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0% found this document useful (0 votes)
50 views43 pages

Solution

The document contains a series of physics and chemistry questions, each with multiple-choice answers. It covers topics such as mechanics, thermodynamics, electromagnetism, and chemical properties. The questions are designed for an examination format, assessing knowledge in both subjects.

Uploaded by

abhijbgs
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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17-03-2021

1001CJM170321EVE JM

PART-1 : PHYSICS

SECTION-A

1) A rubber ball is released from a height of 5 m above the floor. It bounces back repeatedly, always
rising to of the height through which it falls. Find the average speed of the ball. (Take g = 10 ms–2)

(A) 3.0 ms–1


(B) 3.50 ms–1
(C) 2.0 ms–1
(D) 2.50 ms–1

2) If one mole of the polyatomic gas is having two vibrational modes and β is the ratio of molar

specific heats for polyatomic gas then the value of β is :

(A) 1.02
(B) 1.2
(C) 1.25
(D) 1.35

3) A block of mass 1 kg attached to a spring is made to oscillate with an initial amplitude of 12 cm.
After 2 minutes the amplitude decreases to 6 cm. Determine the value of the damping constant for
this motion. (take In 2 = 0.693)

(A) 0.69 × 102 kg s–1


(B) 3.3 × 102 kg s–1
(C) 1.16 × 102 kg s–1
(D) Insufficient data

4) Which one of the following will be the output of the given circuit ?

(A) NOR Gate


(B) NAND Gate
(C) AND Gate
(D) XOR Gate

5) An object is located at 2 km beneath the surface of the water. If the fractional compression is
1.36% , the ratio of hydraulic stress to the corresponding hydraulic strain will be ___________.
[Given : density of water is 1000 kg m–3 and g = 9.8 ms–2.]

(A) 1.96 × 107 Nm–2


(B) 1.44 × 107 Nm–2
(C) 2.26 × 109 Nm–2
(D) 1.44 × 109 Nm–2

6) A geostationary satellite is orbiting around an arbitary planet 'P' at a height of 11R above the
surface of 'P' , R being the radius of 'P'. The time period of another satellite in hours at a height of
2R from the surface of 'P' is_________.'P' has the time period of 24 hours.

(A)

(B)

(C) 3
(D) 5

7) A sound wave of frequency 245 Hz travels with the speed of 300 ms–1 along the positive x-axis.
Each point of the wave moves to and fro through a total distance of 6 cm. What will be the
mathematical expression of this travelling wave ?

(A) Y(x,t) = 0.03 [sin 5.1 x – (0.2 × 103)t]


(B) Y(x,t) = 0.06 [sin 5.1 x – (1.5 × 103)t]
(C) Y(x,t) = 0.06 [sin 0.8 x – (0.5 × 103)t]
(D) Y(x,t) = 0.03 [sin 5.1 x – (1.5 × 103)t]

8) Which one is the correct option for the two different thermodynamic processes ?

(A)

(B)

(C)
(D)

(A) (c) and (a)


(B) (c) and (d)
(C) (a) only
(D) (b) and (c)

9) A carrier signal C(t) = 25 sin (2.512 × 1010 t) is amplitude modulated by a message signal m(t) = 5
sin (1.57 × 108 t) and transmitted through an antenna. What will be the bandwidth of the modulated
signal ?

(A) 8 GHz
(B) 2.01 GHz
(C) 1987.5 MHz
(D) 50 MHz

10) The velocity of a particle is v = v0 + gt + Ft2. Its position is x = 0 at t = 0 ; then its displacement
after time (t = 1) is :

(A) v0 + g + F

v0 + +
(B)

(C)
v0 + +F
(D) v0 + 2g + 3F

11) Two cells of emf 2E and E with internal resistance r1 and r2 respectively are connected in series
to an external resistor R (see figure). The value of R, at which the potential difference across the

terminals of the first cell becomes zero is

(A) r1 + r2

(B)

(C)

(D) r1 – r2
12) A hairpin like shape as shown in figure is made by bending a long current carrying wire. What is
the magnitude of a magnetic field at point P which lies on the centre of the semicircle ?

(A)

(B)

(C)

(D)

13) The four arms of a Wheatstone bridge have resistances as shown in the figure. A galvanometer
of 15 Ω resistance is connected across BD. Calculate the current through the galvanometer when a

potential difference of 10V is maintained across AC.

(A) 2.44 μA
(B) 2.44 mA
(C) 4.87 mA
(D) 4.87 μA

14) Two particles A and B of equal masses are suspended from two massless springs of spring
constants K1 and K2 respectively. If the maximum velocities during oscillations are equal, the ratio of
the amplitude of A and B is

(A)

(B)

(C)

(D)
15) Match List-I with List-II

List-I List-II

Phase difference between current


(a) and voltage in a purely resistive AC (i) ; current
circuit leads voltage

Phase difference between current


(b) (ii) zero
and voltage in a pure inductive AC circuit

Phase difference between current


(c) and voltage in a pure capacitive AC (iii) ; current
circuit lags voltage

Phase difference between current


(d) (iv)
and voltage in an LCR series circuit tan–1
Choose the most appropriate answer from the options given below :
(A) (a)–(i),(b)–(iii),(c)–(iv),(d)–(ii)
(B) (a)–(ii),(b)–(iv),(c)–(iii),(d)–(i)
(C) (a)–(ii),(b)–(iii),(c)–(iv),(d)–(i)
(D) (a)–(ii),(b)–(iii),(c)–(i),(d)–(iv)

16) Two identical blocks A and B each of mass m resting on the smooth horizontal floor are
connected by a light spring of natural length L and spring constant K. A third block C of mass m
moving with a speed v along the line joining A and B collides with A. The maximum compression in

the spring is

(A)

(B)

(C)

(D)

17) The atomic hydrogen emits a line spectrum consisting of various series. Which series of
hydrogen atomic spectra is lying in the visible region ?

(A) Brackett series


(B) Paschen series
(C) Lyman series
(D) Balmer series

18) Two identical photocathodes receive the light of frequencies f1 and f2 respectively. If the
velocities of the photo-electrons coming out are v1 and v2 respectively, then
(A)
– = [f1 – f2]

(B)
+ = [f1 + f2]

(C)
v1 + v2 =

(D)
v1 – v2 =

19) What happens to the inductive reactance and the current in a purely inductive circuit if the
frequency is halved ?

(A) Both, inductive reactance and current will be halved.


(B) Inductive reactance will be halved and current will be doubled.
(C) Inductive reactance will be doubled and current will be halved.
(D) Both, inducting reactance and current will be doubled.

20) A sphere of mass 2kg and radius 0.5 m is rolling with an initial speed of 1 ms–1 goes up an
inclined plane which makes an angle of 30° with the horizontal plane, without slipping. How low will

the sphere take to return to the starting point A ?

(A) 0.60 s
(B) 0.52 s
(C) 0.57 s
(D) 0.80 s

SECTION-B

1) The electric field intensity produced by the radiation coming from a 100 W bulb at a distance of
3m is E. The electric field intensity produced by the radiation coming from 60 W at the same

distance is Where the value of x =_________.

2) A body of mass 1 kg rests on a horizontal floor with which it has a coefficient of static friction .
It is desired to make the body move by applying the minimum possible force F N. The value of F will
be __________. (Round off to the Nearest Integer) [Take g = 10 ms–2]

3) A boy of mass 4 kg is standing on a piece of wood having mass 5kg . If the coefficient of friction
between the wood and the floor is 0.5, the maximum force that the boy can exert on the rope so that
the piece of wood does not move from its place is ________N.(Round off to the Nearest Integer)

[Take g = 10 ms–2]

4) Suppose you have taken a dilute solution of oleic acid in such a way that its concentration
becomes 0.01 cm3 of oleic acid per cm3 of the solution. Then you make a thin film of this solution
(monomolecular thickness) of area

4 cm2 by considering 100 spherical drops of radius cm. Then the thickness of oleic
acid layer will be x × 10–14 m. Where x is__________.

5) A particle of mass m moves in a circular orbit in a central potential field U(r) = U0r4 . If Bohr's
quantization conditions are applied, radii of possible orbitals rn vary with , where α
is___________.

0
6) The electric field in a region is given by with E = 4.0 × 103 .The flux of this
field through a rectangular surface area 0.4 m2 parallel to the Y – Z plane is _________Nm2C–1.

7) The disc of mass M with uniform surface mass density σ is shown in the figure. The centre of mass

of the quarter disc (the shaded area) is at the position , where x is ________. (Round off to the
Nearest Integer)
[a is an area as shown in the figure]

8) The image of an object placed in air formed by a convex refracting surface is at a distance of 10 m

behind the surface. The image is real and is at of the distance of the object from the surface .The

wavelength of light inside the surface is times the wavelength in air. The radius of the curved

surface is m. the value of 'x' is__________.

9) A 2 μF capacitor C1 is first charged to a potential difference of 10 V using a battery.Then the


battery is removed and the capacitor is connected to an uncharged capacitor C2 of 8μF. The charge
in C2 on equilibrium condition is_______μC. (Round off to the Nearest Integer)

10) Seawater at a frequency f = 9 × 102 Hz, has permittivity ε = 80ε0 and resistivity ρ = 0.25 Ωm.
Imagine a parallel plate capacitor is immersed in seawater and is driven by an alternating voltage
source V(t)=V0 sin (2πft). Then the conduction current density becomes times the displacement

current density after time t = s. The value of x is ________

PART-2 : CHEMISTRY

SECTION-A

1) Fructose is an example of :-

(A) Pyranose
(B) Ketohexose
(C) Aldohexose
(D) Heptose

2) The set of elements that differ in mutual relationship from those of the other sets is :

(A) Li – Mg
(B) B – Si
(C) Be – Al
(D) Li – Na

3) The functional groups that are responsible for the ion-exchange property of cation and anion
exchange resins, respectively, are :

(A) –SO3H and –NH2


(B) –SO3H and –COOH
(C) –NH2 and –COOH
(D) –NH2 and –SO3H

4) Match List-I and List-II :


List-I List-II

(a) Haematite (i) Al2O3.xH2O

(b) Bauxite (ii) Fe2O3

(c) Magnetite (iii) CuCO3.Cu(OH)2

(d) Malachite (iv) Fe3O4


Choose the correct answer from the options given below :
(A) (a)-(ii), (b)-(iii), (c)-(i), (d)-(iv)
(B) (a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
(C) (a)-(i), (b)-(iii), (c)-(ii), (d)-(iv)
(D) (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii)

5) The correct pair(s) of the ambident nucleophiles is (are) :


(A) AgCN/KCN
(B) RCOOAg/RCOOK
(C) AgNO2/KNO2
(D) AgI/KI

(A) (B) and (C) only


(B) (A) only
(C) (A) and (C) only
(D) (B) only

6) The set that represents the pair of neutral oxides of nitrogen is :

(A) NO and N2O


(B) N2O and N2O3
(C) N2O and NO2
(D) NO and NO2

7) Match List-I with List-II :

List-I List-II

(a) [Co(NH3)6] [Cr(CN)6] (i) Linkage isomerism

(b) [Co(NH3)3 (NO2)3] (ii) Solvate isomerism

(c) [Cr(H2O)6]Cl3 (iii) Co-ordination isomerism

(d) cis-[CrCl2(ox)2]3– (iv) Optical isomerism


Choose the correct answer from the options given below :
(A) (a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
(B) (a)-(iv), (b)-(ii), (c)-(iii), (d)-(i)
(C) (a)-(ii), (b)-(i), (c)-(iii), (d)-(iv)
(D) (a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
8) Primary, secondary and tertiary amines can be separated using :-

(A) Para-Toluene sulphonyl chloride


(B) Chloroform and KOH
(C) Benzene sulphonic acid
(D) Acetyl amide

9) The common positive oxidation states for an element with atomic number 24, are :

(A) +2 to +6
(B) +1 and +3 to +6
(C) +1 and +3
(D) +1 to +6

10) Match List-I with List-II :

List-II
List-I Chemical compound
Used as

(a) Sucralose (i) Synthetic detergent

(b) Glyceryl ester of stearic acid (ii) Artificial sweetener

(c) Sodium benzoate (iii) Antiseptic

(d) Bithionol (iv) Food preservative


Choose the correct match :
(A) (a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
(B) (a)-(ii), (b)-(i), (c)-(iv), (d)-(iii)
(C) (a)-(iii), (b)-(ii), (c)-(iv), (d)-(i)
(D) (a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)

11) Given below are two statements :


Statement-I : 2-methylbutane on oxidation with KMnO4 gives 2-methylbutan-2-ol.
Statement-II : n-alkanes can be easily oxidised to corresponding alcohol with KMnO4.
Choose the correct option :

(A) Both statement I and statement II are correct


(B) Both statement I and statement II are incorrect
(C) Statement I is correct but Statement II is incorrect
(D) Statement I is incorrect but Statement II is correct

12) Nitrogen can be estimated by Kjeldahl's method for which of the following compound ?

(A)
(B)

(C)

(D)

13) Amongst the following, the linear species is :

(A) NO2
(B) Cl2O
(C) O3
(D)

14) C12H22O11+H2O C6H12O6+C6H12O6


Sucrose Glucose Fructose
C6H12O6 2C2H5OH+2CO2
Glucose
In the above reactions, the enzyme A and enzyme B respectively are :-

(A) Amylase and Invertase


(B) Invertase and Amylase
(C) Invertase and Zymase
(D) Zymase and Invertase

15) One of the by-products formed during the recovery of NH3 from Solvay process is :

(A) Ca(OH)2
(B) NaHCO3
(C) CaCl2
(D) NH4Cl

16)
In the above reaction, the structural formula of (A), "X" and "Y" respectively are :
(A)

(B)

(C)

(D)

17) For the coagulation of a negative sol, the species below, that has the highest flocculating power
is :

(A)
(B) Ba2+
(C) Na+
(D)

18) Which of the following statement(s) is (are) incorrect reason for eutrophication ?
(A) excess usage of fertilisers
(B) excess usage of detergents
(C) dense plant population in water bodies
(D) lack of nutrients in water bodies that prevent plant growth
Choose the most appropriate answer from the options given below :

(A) (A) only


(B) (C) only
(C) (B) and (D) only
(D) (D) only

19) Choose the correct statement regarding the formation of carbocations A and B given :-

(A) Carbocation B is more stable and formed relatively at faster rate


(B) Carbocation A is more stable and formed relatively at slow rate
(C) Carbocation B is more stable and formed relatively at slow rate
(D) Carbocation A is more stable and formed relatively at faster rate

20) During which of the following processes, does entropy decrease ?


(A) Freezing of water to ice at 0°C
(B) Freezing of water to ice at –10°C
(C) N2(g) + 3H2(g) → 2NH3(g)
(D) Adsorption of CO(g) and lead surface
(E) Dissolution of NaCl in water

(A) (A), (B), (C) and (D) only


(B) (B) and (C) only
(C) (A) and (E) only
(D) (A), (C) and (E) only

SECTION-B

1) A KCl solution of conductivity 0.14 S m–1 shows a resistance of 4.19 Ω in a conductivity cell. If the
same cell is filled with an HCl solution, the resistance drops to 1.03 Ω. The conductivity of the HCl
solution is _____× 10–2 S m–1. (Round off to the Nearest Integer).

2) On complete reaction of FeCl3 with oxalic acid in aqueous solution containing KOH, resulted in
the formation of product A. The secondary valency of Fe in the product A is ____.
(Round off to the Nearest Integer).

3) The reaction 2A + B2 → 2AB is an elementary reaction.


For a certain quantity of reactants, if the volume of the reaction vessel is reduced by a factor of 3,
the rate of the reaction increases by a factor of _____. (Round off to the Nearest Integer).

4) The total number of C–C sigma bond/s in mesityl oxide (C6H10O) is_____. (Round off to the Nearest
Integer).

5) A 1 molal K4Fe(CN)6 solution has a degree of dissociation of 0.4. Its boiling point is equal to that of
another solution which contains 18.1 weight percent of a non electrolytic solute A. The molar mass
of A is_____ u. (Round off to the Nearest Integer).
[Density of water = 1.0 g cm–3]

6) In the ground state of atomic Fe(Z = 26), the spin-only magnetic moment is ______× 10–1 BM.
(Round off to the Nearest Integer).
[Given : = 1.73, = 1.41]

7) The number of chlorine atoms in 20 mL of chlorine gas at STP is_____1021. (Round off to the
Nearest Integer).[Assume chlorine is an ideal gas at STP
R = 0.083 L bar mol–1 K–1, NA = 6.023 ×1023]
8) KBr is doped with 10–5 mole percent of SrBr2. The number of cationic vacancies in 1 g of KBr
crystal is _____1014. (Round off to the Nearest Integer).
[Atomic Mass : K : 39.1 u, Br : 79.9 u, NA = 6.023 × 1023]

9) Consider the reaction N2O4(g) 2NO2(g). The temperature at which KC = 20.4 and
KP = 600.1, is_____K. (Round off to the Nearest Integer).
[Assume all gases are ideal and R = 0.0831 L bar K–1 mol–1]

10)
Consider the above reaction. The percentage yield of amide product is _______. (Round off to the
Nearest Integer).
(Given : Atomic mass : C : 12.0 u, H : 1.0u, N : 14.0 u, O : 16.0 u, Cl : 35.5 u)

PART-3 : MATHEMATICS

SECTION-A

1) Let f : R → R be defined as f(x) = e–x sinx. If F : [0, 1] → R is a differentiable function such that

, then the value of lies in the interval

(A)

(B)

(C)

(D)

2) If the integral , where α, β, γ are integers and [x] denotes the


greatest integer less than or equal to x, then the value of α + β + γ is equal to :

(A) 0
(B) 20
(C) 25
(D) 10
3) Let y = y(x) be the solution of the differential equation cosx (3sinx + cosx + 3)dy = (1 + y sinx

(3sinx + cosx + 3))dx, , y(0) = 0. Then , is equal to:

(A)

(B)

(C)

(D)

4) The value of is equal to :

(A) 1124
(B) 1324
(C) 1024
(D) 924

5) The value of , where r is non-zero real number and [r] denotes the
greatest integer less than or equal to r, is equal to :

(A)

(B) r
(C) 2r
(D) 0

6) The number of solutions of the equation,

for x ∈ [–1, 1], and [x] denotes the greatest integer less than or equal to x, is :

(A) 2
(B) 0
(C) 4
(D) Infinite

7) Let a computer program generate only the digits 0 and 1 to form a string of binary numbers with

probability of occurrence of 0 at even places be and probability of occurrence of 0 at the odd

place be . Then the probability that '10' is followed by '01' is equal to :


(A)

(B)

(C)

(D)

8) The number of solutions of the equation x + 2 tanx = in the interval [0, 2π] is :

(A) 3
(B) 4
(C) 2
(D) 5

9) Let S1, S2 and S3 be three sets defined as

Then the set S1 ∩ S2 ∩ S3

(A) is a singleton
(B) has exactly two elements
(C) has infinitely many elements
(D) has exactly three elements

10) If the curve y = y(x) is the solution of the differential equation 2(x2 + x5/4)dy – y(x + x1/4)dx = 2x9/4

dx , x > 0 which passes through the point , then the value of y(16) is equal to :

(A)

(B)

(C)

(D)

11) If the sides AB, BC and CA of a triangle ABC have 3, 5 and 6 interior points respectively, then
the total number of triangles that can be constructed using these points as vertices, is equal to :

(A) 364
(B) 240
(C) 333
(D) 360

12) If x, y, z are in arithmetic progression with common difference d, x ≠ 3d, and the determinant of

the matrix is zero, then the value of k2 is

(A) 72
(B) 12
(C) 36
(D) 6

13) Let O be the origin. Let and , x, y ∈ R, x > 0, be such that

and the vector is perpendicular to . If , z ∈ R, is coplanar with


and , then the value of x2 + y2 + z2 is equal to

(A) 7
(B) 9
(C) 2
(D) 1

14) Two tangents are drawn from a point P to the circle x2 + y2 – 2x – 4y + 4 = 0, such that the angle

between these tangents is , where ∈ (0, π). If the centre of the circle is
denoted by C and these tangents touch the circle at points A and B, then the ratio of the areas of
ΔPAB and ΔCAB is :

(A) 11 : 4
(B) 9 : 4
(C) 3 : 1
(D) 2 : 1

15) Consider the function f : R → R defined by . Then f is :

(A) monotonic on (–∞, 0) ∪ (0, ∞)


(B) not monotonic on (–∞, 0) and (0, ∞)
(C) monotonic on (0, ∞) only
(D) monotonic on (–∞, 0) only

16) Let L be a tangent line to the parabola y2 = 4x – 20 at (6, 2). If L is also a tangent to the ellipse
, then the value of b is equal to :

(A) 11
(B) 14
(C) 16
(D) 20

17) The value of the limit is equal to :

(A)

(B)

(C) 0

(D)

18) Let the tangent to the circle x2 + y2 = 25 at the point R(3, 4) meet x-axis and y-axis at point P and
Q, respectively. If r is the radius of the circle passing through the origin O and having centre at the
incentre of the triangle OPQ, then r2 is equal to

(A)

(B)

(C)

(D)

19) If the Boolean expression is a tautology, then and are respectively given
by

(A) →, →
(B)
(C)
(D)

20) If the equation of plane passing through the mirror image of a point (2, 3, 1) with respect to line

and containing the line is αx + βy + γz = 24, then α + β +


γ is equal to :

(A) 20
(B) 19
(C) 18
(D) 21

SECTION-B

1) If 1, log10(4x – 2) and are in arithmetic progression for a real number x, then the

value of the determinant is equal to :

2) Let f : [– 1, 1] → R be defined as f(x) = ax2 + bx + c for all x ∈ [–1, 1], where a, b, c ∈ R such that

f(–1) = 2, f'(–1) = 1 and for x ∈ (–1, 1) the maximum value of f"(x) is . If f(x) ≤ α, x ∈ [–1, 1], then the
least value of α is equal to ______.

3) Let f : [–3, 1] → R be given as

If the area bounded by y = f(x) and x-axis is A, then the value of 6A is equal to ______.

4) Let tanα, tanβ and tanγ; α, β, γ ≠ n ∈ N be the slopes of three line segments OA, OB
and OC, respectively, where O is origin. If circumcentre of ΔABC coincides with origin and its

orthocentre lies on y-axis, then the value of is equal to :

5) Consider a set of 3n numbers having variance 4. In this set, the mean of first 2n numbers is 6 and
the mean of the remaining n numbers is 3. A new set is constructed by adding 1 into each of first 2n
numbers, and subtracting 1 from each of the remaining n numbers. If the variance of the new set is
k, then 9k is equal to ______.

6) Let the coefficients of third, fourth and fifth terms in the expansion of , x ≠ 0, be in the
ratio 12 : 8 : 3. Then the term independent of x in the expansion, is equal to _______.

7) Let and such that AB = B and a + d = 2021, then the value of ad


– bc is equal to ________.
8) Let be a vector in the plane containing vectors and . If the vector is

perpendicular to and its projection on is , then the value of is equal to


________.

9) Let , where n ∈ N. If (20)I10 = αI9 + βI8 , for natural numbers α and β, then α
- β equal to _______.

10) Let P be an arbitrary point having sum of the squares of the distance from the planes x + y + z
= 0, lx – nz = 0 and x – 2y + z = 0, equal to 9. If the locus of the point P is x2 + y2 + z2 = 9, then the
value of l – n is equal to _______.
ANSWER KEYS

PART-1 : PHYSICS

SECTION-A

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D B D D D C D B D B B B C D D A D A B C

SECTION-B

Q. 21 22 23 24 25 26 27 28 29 30
A. 3.00 5.00 30.00 25.00 3.00 640.00 4.00 30.00 16.00 6.00

PART-2 : CHEMISTRY

SECTION-A

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. B D A D C A A A A B C B D C C A B D A A

SECTION-B

Q. 51 52 53 54 55 56 57 58 59 60
A. 57.00 6.00 27.00 5.00 85.00 49.00 1.00 5.00 354.00 77.00

PART-3 : MATHEMATICS

SECTION-A

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. B A B D A B D A C C C A B B B B A C A B

SECTION-B

Q. 81 82 83 84 85 86 87 88 89 90
A. 2.00 5.00 41.00 144.00 68.00 4.00 2020.00 486.00 1.00 0.00
SOLUTIONS

PART-1 : PHYSICS

1) v0 =
v= =
⇒ e = 0.9
S = h + 2e2h + 2e4h +..........

t= + 2e + 2e2 +..........

vav= = 2.5 m/s

2) f = 4 + 3 + 3 = 10
assuming non linear

= 1.2

3) A = A0e–γt

ln2 =

1.16 × 10–2 kg/sec

4) Conceptual

5) P = hρg

β=
= 1.44 × 109 N/m2

6) T ∝ R3/2

7) ω = 2π f
= 1.5 × 103

A= = 3 cm = 0.03 m

8) (2) Option (a) is wrong ; since in adiabatic process V ≠ constant.


Option (b) is wrong, since in isothermal process T = constant
Option (c) & (d) matches isothermes & adiabatic formula :

TVγ–1= constant & = constant

9) Band width = 2 fm
ωm = 1.57 × 108 = 2πfm

BW = 2fm = = 50 MHz

10) v = v0 + gt + Ft2

0
= v + gt + Ft2

= (v + gt + Ft2)dt

s=

0
s=v + +

11)

i=
TPD = 2E – ir1 = 0
2E = ir1

2E =
2R + 2r1 + 2r2 = 3r1

R=

12) B = 2 × Bst.wire + Bloop

B=2

B=
13)

=0
53x – 20y = 30 .....(1)

=0
17 y – 4x = 10 ......(2)
on solving (1) & (2)
x = 0.865
y = 0.792
ΔV = 0.073 R = 15Ω
i = 4.87 mA

14) A1ω1 = A2ω2

15) (a)

(b)

(c)

(d) tan ϕ =

16) C comes to rest

Vcm of A & B =

⇒ is kx2
=
x=

17) Conceptual

18) = hf1 – ϕ

= hf2–ϕ

19) XL = ωL

i=

20) a = = × =

t=
= 0.56

21)

⇒ =
⇒x=3

22)
F cos θ = μN
F sin θ + N = mg

⇒F=

Fmin = =
23)
N + T = 90
T = μ N = 0.5 (90–T)
1.5 T = 45
T = 30

24) 4tT = 100 × πr3

= 100 × × × 10–9 = 10–8 cm3


–10
tT = 25 × 10 cm
= 25 × 10–12 m
t0 = 0.01 tT = 25 × 10–14 m
= 25

0
25) F = = –4U r3 =
mv2 = 4U0r4
v ∝ r2

mvr =
r3 ∝ n
r ∝ n1/3
=3

26) ϕ = Ex A ⇒ × 4 × 103 × 0.4 = 640

27) C.O.M of quarter disc is at ,


=4

28) λm = ⇒

R=
= 30
29) 20 = (C1+ C2) V ⇒ V = 2 volt.
Q2 = C2V = 16μC
= 16

30) Jc =

Jd =

0
⇒ =10x × V (2πf) cos 2πft

tan = 10x ×
=x=6

PART-2 : CHEMISTRY

31) Fructose is a ketohexose.

32) Li–Mg, B–Si, Be–Al show diagonal relationship but Li and Na do not show diagonal
relationship as both belongs to same group and not placed diagonally.

33) Cation exchanger contains –SO3H or –COOH groups while anion exchanger contains basic
groups like –NH2.

34)

Ore Formula

(a) Haematite Fe2O3

(b) Bauxite Al2O3.xH2O

(c) Magnetite Fe3O4

(d) Malachite CuCO3.Cu(OH)2


35) Ambident nucleophile
(A) KCN & AgCN
(C) AgNO2 & KNO2

36) N2O and NO are neutral oxides of nitrogen NO2 and N2O3 are acidic oxides.

37) Complex Type of Isomerism


(a) [Co(NH3)6] [Cr(CN)6] Co-ordination isomerism
(b) [Co(NH3)3 (NO2)3] Linkage isomerism
(c) [Cr(H2O)6]Cl3 Solvate isomerism
(d) cis-[CrCl2(ox)2]3– Optical isomerism

38) Primary amines react with Para Toluene sulfonyl chloride to form a precipitate that is
soluble in NaOH.
Secondary amines reacts with para toluene sulfonyl chloride to give a precipitate that is
insoluble in NaOH.
Tertiary amines do not react with para toluen.

39) Cr(Z=24)
[Ar] 4s13d5 Cr shows common oxidation states starting from +2 to +6.

40) Artificial sweetner : Sucralose


Antiseptic : Bithional
Preservative : Sodium Benzoate
Glyceryl ester of stearic acid : Sodium steasate

41) Alkane are very less reactive, tertiary hydrogen can oxidise to alcohal with KMnO4.

42) Kjeldahl method is not applicable to compounds containing nitrogen in nitrogroup, Azo
groups and nitrogen present in the ring (e.g Pyridine) as nitrogen of these compounds does
not change to Ammonium sulphate under these conditions.

43)

44) Informative
OR
46)

47) To coagulate negative sol, cation with higher charge has higher coagulation value.

48) The process in which nutrient enriched water bodies support a dense plant population
which kills animal life by depriving it of oxygen and results in subsequent loss of biodiversity is
known as eutrophication.

49)
This is more stable due to secondary cation formation and formed with faster rate due to low
activation energy.

50) (A) Water ice; ΔS = –ve


(B) Water ice; ΔS = –ve
(C) N2(g) + 3H2(g) → 2NH3(g); ΔS = –ve
(D) Adsorption; ΔS = –ve
(E) NaCl(s) → Na+(aq) + Cl–(aq); ΔS = +ve

51) κ =
For same conductivity cell, G* is constant and hence k.R. = constant.
∴ 0.14 × 4.19 = k × 1.03

or, κ of HCl solution =


= 0.5695 Sm–1
= 56.95 × 10–2 Sm–1 ≈ 57 × 10–2 Sm–1

52) Fe3+ + 3K+ + 3C2O42– → K3[Fe(C2O4)3]


(A)
Secondary valency of Fe in 'A' is 6.

53) Reaction : 2A + B2 —→ 2AB


As the reaction is elementary, the rate of reaction is
r = K . [A]2 [B2]
on reducing the volume by a factor of 3, the concentrations of A and B2 will become 3 times
and hence, the rate becomes 32 × 3 = 27 times of initial rate.

54) Mesityle oxide

55) K4 Fe(CN)6 4K+ + Fe(CN)64–


Initial conc. 1m 0 0
Final conc. (1 – 0.4)m 4 × 0.4 0.4m
= 0.6 m = 1.6 m
Effective molality = 0.6 + 1.6 + 0.4 = 2.6m
For same boiling point, the molality of another solution should also be 2.6 m.
Now, 18.1 weight percent solution means 18.1 gm solute is present in 100 gm solution and
hence, (100 – 18.1 =) 81.9 gm water. Now

2.6 =
∴ Molar mass of solute, M = 85

56) Fe → [Ar] 4s23d6


Number of unpaired e– = 4

μ = 4.89 B.M.
μ = 48.9 × 10–1 B.M.
Nearest integer value will be 49.

57) PV = nRT

1.0 ×
∴ Number of Cl2 molecules, N = 5.3 × 1020
Hence, Number of Cl-atoms = 1.06 × 1021≈ 1 × 1021

58) 1 mole KBr (= 119 gm) have moles SrBr2 and hence, 10–7 moles cation vacancy
(as 1 Sr2+ will result 1 cation vacancy)
∴ Required number of cation vacancies

59) N2O4(g) 2NO2(g); Δng = 2 – 1 = 1


Now, Kp = Kc . (RT)Δng
or, 600.1 = 20.4 × (0.0831 × T)1
∴ T = 353.99 K = 354K

60)

∴ 0.140 gm
L.R. = 0.168 gm < 0.388 gm
excess
∴ Theoretical amount of given product formed

=
But its actual amount formed is 0.210 gm.
Hence, the percentage yield of product.

=
OR

Mole of Ph – CoCl = = 10–3 mol

Mole of , that should be obtained by mol-mol analysis = 10–3 mol.


Theoritical mass of product = 10–3 × 273 = 273 × 10–3g
Observed mass of product = 210 × 10–3g

%yield of product = =76.9%=77

PART-3 : MATHEMATICS

61)

Now, ⇒ F'(x) = f(x)

=
= =

=
= 2(1 – cos 1)

62) Let =

Function is periodic with period '1'


Therefore

Now,
= (given)
⇒ α = 10, β = –10, γ = 0
⇒α+β+γ=0

63)
=

Solution of D.E.

Now

let

Put ⇒

So solution of D.E.

⇒ for
Now, it is given y(0) = 0

⇒ ⇒

For

64)
Now,

Comparing coefficeint of x6 both sides

= 924

65) We know that


r ≤ [r] < r + 1
and 2r ≤ [2r] < 2r + 1
3r ≤ [3r] < 3r + 1

nr ≤ [nr] < nr + 1
____________________
r + 2r + ....+ nr
≤ [r] + [2r] +....+ [nr] < (r + 2r +....+ nr) + n

Now,

and
So, by Sandwich Theorem, we can conclude that

66) Given equation

Now, is defined if

⇒ ...........(1)

and is defined if

⇒ ....(2)
So, form (1) and (2) we can conclude
Case - I if

⇒ x + π = x2
⇒ x2 = π

but
⇒No valueof 'x'

Case - II if


⇒ x2 = π

but
⇒ No value of 'x'
So, number of solutions of the equation is zero.

68)

Number of solutions of the given equation is '3'.

69) For , z lies on and inside the circle of radius units and centre (1, 0).
For S2
Let z = x + iy
Now, (1 – i) (z) = (1 – i) (x + iy)
Re((1 – i)z) = x + y
⇒x+y≥1
⇒ S1 ∩ S2 ∩ S3 has infinity many elements

70)

x = t4 ⇒ dx = 4t3 dt

⇒C=

= =
71)
Total Number of triangles formed
= 14C3 – 3C3 – 5C3 – 6C3
= 333

72)
R2 → R1 + R3 – 2R2


if 3z – 5x = 0 ⇒ 3(x + 2d) – 5x = 0
⇒ x = 3d (Not possible)
⇒ ⇒ k2 = 72

73)
⇒ –x + 2y – 3x = 0
⇒ y = 2x .....(i)

⇒ (x + 1)2 + (y – 2)2 + (1 + 3x)2 = 20


⇒x=1
are coplanar.


⇒ 1(–14 – 3z) – 2(7 – 9) – 1 (–z – 6) = 0
⇒ z = –2
∴ x2 + y2 + z2 = 1 + 4 + 4 = 9
74)

∴ area of ΔPAB =

= =

area of ΔCAB =

75)

f'(x) is an oscillating function which is non-monotonic in (–∞, 0) ∪ (0, ∞).

76) Tangent to parabola


2y = 2(x + 6) – 20
⇒y=x–4
Condition of tangency for ellipse.
16 = 2(1)2 + b
⇒ b = 14

77)
78) Tangent to circle 3x + 4y = 25

OP + OQ + OR = 25

Incentre =

∴ =

79) Option (1)

=
=
=
=
=t
Option (2)
(Not a tautology)
Option (3)

=
= (Not a tautology)
Option 4
=
= (Not a tautology)

80) Line
4l – 6 + l + l + 3 = 0 ⇒

∴ Reflection (–2, 4, –6)

Plane :
⇒ (x – 2) (–10 + 3) – (y – 1) (15 – 4) + (z + 1) (–1) = 0
⇒ –7x + 14 – 11y + 11 – z – 1 = 0
⇒ 7x + 11y + z = 24
∴ α = 7, β = 11, γ = 1
α + β + γ = 19

81)

(4x)2 + 4 – 4(4x) – 32 = 0
(4x – 16) (4x + 2) = 0
4x = 16
x=2

= 3(–2) – 1(0 – 4) + 4(1)


=–6+4+4=2

82) f : [–1, 1] → R
f(x) = ax2 + bx + c
f(–1) = a – b + c = 2 ...(1)
f'(–1) = –2a + b = 1 ...(2)
f"(x) = 2a

⇒ Max. value of f"(x) = 2a =

⇒ a= ; b= ; c=
∴ f(x) =

For, x ∈ [–1, 1] ⇒ 2 ≤ f(x) ≤ 5


∴ Least value of α is 5

83) f : [–3, 1] → R

area bounded by y = f(x) and x-axis

A=
6A = 41

84) Since orthocentre and circumcentre both lies on y-axis


⇒ Centroid also lies on y-axis
⇒ Σcos α = 0
cos α + cos β + cos γ = 0
⇒ cos3α + cos3β + cos3γ = 3cosα cosβ cosγ

=
= 12

85) Let number be a1,a2,a3, ...... a2n, b1,b2,b3....bn


Now, distribution becomes
a1 + 1, a2 + 1, a3 + 1, .......a2n + 1, b1 – 1,
b2 – 1 .....bn – 1
Variance
=


⇒ 9k = 3(108) – (16)2 = 324 – 256 = 68

86)

: : = 12 : 8 : 3
After solving

n = 6,
For term independent of 'x' ⇒ n = 3r
r=2

∴ Coefficient is
Nearest integer is 4.

87) ,
AB = B
⇒ (A – I) B = O
⇒ |A – I | = O, since B ≠ O

ad – bc = 2020

88) Let (λ and μ are scalars)

Since
3λ + 8μ = 0 .....(1)

Also Projection of on is

6λ – μ = 51 .....(2)
From (1) and (2)
λ = 8, μ = –3

89)

20In = e20 – nIn–1


∴ 20I10 = e20 – 10I9
20I9 = e20 – 9I8
⇒ 20I10 = 10I9 + 9I8
α = 10, β = 9

90) Let point P is (α, β, γ)

Locus is

Since its given that x2 + y2 + z2 = 9


After solving ℓ = n

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