x 10° kg m*/s) a) 2.36x 10-?%m b) 5.25% 10-2%m ©) 2.27 10-%m ) 5.27% 10-%m 49, Alltypes of electromagnetic radiations possess same: a) Energy b) Velocity ©) Frequency 4) Wavelength 50. The values of four quantum numbers of valence electron of an element are n=4l=0,m=0ands= +2, ‘The element is ayk by Ti Na a) se 51. Ground state electronic configuration of nitrogen atom can be represented as a) HI) yO »hMHCoH »Wooy 52. The value of charge on the oil droplets experimentally observed were —1.6 x 10729 and —4 x 10719 coulomb. The value of the electronic charge, indicated by these results a) 1.6 10-27 b)—2.4 x 107% ) 4x 10717 d) -0.8 x 107% 53. Transition from n = 4,5,6 to n = 3 in hydrogen spectrum gives: a) Lyman series b) Paschen series c) Balmer series d) Pfund series 54, The atomic numbers of elements X, Y and Z are 19, 21 and 25 respectively. The number of electrons present in the M-shell of these elements follow the order a)Z>X>¥ DX >¥>Z )Z>¥>Xx ay >Z>x 55. The mass number of an element is 23 and atomic number is 11, The number of protons, electrons and neutrons respectively present in the atom of the elements are: a) 11,11,12 by 12,12,11 cc) 11,12, 11 d) 12, 11,12 56. In photoelectric emission the energy of the emitted electrons is: a) Larger than that of incident photon b) Smaller than that of incident photo ) Same as that of incident photon 4) Proportional to intensity of incident light 57. Angular momentum of an electron in an orbital is given by: h h h and wix JTFH oak 4) None ofthese 58, What is the mass of a photon of sodium light with a wavelength of 5890 A'?(h = 6.63 x 10°27 erg-s) a) 5.685 x 107 g b) 6.256 x 107" g ©) 4.256 x 107 g ) 3.752 x 10" g 59. Consider the ground state of (Z = 24). The numbers of electrons with the azimuthal quantum numbers, 1 = Land 2 are respectively a) 12 and 4 b) 12 and 5, ©) 16 and 4 d) 16 and 5 60. The charge on an electron was discovered by a) JJ. Thomson ) Neil Bohr ©) James Chadwick @) Mullikan 61. tfanelectron has spin quantum number of + Zand a magnetic quantum number of ~1, itcannot be represented in an a) s ~orbital b) p orbital ©) d orbital d) f orbital62. The orbital angular momentum for an electron revolving in an orbitis given by JT¥ 1) 2 This ‘momentum for an s-electron will be given by LA b) Zero h ah doe ) on aae 63. Aheavy element has atomic number X and mass number ¥. Correct relationship between X and ¥ is ax ¥ waxy xy ax za yy 64. Protonis: a) Nucleus of deuterium b) lonised hydrogen molecule 6) lonised hydrogen atom @) Ane-particle 65. Anisotone of 73Ge is a) 33Ge b) HAs ©) Use ) 6Se 66. Which principle/rule limits the maximum number of electrons in an orbital to two? a) Aufbau principle b) Pauli’s exclusion principle ©) Hund’s rule of maximum multiplicity 4) Heisenberg’s uncertainty principle 67, Magnitude of kinetic energy in an orbit is equal to a) Half of the potential energy b) Twice of the potential energy ©) One fourth of the potential energy 4) None ofthe above 68, The shortest @ for the Lyman series is: (Given Ry, = 109678 cm~1) a) 991A ») 700A 9) 600A aad 69. The maximum number of atomic orbitals associated with a principal quantum number 5 is: a9 byi2 9) 16 25 70. The number of orbitals present in the shell with n = 4s a) 16 v8 Q18 a) 32 71. Which one of the following is the set of correct quantum numbers of an electron in 3d orbital? a)n=3,1=0,m=0,s=-1/2 b)n=2,=3,m=0,s= 41/2 on =3,l=1m=0,s=-1/2 d)n=3,1=2,m=1Ls= 41/2 72, Different lines in Lyman series of hydrogen spectrum lie in .. region a) Ultraviolet b) Infrared ©) Visible 4) Far infrared 73. The first energy level that can have d-orbitals is a)2 »)3 o4 d) Allare correct, 74, The uncertainty in the momentum of an electron is 1.0 x 10~Skg ms“. The uncertainty in its position will be a) 1.50 10-?%m ) 1.05 x 10-?%m 6) 5.27 x 107m 4) 5.25 x 107m 75. Which of the following particles moving with same velocity would be associated with smaller de-Broglie wavelength? a) Helium molecule) Oxygen molecule —_—_c) Hydrogen molecule _d) Carbon molecule 76, Stark effect refers to the a) Splitting up of the lines in an emission spectrum in the presence of an external electrostatic field b) Random scattering of light by colloidal particles 6) Splitting up of the lines in an emission spectrum in a magnetic field 4) Emission of electrons from metals when light falls upon them 77. For which species, Bohr's theory does not apply: a) H b) Be o) Het ay Litt 78. ‘The energy of electron in first orbit of He* is (Ryy = ~871.6 x 10-?° }). The energy of electron in the first orbit of His:a) ~B71.6 x 107°] b) 435.8 x 107297 ¢) ~217.9 x 10-7 J d) 108.9 x 1077] 79. ‘The quantum levels upton = 3 has: a) sand p-levels d)s,p.d, f-levels ) 5,p,d-levels 4) s-tevel 80. Which of the subshell has double dumb-bell shape? as wp oa af 81, The lightest particle is a) -particle ) Positron ©) Proton 4) Neutron, 82, The ratio of speed of y-rays and X-rays is a)t p< g>t 4) None of these 83, The radius of second Bohs orbit of hydrogen atom is, a) 0.053 nm ») 0.106 am 6) 0.2116 nm ) 0.4256 nm 84, Which set of phenomenon shown by the radiation proves the dual nature of radiation? a) Scintillation }) Interference and diffraction ) Interference and photoelectric effect d) None ofthe above 85, The hydrogen spectrum from an incandescent source of hydrogen is: a) A band spectrum in emission ) Aline spectrum in emission ©) Aband spectrum in absorption 4) Aline spectrum in absorption 86, The total spin resulting from a d” configuration is: a) £1/2 b) £2 ott 4) $3/2 87. The path of deflection of electron beam is: a) Directly proportional to the magnitude of applied magnetic field b) Inversely proportional to the magnitude of applied magnetic field ©) Inversely proportional to the velocity of electron 4) Directly proportional to the e/m value 88. Which one of the following groupings represents a collection of isoelectronic species? (At no, €s=55, Br=35) a) Na, Ca®, Mg? D) NSF, Na ©) Be, AI’, Cl 4) Ca?, Cs, Br 89, Which particle may be removed from a stable neutral atom with least energy change? a) Ane-particle b) Aneutron ©) Aproton d) Anelectron 90. Visible spectrum of hydrogen shows that it exists in two different forms which are based on direction of spin ofthe: a) Molecule of hydrogen b) Nuclei of hydrogen atoms ©) Electrons of hydrogen 4) Atoms of hydrogen molecule 91, Evidence for the existence of different energy levels in atom is supplied by: { a) Spectral lines b) Mass defects ©) Atomic numbers) Atomic radii 1 92, Rutherford's experiment on the scattering of a particles showed for the first time that the atom has ! a) Electrons ») Protons ©) Nucleus 4) Neutrons ' 93. ‘The longest 4 for the Lyman series is : (Given Ry, = 109678 cm”*) ' a) 1215 A by 131s A 91415 A aisisé ! 94. The angular momentum of electron in nth orbit is given by: : h nh nh 1 a) mh oe at on ' 95. According to Bohr's postulates which quantity can take up only discrete values: 1 a) Kinetic energy ) Angular momentum —c) Momentum 4) Potential energy ! i 1 !96. When the frequency of light incident on a metallic plate is doubled, the KE of the emitted photoelectrons. will be: a) Doubled b) Halved 6) Increased but more than doubled of the previous KE 4) Unchanged 97. The mass of one mole of electron is: a) 055 mg 1b) 0.008 mg, ©) 1.008 mg ) 0.184 mg 98. The velocities of two particles A and B are 0.05 and 0.02 ms~ respectively. The mass of B is five times the ‘mass of A, The ratio of their de-Broglie's wavelength is a) 2:1 bjit Oia dla 99. Which are in the ascending order of wavelength? a) HasHp, My »«lines in Balmer series of hydrogen atom ) Lyman limit, Balmer limit, Paschen limitin the hydrogen spectrum ©) Blue, violet, yellow, red colours in solar spectrum 4) None of the above 100. The representation of the ground state TIT] electronic configuration of He by box-diagram as is wrong because it violates, a) Heisenberg's uncertainty principle ) Bohr's quantization theory of angular momenta 6) Pauli exclusion principle 4) Hund’s rule 101. The electronic configuration of the element which is just above the element with atomic number 43 in the same particle group is: a) 152, 2s?2p%, 35°3p°3d"°, 4s 4p® b) 1s?, 25?2p%, 35 3p°3a, 45? 6) 1s?, 25?2p5,35?3p°3d%, 451 d) 1s?,2s?2p°, 35*3p°3d", 4s?4p> 102. The order of filling of electrons in the orbital of an atom will be: a) 3d 4s 4p 4d 5s b) 4s 3d 4p Ss 4d ©) 5s 4p 3d 4d 5s d) 3d 4p 4s 4d 5s 103. The Bohr's energy equation for H atom reveals that the energy level of a shell is given by F = —13.58/n? eV. ‘The smallest amount that an H-atom will absorb, if in ground state is: a) 1.0 eV 0) 339eV ) 679 eV. d) 10.19 ev 104, The amount of energy required to remove the electron from a Li* fon in its ground state is how many times greater than the amount of energy required to remove the electron from an H atom in its ground state? a) b)2 33 as 105. Compared to mass of lightest nucleus the mass ofan electron is only: a) 1/80 ») 1/360 1/1800 ) 1/1000 1 106. Bragg's equation will have no solution, if: t a) 4>2d bya<2d Qacd aasd ' 107. Size of the nucleus is: 7 a) 10m b) 107m 107m 4) 10-%em ' 108. The radius of Bohr's first orbit in H-atom is 0.053 nm. The radius of second orbit in He* would be: I a) 0.0265 nm 9) 0.0530 nm 6) 0.1060 nm ) 0.2120 nm ! 1109. Splitting of spectrum lines in magnetic field is : a) Stark effect b) Raman effect ©) Zeeman effect 4) Rutherford effect ! 110. If the radius of first Bohr's orbit be ag, then the radius of third Bohr’s orbit would be: I a) 3X ay b)6 Xap 9X a 1/9 X ay 1 111, Which of the following atoms has same number of protons and neutrons in its nucleus? 7 1 1 1 !a) Carbon b) Deuterium ©) Tritium d) Nitrogen 112. The ratio of the difference in energy between the first and the second Bohr orbit to that between the second and the third Bohr orbit is, 1 1 4 27 a5 Ds 95 oF 113. The wavelength of radiation emitted when electron falls from 4th Bohr’s orbit to 2nd in H-atom is: (Ru = — 1.09678 x 10-7m~4) a) 972 nm ») 486 nm ©) 243 nm 4) 182 nm 114. In an atom with atomic number 29, mass number 59, the number of electrons is: a)29 »)30 40 459 115. The atomic transition gives rise to the radiation of frequency 10 MHz. The change in energy per mole of atoms taking place would be a) 6.62 x 10-9) b)5.32 x 10-9) ©) 662 x 10-9) a) 3.99), 116. Uncertainty in the position of an electron (mass = 9.1 x 10~#*kg) moving with a velocity 300 ms~ accurate upon 0.001% will be (i= 6.63 x 10-* Js) a) 19.2 10-?m 0) 5.76 x 10-%m 1.92 x 10-?m 384 10-?m 117. Which of the following is not possible? a)n=21=1m=0 b)n=21=0m=-1 Qn=3l=0m=0 d)n=3,l=1,m=-1 118. The dynamic mass of a photon of wavelength 2 is: a) Zero by hc/a oO hycd OHA 119. The atomic radius is of the order of : a) 10-% em 1b) 10% cm 9) 10" em ) 10-7 em 120. When electronic transition occurs from higher energy state to a lower energy state with energy difference equal to AE expressed in electron volts, the wavelength of line emitted is approximately equal to: i 12378, 5 passe wtotem aE 109m) Bither ofthese 121, A Mo atom in its ground state has a 4d°, 5s* configuration and a Ag atom 4d?°, 5s! configuration. This is because a shell which is half-flled or completely filled is particularly a) Strongly exchange destabilized bb) Weakly exchange stabilized ©) Weakly exchange destabilized 4) Strongly exchange destabilized 122, The ionisation enthalpy of hydrogen atom is 1.312 x 10%}mol”?, The energy required to excite the electron in the atom from ny = 1 to nz = 2is a) 8.51% 108Jmol? —b) 6.56 x 10°} mol"? _—c) 7.56 x 10% Jmol"? —d). 9.84 x 10° J mol“* 123. Which of the following sets of quantum number is correct for an electron in 4f-orbital? a)n=4,1=3,m=+45= 41/2 b)n=4,l=4,m = -4,¢=-1/2 Qn=4l=3m=415= 41/2 d)n=3,l=2,m=-2,s= 41/2 124, Number of electrons in ~CONH, are: a) 24 ) 20 22 ais 125. The ratio of radil of two nuclei with mass numbers 27 and 64 is a) 1/2 ») 3/4 932 a2 126. The atomic number of Niand Cu are 28 and 29 respectively. The electronic configuration 152s?2p°3s?3p'3d" represents a) Cut b) Cu2* o) NPT a) Ni 127. The three quantum numbers n, Land m are the outcome of: a) Bohr’s atomic theory b) Solution of Schrodinger principle 6) Heisenberg’s uncertainty principle 4) Aufbau principle 128. Which has the highest e/m ratio?